Material Safety Data Sheet
Section 1. Chemical Product and Company Identification
XC102W
Product Name X-CIDE庐 102W INDUSTRIAL BACTERICIDE Code
Baker Petrolite 2.0
Supplier Version
A Division of Baker Hughes Canada, Inc.
5050 47th Street S.E.
Calgary, Alberta, T2B 3S1, Canada
For Product Information: 403-537-3850 or 281-276-5400
(8:00 a.m. - 5:00 p.m. cst, Monday - Friday)
Industrial Bactericide
Material Uses Effective Date 4/22/2003
CANUTEC 613-996-6666 (Canada 24 hours) 4/22/2003
24 Hour Emergency Print Date
Baker Petrolite 800-231-3606 (North America 24 hour)
Numbers
CHEMTREC 800-424-9300 (U.S. 24 hour)
WHMIS (Pictograms) WHMIS (Classification)
B-2, D-1B, D-2A, D-2B
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the Material
Safety Data Sheet contains all information required by the CPR.
Flammability
National Fire Protection
3
Association (U.S.A.)
3 0
Health Reactivity
Specific Hazard
Section 2. Composition and Information on Ingredients
Name CAS # % by Weight Exposure Limits
1) Isopropanol 67-63-0 10-30 TWA: 490 STEL: 980 (mg/m 3) from ACGIH (TLV)
TWA: 200 STEL: 400 (ppm) from ACGIH (TLV)
TWA: 400 STEL: 500 (ppm) from OSHA (PEL)
TWA: 980 STEL: 1225 (mg/m 3) from OSHA (PEL)
2) Glutaraldehyde 111-30-8 10-30 CEIL: 0.05 (ppm) from ACGIH (TLV)
CEIL: 0.2 (ppm) from OSHA (PEL)
3) Methanol 67-56-1 0.1-1 TWA: 262 STEL: 328 (mg/m 3) from ACGIH (TLV) SKIN
TWA: 200 STEL: 250 (ppm) from ACGIH (TLV) SKIN
TWA: 200 STEL: 250 (ppm) from OSHA (PEL) SKIN
TWA: 260 STEL: 325 (mg/m 3) from OSHA (PEL) SKIN
Please consult with local authorities for acceptable provincial exposure limits since values can vary from jurisdiction to jurisdiction.
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Section 3. Hazards Identification
Physical State and State: Liquid., Color: Amber., Odor: Characteristic.
Appearance
Hazard Summary DANGER. May cause chronic effects. Flammable liquid. Vapors can form an ignitable or explosive
mixture with air. Can form explosive mixtures at temperatures at or above the flash point. Vapors can
flow along surfaces to a distant ignition source and flash back. Static discharges can cause ignition or
explosion when container is not bonded. May be irritating to eyes, skin and respiratory tract. May cause
skin sensitization (allergic reaction). May cause respiratory tract sensitization (allergic reaction).
Routes of Exposure Skin (Contact), Eyes, Inhalation.
Potential Acute Health
Effects
Eyes May be corrosive to the eyes. May cause eye burns and permanent eye injury.
Skin May be severely irritating to the skin. May cause burns on prolonged contact. Skin sensitizer. May cause
allergic skin reactions with repeated exposure.
Inhalation Not considered a likely route of exposure, however, may cause central nervous system (CNS) and/or
irritation effects if inhaled. May be severely irritating to the lungs. May cause respiratory sensitization, an
allergic reaction.
Ingestion Not considered a likely route of exposure, however, may be corrosive if swallowed.
Medical Conditions Exposure to this product may aggravate medical conditions involving the following: nervous system,
aggravated by Exposure respiratory tract, skin/epithelium, eyes.
See Toxicological Information (section 11)
Additional Hazard Glutaraldehyde is a potent skin sensitizer. Persons may already be sensitized to glutaraldehyde before
Identification Remarks exposure in the workplace through contact with glutaraldehyde-containing medictions and tanned
leather.
Section 4. First Aid Measures
Eye Contact Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and
lower eyelids. Get medical attention if irritation occurs.
Skin Contact Remove contaminated clothing and shoes immediately. Wash affected area with soap and mild
detergent and large amounts of water until no evidence of chemical remains (approximately 15-20
minutes). Get medical attention immediately.
Inhalation Remove to fresh air. Oxygen may be administered if breathing is difficult. If not breathing, administer
artificial respiration and seek medical attention. Get medical attention if symptoms appear.
Ingestion Get medical attention immediately. If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Wash out mouth with water if person is conscious. Never induce vomiting or give
anything by mouth to a victim who is unconscious or having convulsions.
Notes to Physician Not available.
Additional First Aid EYE CONTACT: Corrosive to the eyes! Direct contact will cause severe irritation and possibly burns
Remarks and permanent eye damage. Mists and vapors may cause moderate to severe eye irritation.
SKIN CONTACT: May cause severe irritation and dermatitis. Prolonged contact may cause burns.
Repeated skin contact may cause allergic sensitization. In such cases, minor contact may result in
allergic rashes.
INHALATION: Intense irritation may occur. Prolonged, repeated, or high exposures may cause
chemical pneumonitis and in extreme cases pulmonary edema. Prolonged, repeated or high exposures
may cause central nervous system depression with headaches, nausea, drowsiness, dizziness, narcosis
and in extreme cases, loss of consciousness and coma.
INGESTION: Harmful if swallowed. May cause severe irritation, gastrointestinal disturbances, and
possibly burns. Cardiovascular disturbances may occur. Other effects may be similar as those from
inhalation.
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Section 5. Fire Fighting Measures
Flammability of the ProductFlammable liquid. Vapors can form an ignitable or explosive mixture with air. Can form explosive
mixtures at temperatures at or above the flash point. Vapors can flow along surfaces to a distant ignition
source and flash back. Static discharges can cause ignition or explosion when container is not bonded.
Autoignition temperature Not available.
Flash Points CLOSED CUP: 28掳C (82掳F). (SFCC)
Flammable Limits L.E.L. Not available. U.E.L. Not available.
Products of Combustion These products are carbon oxides (CO, CO2).
Fire Hazards in Presence ofOpen Flames/Sparks/Static. Heat.
Various Substances
Fire Fighting Media In case of fire, use foam, dry chemicals, or CO2 fire extinguishers. Evacuate area and fight fire from a
and Instructions safe distance. Water spray may be used to keep fire-exposed containers cool. Keep water run off out of
sewers and public water ways. Note that flammable vapors may form an ignitable mixture with air.
Vapors may travel considerable distances and flash back if ignited.
Protective Clothing (Fire) Do not enter fire area without proper personal protective equipment, including NIOSH approved
self-contained breathing apparatus.
Special Remarks on Fire Not available.
Hazards
Section 6. Accidental Release Measures
Spill Put on appropriate personal protective equipment. Keep personnel removed and upwind of spill. Shut
off all ignition sources; no flares, smoking, or flames in hazard area. Approach release from upwind.
Shut off leak if it can be done safely. Contain spilled material. Keep out of waterways. Dike large spills
and use a non-sparking or explosion proof means to transfer material to an appropriate container for
disposal. For small spills add absorbent (soil may be used in the absence of other suitable materials)
scoop up material and place in a sealed, liquid-proof container. Note that flammable vapors may form an
ignitable mixture with air. Vapors may travel considerable distances from spill and flash back, if ignited.
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Additional Accidental Not available.
Release Measures
Remarks
Section 7. Handling and Storage
Handling and Storage Put on appropriate personal protective equipment. Avoid contact with eyes, skin, and clothing. Avoid
breathing vapors or spray mists. Use only with adequate ventilation. Store in a dry, cool and well
ventilated area. Keep away from heat, sparks and flame. Keep away from incompatibles. Keep
container tightly closed and dry. To avoid fire or explosion, ground container equipment and personnel
before handling product.
Additional Handling and Not available.
Storage Remarks
Section 8. Exposure Controls/Personal Protection
Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors
or particles below their respective threshold limit value. Ensure that eyewash stations and safety
showers are proximal to the work-station location.
Personal Protection
Personal Protective Equipment recommendations are based on anticipated known manufacturing and use conditions. These
conditions are expected to result in only incidental exposure. A thorough review of the job tasks and conditions by a safety
professional is recommended to determine the level of personal protective equipment appropriate for these job tasks and conditions.
Eyes Chemical safety goggles.
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Body Wear long sleeves to prevent repeated or prolonged skin contact.
Respiratory Respirator use is not expected to be necessary under normal conditions of use. In poorly ventilated
areas, emergency situations or if exposure levels are exceeded, use NIOSH approved full face
respirator.
Hands Chemical resistant gloves.
Feet Chemical resistant boots or overshoes.
Other information Butyl rubber gloves. Neoprene gloves.
Protective Clothing
(Pictograms)
Additional Exposure Not available.
Control Remarks
Section 9. Typical Physical and Chemical Properties
Physical State and Odour
Liquid. Characteristic.
Appearance
pH Colour
3 - 4.5 (Neat - without dilution) Amber.
Specific gravity 0.993 - 1.005 @ 16掳C (60掳F)
Vapour Density >1 (Air = 1)
Vapour Pressure Not Available or Not Applicable for Solids.
Boiling Point Not available.
Evaporation Rate >1 (compared to Ether (anhydrous)).
VOC Not available.
Viscosity 12 - 14 cps
Pour Point Not available.
Solubility (Water) Soluble
Odour threshold Not available.
Partition coefficient Not available.
Physical Chemical Not available.
Comments
Section 10. Stability and Reactivity
Stability and Reactivity The product is stable.
Conditions of Instability Not available.
Incompatibility with Oxidizing material.
Various Substances
Hazardous Decomposition Not applicable.
Products
Hazardous Polymerization Hazardous polymerization is not expected to occur.
Special Stability & Not available.
Reactivity Remarks
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Section 11. Toxicological Information
Component Toxicological Information
Acute Animal Toxicity
1) Isopropanol ORAL (LD50): Acute: 5045 mg/kg [Rat]. 3600 mg/kg [Mouse].
DERMAL (LD50): Acute: 12800 mg/kg [Rabbit]. VAPOR (LC50):
Acute: 16000 ppm 8 hours [Rat].
2) Glutaraldehyde ORAL (LD50): Acute: 100 mg/kg [Mouse]. 134 mg/kg [Rat].
3) Methanol ORAL (LD50): Acute: 5628 mg/kg [Rat]. 7300 mg/kg [Mouse].
DERMAL (LD50): Acute: 15800 mg/kg [Rabbit].
Chronic Toxicity Data
1) Isopropanol
Isopropanol, a component of this product. Ingestion has produced hyperglycemia (high blood sugar) in humans (Lacouture, P, et al,
1983, "American Journal of Medicine" and Chan K-M, et al, 1993, "Clinical Chemistry").
In a four month study, inhalation of isopropanol vapors for 20 hours per week by laboratory animals produced bronchitis, pneumonia,
and blood effects (International Program of Chemical Safety, 1990, Environmental Health Criteria 103: 2-propanol, World Health
Organization). Ataxia (a jerky or shaky movement that occurs during voluntary muscle movement) and microscopic hyaline droplets
(fungal or branched structures) in the kidneys were seen in rats exposed to isopropanol at concentrations up to 5000 ppm for 6 hours
per day, 5 days per week, for 13 weeks (Burleighflayer et al, 1994). Inhalation of high levels of isopropanol (4,000 and 8,000 ppm for 8
hours) has produced congestion in the liver, lungs, and spleen of laboratory animals (Laham S, et al, 1980, "Drug and Chemical
Toxicology).
In addition, isopropanol has shown to be a fetotoxin in tests on laboratory animals [Nelson, BK et al (1988), Food and Chemical
Toxicology, 26(3), pps 247-254].
2) Glutaraldehyde
Glutaraldehyde is a component of this product. In long-term experimental animal studies, glutaraldehyde caused liver damage in mice
(ACGIH, 1992), but it was not neurotoxic in rats (Spencer et al, 1978).
Female rats had increased large granular lymphocytic leukemias after receiving glutaraldehyde in the drinking water at levels up to
1,000 ppm for 2 years (Andersen, 1996).
The results of genetic studies have been mixed with no conclusive evidence of positive effects.
In 2-year inhalation studies, there was no evidence of carcinogenic activity in male or female rats exposed to 250, 500 or 750 ppb, or in
male or female mice exposed to 62.5, 125, or 250 ppb glutaraldehyde. (OSHA ceiling limit is 0.2 ppm, ACGIH ceiling limit is 0.095
ppm). Incidences of nasal and respiratory lesions were increasedin both male/female rats and mice. Reduction in body weight, as
compared to the controls was also noted.
3) Methanol
Methanol is a component of this product. Because methanol is eliminated from the body more slowly than ethanol, it can have
cumulative toxicity with repeated exposures (ACGIH, 1992).
Methanol was mutagenic in yeast (RTECS). Methanol has caused chromosome aberrations in yeast (RTECS) and grasshoppers
(Saha & Khudabaksh, 1974).
Methanol has caused birth defects in rats exposed by the oral (Infurna et al, 1981) and inhalation (Nelson et al, 1984; Nelson et al,
1985) routes. Exencephaly (a defect in the skull bone structure that leaves the brain exposed) and cleft palate (a fissure or unformed
bone structure in the roof of the mouth (palate), lip, or facial area, occurring during the embryonic stage of development) were
increased in fetal mice exposed to methanol at an airborne concentration of 5,000 ppm or higher for 7 hours/day on days 6 to 15 of
gestation.
Embryotoxicity and fetotoxicity were seen with maternal exposure to airborne concentrations of 7,500 ppm and above, and reduced
fetal weights with concentrations of 10,000 ppm or greater. The NOAEL was 1,000 ppm. Effects similar to those seen in the 10,000
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ppm dosage group were also seen in offspring of mice given a dose of 4 g/kg orally (Rogers et al, 1993).
Product Toxicological Information
Acute Animal Toxicity Not available.
Target Organs nervous system, respiratory tract, skin/epithelium, eyes.
Other Adverse Effects Not available.
Section 12. Ecological Information
Ecotoxicity Not available.
BOD5 and COD Not available.
Biodegradable/OECD Not available.
Toxicity of the Products of Not available.
Biodegradation
Special Remarks An EcoTox鈩? Report, and/or the material's environmental fate is available upon request at the following
number:
1-800-235-4249, then press 4.
Section 13. Disposal Considerations
Responsibility for proper waste disposal rests with the generator of the waste. Dispose of any waste material in accordance with all
applicable federal, state and local regulations. Note that these regulations may also apply to empty containers, liners and rinsate.
Processing, use, dilution or contamination of this product may cause its physical and chemical properties to change.
Additional Waste Remarks Not available.
Section 14. Transport Information
TDG Classification
FLAMMABLE LIQUID, N.O.S., (contains Isopropanol), Class 3,
UN1993, PG III
Marine Pollutant Not applicable.
Additional TDG informationNot available.
Emergency Response 128
Guide Page Number
Section 15. Regulatory Information
Canadian Regulations
Environmental National Pollutant Release Inventory: Isopropanol; Methanol;
Regulations
DSL Inventory All components are compliant with or are exempted from listing on the Canadian Domestic Substance
List.
TSCA Inventory All components are included or are exempted from listing on the US Toxic Substances Control Act
Status Inventory.
This product contains the following components that are subject to the reporting requirements of TSCA
Section 12(b) if exported from the United States: Isopropanol.
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International Regulations
European Union All components are included or are exempted from listing on the European Inventory of Existing
Commercial Chemical Substances or the European List of Notified Chemical Substances.
International inventory status information is available upon request from Baker Petrolite for the following
countries: Australia, and Australia (NICNAS), China, Korea (TCCL), Philippines (RA6969), or Japan.
Harmonized Tariff Code Not available.
Other Regulatory In Canada, this product is subject to regulation under the Pest Control Products Act (PCPA) and is
Information therefore exempt from Environment Canada鈥檚 Domestic Substance List (DSL) Inventory requirements.
Pest Control Products Act Registration No. 24569.
Offshore Chemical Notification Scheme (OCNS) rating: Group C
Section 16. Other Information
Other Special File 17
Considerations 04/22/03 - Changes to Sections 2, 5 and 8.
Baker Petrolite Disclaimer
NOTE: The information on this MSDS is based on data which is considered to be accurate. Baker Petrolite, however, makes no
guarantees or warranty, either expressed or implied of the accuracy or completeness of this information.
The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our
knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense
arising out of or in any way connected with the handling, storage, use or disposal of this product.
This MSDS was prepared and is to be used for this product. If the product is used as a component in another product, this MSDS
information may not be applicable.
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