EMS CATALOG NO: 19220
EMS PRODUCT: Parlodion
DATE: 11/17/2001
PAGE NUMBER: One of 5
MATERIAL SAFETY DATA SHEET
The information contained herein is based on data considered
accurate. However, no warranty is expressed or implied
regarding the accuracy of these data or the results to be
obtained from the use thereof.
Electron Microscopy Sciences assumes no responsibility for
personal injury or property damage to vendees, users or
third parties caused by the material. Such vendees or users
assume all risks associated with the use of the material.
ELECTRON MICROSCOPY SCIENCES
321 MORRIS ROAD
P.O. BOX 251
FORT WASHINGTON, PA 19034 24 HOUR EMERGENCY PHONE NUMBER
(215) 646-1566 CHEMTREC: (800) 424-9300
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FOR PRODUCT AND SALES INFORMATION
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CONTACT ELECTRON MICROSCOPY SCIENCES OFFICE ABOVE.
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PRODUCT IDENTIFICATION
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PRODUCT NAME: Parlodion
CAS NUMBER: 9004-70-0
SYNONYM: Pyroxylin Purified Strips
CHEMICAL FORMULA: C12H16N4O18
MOLECULAR WEIGHT: 504.28
HAZARDOUS INGREDIENTS: Not applicable
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PRECAUTIONARY MEASURES
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WARNING! FLAMMABLE! CAUSES BURNS.
Keep away from heat, sparks and flame.
Do not get in eyes, on skin, or on clothing.
Keep container closed.
Use with adequate ventilation.
Wash thoroughly after handling.
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EMERGENCY/FIRST AID
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In case of contact, immediately flush skin or eyes with plenty of
water for at least 15 minutes. Call a physician.
See HEALTH HAZARD INFORMATION section.
DOT HAZARD CLASS: Flammable solid
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PHYSICAL DATA
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ODOR: Slight odor of alcohol.
SOLUBILITY: Insoluble in water.
BOILING POINT: No information found.
MELTING POINT: Ignites at 165oC /329oF
SPECIFIC GRAVITY: 1.66
VAPOR DENSITY: No information found. (Air=1)
VAPOR PRESSURE: No information found. (mm Hg)
EVAPORATION RATE: Not applicable
APPEARANCE: Thin, transparent, colorless to pale yellow
strips.
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FIRE AND EXPLOSION INFORMATION
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FIRE: FLAMMABLE!
FLASH POINT: 13oC / 55oF
AUTOIGNITION TEMPERATURE: 165oC /329oF
Presents an unusually severe fire hazard; when dry, ignites
readily and burns explosively. Should never be kept for any
appreciable time in any dry fibrous state. Unstabilized product
decomposes generally at relatively low temperature, with
evolution of copious volumes of toxic and flammable gases, and
rapid heat generation. In prolonged storage and aging of
nitrocellulose plastics, camphor is lost with deterioration and
the decomposition temperature may be lowered to 100oF. The
resulting flameless decomposition is self-sustaining and
accelerative, presenting the added hazard of dangerous pressures
in building structures.
EXPLOSION:
An explosion may be initiated by sudden shock, by high
temperature or by a combination of the two.
FIRE EXTINGUISHING MEDIA:
Water spray, dry chemical, alcohol foam, or carbon dioxide.
SPECIAL INFORMATION:
In the event of a fire, wear full protective clothing and NIOSH-
approved self-contained breathing apparatus with full facepiece
operated in the pressure demand or other positive pressure mode.
Use extreme caution in approaching fires involving this material
as it may explode. No attempt should be made to fight advanced
fires, except for remote activation of installed fire extin-
guishing equipment and/or with unmanned fixed turrents and hose
nozzles. The surrounding area should be evacuated. Fires should
be approached from upwind and self-contained breathing apparatus
used. Since cellulose nitrate supplies its own oxygen, prompt
cooling with a large quantity of water is essential; water
applied through spray nozzles is effective if used quickly and in
sufficient volume, in a manner to set the entire exposed surface.
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REACTIVITY DATA
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STABILITY: Stable at room temperature in sealed containers.
HAZARDOUS DECOMPOSITION PRODUCTS:
Oxides of nitrogen, hydrogen cyanide, carbon monoxide.
HAZARDOUS POLYMERIZATION: Will not occur.
INCOMPATIBILITIES: Heat, flame, powerful oxidizers.
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LEAK/SPILL DISPOSAL INFORMATION
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Dangerous material. Partially decomposed material may detonate
or autoignite. Handle decomposed material as an explosive that
may detonate with mild shock using explosive disposal
procedures. Submerge fresh parlodian strips in water and burn in
small quantities in an approved incinerator.
Ensure compliance with local, State and Federal regulations.
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HEALTH HAZARD INFORMATION
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EXPOSURE/HEALTH EFFECTS:
INHALATION: Formation of large quantities of extremely toxic gases,
notably oxides of nitrogen, hydrogen cyanide and carbon
monoxide may occur upon decomposition. Effects from
exposures to decomposition products are severe and life
threatening.
INGESTION: Although ingestion is highly unlikely, swallowing may
result in a severe stomach pain.
SKIN CONTACT: Corrosive to the skin. Discoloration and pain may
result.
EYE CONTACT: Although eye contact is highly unlikely, it may result
in severe pain.
CHRONIC EXPOSURE: No information found.
AGGRAVATION OF PRE-EXISTING CONDITIONS: No information found.
FIRST AID:
INHALATION: Remove to fresh air. Get medical attention for
any breathing difficulty.
INGESTION: Get medical attention immediately. Never give
anything by mouth to an unconscious person.
SKIN EXPOSURE: In case of contact, immediately flush skin with
plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Call a
physician.
EYE EXPOSURE: Wash eyes with plenty of water for at least 15
minutes, lifting lower and upper eyelids
occasionally. Get medical attention immediately.
TOXICITY DATA (RTECS, 1982): No information found.
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OCCUPATIONAL CONTROL MEASURES
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AIRBORNE EXPOSURE LIMITS: None established.
VENTILATION SYSTEM:
A local exhaust system which captures the contaminant at its
source is recommended to prevent dispersion of the contaminant
into the workroom air.
PERSONAL RESPIRATORS (NIOSH APPROVED):
For conditions of use where exposure to the vapor is apparent, a
half mask chemical cartridge respirator may be worn. For emer-
gencies, a self-contained breathing apparatus may be necessary.
SKIN PROTECTION:
Wear protective gloves and clean body-covering clothing.
EYE PROTECTION:
Use chemical safety goggles. Contact lenses should not be worn
when working with this material. Maintain eye wash fountain and
quick-drench facilities in work area.
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STORAGE AND SPECIAL INFORMATION
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Drums should be protected against damage and not exposed to heating,
nor should material be allowed to dry out. Storage should be
segregated, well-ventilated, and equipped with both decomposition and
explosion vents, having the maximum amount of free opening. Protect
against excessive heat and direct sunlight, avoid contact with
electric light bulbs, steam coils, or other sources of heat; prohibit
open flames or other sources of ignition.
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