Syngenta Crop Protection Canada, Inc.
MATERIAL SAFETY DATA SHEET
FORCE 庐3G
Date issued: 03-09-18 (Y/M/D)
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Company : Syngenta Crop Protection Canada, Inc.
140 Research Lane
Guelph
Ontario N1G 4Z3
Phone number :1-87S-YNGENTA (1-877-964-3682)
Emergency phone : 1-800-327-8633 (1-800-FASTMED)
: FORCE庐 3G
Name used on label
Product use : Insecticide
Formulation Number : A12868A
Registration Number : 23917
A Registered Trade Mark of a Syngenta group company.
Section 2 - COMPOSITION/INFORMATION ON INGREDIENTS
Identity CAS-no. Typical % Other information
TEFLUTHRIN TECHNICAL
79538-32-2 2 .. 4 % w/w
MONTMORILLONITE CLAY
85 .. 95 % w/w Including crystalline silica as
quartz (CAS no. 14808-60-7).
Methyl Oleate
112-62-9 5 .. 10 % w/w
Ingredients not precisely identified are proprietary or non hazardous.
Values are not product specifications.
Section 3 - HAZARDS IDENTIFICATION
Physical hazards:
None
Health hazards:
Harmful by inhalation, in contact with skin and if swallowed. Irritating
to eyes, respiratory system and skin. May cause sensitisation by
inhalation and skin contact.
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MATERIAL SAFETY DATA SHEET
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Section 4 - FIRST AID MEASURES
GENERAL ADVICE:
SPEED IS ESSENTIAL. OBTAIN IMMEDIATE MEDICAL ATTENTION.
IF IN EYES:
Immediately flush eyes with running water for a minimum of 20 minutes.
Hold eyelids open during flushing. If irritation persists, repeat
flushing. Obtain medical attention immediately.
IF ON SKIN:
Flush skin with running water for a minimum of 20 minutes. Start flushing
while removing contaminated clothing. If irritation persists, repeat
flushing. Obtain medical attention immediately.
IF SWALLOWED:
Provided the patient is conscious, wash out mouth with water. Immediately
contact Syngenta鈥檚 Emergency Information Network at 1-800-F-A-S-T-M-E-D
(327-8633). If spontaneous vomiting occurs, have the victim lean forward with
head down to avoid breathing in of vomitus, rinse mouth and administer
water. IMMEDIATELY contact local poison control centre. Vomiting should
only be induced under the direction of a physician or a poison control
center. Immediately transport victim to an emergency facility.
IF INHALED:
Remove victim to fresh air. If not breathing, give artificial respiration,
preferably mouth-to-mouth. If breathing is laboured, give oxygen. Obtain
immediate medical attention.
MEDICAL ADVICE:
Symptomatic treatment and supportive therapy as indicated.
Section 5 - FIRE FIGHTING MEASURES
Flash point: Not applicable (124掳C tefluthrin)
Flammable limits (STP): Not applicable
Autoignition temperature: Not applicable(445掳C tefluthrin)
Decomposition temperature: Not applicable(295掳C tefluthrin)
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EXTINGUISHING MEDIA:
Foam, carbon dioxide, water or dry chemical. Use water as a spray or fog;
avoid use of water jet. Water spray should be used to cool containers.
PROTECTIVE EQUIPMENT:
Self-contained breathing apparatus with full face-piece and protective
clothing
Unusual fire and explosion hazards:
None known.
Section 6 - ACCIDENTAL RELEASE MEASURES
METHODS FOR CLEANING UP:
Place sweepings in a chemical waste container for disposal. Do not allow
the material to enter streams, sewers or other waterways.
ADDITIONAL INFORMATION:
Seal drum and dispose of contaminated material in a facility permitted for
hazardous waste. Large spills should be handled according to spill plan.
Deactivating Chemicals:
None known.
Section 7 - HANDLING AND STORAGE
SAFE HANDLING ADVICE:
Take all precautions to avoid personal contact. Wear suitable protective
clothing.
REQUIREMENTS FOR STORAGE ROOMS:
Keep only in the original container in a cool, well-ventilated place. Keep
out of the reach of children and away from food.
ADDITIONAL INFORMATION:
Do not expose sealed containers to temperatures above 40 Deg. C.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Occupational exposure limits
Syngenta Standard TEFLUTHRIN TECHNICAL
8 hr TWA 0.04 mg/m鲁
Sk : Can be absorbed through skin
TLV/ACGIH MONTMORILLONITE CLAY
TWA 10 mg/m鲁
OSHA PEL MONTMORILLONITE CLAY
10 mg/m鲁
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ACGIH TLV crystalline silica, respirable
(Respirable Dust)
TWA 0.1 mg/m鲁
OSHA TLV crystalline silica, respirable
(Respirable Dust)
TWA 0.1 mg/m鲁
ENGINEERING CONTROLS:
Use ventilation adequate to maintain safe levels.
EYE PROTECTION:
Eye contact with the material should be avoided through the use of
chemical safety glasses, goggles or a face-shield, selected in regard to
exposure potential.
BODY PROTECTION:
Protective clothing as needed, impervious gloves, apron and arm covers.
User should verify impermeability under normal conditions of use prior to
general use.
RESPIRATORY PROTECTION:
If needed, use MSHA-NIOSH approved respirator for pesticides.
Other protective equipment:
Eyewash station and safety shower in work area
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Granule
Colour: tan-brown
Odour: None
Boiling point: Not applicable
Melting point: Not applicable (39 to 43掳C tefluthrin)
Vapor Pressure: 6 x 10-5 mmHg @ 20 掳C (tefluthrin)
Evaporation Rate: Not available.
Vapour density: Not applicable
Specific gravity: Not available.
Bulk density: 580 - 665 kg/m鲁
pH: 5.3 (1% dilution in deionized water)
Solubility in water: Insoluble (tefluthrin)
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Section 10 - STABILITY AND REACTIVITY
HAZARDOUS REACTIONS (CONDITIONS TO AVOID)
Stability: Stable at room temperature.
Incompatibility: Strong oxidizing agents.
Hazardous polymerization: Will not occur.
Conditions to avoid: High temperatures, sparks, open flames.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon dioxide, carbon monoxide and, possibly,
irritating gases.
Section 11 - TOXICOLOGICAL INFORMATION
ACUTE TOXICITY (LETHAL DOSES)
LD50 Oral male rats
Dose : 969 mg/kg
LD50 Oral female rats
Dose : 1213 mg/kg
Additional inform. : Irritant and can cause nausea and vomiting.
LD50 Dermal rat
Dose : > 2000 mg/kg
Additional inform. : In humans may cause tingling or numbness in exposed
areas (paraesthesia). The effect may result from
splash, aerosol or transfer to the face from
contaminated gloves and hands. This effect is
transient, lasting up to 24 hours.
LC50 Inhalation male rats
Dose : 1970 mg/m鲁/4H
LC50 Inhalation female rats
Dose : 1770 mg/m鲁/4H
Additional inform. : High concentrations of this product are irritating to
the respiratory tract.
ACUTE TOXICITY (IRRITATION, SENSITIZATION ETC.)
Eye contact
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Additional inform. : This material may cause mild irritation, redness and
possible damage due to the abrasiveness of this
granular material.
GENERAL INFORMATION ABOUT ACUTE OR OTHER TOXICITIES
General information
An ingredient (quartz) of this product is classified as a probably
carcinogenic by ACGIH or IARC. Studies in animals have shown that
repeated doses may produce carcinogenic effects.
There is no evidence of mutagenic potential. There is also no evidence of
adverse reproductive effects, teratogenicity or fetotoxicity in the
absence of maternal toxicity.
Section 12 - ECOLOGICAL INFORMATION
ECOTOXICITY
Assessment : Toxic to aquatic organisms.
Additional inform. : Do not contaminate domestic or irrigation water
supplies, drinking water, lakes, streams, ponds, or
rivers.
Section 13 - DISPOSAL CONSIDERATIONS
Disposal Method:
Dispose of in facility permitted for hazardous waste.
Section 14 - TRANSPORT INFORMATION
ROAD TRANSPORT DOT
Not Regulated By TDG
Section 15 - REGULATORY INFORMATION
HAZARDOUS INGREDIENTS
MONTMORILLONITE CLAY
Other regulations, restrictions and prohibitions
Pest Control Products (PCP) Act Registration No.:
23917
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Section 16 - OTHER INFORMATION
The information contained herein is offered only as a guide to the
handling of this specific material and has been prepared in good faith by
technically knowledgeable personnel. It is not intended to be
all-inclusive and the manner and conditions of use and handling may
involve other and additional considerations. No warranty of any kind is
given or implied and Syngenta will not be liable for any damages,
losses, injuries or consequential damages which may result from the use of
or reliance on any information contained herein. This Material Safety Data
Sheet is valid for three years. This product is under the jurisdiction of
the Pest Control Products Act and is exempt from the requirements for a
WHMIS compliant MSDS. Hazardous properties of all ingredients have been
considered in the preparation of this MSDS. Read the entire MSDS for the
complete hazard evaluation of this product.
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