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Material 24 Hour Emergency Phone Numbers:
Medical: 1-800-327-3874
1-513-558-5111
Safety Transportation:
1-800-535-5053
1-352-323-3500
Data
Sheet
NOTE: National Response Center emergency numbers to be used
only in the event of chemical emergencies involving a spill, leak,
fire, exposure or accident involving chemicals.
IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or
disposing of this product. This product is covered by the OSHA Hazard Communication Standard and this document has been
prepared in accordance with requirements of this standard. All abbreviated terms used in this MSDS are further described in Section
16.
Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request.
Esta hoja de datos de la seguridad de los materiales est谩 disponible en franc茅s canadiense y en espa帽ol a su solicitud.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.
Product Name: Quick Plug Hydraulic Cement Revision Date: 03/06/2006
Product UPC 7079810050, 7079810060, 7079810070, Supercedes: 12/30/2004
Number: 7079810080, 7079814084, 7079814086,
7079814090
Product Use/Class: DM Water Putty Wood Repair MSDS Number: 00079705001
Manufacturer: DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888-327-8477 (non-emergency matters)
Section 2 - Composition / Information On Ingredients
ACGIH
Chemical Name CASRN WT% ACGIH TWA ACGIH CEIL OSHA TWA OSHA STEL OSHA CEIL Skin
STEL
Portland cement 65997-15 -1 30-60 10 MGM3 N.E. N.E. 5 MGM3 N.E. N.E. No
10梅(%SiO2
Silica, crystalline 14808-60 -7 15-40 0.05 MGM3 N.E. N.E. N.E. N.E. No
+2) MGM3
Fused calcium aluminate 65997-16 -2 10-30 N.E. N.E. N.E. N.E. N.E. N.E. No
Calcium sulfate 7778 -18-9 1-5 10 MGM3 N.E. N.E. 5 MGM3 N.E. N.E. No
Hydrated lime 39445-23 -3 1-5 N.E. N.E. N.E. N.E. N.E. N.E. No
Exposure Notes:
14808-60-7 The 2002 ACGIH Threshold Limit Values for Chemical Substances and Physical Agents
lists the median Respirable Particulate Mass (RPM) point for crystalline silica at 4.0 microns in terms of
the particle's aerodynamic diameter.
The TLVs for crystalline silica represent the respirable fraction.
OSHA PEL TWA for Quartz is calculated using the following formula: 10 mg/m3/(% SiO2 + 2). Both
concentration and percent quartz for the application of this limit are to be determined from the fraction
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passing a size selector with the following characteristics.
|------------------------------------------------------------------------------------|----------------------------------------
-|
| ....... Aerodynamic diameter ( unit density sphere ) .....| Percent passing selector |
| 2 ................................................................................|.................90....................|
| 2.5 .............................................................................|..................75...................|
| 3.5 .............................................................................|..................50...................|
| 5.0 .............................................................................|..................25...................|
| 10 ..............................................................................|...................0....................|
Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits
may vary between states.
Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the
extent necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment,
engineering controls or work practices
Section 3 - Hazards Identification
Emergency Overview: A gray powder with a little or none odor. WARNING: INJURIOUS TO EYES. CAUSES
SKIN IRRITATION. Avoid skin and eye contact. Removal of this product after use or by dry sanding will generate
dust and exposure to this dust may be irritating to the eyes, ears, nose and mouth. If dry-sanded, exposure to
dust may result in build -up of material in eyes, ears, nose, and mouth. Contains Portland Cement. When mixed
with water, this material hardens and then slowly becomes hot. DO NOT attempt to make a cast enclosing any
part of the body using this material. Failure to follow these instructions may cause severe burns that may require
surgical removal of affected tissues.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: Causes eye irritation.
Effects Of Overexposure - Skin Contact: Causes skin irritation. May cause dry skin. May develop enough heat
to cause burns if a large mass such as a cast of hand or arm, is kept in contact with skin while hardening. Wet
cement can dry skin and cause alkali burns.
Effects Of Overexposure - Inhalation: Prolonged, repeated, or high exposures may cause irritation to the
respiratory tract (nose, mouth, mucous membranes).
Effects Of Overexposure - Ingestion: Ingestion may result in obstruction when material hardens. Irritating to
mouth, throat and stomach.
Effects Of Overexposure - Chronic Hazards:
The International Agency for Research on Cancer (IARC) has determined that crystalline silica in the form of
quartz or cristobalite that is inhaled from occupational sources is carcinogenic to humans (Group 1- carcinogenic
to humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (published in June 1997) in
conjunction with the use of these materials. The National Toxicology Program (NTP) classifies respirable
crystalline silica as "known to be a human carcinogen". Refer to the 9th Report on Carcinogens (2000). The
American Conference of Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a
suspected human carcinogen (Group A2).
Breathing dust containing respirable crystalline silica may not cause noticeable injury or illness even though
permanent lung damage may be occurring. Inhalation of dust may have the following serious chronic health
effects: Excessive inhalation of respirable dust can cause pneumoconiosis, a respiratory disease, which can
result in delayed, progressive, disabling and sometimes fatal lung injury. Symptoms include cough, shortness of
breath, wheezing, non-specific chest illness and reduced pulmonary function. Smoking exacerbates this disease.
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Individuals with pneumoconiosis are predisposed to develop tuberculosis. There is some evidence that
breathing respirable crystalline silica or the disease silicosis is associated with an increased incidence of
significant disease endpoints such as scleroderma (an immune system disorder manifested by fibrosis of the
lungs, skin and other internal organs) and kidney disease.
Primary Route(s) Of Entry: Skin Contact, Inhalation, Eye Contact
Medical Conditions which May be Aggravated by Exposure: If dry sanded, asthma and asthma-like conditions
may worsen from prolonged or repeated exposure to dust.
Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
Get medical attention immediately.
First Aid - Skin Contact: If skin irritation persists, call a physician. Wash thoroughly with soap and water.
First Aid - Inhalation: First Aid: If you experience difficulty in breathing, leave the area to obtain fresh air. If
continued difficulty is experienced, get medical attention Immediately.
First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately.
Note to Physician: None.
COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arises from any of the
above routes of entry.
Section 5 - Fire Fighting Measures
Flash Point, F: greater than 200 Lower Explosive Limit, %: Not Established
Method: (Seta Closed Cup) Upper Explosive Limit, %: Not Established
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam
Unusual Fire And Explosion Hazards: None known. Material will not burn.
Special Firefighting Procedures: None known.
Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in
Section 8. Sweep up excess powder. Place remaining powder into containers.
Section 7 - Handling And Storage
Handling: KEEP OUT OF REACH OF CHILDREN! Use in well ventilated area. Wash thoroughly after handling.
Do not breathe dust. Do not get in eyes. Avoid prolonged or repeated contact with skin. Removal of this product
after use will result in the generation of Dust. If dry-sanded, exposure to dust may result in the build-up of material
in eyes, ears, nose, and mouth which may cause irritation. Prevent build up of dust by providing fresh air such
that dust cannot be detected during use of this product or while sanding this product. While dry sanding, use of a
NIOSH-approved dust mask is recommended.
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Storage: Store away from caustics and oxidizers. Store containers away from excessive heat and freezing. Keep
containers tightly closed. Do not store at temperatures above 120 degrees F.
Section 8 - Exposure Controls / Personal Protection
Precautionary Measures: Please refer to other sections and subsections of this MSDS.
Engineering Controls: If dry-sanding, provide sufficient mechanical ventilation to maintain exposure below PEL
and TLV. While mixing, provide sufficient mechanical ventilation (local or general exhaust) to maintain exposure
below PEL and TLV. Wet sanding is recommended to avoid generation of dust.
Respiratory Protection:
National Institute for Occupational Safety and Health (NIOSH) has recommended that the permissible exposure
limit be changed to 50 micrograms respirable free silica per cubic meter of air (0.05 mg/m3) as determined by a
full shift sample up to 10-hour work shift.
Skin Protection: Wear gloves with repeated or prolonged use.
Eye Protection: Goggles or safety glasses with side shields.
Other protective equipment: Provide eyewash. Provide coveralls if body contact may occur.
Hygienic Practices: Remove and wash contaminated clothing before re-use.
Section 9 - Physical And Chemical Properties
Not Established Not Established
Boiling Range: Vapor Density:
Odor: Little or None Odor Threshold: Not Established
Appearance: Gray Evaporation Rate: Not Established
Solubility in H2O: Not Established Specific Gravity: 2.975
Freeze Point: Not Established pH: Not Established
Vapor Pressure: Not Established Viscosity: Not Established
Physical State: Powder
When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined
experimentally.
(See section 16 for abbreviation legend)
Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Incompatible with strong bases and oxidizing agents.
Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under recommended storage conditions.
Section 11 - Toxicological Information
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Product LD50: Not Established Product LC50: Not Established
None
Carcinogenicity:
CAS No. Chemical Name ACGIH OSHA IARC NTP WT%
Suspected human
14808-60 -7 Silica, crystalline Not Listed. Human carcinogen. Known carcinogen. 15-40
carcinogen.
Significant Data with Possible Relevance to Humans: None
Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.
Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and
Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste
disposal is with the owner of the waste.
EPA Waste Code if Discarded (40 CFR Section 261): none
Section 14 - Transportation Information
Not Regulated N.A.
DOT Proper Shipping Packing Group:
Name:
DOT Technical Name: N.A. Hazard Subclass: N.A.
DOT Hazard Class: N.A. DOT UN/NA Number: N.A.
Note: The shipping information provided is applicable for domestic ground transport only. Different categorization
may apply if shipped via other modes of transportation and/or to non-domestic destinations.
Section 15 - Regulatory Information
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and
312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of
the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
None
Toxic Substances Control Act:
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All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if
exported from the United States:
None
U.S. State Regulations
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product:
None
Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%:
None
California Proposition 65:
Warning: The following ingredients present in the product are known to the State of California to cause cancer:
Chemical Name CAS Number Definition Date Listed WT%
Silica, crystalline 14808-60-7 Carcinogenic. Listed: October 1, 1988 15-40
Warning: The following ingredients present in the product are known to the State of California to cause birth
defects or other reproductive harm:
None
Section 16 - Other Information
HMIS Ratings:
Health: 1 Flammability: 0 Reactivity: 0 Personal Protection: X
VOLATILE ORGANIC COMPOUNDS, GR/LTR: 0.0 LB/GAL: 0.0 WT%: 0.0
REASON FOR REVISION: Periodic Update
Legend: N.A. 鈥? Not Applicable ACGIH 鈥? American Conference of Governmental Industrial Hygienists
N.E. 鈥? Not Established SARA 鈥? Superfund Amendments and Reauthorization Act of 1986
N.D. 鈥? Not Determined NJRTK 鈥? New Jersey Right-to-Know Law
VOC 鈥? Volatile Organic Compound OSHA 鈥? Occupational Safety and Health Administration
PEL 鈥? Permissible Exposure Limit HMIS 鈥? Hazardous Materials Identification System
TLV 鈥? Threshold Limit Value NTP 鈥? National Toxicology Program
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STEL 鈥? Short Term Exposure Limit CEIL 鈥? Ceiling Exposure Limit
LD50 鈥? Lethal Dose 50 LC50 鈥? Lethal Concentration 50
F 鈥? Degree Fahrenheit C 鈥? Degree Celsius
MSDS 鈥? Material Safety Data Sheet CASRN 鈥? The Chemical Abstracts Service Registry Number
DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as
typical values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF
FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS
MADE WITH REGARD TO THE INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE
INFORMATION REFERS. Since this document is intended only as a guide to the appropriate use and precautionary
handling of the referenced product by a properly trained person, it is therefore the responsibility of the user to (i) review the
recommendations with due consideration for the specific context of the intended use and (ii) determine if they are
appropriate.
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