EMS CATALOG NO: 13600
EMS PRODUCT: DMP-30
DATE: 10/24/2007
PAGE NUMBER: One of 8
MATERIAL SAFETY DATA SHEET
The information contained herein is based on data considered accurate. However, no
warranty is expressed or implied regarding the accuracy of these data or the results to
be obtained from the use thereof.
Electron Microscopy Sciences assumes no responsibility for personal injury or property
damage to vendees, users or third parties caused by the material. Such vendees or
users assume all risks associated with the use of the material.
ELECTRON MICROSCOPY SCIENCES
1560 INDUSTRY ROAD
P.O. BOX 550
HATFIELD, PA 19440 24 HOUR EMERGENCY PHONE NUMBER
(215) 412-8400 CHEMTREC: (800) 424-9300)
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FOR PRODUCT AND SALES INFORMATION
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CONTACT ELECTRON MICROSCOPY SCIENCES OFFICE ABOVE.
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PRODUCT IDENTIFICATION
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PRODUCT NAME: DMP-30
C.A.S. CHEMICAL NAME: Mixture
SYNONYMS: None
CHEMICAL FAMILY: Mannich Base
EMPIRICAL FORMULA: Mixture
INTENDED USE: Curing Agent, Epoxy
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EMERGENCY OVERVIEW
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HMIS HEALTH RATING: 3 FLAMMABILITY: 1 REACTIVITY: 0
PHYSICAL FORM: Mobile liquid
COLOR: Straw yellow
ODOR: Irritating
HAZARDS: Harmful if swallowed. Corrosive to eyes. Corrosive to skin.
Severe eye irritant. Severe respiratory tract irritant. Severe skin irritant.
EXTINGUISHING MEDIA:
Ignition will give rise to a Class B fire. In case of large fire use: Alcohol Foam,
Water Spray. In case of small fire use: Carbon Dioxide (CO2), Dry chemical, Dry sand
or limestone.
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INGREDIENTS
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# % CAS Number and Chemical Name
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1. >85.00 90-72-2 Tris-2,4,6-(DIMETHYLAMINOMETHYL)PHENOL
The remaining components are trade secret.
OSHA (ACGIH) EXPOSURE LIMITS
TWA STEL CEILING
ppm mg/m3 ppm mg/m3 ppm mg/m3
1. OSHA N/E N/E N/E N/E N/E N/E
ACGIH N/E N/E N/E N/E N/E N/E
N/E = Not Established.
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HEALTH HAZARDS
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ROUTES OF EXPOSURE:
Eye Contact
Skin Contact
Ingestion
Skin Absorption
EXPOSURE STANDARDS:
No standards established for the product. Maintain air
contaminant concentrations in the workplace at the lowest
feasible levels.
HEALTH HAZARDS:
Harmful if swallowed.
Corrosive to eyes.
Corrosive to skin.
Severe eye irritant.
Severe respiratory tract irritant.
Catalog #13600 DMP-30 2
Severe skin irritant.
TARGET ORGANS:
Central nervous system
Eye
Skin
Respiratory system
SIGNS AND SYMPTOMS OF EXPOSURE (Acute effects):
Product vapor in low concentrations can cause lacrimation, conjunctivitis and corneal
edema when absorbed into the tissue of the eye from the atmosphere. Corneal edema
may give rise to a perception of 'blue haze''or 'fog'' around lights. The effect is transient
and has no known residual effect. Burns of the eye may cause blindness. Inhalation
of vapors may cause irritation in the respiratory tract. Contact of undiluted product with
the eyes or skin quickly causes severe irritation and pain and may cause burns, necrosis
and permanent injury. Ingestion may cause death unless treated promptly. Inhalation
of aerosols and mists may severely damage contacted tissue and produce scarring.
Product is absorbed through the skin and may cause nausea, headache and general
discomfort.
SIGNS AND SYMPTOMS OF EXPOSURE (Possible Longer Term Effects):
Repeated and/or prolonged exposures may result in: nervous system disorders (such as
narcosis, behavioral changes or decrease in motor function), adverse respiratory effects
(such as cough, tightness of chest or shortness of breath), adverse eye effects (such as
conjuctivitis or corneal damage), muscular dysfunction, adverse skin effects (such as
rash, irritation or corrosion).
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:
Asthma
Chronic respiratory disease (e.g. Bronchitis, Emphysema)
Eye disease
Neurological disorders
Skin disorders and Allergies
CARCINOGENS UNDER OSHA, ACGIH, NTP, IARC, OTHER:
This product contains no carcinogens in concentrations of 0.1 percent or greater.
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FIRST AID
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EYE CONTACT:
Hold eyelids apart and immediately flush eyes with plenty of water for at least 15
minutes. Seek medical advice.
SKIN CONTACT:
Remove product and immediately flush affected area with water for at least 15 minutes.
Remove contaminated clothing and shoes. Destroy contaminated leather apparel.
Cover the affected area with a sterile dressing or clean sheeting and transport for
medical care. DO NOT APPLY GREASES OR OINTMENTS. Control shock, if present.
Launder contaminated clothing prior to reuse.
Catalog #13600 DMP-30 3
INHALATION:
Move patient to fresh air. If breathing has stopped or is labored give assisted respiration
(e.g. mouth-to-mouth). Prevent aspiration of vomit. Turn victim's head to the side.
Seek medical advice.
INGESTION:
In the event of ingestion, administer 3-4 glasses of milk or water. DO NOT INDUCE
VOMITING. Seek medical advice.
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FIRE AND EXPLOSION DATA
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FLASH POINT (closed cup): 148.89oC (300.00oF)
UPPER EXPLOSION LIMIT (UEL): No Data
LOWER EXPLOSION LIMIT (LEL): No Data
AUTOIGNITION TEMPERATURE: No Data
FIRE HAZARD CLASSIFICATION (OSHA/NFPA): Class III B
EXTINGUISHING MEDIA:
Ignition will give rise to a Class B fire. In case of large fire use: Water Spray, Alcohol
Foam. In case of small fire use: Carbon Dioxide (CO2), Dry Chemical, Dry Sand or
Limestone.
SPECIAL FIRE FIGHTING PROCEDURES:
A face shield should be worn. Firefighters should wear butyl rubber boots, gloves and
body suit and a self-contained breathing apparatus. Retain expended liquids from fire
fighting for later disposal.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
May generate toxic or irritating combustion products. Contact of liquid with skin must be
prevented. May generate carbon monoxide gas. May generate toxic nitrogen oxide
gases. May generate ammonia gas. Personnel in vicinity and downwind should be
evacuated.
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ACCIDENTAL RELEASE MEASURES
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CONTAINMENT TECHNIQUES (Removal of ignition sources, diking etc.):
Stop the leak, if possible. Reduce vapor spreading with a water spray. Shut off or
remove all ignition sources. Construct a dike to prevent spreading.
CLEAN UP PROCEDURES:
If recovery is not feasible, admix with dry soil, sand or non-reactive absorbent (sodium
bisulfate) and place in a container or dumpster pending disposal. Transfer to containers
by suction, preparatory for later disposal. Place in metal containers for recovery or
disposal. Flush area with water spray. Clean-up personnel must be equipped with self
contained breathing apparatus and butyl rubber protective clothing. For large spills,
recover spilled materials with a vacuum truck.
Catalog #13600 DMP-30 4
OTHER EMERGENCY ADVICE:
Wear protective clothing, boots, gloves, and eye protection.
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HANDLING AND STORAGE
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STORAGE:
Keep away from: acids, oxidizers. Keep in cool, dry, ventilated storage and in closed
containers. Store in steel containers preferably located outdoors, above ground, and
surrounded by dikes to contain spills or leaks. Do not store in iron or other reactive
metals containers. Recommended suitable container materials include plastic, stainless,
and carbon steels.
HANDLING:
Avoid contact with skin or eyes. Avoid breathing of vapors. Handle in well ventilated
work space. When handling, do not eat, drink, or smoke.
OTHER PRECAUTIONS:
Emergency showers and eye wash stations should be readily accessible. Adhere to work
practice rules established by government regulations (e.g. OSHA).
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PERSONAL PROTECTION/EXPOSURE CONTROLS
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EYE PROTECTION: Full face shield with goggles underneath.
HAND PROTECTION: Neoprene rubber gloves. Impermeable gloves. Cuffed butyl
rubber gloves. Nitrile rubber gloves.
RESPIRATORY PROTECTION: Not required under normal conditions in a well-ventilated
workplace.
PROTECTIVE CLOTHING: Impervious clothing. Slicker Suit. Rubber boots. Full rubber
suit (rain gear). Butyl or latex protective clothing.
ENGINEERING CONTROLS: No Specific controls needed.
WORK AND HYGIENIC PRACTICES: Provide readily accessible eye wash stations and
safety showers. Wash at the end of each workshift and before eating, smoking or using
the toilet. Promptly remove clothing that becomes contaminated. Discard
contaminated leather articles.
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TYPICAL PHYSICAL AND CHEMICAL PROPERTIES
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PHYSICAL FORM: Mobile liquid
COLOR: Straw Yellow
ODOR: Irritating
pH: Alkaline
Catalog #13600 DMP-30 5
VAPOR PRESSURE (mm Hg @ 21oC (70oF)): >0.01
VAPOR DENSITY (AIR=1): No Data
BOILING POINT: >100.00oC (>212.00oF)
MELTING POINT: No Data
SOLUBILITY IN WATER: 80.00%
SPECIFIC GRAVITY (WATER=1): 0.97
MOLECULAR WEIGHT: Mixture
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STABILITY AND REACTIVITY
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CHEMICAL STABILITY: Stable.
CONDITIONS TO AVOID (if unstable): Not applicable.
INCOMPATIBILITY (Materials to avoid): Mineral acids (i.e. sulfuric, phosphoric, etc.).
Organic acids (i.e. acetic acid, citric acid etc.). Oxidizing agents (i.e. perchlorates,
nitrates etc.). Sodium or Calcium Hypochlorite. Product slowly corrodes copper,
aluminum, zinc and galvanized surfaces. Reaction with peroxides may result in violent
decomposition of peroxide possibly creating an explosion. A reaction accompanied by
large heat release occurs when the product is mixed with acids. Heat generated may be
sufficient to cause vigorous boiling creating a hazard due to splashing or splattering of
hot material.
HAZARDOUS DECOMPOSITION PRODUCTS (FROM BURNING, HEATING, OR
REACTION WITH OTHER MATERIALS):
Carbon Monoxide in a fire. Carbon Dioxide in a fire. Ammonia when heated. Nitrogen
Oxides in a fire. Irritating and toxic fumes at elevated temperatures. Nitric acid in a
fire. Nitrogen oxide can react with water vapors to form corrosive nitric acid (TLV=2
ppm).
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID (IF POLYMERIZATION MAY OCCUR): Not applicable.
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TOXICOLOGICAL PROPERTIES
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ACUTE ORAL TOXICITY (LD50, RAT): 1670.00 mg/kg
ACUTE DERMAL TOXICITY (LD50, RABBIT): No data.
ACUTE INHALATION TOXICITY (LC50,RAT): No data.
OTHER ACUTE EFFECTS: No data.
IRRITATION EFFECTS DATA: Corrosive to the skin of a rabbit.
CHRONIC/SUBCHRONIC DATA: Subchronic exposure of this material or component in
test animals has caused abnormalities in the following organs, however these effects are
not sufficient to characterize the material as a specific organ toxin: Central nervous
system. This product has been tested and shown not to cause sensitization in guinea
pigs.
Catalog #13600 DMP-30 6
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ECOLOGICAL INFORMATION
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ECOTOXICITY:
Rainbow trout (Salmo gairderi) 96 hour TL50=180-240 mg/1
ENVIRONMENTAL FATE: No Data.
ADDITIONAL INFORMATION: Waste from this product may present long term
environmental hazards, thus landfill disposal must be considered less acceptable than
incineration.
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DISPOSAL CONSIDERATIONS
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WASTE DISPOSAL: Comply with all Federal, State and Local Regulations.
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TRANSPORT INFORMATION
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DOT NON-BULK SHIPPING NAME: Amines, liquid, corrosive, n.o.s.
(TRIS-2,4,6-(DIMETHYLAMINOMETHYL)
PHENOL) // 8 // UN2785 // PG III
IMO SHIPPING DATA Amines, liquid, corrosive, n.o.s.
(TRIS-2,4,6-(DIMETHYLAMINOMETHYL)
PHENOL) // 8 // UN2735 // III //
HazMat STCC=4935601 // EmS No: 8-05
// MFAG No: 320
ICAO/IATA SHIPPING DATA: Amines, liquid, corrosive, n.o.s.
(TRIS-2,4,6-(DIMETHYLAMINOMETHYL)
PHENOL) // 8 // UN2735 // III //
Shipment per 49 CFR 171.11
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REGULATORY INFORMATION
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US FEDERAL REGULATIONS
TOXIC SUBSTANCES CONTROL ACT (TSCA):
All components are included in the EPA Toxic Substances Control Act (TSCA) Chemical
Substance Inventory.
OSHA HAZARD COMMUNICATION STANDARD (29CFR1910.1200) HAZARD CLASS:
Corrosive
Catalog #13600 DMP-30 7
EPA SARA TITLE III SECTION 312 (40CFR370) HAZARD CLASS: Immediate Health
Hazard
EPA SARA TITLE III SECTION 313 (40CFR372) TOXIC CHEMICALS ABOVE
"DEMINIMIS" LEVEL ARE: None.
STATE REGULATIONS
PROPOSITION 65 SUBSTANCES (component(s) known to the State of California to cause
cancer and/or reproductive toxicity and subject to warning and discharge requirements
under the "Safe Drinking Water and Toxic Enforcement Act of 1986"):
None.
NEW JERSEY TRADE SECRET REGISTRY NUMBER(S):
05995500-(HK54-U)
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INTERNATIONAL REGULATIONS
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CANADA
DSL
Included on Inventory.
WHMIS HAZARD CLASSIFICATION:
Class E Corrosive.
WHMIS TRADE SECRET REGISTRY NUMBER(S):
None.
WHMIS SYMBOLS:
Test tube/hand.
EUROPEAN ECONOMIC COMMUNITY (EEC)
EINEC MASTER INVENTORY:
Included on Inventory.
EEC SYMBOL:
HARMFUL (XN)
EEC RISK (R) PHRASES:
Irritating to eyes and skin (R26/39).
Harmful if swallowed (R22).
EEC SAFETY PHRASES:
In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice (S26).
After contact with skin, wash immediately with plenty of soap and water (S28).
Catalog #13600 DMP-30 8
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