MATERIAL SAFETY DATA SHEET
Precharged, Fully-Formulated Extended Life
Antifreeze-G 05 (Concentrate)
SECTION 1 鈥? CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
30400, 304G55 鈥? 150,000 Antifreeze
Product/Chemical Name:
Ethylene Glycol Based Antifreeze, Precharged, Fully-formulated Extended Life
Product Description:
Antifreeze (Concentrate) with Dye
Inhibited Ethylene Glycol and Water Solution
Chemical Family:
Mixture
CAS Registry:
Manufacturer:
Star Brite Distributing, Inc.
4041 S. W. 47 Avenue
Ft. Lauderdale, Fl 33314
954-587-6280
Date: October 25, 2006 Supercedes: January 25, 2006
SECTION 2 鈥? COMPOSITION / INFORMATION ON INGREDIENTS
INGREDIENT CAS NO WT. RANGE % EXPOSURE LIMIT
*1,2-ethanediol (Ethylene Glycol) 107-21-1 94.0-95.0% 50ppm Ceiling-ACGIH
Diethlyene glycol 11-46-6 0-5% None established
Proprietary Additives and Inhibitors Not applicable <5.5% Not applicable
Dye Not applicable <1% Not applicable
Water 7732-18-5 Balance Not applicable
*Hazardous according to OSHA (1910.1200) or one or more state Right-to-Know lists.
SECTION 3 鈥? HAZARDOUS IDENTIFICATION
2
Health:
HMIS
1
Flammability:
#2
H
0
Reactivity:
#1
F
None
Special: #0
R
0 = minimal 1= slight 2=moderate 3= serious 4= severe
PPE鈥?
鈥燬ec. 8
Route(s) of Entry
Yes
Inhalation:
Yes
Skin:
Yes
Ingestion:
Yes
Eyes:
Kidneys and Liver
Target Organs:
Effects of overexposure:
Eyes: May cause minimal irritation, experienced as temporary discomfort.
Acute:
MSDS: Precharged, Fully-formulated Extended Life Antifreeze-G 05 Conc.
- - - FOR DISCLAIMER OF LIABILITY SEE FINAL PAGE - - - Page 1 of 6
Skin: Brief contact is not irritating. Prolonged contact, as with clothing wetted
Effects of overexposure
with material may cause defatting of skin or irritation, seen as local
(con鈥檛)
redness with possible mild discomfort. Other than the potential skin
Acute:
irritation effects noted above, acute (short term) adverse effects are not
expected from brief skin contact.
Inhalation: Vapors or mist, in excess of permissible concentrations, or in unusually
high concentrations generated from spraying, heating the material or as
from exposure in poorly ventilated areas or confined spaces, may cause
irritation of the nose and throat, headache, nausea, and drowsiness.
Prolonged or repeated overexposure may result in the absorption of
potentially harmful amounts of material.
Ingestion: Contains ethylene glycol and/or diethylene glycol, which are toxic when
swallowed. A lethal dose for an adult is 1-2 ml per kilogram, or about 4
ounces (one-half cup). Symptoms include headache, weakness,
confusion, dizziness, staggering, slurred speech, loss of concentration,
faintness, nausea and vomiting, increased heart rate, decreased blood
pressure, difficulty breathing and seeing, pulmonary edema,
unconsciousness, convulsions, collapse and coma. Symptoms may be
delayed. Decreased urine output and kidney failure may also occur.
Severe poisoning may cause death. Aspiration may occur during
swallowing or vomiting, resulting in lung damage.
Unknown
Sensitization Properties:
Signs and Symptoms of
See above 鈥淓ffects of Overexposure.鈥?
Exposure:
Medical Conditions Generally
Aggravated by Long-Term
Repeated overexposure may aggravate existing kidney disease.
Exposure:
Repeated ingestion may cause kidney damage
Chronic Effects:
Carcinogenicity
Not listed
NTP:
Not listed
IARC Monographs:
Not listed
OSHA Regulations:
Not listed
ACGIH
SECTION 4 鈥? FIRST AID MEASURES
Immediately flush with large quantities of water for at least 15
Emergency and Eye contact:
minutes and
First Aid Procedures:
Remove excess with cloth or paper towel. Wash thoroughly with
Skin contact:
soap and water. If irritation persists, get medical attention.
Immediately contact a physician, poison control center or
Ingestion:
emergency treatment center. DO NOT induce vomiting.
Aspiration Hazard: Product may be inhaled into lungs if vomited.
Remove to fresh air. Restore and/or support breathing as
Inhalation:
required. Keep victim warm and at rest.
Treat symptomatically
Note to Physicians:
Special Precautions/Procedures: None known
MSDS: Precharged, Fully-formulated Extended Life Antifreeze-G 05 Conc.
- - - FOR DISCLAIMER OF LIABILITY SEE FINAL PAGE - - - Page 2 of 6
SECTION 5 鈥? FIRE-FIGHTING MEASURES
None known
Unusual Fire Fighting procedures:
254潞F (123潞C) NFPA
Flash Point:
Not applicable
Flash Point Method:
1
Not applicable
Burning Rate:
2 0
Not determined
Autoignition Temperature:
0
Flammable limits in air (% by volume):
Not determined
LEL:
Not determined
UEL:
Does not burn, but can emit fumes in a fire.
Flammability Classification:
For large fires use alcohol-type or all purpose foam. For small fires use water
Extinguishing Media:
spray, dry chemical, foam or carbon dioxide to extinguish.
None known
Unusual Fire or Explosion Hazards:
According to the National Fire Protection Association Guide, use water spray,
Fire-Fighting Instructions;
dry chemical, foam or carbon dioxide. A direct stream of water or foam may
cause frothing. Use water spray to disperse the vapors and to provide
protection for person attempting to stop the leak.
Because fire may produce toxic thermal decomposition products, wear a self-
Fire-Fighting Equipment:
contained breathing apparatus (SCBA) with a full facepiece operated in
pressure-demand or positive-pressure mode.
Not required
Unusual Fire Fighting procedures:
Products evolved when subjected to heat or combustion: carbon monoxide
Other Information:
and carbon dioxide may be formed on burning in limited air supply.
SECTION 6 鈥? ACCIDENTAL RELEASE MEASURES
Ventilate area. Avoid breathing vapor. Wear appropriate personal protective
Spill/Leak Procedures:
equipment, including appropriate respiratory protection. Contain spill if
possible. Wipe up or absorb on suitable material and shovel up. Prevent entry
into sewers and waterways. Avoid contact with skin, eyes or clothing.
If more than 10,539 pounds of product is spilled, then report spill according to
Regulatory Requirements:
SARA 304 and/or CERCLA 102(a) requirements, unless product qualifies for
petroleum exemption (CERCLA Section 101 (14)).
SECTION 7 鈥? HANDLING AND STORAGE
Minimum feasible handling temperatures should be maintained. Empty
Handling Precautions
containers contain product residue and may be dangerous.
Periods of exposure to high temperature should be minimized. Water
Storage Requirements:
contamination should be avoided. Keep containers away from open flames.
ETHYLENE GLYCOL BASE 鈥? Ethylene Glycol has produced birth defects in
rodents. Do not store near food.
SECTION 8 鈥? EXPOSURE CONTROLS/PERSONAL PROTECTION
Normal to maintain exposure below TLV
Ventilation:
10mg/cubic meter for particulate mist; 50 ppm (125 mg/cubic meter) ceiling limit
Permissible Concentrations in Air:
for Ethylene Glycol (ACGIH 1984-1985)
Supplied air respiratory protection for cleaning large spills or upon entry into
Respiratory Protection:
tanks, vessels, or other confined spaces. Use a NIOSH approved organic vapor
and gas respirator with mist filter.
Chemical type goggles or face shield optional.
Eye Protection:
Wear chemically protective gloves, boots, aprons, and gauntlets to prevent
Protective Clothing/Equipment:
prolonged or repeated skin contact. Wear protective eyeglasses or chemical
safety goggles.
Exposed employees should exercise reasonable personal cleanliness; this
Work and Hygienic Practices:
includes cleansing exposed skin areas several times daily with soap and water,
and laundering or dry cleaning soiled work clothing at least weekly.
MSDS: Precharged, Fully-formulated Extended Life Antifreeze-G 05 Conc.
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Make emergency eyewash stations, safety/quick-drench showers, and washing
Safety Stations:
facilities available in work area.
Separate contaminated work clothes from street clothes. Launder before reuse.
Contaminated Equipment:
Remove this material from your shoes and clean personal protective
equipment.
Never eat, drink, or smoke in work areas. Practice good personal hygiene after
Comments:
using this material, especially before eating, drinking, smoking, using the toilet,
or applying cosmetics.
SECTION 9 鈥? PHYSICAL AND CHEMICAL PROPERTIES
Clear liquid with a mild odor (may contain dye in one of several colors).
Appearance and odor:
325潞F-330潞F
Boiling Point (760 mm Hg):
-34潞F
Freezing/Melting Point:
1.130-1.140
Specific Gravity (water =1):
1.8
Vapor Density (air =1):
NIL
Percent Volatile by Volume:
Not determined
Evaporation Rate (butyl acetate =1):
100%
Solubility in Water (% by wt):
Vapor Pressure (at 20潞C): 18mm Hg.
8.0-9.5
pH:
Less than 20cst
Viscosity SUS @ 100潞F
SECTION 10 鈥? STABILITY AND REACTIVITY
Stable
Stability:
Does not occur
Polymerization:
Normally unreactive, but try to avoid strong oxidizers, strong acids and strong
Chemical Incompatibilities:
bases at high temperatures.
High temperatures above 413潞C (775潞F) (product can decompose)
Conditions to Avoid:
Carbon dioxide, carbon monoxide
Hazardous decomposition products:
SECTION 11 鈥? TOXICOLOGICAL INFORMATION
Believed to cause slight eye irritation.
Eye Effects:
Can be irritating to skin upon prolonged contact
Skin Effects:
Acute Inhalation Effects: Drowsiness, narcosis, and unconsciousness possible upon exposure to high
concentrations in poorly ventilated confined spaces.
Can cause irritation to mouth, throat and stomach
Acute Oral Effects:
Liver and kidney damage in a 2 year rat feeding study using 1-2% Ethylene
Chronic Effects:
Glycol. Oral administration of very high doses of Ethylene Glycol produced
birth defects in laboratory animals.
Neither product nor its ingredients are listed by IARC, NTD or OSHA
Carcinogenicity:
Not mutagenic
Mutagenicity:
Not Teratogenic
Teratogenicity:
SECTION 12 鈥? ECOLOGICAL INFORMATION
Oral: Believed to be 4.7-8.5 g/kg (rat); moderately toxic
Ecotoxicity:
Inhalation: Not determined.
Dermal: Believed to be 1-3 g/kg (rabbit); slightly toxic
Other: Not determined.
Irritation Index/Estimation of Irritation (Species)
Skin: Believed to be 0.5-1.8/8.0 (rabbit); slightly irritating
Eyes: Believed to be 15-25/110 (rabbit); slightly irritating
Not determined
Soil Absorption/Mobility:
MSDS: Precharged, Fully-formulated Extended Life Antifreeze-G 05 Conc.
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SECTION 13 鈥? DISPOSAL CONSIDERATIONS
Dispose of waste in accordance with Federal, State and Local laws.
Waste Disposal Method:
Under RCRA, it is the responsibility of the user of products to determine, at
Disposal Regulatory Requirements:
the time of disposal, whether product meets RCRA criteria for hazardous
waste. This is because product uses transformations, mixture, processes,
etc., may render the resulting material hazardous (see waste classification)
Containers should be cleaned of residual product before disposal, and
Container Cleaning and Disposal:
disposed of in accordance with all applicable laws and regulations.
SECTION 14 鈥? TRANSPORT INFORMATION
Call for information.
SECTION 15 鈥? REGULATORY INFORMATION
EPA Regulations
RCRA Hazardous Waste Number and RCRA
Hazardous Waste Classification: Unused product is not classified as a hazardous waste by
RCRA criteria
CERCLA Hazardous Substance and CERCLA
Reportable Quantity: Does not contain any ingredients listed as a CERCLA
hazardous substance.
SARA Toxic Chemical and SARA EHS: Contains following substance which is listed in Title III:
Ethylene Glycol.
SARA 313 Information:
SARA Hazard Category: An immediate health hazard A
delayed health hazard
OSHA Regulations:
State Regulations
All components listed on both TSCA (USA) and DSL
Other:
(Canada) inventory.
CANADIAN WHMIS CLASSIFICATION: Class D, Division 2,
Subdivision B (A toxic material causing other chronic effects)
MSDS: Precharged, Fully-formulated Extended Life Antifreeze-G 05 Conc.
- - - FOR DISCLAIMER OF LIABILITY SEE FINAL PAGE - - - Page 5 of 6
SECTION 16 鈥? OTHER INFORMATION
Prepared By:
None
Additional Hazard Rating Systems:
Disclaimer: THE INFORMATION GIVEN HEREIN IS GIVEN IN GOOD FAITH AND FROM SOURCES WE BELIEVE
RELIABLE. BUT NO WARRANTY, EXPRESS OR IMPLIED, REGARDING ITS CORRECTNESS IS MADE.
The conditions or methods of handling, storage, use and disposal of this product are beyond our control and may be
beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for
loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of this
product.
This MSDS was prepared and is to be used only for this product. If the product is used as a component in another
product, this MSDS information may not apply.
CONSULT Company listed in Section 1. FOR FURTHER INFORMATION.
MSDS: Precharged, Fully-formulated Extended Life Antifreeze-G 05 Conc.
- - - FOR DISCLAIMER OF LIABILITY SEE FINAL PAGE - - - Page 6 of 6
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