MATERIAL SAFETY DATA SHEET:DURA-GARD AEROSOL
DATE OF ISSUE: 09/04/2001 SUPERCEDES: 07/18/1997
SECTION I - GENERAL INFORMATION
Chemical Name & Synonyms: Trade Name & Synonyms:
N/A DURA-GARD AEROSOL
Chemical Family: Formula Mixture: X
PETROLEUM HYDROCARBON/AMINE BLEND
Manufacturer's Name:
CHEMSEARCH DIV. OF NCH CORP.
Address:
BOX 152170
IRVING, TX 75015
Prepared By: Product Code Number Emergency Phone Number
C Williamson/Chemist 5014 800-424-9300
SECTION II - HAZARDOUS INGREDIENTS
THE HAZARDS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS
Chemical Name (Ingredients) Hazard TLV PEL STEL CAS #
HYDROTREATED LIGHT PETROLEUM 64742-
COMB/IRR 100PPM 1 500PPM 2 N/E
DISTILLATES 88-7
61790-
TALL OIL FATTY ACID IRR/SENS N/E 1 N/E 2 N/E
12-3
MORPHOLINE CORR/FLAM 20 PPM 1 20 PPM 2 N/E 110-91-8
HEAVY PARAFFINIC PETROLEUM 5 MG/M3 5 MG/M3 10MG/M3 64742-
IRRITANT
DISTILLATES $1 $2 $1 54-7
ISOPROPANOL FLAM/IRR 400PPM 1 400PPM 2 N/E 67-63-0
2500PPM 1000PPM
PROPANE FLAM/ASPHY N/E 74-98-6
1 2
N-BUTANE FLAM/ASPHY 800PPM 1 N/E 2 N/E 106-97-6
$ OIL MIST VALUES
SECTION III - PHYSICAL DATA
Boiling Point (f): Specific Gravity (H20=1):
320潞 0.91
Vapor Pressure (MM HG): Color:
30-45psi YELLOW TO TAN
Vapor Density (Air=1): Odor:
1.8 MORPHOLINE
PH @ 100% : Clarity
N/A OPAQUE
% Volatile by Volume: Evaporation Rate (BU A/C=1):
50 0.08
H20 Solubility: Viscosity:
NEGLIGIBLE SEMI-VISCOUS
SECTION IV - FIRE AND EXPLOSION HAZARD
Flash Point: Flammable Limits: LEL: UEL:
110潞F / SETAFLASH PET DIST/ISOPROPANOL 0.6 12.7
Extinguishing Media:
Foam:X Alcohol Foam: CO2:X Dry Chemical:X Water Spray:X Other:
Special Fire Fighting Procedures:
FIREFIGHTERS SHOULD WEAR A SELF-CONTAINED BREATHING APPARATUS AND FULL
PROTECTIVE GEAR. COOL FIRE-EXPOSED CONTAINERS WITH WATER SPRAY TO PREVENT
BURSTING.
Unusual Fire and Explosion Hazards:
VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL TO DISTANT SOURCES OF IGNITION AND
FLASHBACK. PRODUCT MAY PRODUCE A FLOATING FIRE HAZARD AS LIQUID FLOATS ON WATER.
FLAME EXTENSION > 18 INCHES AND BURNBACK = 5 INCHES.
3
(0=Insignificant 1=Slight 2=Moderate 3=High 4=Extreme)
Health:3 Flammability:4 Instability:0 Special:
SECTION V - HEALTH HAZARD DATA
Threshold Limit Value:
NOT ESTABLISHED FOR MIXTURE. SEE SECTION II.
Effects of Overexposure:
-Acute(Short Term Exposure)
EYE CONTACT: CORROSIVE. CAUSES BURNS, CORNEAL DAMAGE AND
POSSIBLE BLINDNESS. SKIN CONTACT: CORROSIVE. CAUSES BURNS AND
POSSIBLE DEEP ULCERATIONS OR SCARRING. MAY CAUSE ALLERGIC SKIN
REACTION. INHALATION: CAUSES BURNS TO THE RESPIRATORY TRACT,
NOSE, MOUTH AND THROAT, WITH DISCOMFORT, NASAL DISCHARGE,
SNEEZING, COUGHING AND CHEST PAIN. MAY CAUSE HEADACHE,
DIZZINESS AND OTHER CENTRAL NERVOUS SYSTEM EFFECTS. INGESTION:
CORROSIVE. CAUSES BURNS TO THE MOUTH AND THROAT; NAUSEA AND
PAIN.
-Chronic (Long Term Exposure)
MAY CAUSE SKIN SENSITIZATION IN SOME INDIVIDUALS. PROLONGED OR
REPEATED CONTACT MAY PROMOTE DERMATITIS. REPEATED INHALATION
MAY RESULT IN LUNG DAMAGE. ON RARE OCCASIONS, PROLONGED AND
Aerosol
REPEATED EXPOSURE TO OIL MIST POSES A RISK OF CHRONIC LUNG
Level NFPA INFLAMMATION. THIS CONDITION IS USUALLY ASYMPTOMATIC AS ARESULT
(NFPA Hazard OF REPEATED SMALL ASPIRATIONS. SHORTNESS OF BREATH AND
30B): Rating: COUGHING ARE THE MOST COMMON SYMPTOMS. ASPIRATION MAY LEAD TO
PULMONARY EDEMA AND HEMORRHAGE AND MAY BE FATAL. SIGNS OF
LUNG INVOLVEMENT INCLUDE INCREASED RESPIRATION AND HEART RATES
AS WELL AS A BLUISH DISCOLORATION OF THE SKIN. MEDICAL CONDITIONS
AGGRAVATED BY EXPOSURE ARE PRE-EXISTING RESPIRATORY AND SKIN
CONDITIONS SUCH AS ASTHMA, EMPHYSEMA AND DERMATITIS. TARGET
ORGANS: BLOOD-FORMING ORGANS, CENTRAL NERVOUS SYSTEM AND
LUNGS.
Primary Routes of Entry: Inhalation:X Ingestion: Absorption:X
Emergency and First Aid Procedures:
-Inhalation:
REMOVE FROM THE AREA TO FRESH AIR. IF NOT BREATHING, CLEAR THE
AIRWAY AND START MOUTH TO MOUTH ARTIFICIAL RESPIRATION. GET
IMMEDIATE MEDICAL ATTENTION.
-Eye Contact:
IMMEDIATELY RINSE THE EYES WITH WATER. REMOVE ANY CONTACT
LENSES AND CONTINUE FLUSHING FOR AT LEAST 15 MINUTES. HOLD THE
EYELIDS APART TO ENSURE RINSING OF THE ENTIRE SURFACE OF THE
EYES AND LIDS WITH WATER. GET IMMEDIATE MEDICAL ATTENTION.
-Skin Contact:
WASH AFFECTED AREAS WITH LARGE AMOUNTS OF SOAP AND WATER FOR
15 MINUTES. REMOVE CONTAMINATED CLOTHING AND SHOES. GET
IMMEDIATE MEDICAL ATTENTION. WASH CLOTHING AND CLEAN SHOES
BEFORE REUSE.
-Ingestion:
GIVE 3 TO 4 GLASSES OF WATER, BUT DO NOT INDUCE VOMITING. IF
VOMITING OCCURS, GIVE FLUIDS AGAIN. GET IMMEDIATE MEDICAL
ATTENTION. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS OR
CONVULSING PERSON.
-Notes to Physician:
THERE IS NO SPECIFIC ANTIDOTE. TREAT THE PATIENT SYMPTOMATICALLY.
SECTION VI - TOXICITY INFORMATION
Product Contains Chemicals Listed as Carcinogen or Potential Carcinogen By:
IARC: No NTP: No OSHA: No ACGIH: No OTHER: No
HYDROTREATED LIGHT PETROLEUM DISTILLATES
IHL-RAT LD50: >700 PPM 4.
SKN-RBT LD50: >4 G/KG 4.
ORL-RAT LD50: >25 GM/KG 4.
TALL OIL FATTY ACID
EYES: MILD IRRITATION, EFFECTS REVERSIBLE IN LESS THAN 72 HOURS.* 4.
SKIN: MILD IRRITATION, EFFECTS REVERSIBLE IN LESS THAN 72 HOURS.* 4.
OLEIC ACID, A COMPONENT OF TALL OIL FATTY ACID, HAS BEEN SHOWN
TO CAUSE CHROMOSOME ABERRATIONS IN YEAST (SACCHAROMYCES
CEREVISAE) IN CULTURED HAMSTER FIBROBLAST CELLS. 4.
*TESTED L-5 PRODUCT (L-5 IS A GENERIC REPRESENTATIVE OF THIS
PRODUCT.)
MORPHOLINE
SKN-RBT SDT: 995 MG/24H SEVERE 3.
SKN-RBT OPEN: 500 MG MODERATE 3.
EYE-RBT SDT: 2 MG SEVERE 3.
ORL-RAT LD50: 1450 MG/KG 3.
IHL-RAT LC50: 8000 PPM/8H 3.
SKN-RBT LD50: 500 UL/KG 3.
HEAVY PARAFFINIC PETROLEUM DISTILLATES
ORL-RAT: LD50: >5G/KG 4.
SKN-RBT: LD50: >3.16G/KG 4.
ISOPROPANOL
ORL-HMN LDLo: 3570 MG/KG 3.
ORL-RAT LD50: 5045 MG/KG 3.
IHL-RAT LC50: 16000 PPM/8H 3.
SKN-RBT SDT: 500 MG MILD 3.
EYE-RBT SDT: 10 MG MODERATE 3.
ISOPROPANOL HAS BEEN SHOWN TO CAUSE HARM TO THE FETUS IN
LABORATORY ANIMAL
STUDIES. HARM TO THE FETUS OCCURS ONLY AT EXPOSURE LEVELS THAT
HARM THE
PREGNANT ANIMAL. THE RELEVANCE OF THESE FINDINGS TO HUMANS IS
UNCERTAIN.
OVEREXPOSURE TO THIS MATERIAL HAS BEEN FOUND TO CAUSE MILD,
REVERSIBLE LIVER EFFECTS IN LABORATORY ANIMALS.
PROPANE
NO TOXICOLOGICAL DATA AVAILABLE
N-BUTANE
IHL-RAT LC50: 658 G/M3/4H 3.
IHL-MUS LC50: 680 G/M3/4H 3.
PROPANE/BUTANE MIXTURE
HUMAN VOLUNTEERS EXPOSED REPEATEDLY TO GASES OF SIMILAR
HYDROCARON MIXTURES RANGING FROM 250 TO 1000 PPM EXHIBITED NO
CARDIAC OR PULMONARY FUNCTION ABNORMALITIES. 4.
SECTION VII - REACTIVITY DATA
Stability: Stable:X Unstable:
Conditions to
Avoid: AVOID HEAT, HOT
SURFACES, SPARKS
AND OPEN FLAMES.
CONTACT WITH
NITRITES CAN FORM
CANCER-CAUSING
NITROSOAMINES.
Incompatibility (Materials to Avoid):
STRONG OXIDIZING AGENTS SUCH AS CHLORINE BLEACH, CONCENTRATED
HYDROGEN PEROXIDE AND CHROMIC ACID; REDUCING AGENTS SUCH AS
SODIUM THIOSULFATE; STRONG ACIDS, BASES, CHLORINATED
COMPOUNDS, AMINES, ALKANOLAMINES, ALDEHYDES AND NITRITES.
Hazardous Decomposition Products:
OXIDES OF CARBON, NITROGEN AND SULFUR; AMMONIA, ALDEHYDES AND
KETONES.
Hazardous
May Occur: Will Not Occur:X
Polymerization:
Conditions to Avoid: N/A
SECTION VIII - SPILL OR LEAK PROCEDURES
Steps to be Taken if Material is Released or Spilled:
DUE TO THE NATURE OF THE AEROSOL PACKAGING, A LARGE SPILL IS
UNLIKELY. FOR A SMALL SPILL, WEAR APPROPRIATE PROTECTIVE
CLOTHING, VENTILATE THE AREA, ABSORB WITH AN INERT MATERIAL AND
TRANSFER ALL MATERIAL INTO A PROPERLY LABELED CONTAINER FOR
DISPOSAL.
Waste Disposal Method(s):
DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE, AND LOCAL
REGULATIONS. TYPICAL DISPOSAL IS TO WRAP THE EMPTY AEROSOL
CONTAINER IN SEVERAL LAYERS OF NEWSPAPER AND DISPOSE OF IN THE
TRASH. AEROSOL RECYCLING PROGRAMS ARE AVAILABLE IN MANY AREAS.
DO NOT PUNCTURE OR INCINERATE THIS CONTAINER.
Neutralizing Agent:
NONE KNOWN.
SECTION IX - SPECIAL PROTECTION INFORMATION
Required Ventilation:
LOCAL VENTILATION IS RECOMMENDED TO CONTROL EXPOSURE FROM
OPERATIONS THAT CAN GENERATE MISTS OR VAPORS.
Respiratory Protection:
A NIOSH/MSHA APPROVED RESPIRATOR IN POORLY VENTILATED AREAS
AND/OR FOR EXPOSURE ABOVE THE ACGIH TLV OR OSHA PEL OR WHERE
MISTING EXISTS.
Glove Protection:
NEOPRENE OR NITRILE RUBBER GLOVES SHOULD BE WORN.
Eye Protection:
CHEMICAL GOGGLES AND A FACE SHIELD SHOULD BE WORN.
Other Protection:
WEAR PROTECTIVE CLOTHING WHEN HANDLING.
SECTION X - STORAGE AND HANDLING INFORMATION
Storage Temperature: Indoors:X Outdoors: Heated: Refrigerated:
Minimum Temperature:32掳F Maximum Temperature:120掳F
Precautions to be taken in Handling and Storing:
DO NOT STORE NEAR HEAT, SPARKS, PILOT LIGHTS, STATIC ELECTRICITY
AND OPEN FLAME.
Other Precautions:
KEEP OUT OF REACH OF CHILDREN. READ THE ENTIRE LABEL BEFORE
USING THE PRODUCT. FOLLOW THE LABEL DIRECTIONS.
SECTION XI - REGULATORY INFORMATION
Chemical Name CAS Number Upper % Limit
Those Ingredients listed above are subject to the reporting requirements of 313 of
Title III& of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR
part 372.
PLEASE CALL 1-800-527-9919 FOR ADDITIONAL INFORMATION IF YOU
ARE A CALIFORNIA CUSTOMER.
THIS MSDS IS NOT INTENDED FOR USERS IN THE STATE OF
CALIFORNIA
SECTION XII - REFERENCES
1. THRESHOLD LIMIT VALUES FOR CHEMICAL SUBSTANCES AND PHYSICAL
AGENTS AND BIOLOGICAL EXPOSURE INDICES, ACGIH, 2001.
2. OSHA PEL.
3. REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES, CCINFODisc,
2001.
4. VENDOR'S MSDS.
ALL COMPONENTS IN THIS PRODUCT CAN BE FOUND IN THE CURRENT
TSCA INVENTORY.
------------------------------------------------------------------------------------ IRR:IRRITANT,
FLAM/FLAMM:FLAMMABLE, COMB:COMBUSTIBLE, CORR:CORROSIVE
CARC:CARCINOGENIC, TOX:TOXIC, N/A:NOT APPLICABLE, N/E:NOT
ESTABLISHED, COC:CLEVELAND OPEN CUP, PMCC:PENSKY-MARTIN
CLOSED CUP, TCC:TAGLIABUE CLOSED CUP, LEL:LOWER EXPLOSION
LIMIT, UEL:UPPER EXPLOSION LIMIT, NFPA:NATIONAL FIRE PROTECTION
ASSOCIATION, IARC:INTERNATIONAL AGENCY FOR THE RESEARCH ON
CANCER, NTP:NATIONAL TOXICOLOGY PROGRAM, OSHA:OCCUPATIONAL
SAFETY & HEALTH ADMINISTRATION, ACGIH:AMERICAN CONFERENCE OF
GOVERNMENTAL INDUSTRIAL HYGIENISTS, TLV:THRESHOLD LIMIT VALUE,
PEL:PERMISSIBLE EXPOSURE LIMIT, STEL:SHORT-TERM EXPOSURE LIMIT,
MLD:MILD, MOD:MODERATE, SEV:SEVERE, MUT:MUTAGENIC,
ASPHYX:ASPHYXIANT, PNOS: PARTICULATES (INSOLUBLE) NOT
OTHERWISE SPECIFIED, SDT:STANDARD DRAIZE TEST, ORL: ORAL, HMN:
HUMAN, IHL:INHALATION
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED
ACCURATE IN LIGHT OF CURRENT FORMULATION.HOWEVER, NO
WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF
THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
CHEMSEARCH DIV. OF NCH CORP. assumes no responsibility for personal injury
or property damage caused by the use, storage, or disposal of the product in a
manner not recommended on the product label. Users assume all risks associated
with such unrecommended use,storage or disposal of the product."
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