MATERIAL SAFETY DATA SHEET
Emergency Phone: 800-992-5994
Dow AgroSciences 鈥? Indianapolis, IN 46268
Effective Date: 01/01/98
TREFLAN* HFP HERBICIDE Product Code: 48048
MSDS: 005301
INHALATION: Single exposure to vapors is not likely to be
1. PRODUCT AND COMPANY IDENTIFICATION:
hazardous. The LC50 is 5.59 mg/L for male rats and >6.05
PRODUCT: TREFLAN* HFP HERBICIDE mg/L for female rats for 4 hours.
SYSTEMIC (OTHER TARGET ORGAN) EFFECTS: For
COMPANY IDENTIFICATION: trifluralin, in animals, has been shown to cause kidney,
Dow AgroSciences blood, and slight liver effects. Cataracts and other eye
P.O. Box 681428 effects have been reported in humans repeatedly exposed
9330 Zionsville Road to naphthalene vapor or dust.
Indianapolis, IN 46268-1189 CANCER INFORMATION: Contains naphthalene which
www.dowagro.com has caused cancer in some laboratory animals. A low
incidence of urinary tract tumors were seen in one strain of
2. COMPOSITION/INFORMATION ON INGREDIENTS:
rat in one chronic study of five 2-year studies on trifluralin
alpha, alpha, alpha-Trifluoro-2,6-dinitro- N,N-dipropyl- conducted in rats; trifluralin is not anticipated to be a
43.0% carcinogenic risk to man.
p-toluidine {Trifluralin} CAS# 001582-09-8
57.0% TERATOLOGY (BIRTH DEFECTS): Trifluralin did not
Other Proprietary Ingredients, Total:
cause birth defects; other fetal effects occurred only at
doses toxic to the mother.
This document is prepared pursuant to the OSHA Hazard
Communication Standard (29 CFR) 1910.1200). In addition, REPRODUCTIVE EFFECTS: Trifluralin did not interfere
with reproduction in animal studies.
other substances not 鈥楬azardous鈥? per this OSHA Standard
may be listed. Where proprietary ingredient shows, the
4. FIRST AID:
identity may be made available as provided in this
standard.
EYES: Irrigate with flowing water immediately and
3. HAZARDOUS IDENTIFICATIONS: continuously for 15 minutes. Consult medical personnel.
SKIN: Wash off in flowing water or shower.
EMERGENCY OVERVIEW INGESTION: If swallowed, seek medical attention. Do not
Hazardous Chemical. Clear, orange liquid. Aromatic odor. induce vomiting unless directed to do so by medical
Flash point 210掳F. May cause eye irritation. Harmful if personnel.
swallowed, inhaled or absorbed through skin. May cause INHALATION: Remove to fresh air if effects occur. Consult
skin sensitization in certain individuals. Closed containers a physician.
may explode due to pressure build-up when subjected to NOTE TO PHYSICIAN: No specific antidote. Supportive
excessive heat or fire. Toxic fumes are released in fire care. Treatment based on judgment of the physician in
situations. Product is toxic to fish, wildlife, and avian. response to reactions of the patient.
EMERGENCY PHONE NUMBER: (U.S.) 800-992-5994
5. FIRE FIGHTING MEASURES:
POTENTIAL HEALTH EFFECTS: This section includes
FLASH POINT: 210掳F, 99掳C
possible adverse effects which could occur if this material
METHOD USED: PMCC
is not handled in the recommended manner.
FLAMMABLE LIMITS (data based on solvent, 77掳F, 25掳C)
EYE: May cause moderate eye irritation. Corneal injury is
LFL: 1.8% approximately UFL: 11.8% approximately
unlikely.
SKIN: Short single exposure may cause skin irritation. May HAZARDOUS COMBUSTION PRODUCTS: Hazardous
cause drying or flaking of skin. A single prolonged exposure combustion products may include but are not limited to:
is not likely to result in the material being absorbed through nitrogen oxides, carbon monoxide, carbon dioxide and
flourinated hydrocarbons.
skin in harmful amounts. The LD50 for skin absorption in
rabbits is >5000 mg/kg. Has caused allergic skin reactions EXTINGUISHING MEDIA: Use water, CO2, or dry
chemicals.
when tested in guinea pigs.
INGESTION: Single dose oral toxicity is considered to be
low. Small amounts that might be swallowed incidental to
normal handling operations are not likely to cause injury;
swallowing larger amounts may cause injury. The oral LD50
for rats is 3700 mg/kg.
*Trademark of Dow AgroSciences
1
MATERIAL SAFETY DATA SHEET
Emergency Phone: 800-992-5994
Dow AgroSciences 鈥? Indianapolis, IN 46268
Effective Date: 01/01/98
TREFLAN* HFP HERBICIDE Product Code: 48048
MSDS: 005301
(Note: naphthalene is a component of the solvent). PELs
FIRE-FIGHTING INSTRUCTIONS: Dense smoke emitted
are in accord with those recommended by OSHA, as in the
when burned without sufficient oxygen. Keep people away.
1989 revision of PELs.
Isolate fire area and deny unnecessary entry. Closed
ENGINEERING CONTROLS: Provide general and/or local
containers may explode due to pressure build- up when
subjected to excessive heat or intense fire. Containers exhaust ventilation to control airborne levels below the
exposed to intense heat from fires should be kept cool with exposure guidelines.
water to prevent container weakening or rupture. Move EYE/FACE PROTECTION: Use chemical goggles.
container from fire area if this is possible without hazard. RESPIRATORY PROTECTION: Atmospheric levels should
Contain fire water run-off if possible. Fire water run-off if be maintained below the exposure guideline. When
not contained may cause environmental damage. respiratory protection is required for certain operations, use
PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS: Wear a NIOSH approved air-purifying respirator.
positive-pressure self- contained breathing apparatus SKIN PROTECTION: Use glove impervious to this
(SCBA) and protective fire fighting clothing (includes fire material.
fighting helmet, coat, pants, boots and gloves).
9. PHYSICAL AND CHEMICAL PROPERTIES:
6. ACCIDENTAL RELEASE MEASURES:
(See Section 15 for Regulatory Information) BOILING POINT (solvent): 450 to 527 F, 232 to 275掳C
PROTECT PEOPLE: Clear non-emergency personnel from VAPOR PRESSURE (solvent): < 1 mm Hg @ 68掳F, 20掳C
VAPOR DENSITY (solvent): 4.7 (relative to air)
area.
ENVIRONMENTAL PRECAUTIONS: This pesticide is toxic SOLUBILITY IN WATER: Emulsifies in water
SPECIFIC GRAVITY: 1.12 approximately
to fish. Prevent product from entering sewers and natural
APPEARANCE: Clear deep orange liquid
waters.
ODOR: Aromatic odor pH: (aqueous 50/50) 5.0 to 8.0
METHODS OF CLEANUP: Use nonreactive absorbent
material to contain and clean-up small spills. Large spills 10. STABILITY AND REACTIVITY:
report to CHEMTREC and contact Dow AgroSciences for
guidance. Prohibit use of hot or sparking equipment in CHEMICAL STABILITY: Stable under recommended
immediate area. Prevent runoff. storage conditions.
CONDITIONS TO AVOID: Avoid freezing
7. HANDLING AND STORAGE: INCOMPATIBILITY WITH OTHER MATERIALS: Avoid
contact with strong oxidizers.
HANDLING: Users should wash hands before eating, HAZARDOUS DECOMPOSITION PRODUCTS: Hazardous
drinking, chewing gum, using tobacco, or using the toilet. decomposition products depend upon temperature, air
Use only as directed on the label. supply, and the presence of other materials. Hazardous
STORAGE: Store in original container only. Avoid freezing. decomposition products may include but are not limited to:
Store above 40掳F. If frozen, poor weed control may result. carbon dioxide and monoxide, nitrogen oxides, and
Do not store near heat or open flame. fluorinated hydrocarbons.
HAZARDOUS POLYMERIZATION: Will not occur.
8. EXPOSURE CONTROLS / PERSONAL
PROTECTION: 11. TOXICOLOGICAL INFORMATION:
These precautions are suggested for conditions with a high (See section 3 for potential health effects. For detailed
potential for exposure. If handling procedures are such that toxicological data, write the address shown in Section 1 or
there is only a low potential for exposure, less protection call the emergency number)
may be needed. Emergency conditions may require
additional precautions. MUTAGENICITY: For trifluralin, in-vitro mutagenicity
EXPOSURE GUIDELINES: Aromatic 200 (petroleum studies were negative. Animal mutagenicity studies were
solvent): none established. Supplier recommends a predominantly negative.
guideline of 100 ppm for the total product which is a
mixture of aromatic hydrocarbons. Naphthalene: ACGIH
TLV and OSHA PEL are 10 ppm TWA, 15 ppm STEL
*Trademark of Dow AgroSciences
2
MATERIAL SAFETY DATA SHEET
Emergency Phone: 800-992-5994
Dow AgroSciences 鈥? Indianapolis, IN 46268
Effective Date: 01/01/98
TREFLAN* HFP HERBICIDE Product Code: 48048
MSDS: 005301
12. ECOLOGICAL INFORMATION:
U.S. REGULATIONS
(For detailed ecological data, write the address shown in
Section 1 or call the emergency number) SARA 313 INFORMATION: This product contains the
following substances subject to the reporting requirements
ENVIRONMENTAL FATE: of Section 313 of Title III of the Superfund Amendments
MOVEMENT & PARTITIONING: Based largely or and Reauthorization Act of 1986 and 40 CFR Part 372:
completely on information for trifluralin. Bioconcentration
potential is moderate (BCF between 100 and 3000 or Log Chemical Name CAS Number Concentration
Pow between 3 and 5). Potential for mobility in soil is slight TRIFLURALIN {BENZENEAMINE, 2,6-DINITRO-N)
(Koc between 2000 and 5000). 001582-09-8 43 %
DEGRADATION & PERSISTENCE: Based largely or
completely on information for trifluralin. Based on the SARA HAZARD CATEGORY: This product has been
stringent test guidelines, this material cannot be considered reviewed according to the EPA "Hazard Categories"
as readily biodegradable; however, these results do not promulgated under Sections 311 and 312 of the Superfund
necessarily mean that the material is not biodegradable Amendment and Reauthorization Act of 1986 (SARA Title
under environmental conditions. III) and is considered, under applicable definitions, to meet
ECOTOXICOLOGY: Based largely or completely on the following categories:
information for trifluralin. Material is very highly toxic to An immediate health hazard
aquatic organisms on an acute basis (LC50/EC50 <0.1 A delayed health hazard
mg/L in most sensitive species).
TOXIC SUBSTANCES CONTROL ACT (TSCA):
13. DISPOSAL CONSIDERATIONS:
All ingredients are on the TSCA inventory or are not
required to be listed on the TSCA inventory.
DISPOSAL METHOD: Do not contaminate food, feed, or
STATE RIGHT-TO-KNOW: The following product
water by storage or disposal. Pesticide wastes are toxic.
components are cited on certain state lists as mentioned.
Improper disposal or excess pesticide, spray mixture, or
Non-listed components may be shown in the composition
rinsate is a violation of federal law. If wastes resulting from
section of the MSDS.
the use of this product cannot be disposed of according to
Chemical Name CAS Number List
label instructions, dispose of these wastes at an approved
TRIFLURALIN {BENZENEAMINE, 2,6-DINITRO-N,N-DIP
facility. Contact your state pesticide or environmental
001582-09-8 NJ2 NJ3 PA1 PA3
control agency, or the hazardous waste representative at
the nearest EPA regional office for guidance.
NJ2=New Jersey Environmental Hazardous Substance
14. TRANSPORT INFORMATION: (present at greater than or equal to 1.0%).
NJ3=New Jersey Workplace Hazardous Substance
Environmentally Hazardous Substance, Liquid.
(present at greater than or equal to 1.0%).
N.O.S./(Trifluralin)/9/ UN3082/PG III/RQ (Trifluralin).
PA1=Pennsylvania Hazardous Substance (present at
greater than or equal to 1.0%).
15. REGULATORY INFORMATION:
PA3=Pennsylvania Environmental Hazardous Substance
NOTICE: The information herein is presented in good faith (present at greater than or equal to 1.0%).
and believed to be accurate as of the effective date shown
above. However, no warranty, express or implied, is given. OSHA HAZARD COMMUNICATION STANDARD:
Regulatory requirements are subject to change and may This product is a "Hazardous Chemical" as defined by the
differ from one location to another; it is the buyer鈥檚 OSHA Hazard Communication Standard, 29 CFR
responsibility to ensure that its activities comply with 1910.1200.
federal, state or provincial, and local laws. The following
specific information is made for the purpose of complying
with numerous federal, state or provincial, and local laws
and regulations.
*Trademark of Dow AgroSciences
3
MATERIAL SAFETY DATA SHEET
Emergency Phone: 800-992-5994
Dow AgroSciences 鈥? Indianapolis, IN 46268
Effective Date: 01/01/98
TREFLAN* HFP HERBICIDE Product Code: 48048
MSDS: 005301
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA)
RATINGS:
Health 2
Flammability 2
Reactivity 1
COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA, or
SUPERFUND):
This product contains the following substance(s) listed as
"Hazardous Substances" under CERCLA which may require
reporting of releases:
Category:
Chemical CAS Number RQ % in Product
Trifluralin 001582-09-8 10 43%
16. OTHER INFORMATION:
MSDS STATUS: Revised Sections 3, 8, 11, 12
Replaces MSDS dated: 2/12/97
The Information Herein Is Given In Good Faith, But No
Warranty, Express Or Implied, Is Made. Consult Dow
AgroSciences For Further Information.
*Trademark of Dow AgroSciences
4
|