3M MATERIAL SAFETY DATA SHEET SCOTCHBRAND SANDBLAST FILLER NO. 3 11/05/2002
Material Safety Data Sheet
Copyright, 2002, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: SCOTCHBRAND SANDBLAST FILLER NO. 3
MANUFACTURER: 3M
DIVISION: Industrial Tape And Specialties Division
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 11/05/2002
Supercedes Date: 10/21/2002
Document Group: 11-4887-3
Product Use:
Intended Use: ADHESIVE SANDBLAST FILLER NO.3
Specific Use: ADHESIVE SANDBLAST FILLER NO. 3
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
RUBBER 9003-31-0 10 - 30
METHYLHEXANES mixture 15 - 25
METHYLCYCLOHEXANE 108-87-2 5 - 10 (typically 7.97)
DIMETHYLPENTANES mixture 3- 9
TOLUENE 108-88-3 1- 5
ETHYL ALCOHOL 64-17-5 1- 5
METHYL ALCOHOL 67-56-1 0- 2
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Viscous
Odor, Color, Grade: hydrocarbon odor, clear to light yellow in color
General Physical Form: Liquid
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3M MATERIAL SAFETY DATA SHEET SCOTCHBRAND SANDBLAST FILLER NO. 3 11/05/2002
Immediate health, physical, and environmental hazards: Extremely flammable liquid and vapor. May cause target organ
effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.
May be absorbed through skin and cause target organ effects.
Inhalation:
Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
May be absorbed following inhalation and cause target organ effects.
Ingestion:
Ingestion may cause:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting.
May be absorbed following ingestion and cause target organ effects.
Target Organ Effects:
Prolonged or repeated exposure may cause:
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination,
nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.
Prolonged or repeated exposure, above recommended guidelines, may cause:
Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and
jaundice.
Kidney Effects: Signs/symptoms may include reduced or absent urine production, increased serum creatinine, lower back
pain, increased protein in urine, and increased blood urea nitrogen (BUN).
Central Neuropathy: Signs/symptoms may include irritability, memory impairment, personality changes, sleep disorders, and
decreased ability to concentrate.
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3M MATERIAL SAFETY DATA SHEET SCOTCHBRAND SANDBLAST FILLER NO. 3 11/05/2002
Contains a chemical or chemicals which can cause birth defects or other reproductive harm.
Carcinogenicity:
NOTE: This product contains ethanol. In IARC published Monograph No. 44, entitled, "Alcohol Drinking", the carcinogenicity of
ethanol was determined based on chronic exposure to ethanol through human consumption of alcoholic beverages. This is not an
expected effect during the foreseeable use of this product.
Ingredient C.A.S. No. Class Description Regulation
ETHYL ALCOHOL 64-17-5 Group 1 International Agency for Research on
Cancer
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention.
Inhalation: Remove person to fresh air. If signs/symptoms persist, get medical attention.
If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person.
Get immediate medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
246 潞C
Autoignition temperature
<=-1 潞F [Test Method: Tagliabue Closed Cup] [Details:
Flash Point
SPECIFIC METHOD: ASTM D-56]
1%
Flammable Limits - LEL
7.1 %
Flammable Limits - UEL
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: ***Missing Data***
Unusual Fire and Explosion Hazards: Flammable liquid and vapor. Closed containers exposed to heat from fire may build
pressure and explode.
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3M MATERIAL SAFETY DATA SHEET SCOTCHBRAND SANDBLAST FILLER NO. 3 11/05/2002
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards,
respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information
on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up
by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non-
sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to
disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and
could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drains and build
dikes to prevent entry into sewer systems or bodies of water. Cover spill area with a fire-extinguishing foam. An aqueous film
forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or
commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an
absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible
using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the
area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Place in a metal container approved for
transportation by appropriate authorities. Seal the container. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Avoid eye contact. Avoid prolonged or repeated skin contact. Avoid breathing of fumes. Avoid vapor contact with open flame,
welding arcs or other high temperature sources which may causevapor decomposition to produce toxic gases. Do not eat, drink or
smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep container closed when not in use. Ground
containers securely when transferring contents. Wear low static or properly grounded shoes. For industrial or professional use only.
Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits.
If ventilation is not adequate, use respiratory protection equipment.
7.2 STORAGE
Store away from heat. Keep container tightly closed. Do not heat under confinement to avoid risk of explosion
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Do not use in a confined area or areas with little or no air movement. Provide local exhaust ventilation at transfer points. Use in a
well-ventilated area.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
The following eye protection(s) are recommended: Safety Glasses with side shields, Indirect Vented Goggles.
8.2.2 Skin Protection
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3M MATERIAL SAFETY DATA SHEET SCOTCHBRAND SANDBLAST FILLER NO. 3 11/05/2002
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Fluoroelastomer (Viton), Nitrile Rubber.
8.2.3 Respiratory Protection
Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with
OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges. Consult the current 3M
Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of Swallowing
Do not ingest. Wash hands after handling and before eating.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
ETHYL ALCOHOL ACGIH TWA 1000 ppm Table A4
ETHYL ALCOHOL OSHA TWA 1000 ppm Table Z-1
METHYL ALCOHOL ACGIH TWA 200 ppm Skin Notation*
METHYL ALCOHOL ACGIH STEL 250 ppm Skin Notation*
METHYL ALCOHOL OSHA TWA 200 ppm Skin Notation*; Table Z-1A
METHYL ALCOHOL OSHA STEL 250 ppm Skin Notation*; Table Z-1A
METHYLCYCLOHEXANE ACGIH TWA 400 ppm
METHYLCYCLOHEXANE OSHA TWA, 400 ppm
Vacated
METHYLCYCLOHEXANE OSHA TWA 500 ppm Table Z-1
TOLUENE ACGIH TWA 50 ppm Skin Notation*; Table A4
TOLUENE CMRG STEL 75 ppm Skin Notation*
TOLUENE OSHA TWA, 100 ppm
Vacated
TOLUENE OSHA STEL, 150 ppm
Vacated
TOLUENE OSHA TWA 200 ppm Table Z-2
TOLUENE OSHA CEIL 300 ppm Table Z-2
* Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous
membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter
skin absorption.
VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local
regulatory agency.
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Viscous
Specific Physical Form:
hydrocarbon odor, clear to light yellow in color
Odor, Color, Grade:
Liquid
General Physical Form:
246 潞C
Autoignition temperature
<=-1 潞F [Test Method: Tagliabue Closed Cup] [Details: SPECIFIC
Flash Point
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3M MATERIAL SAFETY DATA SHEET SCOTCHBRAND SANDBLAST FILLER NO. 3 11/05/2002
METHOD: ASTM D-56]
1%
Flammable Limits - LEL
7.1 %
Flammable Limits - UEL
Approximately 200 潞F [Details: CONDITIONS: (HEPTANE)]
Boiling point
0.70 g/ml
Density
Approximately 3.5 [Ref Std: AIR=1] [Details: CONDITIONS:
Vapor Density
(HEPTANE)]
44 mmHg [@ 20 潞C]
Vapor Pressure
0.776 [Test Method: ASTM METHOD] [Ref Std: WATER=1]
Specific Gravity
[Details: SPECIFIC METHOD: D-1475]
Not Applicable
pH
-132 潞C
Melting point
Slight (less than 10%)
Solubility in Water
No Data Available
Evaporation rate
2 - 5 % weight
Hazardous Air Pollutants
670 g/l [Test Method: ASTM METHOD] [Details: SPECIFIC
Volatile Organic Compounds
METHOD: D-3960]
86.44 % [Test Method: ASTM METHOD] [Details: SPECIFIC
Percent volatile
METHOD: D-2369]
670 g/l
VOC Less H2O & Exempt Solvents
Approximately 12000 centipoise [Test Method: Brookfield]
Viscosity
[Details: CONDITIONS: CALCULATED]
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: None known
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Hydrocarbons Not Specified
Carbon monoxide Not Specified
Carbon dioxide Not Specified
Oxides of Zinc Not Specified
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
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3M MATERIAL SAFETY DATA SHEET SCOTCHBRAND SANDBLAST FILLER NO. 3 11/05/2002
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
CHEMICAL FATE INFORMATION
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Dispose of according to the policies/procedures contained in the 3M Waste Management Program Manual
and the instructions provided on the Waste Stream Profile Reference Sheet. Consult your Waste Management (RCRA) Coordinator
with any questions. Consult 3M Waste Disposal Manual for proper procedures for packaging, labelling, marking, and shipping waste.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable)
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
41-3200-1173-1
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):
Ingredient C.A.S. No % by Wt
TOLUENE 108-88-3 1- 5
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3M MATERIAL SAFETY DATA SHEET SCOTCHBRAND SANDBLAST FILLER NO. 3 11/05/2002
STATE REGULATIONS
Contact 3M for more information.
CALIFORNIA PROPOSITION 65
Ingredient C.A.S. No. Classification
TOLUENE 108-88-3 *Developmental Toxin
* WARNING: contains a chemical or chemicals which can cause birth defects or other reproductive harm.
CHEMICAL INVENTORIES
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 1 Flammability: 3 Reactivity: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
Revision Changes:
Section 3: Carcinogenicity information was modified.
Section 3: Immediate other hazard(s) was modified.
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3M MATERIAL SAFETY DATA SHEET SCOTCHBRAND SANDBLAST FILLER NO. 3 11/05/2002
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
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