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| MATERIAL SAFETY DATA SHEET |
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| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
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THIS MSDS IS OFFERED IN CANADIAN-FRENCH UPON REQUEST.
ON PEUT DEMANDER CETTE MSDS A LA LANGUE FRANCAISE-CANADIENNE.
PRODUCT NAME : STUCCO PATCH RTU
UPC NUMBER : 7079860584
PRODUCT USE/CLASS : Stucco patching
MANUFACTURER: 24 HOUR EMERGENCY:
DAP CANADA CORP. TRANSPORTATION: 1-800-535-5053 (352-323-3500)
475 FINCHDENE SQUARE UNIT 5 MEDICAL : 1-800-327-3874 (513-558-5111)
SCARBOROUGH, ONTARIO M1X 1B7
PREPARE DATE: 11/1/1999 GENERAL INFORMATION:
REVISION NO.: 3 DAP INC. : 1-888-DAP-TIPS (1-888-327-8477)
REVISION DATE: 09/16/2002
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| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
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WT/WT %
ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER RANGE
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01 Calcium Carbonate 1317-65-3 20.0-25.0 %
02 Crystalline Silica 14808-60-7 45.0-50.0 %
03 Magnesium Aluminum Silicate(polygorskite) 12174-11-7 1.0-5.0 %
---------------------- EXPOSURE LIMITS --------------------
ACGIH OSHA COMPANY
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN
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01 10 mg/m3 N.E. 15 mg/m3 N.E. N.E. NO
02 0.05 mg/m3* N.E. 10 mg/m3dust N.E. N.E. NO
03 N.E. N.E. N.E. N.E. N.E. NO
(See Section 16 for abbreviation legend), * - TLV-Ceiling Value
* The 2001 ACGIH Threshold Limit Values for Chemical Substances and
Physical Agents lists the median Respirable Particulate Mass (RPM) point
for crystalline silica at 4.0 microns in terms of the particle's
aerodynamic diameter.
Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor
OSHA Final Rule Limits (CFR 29 1910.1000); limits may vary between states.
Remaining ingredients are not considered hazardous per the OSHA Hazard
Communication Standard.
(Continued on Page 2)
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Product Name: STUCCO PATCH RTU
Revision Date: 09/16/2002 Page 2
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| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
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| SECTION 3 - HAZARDS IDENTIFICATION |
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EMERGENCY OVERVIEW: CAUTION! Prolonged or repeated contact with skin may
cause irritation. May irritate eyes, skin, nose, and respiratory tract.
POTENTIAL HEALTH EFFECTS:
EFFECTS OF OVEREXPOSURE - EYE CONTACT: May cause eye irritation.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation.
EFFECTS OF OVEREXPOSURE - INHALATION: Inhalation may affect the brain or
nervous system causing dizziness, headache, or nausea.
EFFECTS OF OVEREXPOSURE - INGESTION: If swallowed may cause vomiting,
diarrhea, and depressed respiration.
EFFECTS OF OVER EXPOSURE 没 CHRONIC HAZARDS
The International Agency for Research on Cancer (IARC)has determined that
crystalline silica in the form of quartz or cristobalite that is inhaled
from occupational sources is carcinogenic to humans (Group 1没 carcinogenic
to humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic
Fibres (published in June 1997) in conjunction with the use of these
materials. The National Toxicology Program (NTP) classifies respirable
crystalline silica as known to be a human carcinogen. Refer to the 9th
Report on Carcinogens (2000). The American Conference of Governmental
Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a
suspected human carcinogen (A2).
Breathing dust containing respirable crystalline silica may not cause
noticeable injury or illness even though permanent lung damage may be
occurring. Inhalation of dust may have the following serious chronic health
effects: Excessive inhalation of respirable dust can cause pneumoconiosis,
a respiratory disease, which can result in delayed, progressive, disabling
and sometimes fatal lung injury. Symptoms include cough, shortness of
breath, wheezing, non-specific chest illness and reduced pulmonary
function. Smoking exacerbates this disease. Individuals with pneumoconiosis
are predisposed to develop tuberculosis. There is some evidence that
breathing respirable crystalline silica or the disease silicosis is
associated with an increased incidence of significant disease endpoints
such as scleroderma (an immune system disorder manifested by fibrosis of
the lungs, skin and other internal organs) and kidney disease.
MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY CONTACT: None known.
PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT INHALATION
(Continued on Page 3)
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Product Name: STUCCO PATCH RTU
Revision Date: 09/16/2002 Page 3
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| SECTION 3 - HAZARDS IDENTIFICATION |
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| SECTION 4 - FIRST AID MEASURES |
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EYE CONTACT: Flush with large quantities of water until irritation
subsides. Contact a physician.
SKIN CONTACT: Wash with soap and water.
INHALATION: Remove to fresh air. Contact a physician immediately.
INGESTION: DO NOT INDUCE VOMITING. Contact a physician or Regional Poison
Control Center immediately.
COMMENTS: None.
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| SECTION 5 - FIRE FIGHTING MEASURES |
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FLASH POINT: >200 F LOWER EXPLOSIVE LIMIT: N.A.
(SETAFLASH CLOSED CUP) UPPER EXPLOSIVE LIMIT: N.A.
AUTOIGNITION TEMPERATURE: N.E.
EXTINGUISHING MEDIA: CO2 DRY CHEMICAL FOAM
UNUSUAL FIRE AND EXPLOSION HAZARDS: None known.
SPECIAL FIREFIGHTING PROCEDURES: As in any fire, wear self-contained
breathing apparatus pressure-demand (MSHA/NIOSH approved or equivalent) and
full protective gear. Use water spray to cool exposed surfaces.
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| SECTION 6 - ACCIDENTAL RELEASE MEASURES |
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SPILL OR LEAK PROCEDURES: Scrape up dried material and place into
containers.
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| SECTION 7 - HANDLING AND STORAGE |
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HANDLING INFORMATION: KEEP OUT OF REACH OF CHILDREN. Avoid prolonged or
repeated contact with skin. Avoid contact with eyes.
STORAGE INFORMATION: Store away from caustics and oxidizers. Keep
containers tightly closed when not in use. Keep containers from excessive
heat and freezing. Do not store at temperatures above 120 degrees F.
(Continued on Page 4)
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Product Name: STUCCO PATCH RTU
Revision Date: 09/16/2002 Page 4
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| SECTION 7 - HANDLING AND STORAGE |
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OTHER PRECAUTIONS: Use in a well ventilated area. Provide fresh air such
that chemical odors cannot be detected during use and while drying.
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| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
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ENGINEERING CONTROLS: Good mechanical ventilation and local exhaust.
RESPIRATORY PROTECTION:
Dry sanding of dried product results in the generation of dust which
contains crystalline silica. Avoid exposure to dust by wearing an
appropriate, properly fitted, dust respirator during dry sanding. Follow
respiratory manufacturer's directions for respirator use.
If the 8 hour exposure limit or value is exceeded for any component, use an
approved NIOSH/OSHA respirator. Consult your safety equipment supplier and
the OSHA regulation, 29 CFR 1910.134 for respirator requirements. A
respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2
requirements must be followed whenever workplace conditions warrant a
respirator's use.
The National Institute for Occupational Safety and Health (NIOSH)
recommended permissible exposure limit of 50 micrograms respirable free
silica per cubic meter of air (0.05 mg/m3) as determined by a full shift
sample up to 10 hour working day, 40 hours per week.
EYE PROTECTION: Safety glasses with side shields recommended.
SKIN PROTECTION: Gloves recommended for repeated or prolonged contact with
skin.
OTHER PROTECTIVE EQUIPMENT: None.
HYGIENIC PRACTICES: Although this product is not considered an eye
irritant, inhalation hazard, or a skin contact hazard under normal
conditions, it is advisable that personnel minimize skin contact,
inhalation of vapors, and eye contact. Wash contaminated clothing before
reuse.
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| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
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BOILING RANGE : 210 - 220 F VAPOR DENSITY : Is heavier than air
ODOR : Little or none
APPEARANCE : Gray paste EVAPORATION RATE: Is slower than Butyl
SOLUBILITY IN H2O : Soluble Acetate
SPECIFIC GRAVITY : 1.895
VAPOR PRESSURE : 17.5 mm Hg @ 68F.
(Continued on Page 5)
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Product Name: STUCCO PATCH RTU
Revision Date: 09/16/2002 Page 5
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| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
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PHYSICAL STATE : Paste
(See Section 16 for abbreviation legend)
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| SECTION 10 - STABILITY AND REACTIVITY |
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CONDITIONS TO AVOID: Excessive heat and freezing.
INCOMPATIBILITY: Strong oxidizers and caustics.
HAZARDOUS DECOMPOSITION PRODUCTS: Normal decomposition products, i.e. COx,
Nox.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
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| SECTION 11 - TOXICOLOGICAL PROPERTIES |
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No Information.
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| SECTION 12 - ECOLOGICAL INFORMATION |
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No Information.
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| SECTION 13 - DISPOSAL CONSIDERATIONS |
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WASTE MANAGEMENT/DISPOSAL: Dispose of according to Federal, State, and
Local Standards. Do not reuse empty containers. Discarded material should
be incinerated at a permitted facility. State and Local
regulations/restrictions are complex and may differ from Federal
regulations. Responsibility for proper waste disposal is with the owner of
the waste.
EPA WASTE CODE - If discarded (40 CFR 261): None.
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| SECTION 14 - TRANSPORTATION INFORMATION |
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DOT PROPER SHIPPING NAME: Not Regulated by D.O.T.
DOT HAZARD CLASS: NONE
(Continued on Page 6)
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Product Name: STUCCO PATCH RTU
Revision Date: 09/16/2002 Page 6
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| SECTION 14 - TRANSPORTATION INFORMATION |
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DOT UN/NA NUMBER: NONE PACKING GROUP: NONE
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| SECTION 15 - REGULATORY INFORMATION |
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U.S. FEDERAL REGULATIONS: AS FOLLOWS -
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372:
None
TOXIC SUBSTANCES CONTROL ACT:
This product contains the following chemical substances subject to the
reporting requirements of TSCA 12(B) if exported from the United States:
None
NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:
----------- CHEMICAL NAME ----------- CAS NUMBER
Water 7732-18-5
Acrylic polymer Proprietary
PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
----------- CHEMICAL NAME ----------- CAS NUMBER
Water 7732-18-5
Acrylic polymer Proprietary
CALIFORNIA PROPOSITION 65:
WARNING: The chemical(s) noted below and contained in this product, are
known to the state of California to cause cancer:
----------- CHEMICAL NAME ----------- CAS NUMBER
Crystalline silica 14808-60-7
Polygorskite 12174-11-7
INTERNATIONAL REGULATIONS: AS FOLLOWS -
(Continued on Page 7)
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Product Name: STUCCO PATCH RTU
Revision Date: 09/16/2002 Page 7
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| SECTION 15 - REGULATORY INFORMATION |
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CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: No information available.
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| SECTION 16 - OTHER INFORMATION |
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HMIS RATINGS - HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 0
PREVIOUS MSDS REVISION DATE: 04/25/2000
REASON FOR REVISIONS:
Section 2. Update exposure limits for crystalline silica.
Section 3. Update health hazards for crystalline silica
Section 8. Update respiratory protection guidelines for crystalline silica.
Section 15. Update TSCA 12b information.
VOC less water, less exempt solvent: 15-20 g/L (1-2 weight%)
VOC material : 10-15 g/L
LEGEND: ACGIH - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
PEL - PERMISSIBLE EXPOSURE LIMIT
NTP - NATIONAL TOXICOLOGY PROGRAM
SARA - SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986
STEL - SHORT TERM EXPOSURE LIMIT
TLV - THRESHOLD LIMIT VALUE(8 HR. TIME WEIGHTED AVERAGE OR TWA)
VOC - VOLATILE ORGANIC COMPOUND
NJRTK - NEW JERSEY RIGHT TO KNOW LAW
N.D. - NOT DETERMINED
MSDS# 79728
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(Continued on Page 8)
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Product Name: STUCCO PATCH RTU
Revision Date: 09/16/2002 Page 8
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| SECTION 16 - OTHER INFORMATION |
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This data is offered in good faith as typical values and not as a product
specification. No warranty either expressed or implied, is hereby made.
The recommended industrial hygiene and safe handling procedures are
believed to be generally applicable. However, each user should review the
recommendations in specific context of the intended use and determine if
they are appropriate.
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< End OF MSDS >
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