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                                       072295




DOD Hazardous Materials Information System
DoD 6050.5-L
AS OF July 1998
FSC: 6810
NIIN: 00N040149
Manufacturer's CAGE: 60928
Part No. Indicator: A
Part Number/Trade Name: BUTADIENE SULFONE, 98%, 88450-5
===========================================================================
General Information
===========================================================================
Item Name: BUTADIENE SULFONE
Company's Name: ALDRICH CHEMICAL CO
Company's Street:
Company's P. O. Box: 355
Company's City: MILWAUKEE
Company's State: WI
Company's Country: US
Company's Zip Code:
Company's Emerg Ph #: 414-273-3850
Company's Info Ph #: 414-273-3850
Distributor/Vendor # 1:
Distributor/Vendor # 1 Cage:
Distributor/Vendor # 2:
Distributor/Vendor # 2 Cage:
Distributor/Vendor # 3:
Distributor/Vendor # 3 Cage:
Distributor/Vendor # 4:
Distributor/Vendor # 4 Cage:
Safety Data Action Code:
Safety Focal Point: N
Record No. For Safety Entry: 001
Tot Safety Entries This Stk#: 001
Status: SMJ
Date MSDS Prepared: 20DEC91
Safety Data Review Date: 22MAR93
Supply Item Manager:
MSDS Preparer's Name:
Preparer's Company:
Preparer's St Or P. O. Box:
Preparer's City:
Preparer's State:
Preparer's Zip Code:
Other MSDS Number:
MSDS Serial Number: BRZHL
Specification Number:
Spec Type, Grade, Class:
Hazard Characteristic Code: NK
Unit Of Issue:
Unit Of Issue Container Qty:
Type Of Container:
Net Unit Weight:

Report for NIIN: 00N040149

NRC/State License Number:
Net Explosive Weight:
Net Propellant Weight-Ammo:
Coast Guard Ammunition Code:
===========================================================================
Ingredients/Identity Information




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072295




===========================================================================
Proprietary: NO
Ingredient: THIOPENE, 2,5-DIHYDRO-, 1,1-DIOXIDE; (BUTADIENE SULFONE)
Ingredient Sequence Number: 01
Percent: 98
Ingredient Action Code:
Ingredient Focal Point: N
NIOSH (RTECS) Number: XM9100000
CAS Number: 77-79-2
OSHA PEL: NOT APPLICABLE
ACGIH TLV: NOT APPLICABLE
Other Recommended Limit: N/K
===========================================================================
Physical/Chemical Characteristics
===========================================================================
Appearance And Odor: OFF-WHITE CRYSTALS
Boiling Point: N/K
Melting Point: 149F,65C
Vapor Pressure (MM Hg/70 F): N/K
Vapor Density (Air=1): N/K
Specific Gravity: N/K
Decomposition Temperature: N/K
Evaporation Rate And Ref: N/K
Solubility In Water: N/K
Percent Volatiles By Volume: N/K
Viscosity:
pH: N/K
Radioactivity:
Form (Radioactive Matl):
Magnetism (Milligauss):
Corrosion Rate (IPY): N/K
Autoignition Temperature:
===========================================================================
Fire and Explosion Hazard Data
===========================================================================
Flash Point: >230F,>110C
Flash Point Method: N/P
Lower Explosive Limit: N/K
Upper Explosive Limit: N/K
Extinguishing Media: WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR
APPROPRIATE FOAM.
Special Fire Fighting Proc: WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT (FP N).
Unusual Fire And Expl Hazrds: EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

Report for NIIN: 00N040149

===========================================================================
Reactivity Data
===========================================================================
Stability: YES
Cond To Avoid (Stability): NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: STRONG OXIDIZING AGENTS.
Hazardous Decomp Products: TOXIC FUMES OF: CARBON MONOXIDE, CARBON
DIOXIDE, SULFUR OXIDES.
Hazardous Poly Occur: NO
Conditions To Avoid (Poly): NOT RELEVANT
===========================================================================
Health Hazard Data
===========================================================================
LD50-LC50 Mixture: LD50 (ORAL,RAT): 2830 MG/KG




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Route Of Entry - Inhalation: YES
Route Of Entry - Skin: YES
Route Of Entry - Ingestion: YES
Health Haz Acute And Chronic: ACUTE: MAY BE HARMFUL BY INHALATION,
INGESTION, OR SKIN ABSORPTION. CAUSES SEVERE EYE IRRITATION. TO THE BEST OF
MFR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND TOXICOLOGICAL PROPERTIES HAVE
NOT BEEN THOROUGHLY INVESTIGATED.
Carcinogenicity - NTP: NO
Carcinogenicity - IARC: NO
Carcinogenicity - OSHA: NO
Explanation Carcinogenicity: NOT RELEVANT
Signs/Symptoms Of Overexp: SEE HEALTH HAZARDS.
Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER.
Emergency/First Aid Proc: EYES: FLUSH EYES WITH COPIOUS AMOUNTS OF WATER
FOR AT LEAST 15 MIN. SKIN: IMMED WASH SKIN WITH SOAP AND COPIOUS AMOUNTS OF
WATER. INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTF RESP. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. INGEST: WASH OUT MOUTH WITH WATER
PROVIDED PERSON IS CONSCIOUS. CALL MD. WASH CONTAMINATED CLOTHING BEFORE
REUSE.
===========================================================================
Precautions for Safe Handling and Use
===========================================================================
Steps If Matl Released/Spill: WEAR NIOSH/MSHA APPROVED SCBA, RUBBER BOOTS
AND HEAVY RUBBER GLOVES. SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE
DISPOSAL. AVOID RAISING DUST. VENTILATE AREA AND WASH SPILL SITE AFTER
MATERIAL PICKUP IS COMPLETE.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Method: DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND
SCRUBBER.
Precautions-Handling/Storing: AVOID CONTACT AND INHALATION. DO NOT GET IN
EYES, ON SKIN, ON CLOTHING. SEVERE EYE IRRITANT. KEEP TIGHTLY CLOSED. STORE
IN A COOL DRY PLACE.
Other Precautions: NONE SPECIFIED BY MANUFACTURER.
===========================================================================
Control Measures
===========================================================================
Respiratory Protection: NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation: MECHANICAL EXHAUST REQUIRED.

Report for NIIN: 00N040149

Protective Gloves: RUBBER GLOVES.
Eye Protection: CHEMICAL SAFETY GOGGLES.
Other Protective Equipment: SAFETY SHOWER AND EYE BATH.
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING.
Suppl. Safety & Health Data: NONE SPECIFIED BY MANUFACTURER.
===========================================================================
Transportation Data
===========================================================================
Transportation Action Code:
Transportation Focal Point:
Trans Data Review Date:
DOT PSN Code:
DOT Symbol:
DOT Proper Shipping Name:
DOT Class:
DOT ID Number:
DOT Pack Group:
DOT Label:
DOT/DoD Exemption Number:




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072295




IMO PSN Code:
IMO Proper Shipping Name:
IMO Regulations Page Number:
IMO UN Number:
IMO UN Class:
IMO Subsidiary Risk Label:
IATA PSN Code:
IATA UN ID Number:
IATA Proper Shipping Name:
IATA UN Class:
IATA Subsidiary Risk Class:
IATA Label:
AFI PSN Code:
AFI Symbols:
AFI Prop. Shipping Name:
AFI Class:
AFI ID Number:
AFI Pack Group:
AFI Label:
AFI Special Prov:
AFI Basic Pac Ref:
MMAC Code:
N.O.S. Shipping Name:
Additional Trans Data:
===========================================================================
Disposal Data
===========================================================================
Disposal Data Action Code:
Disposal Data Focal Point:
Disposal Data Review Date:
Rec # For This Disp Entry:
Tot Disp Entries Per NSN:
Landfill Ban Item:
Disposal Supplemental Data:

Report for NIIN: 00N040149

1st EPA Haz Wst Code New:
1st EPA Haz Wst Name New:
1st EPA Haz Wst Char New:
1st EPA Acute Hazard New:
2nd EPA Haz Wst Code New:
2nd EPA Haz Wst Name New:
2nd EPA Haz Wst Char New:
2nd EPA Acute Hazard New:
3rd EPA Haz Wst Code New:
3rd EPA Haz Wst Name New:
3rd EPA Haz Wst Char New:
3rd EPA Acute Hazard New:
===========================================================================
Label Data
===========================================================================
Label Required: YES
Technical Review Date: 22MAR93
Label Date: 26FEB93
MFR Label Number:
Label Status: G
Common Name: BUTADIENE SULFONE, 98%, 88450-5
Chronic Hazard: NO
Signal Word: WARNING!
Acute Health Hazard-None:




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072295




Acute Health Hazard-Slight: X
Acute Health Hazard-Moderate:
Acute Health Hazard-Severe:
Contact Hazard-None:
Contact Hazard-Slight:
Contact Hazard-Moderate: X
Contact Hazard-Severe:
Fire Hazard-None:
Fire Hazard-Slight: X
Fire Hazard-Moderate:
Fire Hazard-Severe:
Reactivity Hazard-None: X
Reactivity Hazard-Slight:
Reactivity Hazard-Moderate:
Reactivity Hazard-Severe:
Special Hazard Precautions: AVOID CONTACT AND INHALATION. DO NOT GET IN
EYES, ON SKIN, ON CLOTHING. STORE IN A COOL, DRY PLACE. ACUTE: MAY BE
HARMFUL BY INHALATION, INGESTION OR SKIN ABSORPTION. CAUSES SEVERE EYE
IRRITATION. TO THE BEST OF MFR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND
TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED. CHRONIC:
NONE LISTED BY MANUFACTURER.
Protect Eye: Y
Protect Skin: Y
Protect Respiratory: Y
Label Name: ALDRICH CHEMICAL CO
Label Street:
Label P.O. Box: 355
Label City: MILWAUKEE
Label State: WI

Report for NIIN: 00N040149

Label Zip Code:
Label Country: US
Label Emergency Number: 414-273-3850
Year Procured:




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