EMS CAT AL OG NO: 13710
EMS PR ODUCT : DDS A S PECI AL L Y DI S T I L L ED
DAT E: 12/ 23/ 2001
PAGE NUMB ER : One of 6
MAT ER I AL S AFET Y DAT A S HEET
T he information contained herein is based on data considered accurate. However, no
warranty is expressed or implied regarding the accuracy of these data or the results to
be obtained from the use thereof.
Electron Microscopy Sciences assumes no responsibility for personal injury or property
damage to vendees, users or third parties caused by the material. Such vendees or
users assume all risks associated with the use of the material.
EL ECT R ON MI CR OS COPY S CI ENCES
321 MOR R I S R OAD
P.O. B OX 251
FOR T W AS HI NGT ON, PA 19034 24 HOUR EMER GENCY PHONE NUMB ER
(215) 646-1566 CHEMT R EC: (800) 424-9300
_________________________________________________________________
FOR PR ODUCT AND S AL ES I NFOR MAT I ON
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CONT AC ELEC RON MI C
T T ROSCOPY SC ENC OFFI C ABOVE.
I ES E
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PR ODUCT I DENT I FI CAT I ON
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PRODUC NAME:
T Dodecenyl Special Distilled (K-12-SP)
CHEMI C FAMI LY: Alkenyl Anhydride.
AL
PRODUC USE:
T Epoxy C uring Agent
WHMI S CLASS: Not established
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COMPONENT S
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NAME: C NUMBER: WEI G % :
AS HT
Dodecenyl Special Distilled 26544-38-7 > 95%
Dodecenyl Succinic Acid 27859-58-1 5%
_
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HAZ AR DS I DENT I FI CAT I ON
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EMER GENCY OVER VI EW
C lear, light yellow liquid with a slight odor. Material presents little or no immediate
significant hazard is spilled. T his material presents no unusual hazard if involved in a
fire.
BREAT HI NG : Slightly irritating to eyes and respiratory tract.
SKI N CONT AC : May cause skin irritant.
T
EYE C ONT AC : C
T ontact may cause eye irritation.
SWALLOWI NG Substance is harmful if swallowed.
:
LONG T ERM HEALT H EFFEC S: T Not known.
CONDI T I ONS AG RAVAT ED BY EXPOSURE: Not known.
G
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FI R S T AI D MEAS UR ES
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BREAT HI NG Remove to fresh air. I f not breathing, give artificial respiration. I f
:
breathing is difficult, give oxygen. Seek medical attention.
SKI N: I mmediately flush with water for at least 15 minutes. Use soap if available.
Remove contaminated clothing, including shoes after flushing has begun. G prompt
et
medical attention. T horoughly wash contaminated clothing and shoes or discard in a
manner which limits further exposure.
EYE: I mmediately flush eyes with plenty of water for at least 15 minutes, holding
eyelids apart. G medical attention if irritation or other symptoms occur.
et
SWALLOWI NG G immediately medical attention. Never give anything by mouth an
: et
unconscious person. Dilute with milk or water.
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FI R E FI GHT I NG MEAS UR ES
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FLASH POI NT : 333oF, 167.22oC
MET HOD: BPF
LOWER EXPLOSI VE LI MI T : N/A
UPPER EXPLOSI VE LI MI T : N/A
AUT O I G T I ON T EMPERAT URE: N/A
NI
EXT I NG SHI NG MEDI A:
UI C arbon dioxide, dry chemical, alcohol foam water spray
FI RE FI G I NG PROC
HT EDURES:
Evacuate area and fight fire from safe distance. Wear pressure demand self contained
breathing apparatus (MSHA/NI OSH approved or equivalent) and full protective gear.
Catalog # 13710 2
DDSA Specially Distilled
SPEC AL FI RE FI G I NG PROC
I HT EDURES: C burn in fire releasing toxic vapors. As in
an
any fire, wear pressure demand self contained breathing apparatus (MSHA/NI OSH
approved or equivalent) and full protective gear. Using water can cause frothing with
increasing fire intensity.
UNUSUAL FI RE AND EXPLOSI ON HAZARDS: None known.
SENSI T I VI T Y T O EXPLOSI ON:
Explosion by mechanical impact - none.
Explosion by static discharge - none.
CONDI T I ONS OF FLAMMABI LI T Y: Avoid temperatures above flash point. May burn in
a fire.
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ACCI DENT AL R EL EAS E MEAS UR ES
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GENERAL: T his material should be prevented from contaminating soil or from entering
sewerage and drainage systems and bodies of water. I solate hazard area. Keep
unnecessary and unprotected personnel from entering. Prevent skin and eye contact.
See Exposure C ontrols/Personal Protection.
SMALL SPI LL: Absorb spill with inert material (e.g., dry sand or earth), then place in a
chemical waste container.
LARG SPI LL: Shut off leak, if safe to do so. C
E lean up spills immediately, observing
precautions in Protective Equipment section. C ontain spilled liquid with sand or earth.
Retain all contaminated water for removal and treatment. DO NOT use combustible
materials such as saw dust.
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HANDL I NG & S T OR AGE
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HANDLI NG Use with adequate ventilation. Avoid contact with skin and eyes. Wash
:
thoroughly after handling. Follow all MSDS/label precautions even after container is
emptied because it may retain product residues.
ST ORAG Keep container closed when not in use.
E:
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EXPOS UR E CONT R OL S / PER S ONAL PR OT ECT I ON
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EXPOSURE LEVELS: None established.
Catalog # 13710 3
DDSA Specially Distilled
ENG NEERI NG C
I ONT ROLS: Use process enclosures, local exhaust ventilation, or other
engineering controls to control sources of dust, mist or vapor.
RESPI RAT ORY PROT EC I ONS: Use a NI OSH/MSHA approved air purifying respirator
T
may be permissible under certain circumstances where airborne concentrations are
expected to exceed exposure limits if established. C onsult with respirator's
manufacturer to determine the appropriate type of equipment for a given application.
Protection provided by air purifying respirators is limited. Use a positive pressure air
supplied respirator if there is any potential for an uncontrolled release, exposure levels
are not known or any other circumstances where air purifying respirators may not
provide adequate protection. A respiratory protection program that meets OSHA
1910.134 and ANSI Z88.2 requirements must be followed whenever workplace
conditions warrant a respirator's use.
EYE/FAC PROT EC I ON: Use safety glasses. Where contact with the eyes is likely, use
E T
chemical goggles. Use a face shield as needed.
SKI N PROT EC I ON: Use impervious gloves. Use clean protective body-covering
T
clothing as needed to minimize contact with clothing and skin.
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PHYS I CAL AND CHEMI CAL PR OPER T I ES
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APPEARANC E: C lear, light yellow liquid.
ODOR: Slight.
I NI T BOI LI NG POI NT : 662.0oF / 350.0oC
FI NAL BOI LI NG POI NT : 662.0oF / 350.0oC
SPEC FI C G
I RAVI T Y: 1.005 (Relative to water)
VAPOR DENSI T Y: 9.2 (Relative to air)
VAPOR PRESSURE: <1
pH: N/A
SOLUBI LI T Y I N WAT ER: I nsoluble.
FREEZI NG /MELT I NG POI NT : N/A
OC ANOL/WAT ER PART I T I ON C
T OEFFI C ENT : N/A
I
ODOR T HRESHOLD: N/A
VI SC T Y:
OSI N/A
EVAPORAT I ON RAT E: < 0.7 (Relative to n-Butyl acetate)
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S T AB I L I T Y/ R EACT I VI T Y
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ST ABI LI T Y: Stable
ST RONG OXI DI ZER: No
HAZARDOUS POLYMERI ZAT I ON: Not prone to hazardous polymerization.
I NCOMPAT I BI LI T Y: C react vigorously with oxidizing materials, alkali metals and
an
amines.
C ONDI T I ONS T O AVOI D: Keep from contact with oxidizing materials.
Catalog # 13710 4
DDSA Specially Distilled
HAZARDOUS DEC OMPOSI T I ON PRODUC S: Products of incomplete combustion may
T
include C C and dense smoke.
0, 02,
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T OXI COL OGI CAL I NFOR MAT I ON
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T OXI COLOG DODEC
Y: ENYL SUC I NI C ANHYDRI DE C # 26544-38-7 ipr-mus LD50:
C AS
320 mg/kg
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W AS T E DI S POS AL
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WAST E DI SPOSAL: Dispose of in accordance with all Federal, State and local
regulations.
CONT AI NER DI SPOSAL: Dispose of in accordance with all Federal, State and local
regulations.
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T R ANS POR T I NFOR MAT I ON
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DOT Shipping Name: Not Regulated
I MO Shipping Name: Not Regulated
I AT A Shipping Name: Not Regulated
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R EGUL AT OR Y I NFOR MAT I ON
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SARA 311/312 CHRONI C HEALT H HAZARD: No
SARA 311/312 AC E HEALT H HAZARD:
UT No
SARA 311/312 FI RE HAZARD: No
SARA 311/312 SUDDEN PRESSURE: No
SARA 311/312 REAC I VI T Y HAZARD:
T No
T SC - T his substance is listed on the T SC inventory.
A A
SEC I ON 302 EXT REMELY HAZARDOUS I NG
T REDI ENT S: None
CERC HAZARDOUS SUBST ANC I NG
LA ES REDI ENT S: None
SEC I ON 313 T OXI C C
T HEMI CALS I NGREDI ENT S: None
NJ ENVI RONMENT AL HAZARDOUS SUBST ANC LI ST I NG
E REDI ENT S: None
C FORNI A PROPOSI T I ON 65 I NG
ALI REDI ENT S: None
REPORT ED I N T SC I NVENT ORY:
A None
Catalog # 13710 5
DDSA Specially Distilled
NFPA RAT I NG : HMI S RAT I NG :
Health -1 Health -1
Fire -1 Fire -1
Reactivity - 0 Reactivity - 0
Catalog # 13710 6
DDSA Specially Distilled
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