00020099001 English Page 1 of 6
24 Hour Emergency Phone Numbers:
Material
Medical/Poison Control:
1-800-327-3874
1-513-558-5111
Safety Transportation/National Response
Center:
1-800-535-5053
Data 1-352-323-3500
Sheet NOTE: The National Response Center emergency numbers to
be used only in the event of chemical emergencies involving a
spill, leak, fire, exposure or accident involving chemicals.
IMPORTANT: Provide this information to employees, customers, and users of this product. Read this MSDS before handling or disposing of
this product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with
requirements of this standard. All abbreviated terms used in this MSDS are further described in Section 16.
Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Hispanic American Spanish upon request.
On peut demader cette fiche signal茅tique (MSDS) a la langue francaise-canadienne.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.
Product Name: Revision Date: 09/10/2007
DAP 庐 4000庐 VOC Subfloor & Deck Construction
Adhesive
Product UPC Number: 070798270305, 070798270381 Supercedes: 06/04/2003
Product Use/Class: Subfloor/Deck Construction Adhesive Latex MSDS Number: 00020099001
Manufacturer: DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888 -327-8477 (non-emergency matters)
Section 2 - Hazards Identification
Emergency Overview: A tan paste product with a slight alcoholic odor. WARNING! May cause eye, skin, nose, throat
and respiratory tract irritation. Harmful if swallowed or absorbed through the skin.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: Causes eye irritation.
Effects Of Overexposure - Skin Contact: Causes skin irritation. Harmful if absorbed through the skin.
Effects Of Overexposure - Inhalation: Vapor harmful. May affect the brain or nervous system causing dizziness,
headache or nausea. Inhalation may cause irritation to the respiratory tract (nose, mouth, mucous membranes).
Effects Of Overexposure - Ingestion: Harmful if swallowed. May be fatal or cause blindness if swallowed. Cannot be
made non-poisonous.
Effects Of Overexposure - Chronic Hazards: NOTICE: Reports have associated repeated and prolonged occupational
overexposure to solvents with permanent brain and nervous system damage. Symptoms include: loss of memory, loss of
intellectual ability and loss of coordination. Intentional misuse by deliberately concentrating and inhaling the contents may
be harmful or fatal. Repeated or prolonged exposure may cause respiratory system damage.
Prolonged and repeated skin contact may cause irritation and possibly dermatitis. Overexposure may cause kidney,
cardiovascular, skin and liver damage.
00020099001 English Page 2 of 6
Primary Route(s) Of Entry: Skin Contact, Inhalation, Ingestion, Eye Contact
Medical Conditions which May be Aggravated by Exposure: None known.
Carcinogenicity:
CAS No. Chemical Name ACGIH OSHA IARC NTP
64-17-5 Ethyl alcohol Not Listed. Not Listed. Human carcinogen. Known carcinogen.
Confirmed animal
79-06-1 Acrylamide carcinogen with unknown Not Listed. Probable carcinogen. Anticipated carcinogen.
relevance to humans.
Section 3 - Composition / Information On Ingredients
Chemical Name CASRN Wt%
Calcium Carbonate 471-34-1 15 -40
Magnesite 546-93-0 1-5
Diethylene glycol dibenzoate 120-55-8 1-5
Ethyl alcohol 64-17 -5 1-5
Urea 57-13 -6 1-5
Dipropylene glycol dibenzoate 27138-31 -4 1-5
Triethylene glycol dibenzoate 120-56-9 1-5
Magnesium aluminum silicate 12174-11 -7 0.5-1.5
Methanol 67-56 -1 0.1-1.0
Acrylamide 79-06 -1 <0.003
Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes
until irritation subsides. Get medical attention immediately.
First Aid - Skin Contact: Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical aid if
symptoms persist. Remove and wash contaminated clothing.
First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If
continued breathing difficulty is experienced, get medical attention immediately.
First Aid - Ingestion: POISON. If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately.
Note to Physician: None.
COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arises from any of the above
routes of entry.
Section 5 - Fire Fighting Measures
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: No special protective measures against fire required.
Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or
equivalent) and full protective gear. Use water spray to cool exposed surfaces.
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Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Use
absorbent material or scrape up dried material and place in container.
Section 7 - Handling And Storage
Handling: KEEP OUT OF REACH OF CHILDREN! DO NOT TAKE INTERNALLY. Avoid breathing vapor and contact
with eyes, skin and clothing. Use only with adequate ventilation. Open all windows and doors or use other means to
ensure cross-ventilation and fresh air entry during application and drying. Odor is not an adequate warning for hazardous
conditions. Do not get in eyes, on skin or clothing. Wash thoroughly after handling.
Storage: Do not store at temperatures above 120 degrees F. Store containers away from excessive heat and freezing.
Close container after each use. Store away from caustics and oxidizers.
Section 8 - Exposure Controls / Personal Protection
Chemical Name CASRN ACGIH TWA ACGIH STEL ACGIH CEIL OSHA TWA OSHA STEL OSHA CEIL Skin
5 MGM3
Calcium Carbonate 471-34-1 10 MGM3 N.E. N.E. (respirable N.E. N.E. No
fraction)
Magnesite 546-93-0 10 MGM3 N.E. N.E. 5 MGM3 N.E. N.E. No
Diethylene glycol dibenzoate 120-55-8 N.E. N.E. N.E. N.E. N.E. N.E. No
Ethyl alcohol 64-17-5 1000 PPM N.E. N.E. 1000 PPM N.E. N.E. No
Urea 57-13-6 N.E. N.E. N.E. N.E. N.E. N.E. No
Dipropylene glycol dibenzoate 27138-31-4 N.E. N.E. N.E. N.E. N.E. N.E. No
Triethylene glycol dibenzoate 120-56-9 N.E. N.E. N.E. N.E. N.E. N.E. No
Magnesium aluminum silicate 12174-11-7 N.E. N.E. N.E. N.E. N.E. N.E. No
Methanol 67-56-1 200 PPM 250 PPM N.E. 200 PPM N.E. N.E. Yes
Acrylamide 79-06-1 0.03 MGM3 N.E. N.E. 0.3 MGM3 N.E. N.E. Yes
Exposure Notes:
None.
Precautionary Measures: Please refer to other sections and subsections of this MSDS.
Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Ensure adequate
ventilation, especially in confined areas. Local ventilation of emission sources may be necessary to maintain ambient
concentrations below recommended exposure limits.
Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSH-approved air
purifying respirator with an organic vapor cartridge or canister may be necessary under certain circumstances where
airborne concentrations are expected to exceed exposure limits. A respiratory protection program that meets the OSHA
1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use.
Skin Protection: Rubber gloves.
Eye Protection: Goggles or safety glasses with side shields.
Other protective equipment: Not required under normal use.
Hygienic Practices: Wash hands before breaks and at the end of workday. Remove and wash contaminated clothing
before re-use.
Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary
between states.
Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent
necessary under the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work
practices.
00020099001 English Page 4 of 6
Section 9 - Physical And Chemical Properties
Boiling Range: Not Established Vapor Density: Heavier Than Air
Odor: Slight Alcoholic Odor Threshold: Not Established
Color: Tan Evaporation Rate: Slower Than n-Butyl Acetate
Solubility in H2O: Negligible Specific Gravity: 1.3
Freeze Point: Not Established pH: Between 7.0 and 12.9
Vapor Pressure: 100 mm Hg @ 68 F Viscosity: Not Established
Physical State: Paste Flammability: Non-Flammable
(Seta Closed Cup)
Flash Point, F: > 200 F Method:
Lower Explosive Limit, %: Not Established Upper Explosive Limit, %:Not Established
When reported, vapor pressure of this product has been calculated theoretically based on its constituent makeup and has not been determined experimentally.
(See section 16 for abbreviation legend)
Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Incompatible with strong bases and oxidizing agents.
Hazardous Decomposition Products: Normal decomposition products, i.e., COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under recommended storage conditions.
Section 11 - Toxicological Information
Product LD50: Not Established Product LC50: Not Established
CASRN Chemical Name LD50 LC50
471-34-1 Calcium Carbonate Rat:6450 mg/kg -------------
120-55-8 Diethylene glycol dibenzoate 2830 mg/kg -------------
64-17-5 Ethyl alcohol ------------- Rat:20000 ppm/10H
57-13-6 Urea Rat:8471 mg/kg -------------
67-56-1 Methanol Rat:5628 mg/kg Rat:64000 ppm/4H
79-06-1 Acrylamide Oral Rat:124 mg/kg -------------
Significant Data with Possible Relevance to Humans: None.
Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.
Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local
regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is
with the owner of the waste.
EPA Waste Code if Discarded (40 CFR Section 261): None.
Section 14 - Transportation Information
00020099001 English Page 5 of 6
DOT Proper Shipping Not Regulated Packing Group: N.A.
Name:
DOT Technical Name: N.A. Hazard Subclass: N.A.
DOT Hazard Class: N.A. DOT UN/NA Number: None
Note: The shipping information provided is applicable for domestic ground transport only. Different categorization may
apply if shipped via other modes of transportation and/or to non-domestic destinations.
Section 15 - Regulatory Information
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311 and 312 of
the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable
definitions, to meet the following categories:
Immediate Health Hazard, Chronic Health Hazard
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
None
Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported
from the United States:
None
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product:
Chemical Name CAS Number
Water 7732-18-5
Acrylic polymer Proprietary
Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%:
Chemical Name CAS Number
Water 7732-18-5
Acrylic polymer Proprietary
California Proposition 65:
WARNING: This product contains chemicals known to the State of California to cause cancer, birth defects or other
reproductive harm.
Section 16 - Other Information
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HMIS Ratings:
Health: 1 Flammability: 1 Reactivity: 0 Personal Protection: X
Volatile Organic Compounds (VOC), less water less exempts: g/L: 47.5 lb/gal: 0.4 wt:wt%: 2.1
Volatile Organic Compounds (VOC), less water less exempts, less LVP -VOCs: wt:wt%: 1.9
REASON FOR REVISION: Periodic Update
Legend: N.A. 鈥? Not Applicable ACGIH 鈥? American Conference of Governmental Industrial Hygienists
N.E. 鈥? Not Established SARA 鈥? Superfund Amendments and Reauthorization Act of 1986
N.D. 鈥? Not Determined NJRTK 鈥? New Jersey Right-to-Know Law
VOC 鈥? Volatile Organic Compound OSHA 鈥? Occupational Safety and Health Administration
PEL 鈥? Permissible Exposure Limit HMIS 鈥? Hazardous Materials Identification System
TLV 鈥? Threshold Limit Value NTP 鈥? National Toxicology Program
CEIL 鈥? Ceiling Exposure Limit STEL 鈥? Short Term Exposure Limit
LD50 鈥? Lethal Dose 50 LC50 鈥? Lethal Concentration 50
F 鈥? Degree Fahrenheit MSDS 鈥? Material Safety Data Sheet
C 鈥? Degree Celsius CASRN 鈥? The Chemical Abstracts Service Registry Number
DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical
values and not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY
PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE
INFORMATION HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this
document is intended only as a guide to the appropriate use and precautionary handling of the referenced product by a properly trained
person, it is therefore the responsibility of the user to (i) review the recommendations with due consideration for the specific context
of the intended use and (ii) determine if they are appropriate.
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