MATERIAL SAFETY 3M
DATA SHEET 3M Center
St. Paul, Minnesota
55144-1000
1-800-364-3577 or (651) 737-6501 (24 hours)
Copyright, 2001, Minnesota Mining and Manufacturing Company.
All rights reserved. Copying and/or downloading of this
information for the purpose of properly utilizing 3M products
is allowed provided that:
1) the information is copied in full with no changes unless
prior agreement is obtained from 3M, and
2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.
DIVISION: INDUSTRIAL TAPE AND SPECIALTIES DIVISION
TRADE NAME:
SCOTCH BRAND SANDBLAST FILLER NO. 2
ID NUMBER/U.P.C.:
70-0708-7710-8 00-21200-43235-4 70-9020-1043-1 00-21200-10959-1
70-9020-1044-9 00-21200-10960-7
ISSUED: November 28, 2001
SUPERSEDES: October 24, 2000
DOCUMENT: 10-3354-7
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1. INGREDIENT C.A.S. NO. PERCENT
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HEPTANE................................. 142-82-5 30 - 40
METHYLHEXANES........................... TradeSecret 15 - 20
RUBBER.................................. 9003-31-0 5 - 10
ZINC OXIDE.............................. 1314-13-2 5 - 10
METHYLCYCLOHEXANE....................... 108-87-2 5 - 10
DIMETHYLPENTANES........................ TradeSecret 5 - 10
ROSIN................................... 8050-09-7 3 - 7
TOLUENE................................. 108-88-3 1.0 - 5.0
ETHYL ALCOHOL........................... 64-17-5 < 0.4
2,5-DI-TERT-AMYLHYDROQUINONE............ 79-74-3 < 0.2
ZINC OXIDE - EXPOSURE LIMITS - AS DUST
This product contains the following toxic chemical or chemicals subject to
the reporting requirements of Section 313 of Title III of the Emergency
Planning and Community Right-To-Know Act of 1986 and 40 CFR Part 372:
ZINC OXIDE
TOLUENE
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2. PHYSICAL DATA
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BOILING POINT:................. ca. 200 F
(HEPTANE)
VAPOR PRESSURE:................ N/D
VAPOR DENSITY:................. ca. 3.5 Air=1
(HEPTANE)
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SCOTCH BRAND SANDBLAST FILLER NO. 2
November 28, 2001 PAGE 2
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2. PHYSICAL DATA (continued)
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EVAPORATION RATE:.............. N/D
SOLUBILITY IN WATER:........... slight
SPECIFIC GRAVITY:.............. 0.732 Water=1 ASTM
PERCENT VOLATILE:.............. 78.2 % ASTM
pH:............................ N/A
VISCOSITY:..................... ca. 2000 centipoise Brookfield
MELTING POINT:................. N/D
APPEARANCE AND ODOR:
Paste, off-white, solvent odor
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3. FIRE AND EXPLOSION HAZARD DATA
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FLASH POINT:................... < 70 F COC
FLAMMABLE LIMITS - LEL:........ N/D
FLAMMABLE LIMITS - UEL:........ N/D
AUTOIGNITION TEMPERATURE:...... N/D
EXTINGUISHING MEDIA:
Water spray, Carbon dioxide, Dry chemical, Foam
SPECIAL FIRE FIGHTING PROCEDURES:
Wear full protective clothing, including helmet, self-contained,
positive pressure or pressure demand breathing apparatus, bunker coat
and pants, bands around arms, waist and legs, face mask, and
protective covering for exposed areas of the head. Water may not
effectively extinguish fire; however, it should be used to keep fire-
exposed containers and surfaces cool and prevent explosive rupture.
For leaks or spills which have not ignited, water spray can be used
to disperse the flammable vapor and protect personnel attempting to
stop the leak.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Vapors may travel long distances along the ground or floor to an
ignition source and flash back.
NFPA HAZARD CODES: HEALTH: 1 FIRE: 3 REACTIVITY: 0
UNUSUAL REACTION HAZARD: none
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4. REACTIVITY DATA
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STABILITY: Stable
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SCOTCH BRAND SANDBLAST FILLER NO. 2
November 28, 2001 PAGE 3
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4. REACTIVITY DATA (continued)
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INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID:
None known.
HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon Monoxide and Carbon Dioxide, Hydrocarbons, Oxides of Zinc.
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5. ENVIRONMENTAL INFORMATION
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SPILL RESPONSE:
Refer to other sections of this MSDS for information regarding
physical and health hazards, respiratory protection, ventilation, and
personal protective equipment. Ventilate area. Extinguish all
ignition sources. Evacuate unprotected personnel from hazard area.
Collect using non-sparking tools. Clean up residue with an
appropriate organic solvent. Read and follow safety precautions on
the solvent label and MSDS. Place in an approved metal container.
Seal the container.
RECOMMENDED DISPOSAL:
Incinerate in a permitted hazardous waste incinerator.
ENVIRONMENTAL DATA:
Not determined.
REGULATORY INFORMATION:
Volatile Organic Compounds: 573 gms/liter ASTM METHOD.
VOC Less H2O & Exempt Solvents: 573 gms/liter.
Since regulations vary, consult applicable regulations or authorities
before disposal. In the event of an uncontrolled release of this
material, the user should determine if the release qualifies as a
reportable quantity. U.S. EPA Hazardous Waste Number = D001
(Ignitable)
EPCRA HAZARD CLASS:
FIRE HAZARD: Yes PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: Yes
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6. SUGGESTED FIRST AID
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EYE CONTACT:
Immediately flush eyes with large amounts of water. Get immediate
medical attention.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SCOTCH BRAND SANDBLAST FILLER NO. 2
November 28, 2001 PAGE 4
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6. SUGGESTED FIRST AID (continued)
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SKIN CONTACT:
Flush skin with large amounts of water. If irritation persists, get
medical attention.
INHALATION:
Remove person to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, get immediate medical
attention.
IF SWALLOWED:
Do not induce vomiting. Drink two glasses of water. Call a physician.
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7. PRECAUTIONARY INFORMATION
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EYE PROTECTION:
Avoid eye contact. The following should be worn alone or in
combination, as appropriate, to prevent eye contact: Wear unvented
goggles during operations in which exposure is likely. Wear safety
glasses with side shields.
SKIN PROTECTION:
Avoid prolonged or repeated skin contact. Wear appropriate gloves
when handling this material. A pair of gloves made from the
following material(s) are recommended: nitrile rubber,
fluoroelastomer (Viton). Use one or more of the following personal
protection items as necessary to prevent skin contact: apron.
Protective garments (other than gloves) should be made of either of
the following materials: nitrile rubber, fluoroelastomer (Viton).
RECOMMENDED VENTILATION:
Use with appropriate local exhaust ventilation. Provide sufficient
ventilation to maintain emissions below recommended exposure limits.
If exhaust ventilation is not adequate, use appropriate respiratory
protection.
RESPIRATORY PROTECTION:
Avoid breathing of vapors. Select one of the following NIOSH
approved respirators based on airborne concentration of contaminants
and in accordance with OSHA regulations: half-mask organic vapor
respirator, full-face organic vapor respirator.
PREVENTION OF ACCIDENTAL INGESTION:
Do not eat, drink or smoke when using this product. Wash exposed
areas thoroughly with soap and water.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SCOTCH BRAND SANDBLAST FILLER NO. 2
November 28, 2001 PAGE 5
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7. PRECAUTIONARY INFORMATION (continued)
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RECOMMENDED STORAGE:
Store away from heat. Keep container closed when not in use. Keep
container in well-ventilated area.
FIRE AND EXPLOSION AVOIDANCE:
Keep container tightly closed. Keep away from heat, sparks, open
flame, and other sources of ignition. Ground containers securely
when transferring contents. Wear low static or properly grounded
shoes. No smoking while handling this material.
OTHER PRECAUTIONARY INFORMATION:
For industrial or professional use only.
EXPOSURE LIMITS
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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HEPTANE.............................. 400 PPM TWA ACGIH
HEPTANE.............................. 500 PPM STEL ACGIH
HEPTANE.............................. 400 PPM TWA OSHAV
OSHA VACATED PEL
HEPTANE.............................. 500 PPM STEL OSHAV
OSHA VACATED PEL
HEPTANE.............................. 500 PPM TWA OSHA
METHYLHEXANES........................ NONE NONE NONE NONE
RUBBER............................... NONE NONE NONE NONE
ZINC OXIDE........................... 10 MG/M3 TWA ACGIH
AS DUST
ZINC OXIDE........................... 10 MG/M3 TWA OSHAV
AS DUST
OSHA VACATED PEL
ZINC OXIDE........................... 5 MG/M3 TWA ACGIH
as fume
ZINC OXIDE........................... 10 MG/M3 STEL ACGIH
as fume
ZINC OXIDE........................... 5 MG/M3 TWA OSHA
as fume
ZINC OXIDE........................... 10 MG/M3 STEL OSHAV
as fume
OSHA VACATED PEL
ZINC OXIDE........................... 15 MG/M3 TWA OSHA
AS TOTAL DUST
ZINC OXIDE........................... 5 MG/M3 TWA OSHA
RESPIRABLE
METHYLCYCLOHEXANE.................... 400 PPM TWA ACGIH
METHYLCYCLOHEXANE.................... 400 PPM TWA OSHAV
OSHA VACATED PEL
METHYLCYCLOHEXANE.................... 500 PPM TWA OSHA
DIMETHYLPENTANES..................... NONE NONE NONE NONE
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SCOTCH BRAND SANDBLAST FILLER NO. 2
November 28, 2001 PAGE 6
EXPOSURE LIMITS (continued)
INGREDIENT VALUE UNIT TYPE AUTH SKIN*
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ROSIN................................ NONE NONE NONE NONE
TOLUENE.............................. 50 PPM TWA ACGIH Y
TOLUENE.............................. 100 PPM TWA OSHAV
OSHA VACATED PEL
TOLUENE.............................. 150 PPM STEL OSHAV
OSHA VACATED PEL
TOLUENE.............................. 200 PPM TWA OSHA
TOLUENE.............................. 300 PPM CEIL OSHA
TOLUENE.............................. 75 PPM STEL CMRG Y
ETHYL ALCOHOL........................ 1000 PPM TWA ACGIH
ETHYL ALCOHOL........................ 1000 PPM TWA OSHA
2,5-DI-TERT-AMYLHYDROQUINONE......... NONE NONE NONE NONE
* SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to
the potential contribution to the overall exposure by the cutaneous route
including mucous membrane and eye, either by airborne or, more particularly,
by direct contact with the substance. Vehicles can alter skin absorption.
SOURCE OF EXPOSURE LIMIT DATA:
- ACGIH: American Conference of Governmental Industrial Hygienists
- CMRG: Chemical Manufacturer Recommended Exposure Guidelines
- OSHA: Occupational Safety and Health Administration
- OSHAV: Occupational Safety and Health Administration Vacated PEL.
Vacated Permissible Exposure Limits (PEL) are enforced as
the OSHA PEL in some states. Check with your local
regulatory authority.
- NONE: None Established
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8. HEALTH HAZARD DATA
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EYE CONTACT:
Mild Eye Irritation: signs/symptoms can include redness, swelling,
pain, and tearing.
SKIN CONTACT:
Mild Skin Irritation: signs/symptoms can include redness, swelling,
and itching.
May be absorbed through the skin and produce effects similiar to
those caused by inhalation and/or ingestion.
Prolonged or repeated exposure may cause:
Allergic Skin Reaction: signs/symptoms can include redness,
swelling, blistering, and itching.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SCOTCH BRAND SANDBLAST FILLER NO. 2
November 28, 2001 PAGE 7
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8. HEALTH HAZARD DATA (continued)
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INHALATION:
Irritation (upper respiratory): signs/symptoms can include soreness
of the nose and throat, coughing and sneezing.
Prolonged or repeated overexposure, above recommended guidelines, may
cause:
Central Nervous System Depression: signs/symptoms can include
headache, dizziness, drowsiness, incoordination, slowed reaction
time, slurred speech, giddiness and unconsciousness.
IF SWALLOWED:
Ingestion may cause:
Irritation of Gastrointestinal Tissues: signs/symptoms can
include pain, vomiting, abdominal tenderness, nausea, blood in
vomitus, and blood in feces.
Central Nervous System Depression: signs/symptoms can include
headache, dizziness, drowsiness, muscular weakness,
incoordination, slowed reaction time, fatigue, blurred vision,
slurred speech, giddiness, tremors and convulsions.
REPRODUCTIVE/DEVELOPMENTAL TOXINS:
WARNING: Contains a chemical which can cause birth defects. (108-88-
3)
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SECTION CHANGE DATES
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PRECAUTIONARY INFO. SECTION CHANGED SINCE October 24, 2000 ISSUE
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SCOTCH BRAND SANDBLAST FILLER NO. 2
November 28, 2001 PAGE 8
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The information in this Material Safety Data Sheet (MSDS) is believed to
be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR
IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF
PERFORMANCE OR USAGE OF TRADE. User is responsible for determining
whether the 3M product is fit for a particular purpose and suitable for
user's method of use or application. Given the variety of factors that
can affect the use and application of a 3M product, some of which are
uniquely within the user's knowledge and control, it is essential that
the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers.
Due to the remote possibility that electronic transfer may have resulted
in errors, omissions or alterations in this information, 3M makes no
representations as to its completeness or accuracy. In addition,
information obtained from a database may not be as current as the
information in the MSDS available directly from 3M.
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