SAFETY DATA SHEET
Based on Directive 2001/58/EC of the Commission of the European Communities
ACRYLITOP PC-100
1. Identification of the substance/preparation and of the company/undertaking
1.1 Identification of the substance or preparation:
Synonyms: Acrylic Coating PC-100
CAS No. : N.A.
EC index No. : N.A. NFPA code : N.D.
EINECS No. : N.A. Molecular weight : N.A.
RTECS No. : N.A. Formula : N.A.
1.2 Use of the substance or the preparation:
Paint
Coating
1.3 Company/undertaking identification:
Firestone Building Products
Ikaroslaan 75
B-1930 Zaventem
Tel. : +32 2 711 44 50
Fax : +32 2 721 27 18
Email: info@fbpe.be
1.4 Telephone number for emergency:
+32 70 245 245
Poison Centre
p/a Militair Hospitaal Koningin Astrid, Bruynstraat 1, B-1120 Brussel
2. Composition/information on ingredients
Hazardous ingredients CAS No. Conc. in Hazard Risks
% symbol
EINECS/ELINCS No. (R-phrases)
1,2-ethanediol 107-21-1 <8 Xn 22 (1)
203-473-3
titanium dioxide 13463-67-7 <18 - -
236-675-5
zinc oxide 1314-13-2 <8 N 50/53 (1)
215-222-5
(1) For R-phrases in full: see heading 16
3. Hazards identification
- Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment
4. First aid measures
4.1 Eye contact:
- Consult a doctor/medical service if irritation persists
- Rinse immediately with water
4.2 Skin contact:
- Consult a doctor/medical service if irritation persists
- Wash with water and soap
Printing date : 02-2006 1/1
Compiled by : Brandweerinformatiecentrum voor Gevaarlijke Stoffen vzw (BIG)
Technische Schoolstraat 43 A, B-2440 Geel
( +32 14 58 45 47 http://www.big.be E-mail: info@big.be
MSDS established : 25-01-2006 Revision date :
Reference number : BIG\43110GB Revision number : 000
Reason for revision :
ACRYLITOP PC-100
4.3 After inhalation:
- Consult a doctor/medical service if breathing problems develop
- Remove the victim into fresh air
- Unconscious: maintain adequate airway and respiration
4.4 After ingestion:
- Consult a doctor/medical service if you feel unwell
- Immediately give lots of water to drink
- Never give water to an unconscious person
- Do not induce vomiting
5. Fire-fighting measures
5.1 Suitable extinguishing media:
- Alcohol-resistant foam
- BC powder
- Carbon dioxide
5.2 Unsuitable extinguishing media:
- No data available
5.3 Special exposure hazards:
- Combustible
- On burning: release of toxic and corrosive gases/vapours (zinc oxide,
nitrous vapours, carbon monoxide - carbon dioxide)
5.4 Instructions:
- Take account of environmentally hazardous firefighting water
- Use firefighting water moderately and contain it
5.5 Special protective equipment for firefighters:
- Heat/fire exposure: compressed air/oxygen apparatus
- Protective clothing for exposure to chemicals
6. Accidental release measures
6.1 Personal protection/precautions:
See heading 8.2/8.3/13
6.2 Environmental precautions:
- Prevent soil and water pollution
- Prevent spreading in sewers
- Contain released substance, pump over in suitable containers
- Plug the leak, cut off the supply
- Dam up the liquid spill
6.3 Methods for cleaning up:
- Warning! Product may cause floors to be slippery
- Take up liquid spill into inert absorbent material, e.g.: sand/earth
- Scoop absorbed substance into closing containers
- Carefully collect the spill/leftovers
- Clean contaminated surfaces with an excess of water
- Wash clothing and equipment after handling
7. Handling and storage
7.1 Handling:
- Observe normal hygiene standards
- Do not discharge the waste into the drain
- Clean contaminated clothing
7.2 Storage:
- Keep container tightly closed
- Store at room temperature
- Ventilation atfloor level
- Protect against frost.
- Keep away from: heat sources
Storage temperature : 15/25 掳C
Quantity limits : N.D. kg
Storage life : 270 days
Printing date : 02-2006 2/2
ACRYLITOP PC-100
Materials for packaging :
- suitable : no data available
- to avoid : no data available
7.3 Specific uses:
- See information supplied by the manufacturer
8. Exposure controls/Personal protection
8.1 Exposure limit values:
1,2-ethanediol
mg/m3
TLV-TWA :- ppm
mg/m3
TLV-STEL :- ppm
mg/m3
TLV-Ceiling : 100 aerosol ppm
mg/m3
OES-LTEL : 10 part/52 va - part/20 va ppm
mg/m3
OES-STEL : -part/104 va - part/40 va ppm
mg/m3
MAK : 26 10 ppm
mg/m3
TRK : ppm
mg/m3
MAC-TGG 8 h : 52 damp
mg/m3
MAC-TGG 15 min. : 104 damp
mg/m3
MAC-Ceiling :
mg/m3
VME-8 h : 52 vapeur 20 vapeur ppm
mg/m3
VLE-15 min. : 104 vapeur 40 vapeur ppm
mg/m3
GWBB-8 h : 52 20 ppm
mg/m3
GWK-15 min. : 104 40 ppm
mg/m3
Momentary value :M M ppm
mg/m3
EC : 52 20 ppm
mg/m3
EC-STEL : 104 40 ppm
titanium dioxide
mg/m3
TLV-TWA : 10 ppm
mg/m3
TLV-STEL :- ppm
mg/m3
TLV-Ceiling : ppm
mg/m3
OES-LTEL : 4 R/10 I - ppm
mg/m3
OES-STEL :- - ppm
mg/m3
MAK : 1.5 A ppm
mg/m3
TRK : ppm
mg/m3
MAC-TGG 8 h : 10
mg/m3
MAC-TGG 15 min. :
mg/m3
MAC-Ceiling :
mg/m3
VME-8 h : 10(Ti) -(Ti) ppm
mg/m3
VLE-15 min. : -(Ti) -(Ti) ppm
mg/m3
GWBB-8 h : 10 - ppm
mg/m3
GWK-15 min. :- - ppm
mg/m3
Momentary value : ppm
mg/m3
EC : ppm
mg/m3
EC-STEL : ppm
Printing date : 02-2006 3/3
ACRYLITOP PC-100
zinc oxide
mg/m3
TLV-TWA : 2R ppm
mg/m3
TLV-STEL : 10 R ppm
mg/m3
TLV-Ceiling : ppm
mg/m3
OES-LTEL : ppm
mg/m3
OES-STEL : ppm
mg/m3
MAK : 1 A Rauch ppm
mg/m3
TRK : ppm
mg/m3
MAC-TGG 8 h : 5 rook
mg/m3
MAC-TGG 15 min. :
mg/m3
MAC-Ceiling :
mg/m3
VME-8 h : 5 fu/10 p - ppm
mg/m3
VLE-15 min. :- - ppm
mg/m3
GWBB-8 h : 5 r/10 stof - ppm
mg/m3
GWK-15 min. : - st/10 rook - ppm
mg/m3
Momentary value : ppm
mg/m3
EC : ppm
mg/m3
EC-STEL : ppm
Sampling methods:
- No data available
8.2 Exposure controls:
8.2.1 Occupational exposure controls:
- Measure the concentration in the air regularly
- Work under local exhaust/ventilation
8.2.2 Environmental exposure controls: see heading 13
8.3 Personal protection:
8.3.1 respiratory protection:
- Insufficient ventilation: wear respiratory protection
8.3.2 hand protection:
- Gloves
Suitable materials: Neoprene
Nitrile rubber
- Breakthrough time: N.D.
8.3.3 eye protection:
- Safety glasses
8.3.4 skin protection:
- Protective clothing
Suitable materials: Neoprene
Nitrile rubber
Printing date : 02-2006 4/4
ACRYLITOP PC-100
9. Physical and chemical properties
9.1 General information:
Appearance (at 20掳C) : Liquid
Odour : Mild
Colour : White-grey to light-brown
9.2 Important health, safety and environmental information:
pH value : N.D.
Boiling point/boiling range : > 100 掳C
Flashpoint : 115 掳C
Explosion limits : N.D. vol% ( 掳C)
Vapour pressure (at 20掳C) : N.D. hPa
Vapour pressure (at 50掳C) : N.D. hPa
Relative density (at 20掳C) : 1.4
Water solubility : Moderately soluble
Soluble in : N.D.
Relative vapour density : >2
Viscosity : N.D. Pa.s
Partition coefficient n-octanol/water : N.D.
Evaporation rate
ratio to butyl acetate : <1
ratio to ether : N.D.
9.3 Other information:
Melting point/melting range : N.D. 掳C
Auto-ignition point : N.D. 掳C
g/m3
Saturation concentration : N.D.
10. Stability and reactivity
10.1 Conditions to avoid/reactivity:
- Stable under normal conditions
10.2 Materials to avoid:
- Keep away from: heat sources
10.3 Hazardous decomposition products:
- On burning: release of toxic and corrosive gases/vapours (zinc oxide,
nitrous vapours, carbon monoxide - carbon dioxide)
11. Toxicological information
11.1 Acute toxicity:
LD50 oral rat : N.D. mg/kg
LD50 dermal rat : N.D. mg/kg
LD50 dermal rabbit : N.D. mg/kg
LC50 inhalation rat : N.D. mg/l/4 h
LC50 inhalation rat : N.D. ppm/4 h
Printing date : 02-2006 5/5
ACRYLITOP PC-100
11.2 Chronic toxicity:
EC carc. cat. : not listed
EC muta. cat. : not listed
EC repr. cat. : not listed
Carcinogenicity (TLV) : A4 (1,2-ethanediol)( titanium dioxide)
Carcinogenicity (MAC) : not listed
Carcinogenicity (VME) : not listed
Carcinogenicity (GWBB) : not listed
Carcinogenicity (MAK) : not listed
Mutagenicity (MAK) : not listed
Teratogenicity (MAK) : C (1,2-ethanediol)( titanium dioxide)
IARC classification : 3(titanium dioxide)
11.3 Routes of exposure: ingestion, inhalation, eyes and skin
11.4 Acute effects/symptoms:
- AFTER INHALATION
- Slight irritation
- AFTER INGESTION
- AFTER ABSORPTION OF HIGH QUANTITIES:
- CNS depression
- Decreased renal function
- AFTER SKIN CONTACT
- Slight irritation
- AFTER EYE CONTACT
- Slight irritation
11.5 Chronic effects:
- Contains a substance of group C (MAK-Schwangerschaftsgruppe)( 1,2-
ethanediol)( titanium dioxide)
- Not listed in carcinogenicity class (IARC,EC,TLV,MAK)
- Not listed in mutagenicity class (EC,MAK)
Printing date : 02-2006 6/6
ACRYLITOP PC-100
12. Ecological information
12.1 Ecotoxicity:
zinc oxide:
- EC50 (48 h) : 0.068 mg/l (DAPHNIA MAGNA)
12.2 Mobility:
- Volatile organic compounds (VOC): N.D.%
- Moderately soluble in water
- Substance sinks in water
For other physicochemical properties see heading 9
12.3 Persistence and degradability:
- biodegradation BOD5 : N.D. % ThOD
- water : - No data available
- soil : T 陆: N.D. days
12.4 Bioaccumulative potential:
- log Pow : N.D.
- BCF : N.D.
12.5 Other adverse effects:
- WGK :3 (Classification based on the components in compliance
with Verwaltungsvorschrift wassergef盲hrdender Stoffe
(VwVwS) of 17 May 1999)
- Effect on the ozone layer : Not dangerous for the ozone layer
(1999/45/EC)
- Greenhouse effect : no data available
- Effect on waste water purification : no data available
13. Disposal considerations
13.1 Provisions relating to waste:
- Waste material code (91/689/EEC, Council Decision 2001/118/EC, O.J. L47 of
16/2/2001): 08 01 11* (waste paint and varnish containing organic solvents
or other dangerous substances)
- Hazardous waste (91/689/EEC)
13.2 Disposal methods:
- Recycle/reuse
- Do not discharge into the sewer
- Do not discharge into surface water
13.3 Packaging/Container:
- Waste material code packaging (91/689/EEC, Council Decision 2001/118/EC,
O.J. L47 of 16/2/2001): 15 01 10* (packaging containing residues of or
contaminated by dangerous substances)
Printing date : 02-2006 7/7
ACRYLITOP PC-100
14. Transport information
90
3082
14.1 Classification of the substance in compliance with UN Recommendations
UN number : 3082
CLASS :9
SUB RISKS :-
PACKING : III
PROPER SHIPPING NAME :
UN 3082, Environmentally hazardous substance, liquid, n.o.s.
(zinc oxide)
14.2 ADR (transport by road)
CLASS :9
PACKING : III
CLASSIFICATION CODE : M6
DANGER LABEL TANKS :9
DANGER LABEL PACKAGES :9
14.3 RID (transport by rail)
CLASS : 9
PACKING : III
CLASSIFICATION CODE : M6
DANGER LABEL TANKS : 9
DANGER LABEL PACKAGES : 9
14.4 ADNR (transport by inland waterways)
CLASS : 9
PACKING : III
CLASSIFICATION CODE : M6
DANGER LABEL TANKS : 9
DANGER LABEL PACKAGES : 9
14.5 IMDG (maritime transport)
CLASS : 9
SUB RISKS : -
PACKING : III
MFAG : -
EMS : F-A, S-F
MARINE POLLUTANT : -
14.6 ICAO (air transport)
CLASS : 9
SUB RISKS : -
PACKING : III
PACKING INSTRUCTIONS PASSENGER AIRCRAFT : 914/Y914
PACKING INSTRUCTIONS CARGO AIRCRAFT : 914
14.7 Special precautions in connection with : none
transport
14.8 Limited quantities (LQ) :
When substances and their packaging meet the conditions established by
ADR/RID/ADNR in chapter 3.4, only the following prescriptions shall be
complied with:
each package shall display a diamond-shaped figure with the following
inscription:
- 鈥楿N 3082'
or, in the case of different goods with different identification numbers
within a single package:
- the letters 'LQ'
Printing date : 02-2006 8/8
ACRYLITOP PC-100
15. Regulatory information
Classification according to directives 67/548/EEC and 1999/45/EC
Dangerous for the
environment
R51/53 : Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment
S61 : Avoid release to the environment. Refer to special
instructions/safety data sheets.
16. Other information
The information provided on this MSDS is correct to the best of our knowledge, information
and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release
and is not to be considered as a warranty or quality specification. The information relates
only to the specific material designated and may not be valid for such material used in
combination with any other material or in any process, unless specified in the text.
N.A. = NOT APPLICABLE
N.D. = NOT DETERMINED
(*) = INTERNAL CLASSIFICATION (NFPA)
Exposure limits:
TLV : Threshold Limit Value - ACGIH USA
OES : Occupational Exposure Standards - United Kingdom
MEL : Maximum Exposure Limits - United Kingdom
MAK : Maximale Arbeitsplatzkonzentrationen - Germany
TRK : Technische Richtkonzentrationen - Germany
MAC : Maximale aanvaarde concentratie - The Netherlands
VME : Valeurs limites de Moyenne d鈥橢xposition - France
VLE : Valeurs limites d鈥橢xposition 脿 court terme - France
GWBB : Grenswaarde beroepsmatige blootstelling - Belgium
GWK : Grenswaarde kortstondige blootstelling - Belgium
EC : Indicative occupational exposure limit values - directive 2000/39/EC
I : Inhalable fraction = T: Total dust = E: Einatembarer Aerosolanteil
R : Respirable fraction = A: Alveoleng盲ngiger Aerosolanteil/Alveolar dust
C : Ceiling limit
a: aerosol r: rook/Rauch (fume)
d: damp (vapour) st: stof/Staub (dust)
du: dust ve: vezel (fibre)
fa: Faser (fibre) va: vapour
fi: fibre om: oil mist
fu: fume on: olienevel/脰lnebel (oil mist)
p: poussi猫re (dust) part: particles
Chronic toxicity:
K : List of the carcinogenic substances and processes - The Netherlands
Full text of any R-phrases referred to under heading 2:
R22 : Harmful if swallowed
R50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment
Printing date : 02-2006 9/9
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