****MATERIAL SAFETY DATA SHEET****
MANUFACTURER: EMERGENCY TELEPHONE NO.:
800-424-9300 or 703-527-3887 Chemtrec
STAR BRITE DISTRIBUTING, INC.
4041 S. W. 47 AVENUE INFORMATION TELEPHONE NO.:
FT. LAUDERDALE, FL 33314 954-587-6280
DATE OF PREPARATION: August 17, 2006
SECTION I: PRODUCT IDENTIFICATION
PRODUCT NAME: STAR BRITE ANTI-FREEZE CHEMICAL NAME: ETHYLENE GLYCOL
PRODUCT NUMBER: 30200, 302G55, 601013 CHEMICAL FAMILY: GLYCOL
SECTION II-A: PRODUCT/INGREDIENT
NO. COMPOSITION CAS NUMBER PERCENT
P STAR BRITE ANTI-FREEZE MIXTURE 100
1 ETHYLENE GLYCOL 107-21-1 84-94
2 DIETHYLENE GLYCOL 111-46-6 0-10
3 WATER 7732-18-5 2-4
4 INORGANIC/ORGANIC SALTS 2-4
NFPA HAZARD RATING: HEALTH 1 FIRE 0 REACTIVITY 0
SECTION II-B: ACUTE TOXICITY DATA
NO. ACUTE ORAL LD50 ACUTE DERMAL LD50 ACUTE INHALATION LC50
1 4.0 G/KG (RAT) NONE NONE
2 14.8 G/KG (RAT) 11.9G/KG (RAT) NONE
SECTION III: HEALTH INFORMATION
THE HEALTH EFFECTS NOTED BELOW ARE CONSISTENT WITH REQUIREMENTS UNDER THE OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910. 1200).
EYE CONTACT: BASED ON PRESENCE OF COMPONENT 1, PRODUCT IS MODERATELY TO SEVERELY
IRRITATING TO THE EYES. VAPORS CAN ALSO CAUSE SEVERE EYE IRRITATION.
SKIN CONTACT: BASED ON PRESENCE OF COMPONENTS 1 AND 2, PRODUCT IS MILDLY IRRITATING TO
THE SKIN AND SLIGHTLY TOXIC ON PROLONGED OR REPEATED CONTACT.
INHALATION: VAPORS ARE MILDLY TO MARKEDLY IRRITATING TO THE LUNGS DEPENDING ON THE
EXPOSURE LEVEL.
INGESTION: PRODUCT MAY BE HARMFUL OR FATAL IF SWALLOWED; MAY PRODUCE CENTRAL
NERVOUS SYSTEM (CNS) DEPRESSION AND KIDNEY DAMAGE WHICH MAY BE FATAL.
INGESTION OF COMPONENT 2 MAY ALSO PRODUCE LIVER DAMAGE.
SIGNS AND
SYMPTOMS: IRRITATION AS NOTED ABOVE. EARLY TO MODERATE CNS DEPRESSION MAY BE
EVIDENCED BY GIDDINESS, HEADACHE, DIZZINESS AND NAUSEA. IN EXTREME CASES,
UNCONSCIOUSNESS AND DEATH MAY OCCUR. KIDNEY DAMAGE MAY BE EVIDENCED
BY CHANGES IN URINE OUTPUT, URINE APPEARANCE OR EDEMA (SWELLING FROM
FLUID RETENTION). LIVER DAMAGE MAY BE EVIDENCED BY LOSS OF APPETITE,
JAUNDICE (YELLOWISH SKIN COLOR) AND SOMETIMES PAIN IN THE UPPER ABDOMEN
ON THE RIGHT SIDE.
PRODUCT NAME: Star brite Anti-Freeze
PRODUCT NUMBER: 30200, 302G55, 601013
SECTION III: HEALTH INFORMATION CONT鈥橠
AGGRAVATED MEDICAL
CONDITIONS: PREEXISTING SKIN, EYE AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY
EXPOSURE TO THIS PRODUCT. IMPAIRED KIDNEY AND LIVER FUNCTIONS FROM
PREEXISTING DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT.
OTHER HEALTH
EFFECTS: INTENTIONAL ABUSE. MISUSE OR OTHER MASSIVE EXPOSURE MAY CAUSE MULTIPLE
ORGAN DAMAGE AND/OR HEALTH.
SEE SECTION VI FOR ADDITIONAL INFORMATION.
SECTION IV: OCCUPATIONAL EXPOSURE LIMITS
OSHA ACGIH OTHER
NO. PEL/TWA PEL/CEILING TLV/TWA TLV/STEL
----------------------------------------------------------------------------------------------------------------------------------------------------------------
1 50 PPM 39.4 PPM*
*CEILING (AEROSOL)
SECTION V: EMERGENCY AND FIRST AID PROCEDURES
EYE CONTACT: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE
HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION.
SKIN CONTACT: FLUSH SKIN WITH WATER. IF IRRITATION OCCURS, GET MEDICAL ATTENTION.
INHALATION: REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS DIFFICULT. GET
MEDICAL ATTENTION.
INGESTION: DO NOT GIVE LIQUIDS IF VICTIM IS UNCONSCIOUS OR VERY DROWSY. OTHERWISE, GIVE
NO MORE THAN 2 GLASSES OF WATER AND INDUCE VOMITING BY GIVING 30CC (2
TABLESPOONS) SYRUP OF IPECAC.* IF IPECAC IS UNAVAILABLE, GIVE 2 GLASSES OF
WATER AND INDUCE VOMITING BY TOUCHING FINGER TO BACK OF VICTIM'S THROAT.
KEEP VICTIM'S HEAD BELOW HIPS WHILE VOMITING. GET MEDICAL ATTENTION.
NOTE TO PHYSICIAN
*IF VICTIM IS A CHILD, GIVE NO MORE THAN 1 GLASS OF WATER AND 15CC (1 TABLESPOON) OF SYRUP OF
IPECAC. IF SYMPTOMS SUCH AS LOSS OF GAG REFLEX, CONVULSIONS OR UNCONSCIOUSNESS OCCUR
BEFORE EMESIS, GASTRIC LAVAGE SHOULD BE CONSIDERED FOLLOWING INTUBATION WITH A CUFFED
ENDOTRACHEAL TUBE.
SECTION VI: SUPPLEMENTAL HEALTH INFORMATION
RARE CASE REPORTS OF ETHYLENE GLYCOL SENSITIZATION (ALLERGY) HAVE BEEN PUBLISHED BUT
ALLERGY TO ETHYLENE GLYCOL IS NOT A COMMON PHENOMENON.
IN ONE STUDY, WHEN ETHYLENE GLYCOL WAS ADMINISTERED IN THE DIET AT DAILY DOSES UP TO 1.0 G/KG
TO PREGNANT RATS. NO MATERIAL TOXICITY, NO EMBRYOTOXICITY NOR TERATOGENICITY WERE
OBSERVED. IN A MORE RECENT STUDY, WHEN ETHYLENE GLYCOL WAS ADMINISTERED BY GAVAGE AT
DAILY DOSES OF 1.25 G/KG AND ABOVE TO PREGNANT RATS, OR AT 750 MG/KG AND ABOVE TO PREGNANT
MICE, THERE WAS AN INCREASE IN THE NUMBER OF MALFORMED FETUSES AT ALL DOSE LEVELS. EXCEPT
AT THE LOWEST DOSE LEVEL IN MICE, THERE WAS ALSO EVIDENCE OF MATERNAL TOXICITY AT ALL DOSE
LEVELS.
PRODUCT NAME: Star brite Anti-Freeze
PRODUCT NUMBER: 30200, 302G55, 601013
SECTION VI: SUPPLEMENTAL HEALTH INFORMATION CON鈥橳
IN ONE STUDY, DIETHYLENE GLYCOL ADMINISTERED ORALLY AT HIGH DOSES TO PREGNANT RATS AND MICE
CAUSED TOXICITY TO THE EMBRYOFETUS INCLUDING DECREASED FETAL BODY WEIGHTS AND INCREASED
VARIATIONS. BUT NO BIRTH DEFECTS WERE OBSERVED. THERE WAS ALSO MATERNAL TOXICITY INCLUDING
SOME LETHALITY.
IN ANOTHER STUDY, DIETHYLENE GLYCOL ADMINISTERED TO HAMSTERS BY I.P. INJECTION AT DOSES OF 2.5
- 4.48 G/KG ON THE 8TH DAY OF GESTATION RESULTED IN NEURAL TUBE ABNORMALITIES IN ALL DOSE
GROUPS BUT NOT IN THE CONTROLS. THERE WAS EVIDENCE OF MATERNAL TOXICITY IN TREATED ANIMALS.
UNDER THE CONDITIONS OF THIS STUDY, DEG CAUSED DEVELOPMENTAL EFFECTS IN HAMSTERS. THE
SIGNIFICANT OF THIS INFORMATION TO MAN IS UNKNOWN.
SECTION VII: PHYSICAL DATA
BOILING POINT: 330-340 SPECIFIC GRAVITY: 1.1373 VAPOR PRESSURE: N/AV
(DEG F) (H20=1) (MM HG)
MELTING POINT: N/AV SOLUBILITY: COMPLETE VAPOR DENSITY: >1
(DEG F) (IN WATER) (AIR=1)
EVAPORATION RATE (N-BUTYL ACETATE = 1): <0.01 POUR POINT =
-40 DEG. F
PH: 10.5
NITRATE: 2400 PPM
SILICON: <250 PPM
APPEARANCE AND ODOR: COLORLESS TO GREEN, SLIGHTLY VISCOUS LIQUID. MILD ODOR.
SECTION VIII: FIRE AND EXPLOSION HAZARDS
FLASH POINT AND METHOD: FLAMMABLE LIMITS /% VOLUME IN AIR
246掳F (118.88掳C) SETAFLASH LOWER: N/AP UPPER: N/AP
EXTINGUISHING MEDIA:
USE WATER FOG, "ALCOHOL" FOAM, DRY CHEMICAL OR CO2.
SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS:
MATERIAL WILL NOT BURN UNLESS PREHEATED. DO NOT ENTER CONFINED FIRE SPACE WITHOUT FULL
BUNKER GEAR (HELMET WITH FACE SHIELD, BUNKER COATS, GLOVES AND RUBBER BOOTS), INCLUDING A
POSITIVE PRESSURE NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
CONTAINERS WITH WATER.
SECTION IX: REACTIVITY
STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
CONDITIONS AND MATERIALS TO AVOID:
KEEP AWAY FROM STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON MONOXIDE AND UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED DURING COMBUSTION.
PRODUCT NAME: Star brite Anti-Freeze
PRODUCT NUMBER: 30200, 302G55, 601013
SECTION X: EMPLOYEE PROTECTION
RESPIRATORY PROTECTION:
IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL EXPOSURE LIMITS (SEC. IV) USE A NIOSH-APPROVED
RESPIRATOR TO PREVENT OVEREXPOSURE. IN ACCORD WITH 29 CFR 1910.134 USE EITHER AN
ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR-PURIFYING RESPIRATOR FOR ORGANIC VAPORS.
PROTECTIVE CLOTHING:
AVOID CONTACT WITH EYES. WEAR CHEMICAL GOGGLES IF THERE IS LIKELIHOOD OF CONTACT WITH EYES.
AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. WEAR CHEMICAL RESISTANT GLOVES AND OTHER
CLOTHING AS REQUIRED TO MINIMIZE CONTACT. TEST DATA FROM PUBLISHED LITERATURE AND/OR GLOVE
PVC OR NATURAL RUBBER GLOVES.
ADDITIONAL PROTECTIVE MEASURES:
USE VENTILATION AS REQUIRED TO CONTROL VAPOR CONCENTRATIONS. EYE WASH FOUNTAINS AND
SAFETY SHOWERS SHOULD BE AVAILABLE FOR EMERGENCY USE.
SECTION XI: ENVIRONMENTAL PROTECTION
SPILL OR LEAK PROCEDURES:
MAY BURN ALTHOUGH NOT READILY IGNITABLE. USE CAUTIOUS JUDGMENT WHEN CLEANING UP LARGE
SPILLS. *** LARGE SPILLS *** WEAR RESPIRATOR AND PROTECTIVE CLOTHING AS APPROPRIATE. SHUT OFF
SOURCE OF LEAK IF SAFE TO DO SO. DIKE AND CONTAIN. REMOVE WITH VACUUM TRUCKS OR PUMP TO
STORAGE/SALVAGE VESSELS. SOAK UP RESIDUE WITH AN ABSORBENT SUCH AS CLAY, SAND OR OTHER
SUITABLE MATERIAL. DISPOSE OF PROPERLY. FLUSH ARE WITH WATER TO REMOVE TRACE RESIDUE.
*** SMALL SPILLS *** TAKE UP WITH AN ABSORBENT MATERIAL AND DISPOSE OF PROPERLY.
SECTION XII: SPECIAL PRECAUTIONS
STORE IN COOL, DRY PLACE WITH ADEQUATE VENTILATION. KEEP AWAY FROM FLAMES AND HIGH
TEMPERATURES.
WASH WITH SOAP AND WATER BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
SECTION XIII: TRANSPORTATION REQUIREMENTS
Call for information
SECTION XIV: OTHER REGULATORY CONTROLS
THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE EPA/TSCA INVENTORY OF CHEMICAL
SUBSTANCES.
PROTECTION OF STRATOSPHERIC OZONE (PURSUANT TO SECTION 611 OF THE CLEAR AIR ACT
AMENDMENTS OF 1990): PER 40 CFR PART 82, THIS PRODUCT DOES NOT CONTAIN NOR WAS IT DIRECTLY
MANUFACTURED WITH ANY CLASS I OR CLASS II OZONE DEPLETING SUBSTANCES.
IN ACCORDANCE WITH SARA TITLE III, SECTION 313, THE ATTACHED ENVIRONMENTAL DATA SHEET (EDS)
SHOULD ALWAYS BE COPIED AND SENT WITH THE MSDS.
PRODUCT NAME: Star brite Anti-Freeze
PRODUCT NUMBER: 30200, 302G55, 601013
SECTION XV: STATE REGULATORY INFORMATION
THE FOLLOWING CHEMICALS ARE SPECIFICALLY LISTED BY INDIVIDUAL STATES. OTHER PRODUCT SPECIFIC
HEALTH AND SAFETY DATA IN OTHER SECTIONS OF THE MSDS MAY ALSO BE APPLICABLE FOR STATE
REQUIREMENTS. FOR DETAILS ON YOUR REGULATORY REQUIREMENTS YOU SHOULD CONTACT THE
APPROPRIATE AGENCY IN YOUR STATE.
STATE LISTED COMPONENT PERCENT STATE CODE
ETHYLENE GLYCOL CA, CT, FL, IL, LA, MA, ME, MN, NJ, PA, RI
(CAS NO: 107-21-1) 84-94
DIETHYLENE GLYCOL 0-10 CA,MN,PA,RI
(CAS NO: 111-46-6)
CA = CALIFORNIA HAZ. SUBST. LIST: CA65C, CA65R, CA65C/R = CALIFORNIA SAFE DRINKING WATER AND
TOXICS ENFORCEMENT ACT OF 1986 OR PROPOSITION 65 LIST. CT = CONNECTICUT TOX. SUBST. LIST. FL =
FLORIDA SUBST. LIST. IL = ILLINOIS TOX. SUBST. LIST. LA = LOUISIANA HAZ. SUBST. LIST. MA =
MASSACHUSETTS HAZ. SUBST. LIST, ME = MAINE HAZ. SUBST. LIST. MN = MINNESOTA HAZ. SUBST. LIST. NJ =
NEW JERSEY HAZ. SUBST. LIST. PA = PENNSYLVANIA HAZ. SUBST. LIST. RI = RHODE ISLAND HAZ. SUBST.
LIST.
SECTION XVI: SPECIAL NOTES
THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE TO US AND IS BELIEVED TO BE
CORRECT. HOWEVER, STAR BRITE MAKES NO WARRANTY, EXPRESSED OR IMPLIED REGARDING THE
ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. STAR BRITE
ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN.
ENVIRONMENTAL DATA SHEET
EDS NUMBER: 80,070-4
PRODUCT: STAR BRITE ANTI-FREEZE
PRODUCT NO: 30200, 302G55, 601013
SECTION I: PRODUCT/COMPOSITION
P STAR BRITE ANTI-FREEZE MIXTURE 100
1 ETHYLENE GLYCOL 107-21-1 84-94
2 DIETHYLENE GLYCOL 111-46-6 0-10
3 WATER 1132-18-5 2-4
4 INORGANIC/ORGANIC SALTS 2-4
NFPA HAZARD RATING: HEALTH 1 FIRE 0 REACTIVITY 0
SECTION II: SARA TITLE III INFORMATION
NO. EHS RQ (LBS) EHS TPQ (LBS) SEC 313 313 CATEGORY 311/312 CATEGORIES
(*1) (*2) (*3) (*4) (*5)
P H-1, H-2
1 YES
-----------------------------------------------------------------------FOOTNOTES-----------------------------------------------------------------------
*1 = REPORTABLE QUANTITY OF EXTREMELY HAZARDOUS SUBSTANCE. SEC.302
*2 = THRESHOLD PLANNING QUANTITY, EXTREMELY HAZARDOUS SUBSTANCE. SEC.302
*3 = TOXIC CHEMICAL, SEC 313
*4 = CATEGORY AS REQUIRED BY SEC 313 (40 CFR 372.65 C), MUST BE USED ON TOXIC RELEASE
INVENTORY FORM
*5 = HAZARD CATEGORY FOR SARA SEC. 311/312 REPORTING
HEALTH H-1 = IMMEDIATE (ACUTE) HEALTH HAZARD H-2 = DELAYED (CHRONIC) HEALTH HAZARD
PHYSICAL P-3 = FIRE HAZARD P-4 = SUDDEN RELEASE OF PRESSURE HAZARD
P-5 = REACTIVE HAZARD
SECTION III: ENVIRONMENTAL RELEASE INFORMATION
EPA - COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT. UNDER EPA-
CERCLA ("SUPERFUND") RELEASES TO AIR, LAND OR WATER WHICH EXCEED THE REPORTABLE QUANTITY
MUST BE REPORTED TO THE NATIONAL RESPONSE CENTER, 800-424-8802.
THE REPORTABLE QUANTITY (RQ) FOR A RELEASE OF THIS PRODUCT IS 5,319 LBS., WHICH IS BASED ON THE
PRESENCE OF COMPONENT #1.
SECTION IV: RCRA INFORMATION
PLACE IN AN APPROPRIATE DISPOSAL FACILITY IN COMPLIANCE WITH LOCAL REGULATIONS.
THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE TO US AND IS BELIEVED TO BE
CORRECT. HOWEVER, STAR BRITE MAKES NO WARRANTY, EXPRESSED OR IMPLIED REGARDING THE
ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. STAR BRITE
ASSUMES NO RESPONSIBILITY FOR INJURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN.
DATE PREPARED: June 2, 2006
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