SAFETY DATA SHEET
Based on Directive 2001/58/EC of the Commission of the European Communities
EPDM BONDING ADHESIVE BA-2004(T)
1. Identification of the substance/preparation and of the company/undertaking
1.1 Identification of the substance or preparation:
Product name: EPDM BONDING ADHESIVE BA-2004(T)
Synonyms: none
CAS No. : N.A.
EC index No. : N.A. NFPA code : N.D.
EINECS No. : N.A. Molecular weight : N.A.
RTECS No. : N.A. Formula : N.A.
1.2 Use of the substance or the preparation:
Adhesive
1.3 Company/undertaking identification:
Firestone Building Products
Ikaroslaan 75
B-1930 Zaventem
Tel. : +32 2 711 44 50
Fax : +32 2 721 27 18
Email: info@fbpe.be
1.4 Telephone number for emergency:
+32 70 245 245
Poison Centre
p/a Militair Hospitaal Koningin Astrid, Bruynstraat 1, B-1120 Brussel
2. Composition/information on ingredients
Hazardous ingredients CAS No. Conc. in Hazard Risks
% symbol
EINECS/ELINCS No. (R-phrases)
n-hexane 110-54-3 50-75 F;Xn;N 11-38-48/20-51/53-
62-65-67 (1)
203-777-6
toluene 108-88-3 5-20 F;Xn 11-38-48/20-63-65-
67 (1)
203-625-9
(1) For R-phrases in full: see heading 16
3. Hazards identification
- Highly flammable
- Irritating to skin
- Harmful: danger of serious damage to health by prolonged exposure through
inhalation
- Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment
- Possible risk of impaired fertility
- Possible risk of harm to the unborn child
- Vapours may cause drowsiness and dizziness
4. First aid measures
4.1 Eye contact:
- Consult a doctor/medical service if irritation persists
- Rinse immediately with plenty of water
Printing date : 07-2007 1/1
Compiled by : Brandweerinformatiecentrum voor Gevaarlijke Stoffen vzw (BIG)
Technische Schoolstraat 43 A, B-2440 Geel
( +32 14 58 45 47 http://www.big.be E-mail: info@big.be
MSDS established : 30-05-2007 Revision date :
Reference number : BIG\43108GB-EPDM Revision number : 000
Reason for revision :
EPDM BONDING ADHESIVE BA-2004(T)
4.2 Skin contact:
- Consult a doctor/medical service if irritation persists
- Soap may be used
- Wash immediately with lots of water
4.3 After inhalation:
- Consult a doctor/medical service if breathing problems develop
- Remove the victim into fresh air
- Unconscious: maintain adequate airway and respiration
4.4 After ingestion:
- Consult a doctor/medical service if you feel unwell
- Never give water to an unconscious person
- Do not induce vomiting
5. Fire-fighting measures
5.1 Suitable extinguishing media:
- Water spray
- Polyvalent foam
- BC powder
- Carbon dioxide
5.2 Unsuitable extinguishing media:
- Solid water jet ineffective as extinguishing medium
5.3 Special exposure hazards:
- Gas/vapour spreads at floor level: ignition hazard
- May build up electrostatic charges: risk of ignition
- Upon combustion CO and CO2 are formed
5.4 Instructions:
- If exposed to fire cool the closed containers by spraying with water
- Take account of environmentally hazardous firefighting water
- Use firefighting water moderately and contain it
5.5 Special protective equipment for firefighters:
- Heat/fire exposure: compressed air/oxygen apparatus
- Large spills/in enclosed spaces: compressed air apparatus
6. Accidental release measures
6.1 Personal protection/precautions:
See heading 8.2/13
6.2 Environmental precautions:
- Prevent soil and water pollution
- Prevent spreading in sewers
- Contain leaking substance
- Dam up the liquid spill
- Try to reduce evaporation
6.3 Methods for cleaning up:
- Take up liquid spill into inert absorbent material, e.g.: sand/earth
- Scoop absorbed substance into closing containers
- Carefully collect the spill/leftovers
- Do not use compressed air for pumping over spills
- Clean contaminated surfaces with an excess of water
- Wash clothing and equipment after handling
- Take collected spill to manufacturer/competent authority
7. Handling and storage
7.1 Handling:
- Observe strict hygiene
- Use spark-/explosionproof appliances and lighting system
- Take precautions against electrostatic charges
- Handle uncleaned empty containers as full ones
- Do not discharge the waste into the drain
Printing date : 07-2007 2/2
EPDM BONDING ADHESIVE BA-2004(T)
7.2 Storage:
- Keep container tightly closed
- Ventilation at floor level
- Provide for a tub to collect spills
- Meet the legal requirements
- Keep away from: heat sources, ignition sources, oxidizing agents, acids,
bases
Storage temperature : N.D. 掳C
Quantity limits : N.D. kg
Storage life : N.D. days
Materials for packaging :
- suitable : no data available
- to avoid : no data available
7.3 Specific uses:
- See information supplied by the manufacturer
8. Exposure controls/Personal protection
8.1 Exposure limit values:
n-hexane
mg/m3
TLV-TWA : 50 ppm
mg/m3
TLV-STEL : - ppm
mg/m3
WEL-LTEL : 72 20 ppm
mg/m3
WEL-STEL :- - ppm
mg/m3
MAK : 180 50 ppm
mg/m3
TRGS900 : 180 50 ppm
mg/m3
MAC-TGG 8 h : 72
mg/m3
MAC-TGG 15 min. : 144
mg/m3
VME-8 h : 170 50 ppm
mg/m3
VLE-15 min. :- - ppm
mg/m3
GWBB-8 h : 179 50 ppm
mg/m3
GWK-15 min. :- - ppm
mg/m3
Momentary value : ppm
mg/m3
EC : 72 20 ppm
mg/m3
EC-STEL : ppm
toluene
mg/m3
TLV-TWA : 20 ppm
mg/m3
TLV-STEL : - ppm
mg/m3
WEL-LTEL : 191 50 ppm
mg/m3
WEL-STEL : 574 150 ppm
mg/m3
MAK : 190 50 ppm
mg/m3
TRGS900 : 190 50 ppm
mg/m3
MAC-TGG 8 h : 150
mg/m3
MAC-TGG 15 min. :
mg/m3
VME-8 h : 375 100 ppm
mg/m3
VLE-15 min. : 550 150 ppm
mg/m3
GWBB-8 h : 191 50 ppm
mg/m3
GWK-15 min. :- - ppm
mg/m3
Momentary value : ppm
mg/m3
EC : 192 50 ppm
mg/m3
EC-STEL : ppm
Printing date : 07-2007 3/3
EPDM BONDING ADHESIVE BA-2004(T)
Sampling methods:
- n-Hexane (Hydrocarbons, BP36 to 126C) NIOSH 1500
- n-Hexane OSHA 7
- Toluene (Hydrocarbons, aromatic) NIOSH 1501
- Toluene NIOSH 4000
- Toluene NIOSH 1500
- Toluene OSHA 07
- Toluene OSHA CSI
8.2 Exposure controls:
8.2.1 Occupational exposure controls:
- Measure the concentration in the air regularly
- Work under local exhaust/ventilation
8.2.1.1 respiratory protection:
- High vapour concentration: gas mask with filter A
8.2.1.2 hand protection:
- Gloves
Suitable materials: No data available
- Breakthrough time: N.D.
8.2.1.3 eye protection:
- Protective goggles
8.2.1.4 skin protection:
- Head/neck protection
- Protective clothing
Suitable materials: No data available
8.2.2 Environmental exposure controls: see heading 13
9. Physical and chemical properties
9.1 General information:
Appearance (at 20掳C) : Liquid
Odour : Aromatic
Colour : Yellow to green
9.2 Important health, safety and environmental information:
pH value : N.D.
Boiling point/boiling range : 65/110 掳C
Flashpoint : 0 掳C
Explosion limits : 1.1/7.5 vol% ( 掳C)
Vapour pressure (at 20掳C) : 49/133 hPa
Vapour pressure (at 50掳C) : N.D. hPa
Relative density (at 20掳C) : 0.79/0.89
Water solubility : Insoluble
Soluble in : N.D.
Relative vapour density : > 3.0
Viscosity : N.D. Pa.s
Partition coefficient n-octanol/water : N.D.
Evaporation rate
ratio to butyl acetate : N.D.
ratio to ether : N.D.
9.3 Other information:
Melting point/melting range : N.D. 掳C
Auto-ignition point : N.D. 掳C
g/m3
Saturation concentration : N.D.
Printing date : 07-2007 4/4
EPDM BONDING ADHESIVE BA-2004(T)
10. Stability and reactivity
10.1 Conditions to avoid/reactivity:
- Stable under normal conditions
10.2 Materials to avoid:
- Keep away from: heat sources, ignition sources, oxidizing agents, acids,
bases
10.3 Hazardous decomposition products:
- Upon combustion CO and CO2 are formed
11. Toxicological information
11.1 Acute toxicity:
LD50 oral rat : N.D. mg/kg
LD50 dermal rat : N.D. mg/kg
LD50 dermal rabbit : N.D. mg/kg
LC50 inhalation rat : N.D. mg/l/4 h
LC50 inhalation rat : N.D. ppm/4 h
11.2 Chronic toxicity:
EC carc. cat. : not listed
EC muta. cat. : not listed
EC repr. cat. : 3 (n-hexane) (toluene)
Carcinogenicity (TLV) : A4 (toluene)
Carcinogenicity (MAC) : not listed
Carcinogenicity (VME) : not listed
Carcinogenicity (GWBB) : not listed
Carcinogenicity (MAK) : not listed
Mutagenicity (MAK) : not listed
Teratogenicity (MAK) : C (n-hexane) (toluene)
IARC classification : 3(toluene)
11.3 Routes of exposure: ingestion, inhalation, eyes and skin
Caution! Substance is absorbed through the skin
11.4 Acute effects/symptoms:
- AFTER INHALATION
- EXPOSURE TO HIGH CONCENTRATIONS:
- Headache
- Nausea
- Irritation of the respiratory tract
- Irritation of the nasal mucous membranes
- Feeling of weakness
- Dizziness
- CNS depression
- Narcosis
- Mental confusion
- Drunkenness
- Coordination disorders
- Disturbed motor response
- Disturbances of consciousness
Printing date : 07-2007 5/5
EPDM BONDING ADHESIVE BA-2004(T)
- AFTER INGESTION
- Risk of aspiration pneumonia
- Nausea
- Abdominal pain
- CNS depression
- Symptoms similar to those listed under inhalation
- AFTER SKIN CONTACT
- Tingling/irritation of the skin
- AFTER EYE CONTACT
- Irritation of the eye tissue
11.5 Chronic effects:
- Possible risk of impaired fertility
- Possibly hazardous to the foetus
- Prolonged exposure: danger of damage to health
- through inhalation
- Causes damage to the central nervous system
- Not listed in carcinogenicity class (IARC,EC,TLV,MAK)
- Not listed in mutagenicity class (EC,MAK)
- ON CONTINUOUS/REPEATED EXPOSURE/CONTACT:
- Dry skin
- Skin rash/inflammation
- Impairment of the nervous system
- Tremor
- Impaired memory
- Impaired concentration
- Brain affection
- Disturbances of heart rate
- Change in the haemogramme/blood composition
- Movement disturbances
- Myasthenia
- Cramps/uncontrolled muscular contractions
- Paralysis
12. Ecological information
12.1 Ecotoxicity:
n-hexane:
- LC50 (96 h) : 113 mg/l (TILAPIA MOSAMBICA)
- EC50 (48 h) : 2.1 mg/l (DAPHNIA MAGNA)
- EC50 ( h) : 114 mg/l (CHLOROPHYTA)
12.2 Mobility:
- Volatile organic compounds (VOC): 55/95%
- Insoluble in water
For other physicochemical properties see heading 9
12.3 Persistence and degradability:
- biodegradation BOD5 : N.D. % ThOD
- water : - No data available
- soil : T 陆: N.D. days
12.4 Bioaccumulative potential:
- log Pow : N.D.
- BCF : N.D.
Printing date : 07-2007 6/6
EPDM BONDING ADHESIVE BA-2004(T)
12.5 Other adverse effects:
- WGK :2 (Classification based on the components in compliance
with Verwaltungsvorschrift wassergef盲hrdender Stoffe
(VwVwS) of 17 May 1999)
- Effect on the ozone layer : Not dangerous for the ozone layer
(1999/45/EC)
- Greenhouse effect : no data available
- Effect on waste water purification : no data available
13. Disposal considerations
13.1 Provisions relating to waste:
- Waste material code (91/689/EEC, Council Decision 2001/118/EC, O.J. L47 of
16/2/2001): 08 04 09* (waste adhesives and sealants containing organic
solvents or other dangerous substances)
- Hazardous waste (91/689/EEC)
13.2 Disposal methods:
- Incinerate under surveillance
- Do not discharge into drains or the environment
13.3 Packaging/Container:
- Waste material code packaging (91/689/EEC, Council Decision 2001/118/EC,
O.J. L47 of 16/2/2001): 15 01 10* (packaging containing residues of or
contaminated by dangerous substances)
Printing date : 07-2007 7/7
EPDM BONDING ADHESIVE BA-2004(T)
14. Transport information
33
1133
14.1 Classification of the substance in compliance with UN Recommendations
UN number : 1133
CLASS :3
SUB RISKS :-
PACKING : II
PROPER SHIPPING NAME :
UN 1133, Adhesives, Special provision 640D
14.2 ADR (transport by road)
CLASS : 3
PACKING : II
CLASSIFICATION CODE : F1
DANGER LABEL TANKS : 3
DANGER LABEL PACKAGES : 3
14.3 RID (transport by rail)
CLASS : 3
PACKING : II
CLASSIFICATION CODE : F1
DANGER LABEL TANKS : 3
DANGER LABEL PACKAGES : 3
14.4 ADNR (transport by inland waterways)
CLASS : 3
PACKING : II
CLASSIFICATION CODE : F1
DANGER LABEL TANKS : 3
DANGER LABEL PACKAGES : 3
14.5 IMDG (maritime transport)
CLASS : 3
SUB RISKS : -
PACKING : II
MFAG : -
EMS : F-E, S-D
MARINE POLLUTANT : -
14.6 ICAO (air transport)
CLASS : 3
SUB RISKS : -
PACKING : II
PACKING INSTRUCTIONS PASSENGER AIRCRAFT : 305/Y305
PACKING INSTRUCTIONS CARGO AIRCRAFT : 307
14.7 Special precautions in connection with : none
transport
14.8 Limited quantities (LQ) :
When substances and their packaging meet the conditions established by
ADR/RID/ADNR in chapter 3.4, only the following prescriptions shall be
complied with:
each package shall display a diamond-shaped figure with the following
inscription:
- 鈥楿N 1133'
or, in the case of different goods with different identification numbers
within a single package:
- the letters 'LQ'
Printing date : 07-2007 8/8
EPDM BONDING ADHESIVE BA-2004(T)
15. Regulatory information
Classification according to directives 67/548/EEC and 1999/45/EC
Highly flammable Harmful Dangerous for the
environment
contains: toluene; n-hexane
R11 : Highly flammable
R38 : Irritating to skin
R48/20 : Harmful: danger of serious damage to health by
prolonged exposure through inhalation
R51/53 : Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment
R62 : Possible risk of impaired fertility
R63 : Possible risk of harm to the unborn child
R67 : Vapours may cause drowsiness and dizziness
S07/09 : Keep container tightly closed in a well- ventilated
place
S16 : Keep away from sources of ignition - No smoking
S33 : Take precautionary measures against static discharges
S36/37 : Wear suitable protective clothing and gloves
S61 : Avoid release to the environment. Refer to special
instructions/safety data sheets.
15.2 National provisions:
Germany:
WGK :2 Classification based on the components in compliance with
Verwaltungsvorschrift wassergef盲hrdender Stoffe (VwVwS)
of 17 May 1999)
Printing date : 07-2007 9/9
EPDM BONDING ADHESIVE BA-2004(T)
16. Other information
The information provided on this MSDS is correct to the best of our knowledge, information
and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release
and is not to be considered as a warranty or quality specification. The information relates
only to the specific material designated and may not be valid for such material used in
combination with any other material or in any process, unless specified in the text.
N.A. = NOT APPLICABLE
N.D. = NOT DETERMINED
(*) = INTERNAL CLASSIFICATION (NFPA)
Exposure limits:
TLV : Threshold Limit Value - ACGIH USA
WEL : Workplace Exposure Limits - United Kingdom
MAK : Maximale Arbeitsplatzkonzentrationen - Germany
TRGS900:Technische Regeln f眉r Gefahrstoffe-Arbeitzplatzgrenzwerte - Germany
MAC : Maximale aanvaarde concentratie - The Netherlands
VME : Valeurs limites de Moyenne d鈥橢xposition - France
VLE : Valeurs limites d鈥橢xposition 脿 court terme - France
GWBB : Grenswaarde beroepsmatige blootstelling - Belgium
GWK : Grenswaarde kortstondige blootstelling - Belgium
EC : Indicative occupational exposure limit values - directive 2000/39/EC
I : Inhalable fraction = T: Total dust = E: Einatembarer Aerosolanteil
R : Respirable fraction = A: Alveoleng盲ngiger Aerosolanteil/Alveolar dust
C : Ceiling limit
a: aerosol r: rook/Rauch (fume)
d: damp (vapour) st: stof/Staub (dust)
du: dust ve: vezel (fibre)
fa: Faser (fibre) va: vapour
fi: fibre om: oil mist
fu: fume on: olienevel/脰lnebel (oil mist)
p: poussi猫re (dust) part: particles
Chronic toxicity:
K : List of the carcinogenic substances and processes - The Netherlands
Full text of any R-phrases referred to under heading 2:
R11 : Highly flammable
R38 : Irritating to skin
R48/20 : Harmful: danger of serious damage to health by prolonged exposure through
inhalation
R51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment
R62 : Possible risk of impaired fertility
R63 : Possible risk of harm to the unborn child
R65 : Harmful: may cause lung damage if swallowed
R67 : Vapours may cause drowsiness and dizziness
Printing date : 07-2007 10/10
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