Unifrax Australia Pty. Ltd.
326 Settlement Road
Thomastown, VIC 3074
FIBERFRAX庐 DURABOARD 1400 & 1600
ACN 093 625 757
Ph: (03) 9463 0000 Fax: (03) 9464 1176
MATERIAL SAFETY DATA SHEET
Classified as Hazardous according to criteria of Worksafe Australia
1. IDENTIFICATION OF MATERIAL & SUPPLIER
庐
Brand Name: FIBERFRAX
Product Names: Duraboard 1600
Duraboard 1400
Ship. Name (CSN): None Allocated
Other Names: Duraboard HD
Duraboard LD
Kernap 40
Kernap 50
Kernap 60
Duraboard 1400
Duraboard 1200
Duraboard 1400Z
Silplate
UN Number: None Allocated
DG Class None Allocated
Packaging Group None Allocated
Hazchem Code None Allocated
Poisons Schedule Not Scheduled
Product Use Thermal Insulation
Manufacturer/Supplier: Unifrax Germany Unifrax Australia Pty. Ltd.
Klienreinsdorf 62 326 Settlement Road
D-07989 Teichwolframsdorf Thomastown 3074
Nuremberg Germany Victoria, Australia.
Contact: See Page 10
2. HAZARDS IDENTIFICATION
Flammability
Fire Hazards: Non flammable
Explosive Hazards: Non explosive
Health Hazards: Irritating to eyes, skin, respiratory system and disturbances to
Gastro intestines.
Authorised by: Alan Smith
Version: 1.6
Control Status: Controlled Document
Created on: 01/08/07 1
Unifrax Australia Pty. Ltd.
326 Settlement Road
Thomastown, VIC 3074
FIBERFRAX庐 DURABOARD 1400 & 1600
ACN 093 625 757
Ph: (03) 9463 0000 Fax: (03) 9464 1176
MATERIAL SAFETY DATA SHEET
Classified as Hazardous according to criteria of Worksafe Australia
3. COMPOSITION AND INFORMATION ON INGREDIENTS
Information on Alumina 鈥? Silicate and Binders
Composition:
Ingredients: Name CAS Proportion
Ceramic Fiber 65997-17-3 99-100%
Refractory Fiber
Ceramic Fiber
MMVF
SMF
Other Information: Remaining components not determined to be hazardous and/or
hazardous components present at less than 1.0% (0.1% for
carcinogens).
4. FIRST AID MEASURES
Ingestion Ingestion is unlikely, but if it does occur DO NOT induce vomiting;
drink plenty of water. Material should be excreted naturally, but if
effects persists seek medical attention.
Eye Flush immediately with large amounts of water for at least 15
minutes, after removing any contact lenses. Eyelids should be held
away from the eyeball to ensure thorough rinsing. Do not rub eyes.
Seek medical advice as good work hygiene practice in all cases of
eye contamination.
Skin If skin becomes irritated, remove contaminated clothing. Wash area
of contact thoroughly with soap and water. Do not rub or scratch
exposed skin. Using a skin cream or lotion after washing may be
helpful. If effects persist seek medical advice.
Inhalation Remove exposed person/s from source of exposure, to fresh air.
Keep exposed person/s comfortable, warm and rested. Recovery
should be rapid after removal from exposure, but if effects persist
seek medical advice.
First Aid Facilities Eyewash station and normal washroom facilities must be provided.
Authorised by: Alan Smith
Version: 1.6
Control Status: Controlled Document
Created on: 01/08/07 2
Unifrax Australia Pty. Ltd.
326 Settlement Road
Thomastown, VIC 3074
FIBERFRAX庐 DURABOARD 1400 & 1600
ACN 093 625 757
Ph: (03) 9463 0000 Fax: (03) 9464 1176
MATERIAL SAFETY DATA SHEET
Classified as Hazardous according to criteria of Worksafe Australia
First Aid Measures cont鈥檇:
Advice to Doctor Acute effects are essential irritant in nature. Refer to 'OTHER
INFORMATION' section for chronic and long-term exposures.
5. FIRE FIGHTING MEASURES.
Fire Explosion Hazard: Not Flammable and not explosive.
Hazardous Reactions/ Refer to SAFE HANDLING INFORMATION
Decomposition Products
Hazchem Code: None Allocated.
6. ACCIDENTAL RELEASE MEASURES
Spills or Release Where possible, use vacuum suction to clean up spilled
To the Environment material. Use dust suppressant where sweeping is necessary.
Avoid clean up procedures that may result in
water pollution. Personal safety and exposure recommendations
described elsewhere in this data sheet
apply to exposure during clean up of spilled material.
7. HANDLING & STORAGE
Storage Precautions: No special storage requirements.
Handling: In the installation of unbonded materials, the following handling
and installation procedures are recommended:
a) All installation practices should be designed to minimise the
liberation of any airborne fibre or dust.
b) In large installations of several days/weeks duration, the
installation area should be clearly designated and barriers
erected to limit access.
c) The Ceramic Materials should be stored in sealed plastic
Authorised by: Alan Smith
Version: 1.6
Control Status: Controlled Document
Created on: 01/08/07 3
Unifrax Australia Pty. Ltd.
326 Settlement Road
Thomastown, VIC 3074
FIBERFRAX庐 DURABOARD 1400 & 1600
ACN 093 625 757
Ph: (03) 9463 0000 Fax: (03) 9464 1176
MATERIAL SAFETY DATA SHEET
Classified as Hazardous according to criteria of Worksafe Australia
Handling & Storage cont鈥檇:
bags or similar containers until installation is to proceed.
These containers should only be opened within the
designated work area when work is to start.
d) Where possible, materials should be delivered in sizes such
that a minimum of handling is required. However when
cutting or drilling is required, these should be done with hand
tools fitted with local exhaust extraction. The exhaust from
such extraction equipment should be fitted and positioned
away from other work areas.
e) Empty storage bags should be folded and stored in a waste
container along with any waste material.
f) Upon completion of the job, all excess materials should be
sealed in bags prior to removal from the designated work
area. The work area should be vacuumed using an industrial
vacuum cleaner. Wet mopping and wiping can be utilised if
an industrial vacuum cleaner is not available.
For removal of Ceramic Fiber materials the following handling
procedures are recommended:
a) All installation practices should be designed to minimise the
liberation of any airborne fibre or dust.
b) In large installations of several days/weeks duration, the
installation area should be clearly designated and barriers
erected to prevent access.
c) Upon completion of the job, all excess materials should be
sealed in bags prior to removal from the designated work
area. The work area should be vacuumed using an industrial
vacuum cleaner. Wet mopping and wiping can be utilised if
an industrial vacuum cleaner is not available.
For removal of embrittled Ceramic Fiber materials the following
procedures, in particular, the selection of respirator protection
should be implemented during the removal of such materials.
a) The removal area should be signposted and contained,
where workable, to minimize the transfer of dust to
other work areas.
b) Separate change areas should be provided to minimize
the transfer of dust to general work areas.
c) Where workable, the spent material should be wetted
to suppress dust generation.
Authorised by: Alan Smith
Version: 1.6
Control Status: Controlled Document
Created on: 01/08/07 4
Unifrax Australia Pty. Ltd.
326 Settlement Road
Thomastown, VIC 3074
FIBERFRAX庐 DURABOARD 1400 & 1600
ACN 093 625 757
Ph: (03) 9463 0000 Fax: (03) 9464 1176
MATERIAL SAFETY DATA SHEET
Classified as Hazardous according to criteria of Worksafe Australia
Handling & Storage cont鈥檇:
d) Waste shall be placed in containers, plastic bags or
other methods which prevent Fiber and/or dust
emission, and disposed of in accordance with local
waste disposal authority requirements.
e) The removal area should then be cleaned using an
Industrial vacuum cleaner and:-
f) Once visible dust has been cleaned up, containment
material should be removed in a manner that minimizes
the liberation of any trapped dust.
8. EXPOSURE CONTROLS & PERSONAL PROTECTION
Personal Protection The Worksafe Australia TWA exposure standard for cristobalite
is 0.1mg/m3; OSHA permissible exposure limit (PEL) for
cristobalite is 0.05mg/m3 (respirable dust). The ACGIH threshold
limit value (TLV) for cristobalite 0.05 1mg/m3 (respirable dust)
(ACGIH 1991-1992).
Use AS, NIOSH or MSHA approved equipment when airborne
limits may be exceeded. Minimal acceptable respirators
recommended for given airborne cristobalite concentrations are
as follows:
CONCENTRATION: Up to 5 fibres/ml or up to 10 times the
OSHA PEL for cristobalite.
RESPIRATOR TYPE: P2 Type, Half-face cartridge respirator
with high efficiency filters. (E.g. 3M 6000
with 2040 filter or equivalent).
CONCENTRATION: Up to 25 fibres/ml or 50 times the OSHA
PEL for cristobalite (2.5mg/m3).
RESPIRATOR TYPE: P3 Type, Full-face cartridge respirator with
high efficiency filters. (E.g. 3M 7800S with
7255 filter or equivalent).
CONCENTRATION: Greater than 25 fibres/ml or 50 times the
OSHA PEL for cristobalite (2.5mg/m3).
RESPIRATOR TYPE: P3 Type, Full-face cartridge respirator with
high-efficiency filters. (E.g. 3M 7800S with
W9435 hose and W2806 regulator or
equivalent).
Authorised by: Alan Smith
Version: 1.6
Control Status: Controlled Document
Created on: 01/08/07 5
Unifrax Australia Pty. Ltd.
326 Settlement Road
Thomastown, VIC 3074
FIBERFRAX庐 DURABOARD 1400 & 1600
ACN 093 625 757
Ph: (03) 9463 0000 Fax: (03) 9464 1176
MATERIAL SAFETY DATA SHEET
Classified as Hazardous according to criteria of Worksafe Australia
Exposure Controls & Personal Protection cont鈥檇:
If airborne filters or cristobalite concentrations are not known, as
minimum protection, use AS, NIOSH or MSHA approved half face,
air-purifying respirator with HEPA filter cartridges. Insulation
surfaces should be lightly sprayed with water before removal to
suppress airborne dust. As water evaporates during removal,
additional water should be sprayed on the surfaces as needed. Only
enough water should be sprayed to suppress dust so that water
does not run onto the floor of the work area. To aid the wetting
process, a surfactant may be used. After RCF removal is
completed, dust suppressing cleaning methods, such as wet
sweeping or vacuuming, should be used to clean the work area. If
dry vacuuming is used, the vacuum must be equipped with a HEPA
filter. Air blowing or dry sweeping should not be used. Dust
suppressing components can be used to clean up light dust.
Eye Protection Safety glasses with side shields, or chemical goggles must be worn
when handling this material. Eye-washing facilities should be
available where eye contact can occur.
Clothing Wear gloves, hats or full body clothing to prevent skin contact as
necessary. Use separate lockers for work clothes to prevent fibre
transfer to street clothes. Avoid taking unwashed work clothes home
or provide disposable work clothing. Wash work clothes separately
from other clothing. Rinse washing machine thoroughly after use. If
clothing is to be laundered by someone else, inform launderer of
proper procedure.
Protective Equipment The National Code of Practice for the Safe Use of Synthetic Mineral
Fibres (NOHSC May 1990) advises that for installation and removal
of both bonded and unbonded ceramic fibre material the following
personal protective equipment should be used.
a) Disposable coveralls or long sleeve, loose fitting clothing and
gloves (launderable clothing should be washed separately
from other clothing).
b) Where overhead work is involved, goggles and head covering
should be worn; and
c) A half-face (P1 or P2) respirator should be worn during work
in enclosed or poorly ventilated spaces, or where evidence
suggests that respirable fibre levels may exceed 0.5 f/ml.
Authorised by: Alan Smith
Version: 1.6
Control Status: Controlled Document
Created on: 01/08/07 6
Unifrax Australia Pty. Ltd.
326 Settlement Road
Thomastown, VIC 3074
FIBERFRAX庐 DURABOARD 1400 & 1600
ACN 093 625 757
Ph: (03) 9463 0000 Fax: (03) 9464 1176
MATERIAL SAFETY DATA SHEET
Classified as Hazardous according to criteria of Worksafe Australia
Exposure Controls & Personal Protection cont鈥檇.
For removal of embrittled or heat effected ceramic materials, the
following personal protective equipment should be used by all
personnel directly involved in the removal work:
a) Disposable coveralls or long sleeve, loose fitting clothing and
gloves (launderable clothing should be washed separately
from other clothing).
b) Where overhead work is involved, goggles and head covering
should be worn. Eye protection would be provided as an
integral component of a full-face respirator
c) A class P2 respirator provides the necessary protection
factor for this task. However, in some circumstances where
excessive levels of dust are created, the limitations of filter
loading capacity and facial seal may necessitate the use of:
a full (P3) cartridge respirator, or
鈥?
a full (P3) powered air-purifying respirator or
鈥?
a full faced, positive pressure demand airline
鈥?
respirator.
All respiratory devices should be tested for compliance with AS/NZS
1715 & AS/NZS 1716.
9. PHYSICAL & CHEMICAL PROPERTIES
Appearance White to tan coloured board with no odour.
Melting Point 1400 Duraboard - 1816潞 C 1600 Duraboard - 1871潞 C
Boiling Point Not applicable
Vapour Pressure Not applicable
Specific Gravity 240 鈥? 400 kg/m3
Flash Point None
Flamm. Limit LEL Not applicable
Flamm. Limit UEL Not applicable
Volatile Component Not applicable
Solubility in Water Not available
Auto Ignition Temp Not applicable
Authorised by: Alan Smith
Version: 1.6
Control Status: Controlled Document
Created on: 01/08/07 7
Unifrax Australia Pty. Ltd.
326 Settlement Road
Thomastown, VIC 3074
FIBERFRAX庐 DURABOARD 1400 & 1600
ACN 093 625 757
Ph: (03) 9463 0000 Fax: (03) 9464 1176
MATERIAL SAFETY DATA SHEET
Classified as Hazardous according to criteria of Worksafe Australia
9. Physical & Chemical Properties cont鈥檇:
Vapour Density Not applicable
pH Value Not applicable
Specific Properties or Risk See 'Health Effects' section
Thermal Decomposition See 'Hazardous Decomposition or by-products'.
Formula Not applicable: Mixture
Molecular Weight Not applicable: Mixture
10. STABILITY & REACTIVITY
Stability: Stable under normal conditions of use.
Hazardous Reactions Refer to SAFE HANDLING INFORMATION
Decomposition Products
11. TOXICOLOGICAL INFORMATION
A number of studies have been conducted on the health effects of inhalation exposure of rats and
hamsters. In a lifetime (6 hours per day, 5 days a week for 24 months) nose only inhalation
study, rats exposed to the maximum Tolerated Dose (30mg.m3, 200 Fibers/ml) developed
progressive lung damage (interstitial fibrosis) and cancer of the lung and mesothelioma. In
contrast, Hamsters similarly exposed, developed interstitial fibrosis and mesothelioma but no lung
cancers. A multiple dose study (3, 9, 16mg/m3; 25, 75 and 150 Fibers/ml) found a dose related
parenchymal fibrosis however, in the lowest exposed group (25 Fibers/ml), no irreversible effects
were found that could be attributed to ceramic Fiber exposure. There was no statistical excess of
lung tumours at any dose. One rat developed a mesothelioma in the 75 Fiber/ml exposure group.
In 1987, the International Agency for Research on Cancer (IARC) reviewed the epidemiological
and animal toxicology data on SMF (including ceramic Fiber, glasswool, rockwool and slagwood)
and classified the group as possible human carcinogens (IARC Group 2B).
Respiratory Type (AS1716) The toxicology data indicates that ceramic fibre should be
handled with caution
Authorised by: Alan Smith
Version: 1.6
Control Status: Controlled Document
Created on: 01/08/07 8
Unifrax Australia Pty. Ltd.
326 Settlement Road
Thomastown, VIC 3074
FIBERFRAX庐 DURABOARD 1400 & 1600
ACN 093 625 757
Ph: (03) 9463 0000 Fax: (03) 9464 1176
MATERIAL SAFETY DATA SHEET
Classified as Hazardous according to criteria of Worksafe Australia
12. ECOLOGICAL INFORMATION
Not available.
13. DISPOSAL CONSIDERATIONS
Waste Disposal: Waste shall be placed in containers, plastic bags or other
methods which will prevent Fiber and/or dust emission and
disposed of in accordance with the local waste disposal authority
requirements. There may be specific regulations at the Local,
State or Federal level that pertain to this material.
14. TRANSPORT INFORMATION
No special transport requirements are necessary.
UN Number None Allocated
Shipping Name None Allocated
DG Class None Allocated
Packaging Group None Allocated
Hazchem Code None Allocated
Poisons Schedule Not Scheduled
15. REGULATORY INFORMATION
Risk Statement: R40 (3) Possible risk of irreversible effects. R36/37/38
Irritating to eyes, respiratory system and skin.
Safety Statement: S22 Do not breathe dust. S52 Avoid contact with eyes. S38
In insufficient ventilation, wear suitable respiratory equipment.
S40 To clean floor and all objects contaminated by this
Material, use AS approved HEPA fitted vacuum cleaner.
S36/37/39 Wear suitable protective clothing, gloves and eye/
face protection.
Hazard Category: Harmful, irritant.
Poisons Schedule: Not scheduled.
Authorised by: Alan Smith
Version: 1.6
Control Status: Controlled Document
Created on: 01/08/07 9
Unifrax Australia Pty. Ltd.
326 Settlement Road
Thomastown, VIC 3074
FIBERFRAX庐 DURABOARD 1400 & 1600
ACN 093 625 757
Ph: (03) 9463 0000 Fax: (03) 9464 1176
MATERIAL SAFETY DATA SHEET
Classified as Hazardous according to criteria of Worksafe Australia
16. OTHER INFORMATION
RCF DEVITRIFICATION
As produced, all RCG fibers are vitreous (glassy) materials which do not contain crystalline silica.
Continued exposure to elevated temperatures may cause these fibers to devitrify (become
crystalline). The first crystalline formation (mullite) begins to occur at approximately 985掳 C
(1805掳 F). Crystalline phase silica may begin to form at temperatures of approximately 1200掳 C
(2192掳 F). The occurrence and extent of crystalline phase formation is dependent on the duration
and temperature of exposure, fiber chemistry and/or the presence of fluxing agents. The
presence of crystalline phases can be confirmed only through laboratory analysis of the 鈥渉ot face鈥?
fiber.
IARC鈥檚 evaluation of crystalline silica states 鈥淐rystalline silica inhaled in the form of quartz or
cristobalite from occupational sources is carcinogenic to humans (Group 1)鈥? and additionally
notes 鈥渃arcinogenicity in humans was not detected in all industrial circumstances studied鈥? (IARC
Monograph Vol. 68, 1997). NTP lists all polymorphs of crystalline silica amongst substances
which may 鈥渞easonably be anticipated to be carcinogens鈥?.
IARC and NTP did not evaluate after-service RCF, which may contain various crystalline phases.
However, an analysis of after-service RCF samples obtained pursuant to an exposure monitoring
agreement with the USEPA, found that in the furnace conditions sampled, most did not contain
detectable levels of crystalline silica. Other relevant RCF studies found that (1) simulated after-
service RCF showed little, or no, activity where exposure was by inhalation or by intraperitoneal
injection; and (2) after-service RCF was not cytotoxic to macrophage-like cells at concentrations
up to 320 g/cm虏 - by comparison, pure quartz or cristobalite were significantly active at much
lower levels (circa 20 g/cm虏).
CONTACT DETAILS:
+61 3 9463 0000
Contact: During Business Hours Ph:
Customer Service Toll Free: Ph: 1300 797 888
Emergency / After Hours Contact: Alan Smith
Ph: 0409 288 916
Authorised by: Alan Smith
Version: 1.6
Control Status: Controlled Document
Created on: 01/08/07 10
Unifrax Australia Pty. Ltd.
326 Settlement Road
Thomastown, VIC 3074
FIBERFRAX庐 DURABOARD 1400 & 1600
ACN 093 625 757
Ph: (03) 9463 0000 Fax: (03) 9464 1176
MATERIAL SAFETY DATA SHEET
Classified as Hazardous according to criteria of Worksafe Australia
References: Replaces MSDS dated 27 March 2007.
NOTICE: The information presented herein is based on data considered to be accurate as of the
date of preparation of this Material Safety Data Sheet. However, no warranty or
representation, express or implied, is made as to the accuracy or completeness of the
foregoing data and safety information, nor is any authorisation given or implied to
practise any patented invention without licence. In addition, no responsibility can be
assumed by the vendor for any damage or injury resulting from abnormal use, from
any failure to adhere to recommended practices, or from any hazards inherent in the
nature of the product.
... End Of Report ...
Authorised by: Alan Smith
Version: 1.6
Control Status: Controlled Document
Created on: 01/08/07 11
|