MATERIAL SAFETY DATA SHEET
Prepared to U.S. OSHA, CMA, ANSI, Canadian WHMIS Standards and European Union Directives
PART I What is the material and what do I need to know in an emergency?
1. PRODUCT IDENTIFICATION
STARBRITE WATERPROOFING WITH PTEF®
TRADE NAME (AS LABELED):
CHEMICAL NAME/CLASS: Stoddard Solvent Mixture
PRODUCT USE: Wood Treatment
PRODUCT NUMBER: 81922, 81900N
MANUFACTURER'S NAME: STAR BRITE
U.S. ADDRESS: 4041 S.W. 47 Avenue
Ft. Lauderdale, FL 33314
U.S. EMERGENCY PHONE: Chemtrec
(800) 424-9300 or (703) 527-3887
U.S. INFORMATION PHONE: (954) 587-6280
INTERNATIONAL ADDRESS:
INTERNATIONAL EMERGENCY PHONE: 703-527-3887
INTERNATIONAL BUSINESS PHONE: 954-587-6280
DATE OF REVISION: July 25, 2006
2. COMPOSITION and INFORMATION ON INGREDIENTS
EU LABELING AND CLASSIFICATION: This product meets the definition of the hazard class of Toxic, as defined by the
European Economic Community Guidelines.
EU CLASSIFICATION: [T] Toxic; Carcinogenic Category 2; F [Flammable]
EU RISK PHRASES: [R: 10]: Flammable. [R: 45]: May cause cancer. [R: 65]: Harmful, may cause lung damage if swallowed.
EU SAFETY PHRASES: [S: 2-]: Keep out of the reach of children. (This safety phrase can be omitted from the label when the substance
or preparation is sold for industrial use only). [S: 23]: Do not breathe fumes, vapors or spray. [S: 24]: Avoid contact with skin. [S:
38]: In case of insufficient ventilation, wear suitable respiratory equipment. [S: 36/37]: Wear suitable protective clothing and gloves.
[S: 62]: If swallowed, do not induce vomiting. Seek medical advice immediately and show this container or label.
CHEMICAL NAME CAS # EINECS # % w/v EU CLASSIFICATION FOR COMPONENTS
Tetraisopropyl Titanate 546-68-9 208-909-6 0.3-1.0% HAZARD CLASSIFICATION: Not applicable.
RISK PHRASES: Not applicable.
Trimethylated Silica 68988-89-6 Unlisted 0.3-1.0% HAZARD CLASSIFICATION: Not applicable.
RISK PHRASES: Not applicable.
Xylene (mixed 1330-20-7 215-535-7 0.3-1.0% HAZARD CLASSIFICATION: Xn [Harmful], F [Flammable]
isomers) RISK PHRASES: Not applicable.
Stoddard Solvent 8052-41-3 232-489-3 99.0-100% HAZARD CLASSIFICATION: T [Toxic], Carcinogenic Category 2
RISK PHRASES: R: 45, R: 65
See Section 15 for full EU classification information of product and components.
NOTE: ALL Canadian WHMIS required information is included in appropriate sections based on the ANSI Z400.1-1998 format. This product has been
classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. The MSDS is also
prepared to include all European Union required information under EU Directives.
3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW: This product is a clear, light-yellow liquid with a kerosene/petroleum odor. Health Hazards:
Inhalation overexposures to mists or sprays of this product can cause central nervous system effects. Severe inhalation
exposures may be fatal. Eye contact may be irritating. Contact with the skin may be irritating, especially if prolonged.
Flammability Hazards: This product is flammable; vapors and liquid may ignite if exposed to an ignition source or if
heated to its flash point of 37.7-39°C (100-102°F). If involved in a fire, this product will produce irritating and toxic materials
such as various carbon oxides, hydrocarbons and aldehydes. Vapors of this product are heavier than air and can spread a
long distance to an ignition source and flashback. Reactivity Hazards: This product is not reactive. Environmental
Hazards: This material may be harmful or fatal to contaminated plant, animal, and aquatic life. Emergency
Recommendations: Although the odor threshold of Stoddard Solvent is below the TLV, it may not be a good warning
property as olfactory fatigue can occur. Emergency responders must wear the personal protective equipment suitable for
the situation to which they are responding.
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3. HAZARD IDENTIFICATION (Continued)
SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The
most significant routes of occupational overexposure are inhalation and HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
contact with skin and eyes. The symptoms of overexposure to this
product are described on the following page.
INHALATION: If this product inhaled, fume, mists or sprays can mildly (BLUE) 1
HEALTH HAZARD
irritate the respiratory system and cause coughing, sneezing, and
difficulty breathing. Depending on the concentration and duration of
exposure, inhalation overexposure can cause central nervous system
depression, including dizziness, headache, nausea, fatigue, vomiting
FLAMMABILITY HAZARD (RED) 3
and incoordination. Severe inhalation overexposure (as may occur in a
confined space with inadequate ventilation) may cause
unconsciousness and death. Chronic exposure may cause liver and
kidney damage.
CONTACT WITH SKIN or EYES: Skin contact can cause mild to PHYSICAL HAZARD (ORANGE) 0
moderate irritation, depending on the duration and concentration of
exposure. Symptoms of such overexposure may cause redness and
irritation. Prolonged or repeated skin contact with this product may
PROTECTIVE EQUIPMENT
cause dermatitis (dry, red, scaly skin) from defatting of the skin. Case
reports indicate that when Stoddard solvent is allowed to remain in
close contact with skin, as when clothing wet with Stoddard solvent is
EYES HANDS BODY
RESPIRATORY
worn, blisters and sores may develop. Eye contact with this product
may cause irritation, redness, and watering.
SKIN ABSORPTION: The components of this product are not known to SEE SECTION 8 SEE SECTION 8
be absorbed through intact skin.
INGESTION: Ingestion is not anticipated to be a significant route of
For Routine Industrial Use and Handling Applications
exposure for any component of this product. If this product is
swallowed, it may cause nausea, vomiting, and diarrhea. A significant
hazard associated with ingestion of this product is aspiration; breathing See Section 16 for Definition of Ratings
this material into the lungs can cause severe lung irritation and tissue
damage, which can cause chemical pneumonia or pulmonary edema (life-threatening lung conditions).
INJECTION: Injection of this product (as may occur if skin is punctured by a contaminated object) can cause pain, redness,
and local swelling.
HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms. In the event of overexposure, the
following symptoms may be observed:
ACUTE: Inhalation of fumes, mists or sprays can cause adverse effects on the central nervous system. Severe inhalation
overexposure may cause unconsciousness and death. A significant hazard associated with ingestion of this product is
aspiration; breathing this material into the lungs can cause severe lung irritation and tissue damage, which can cause
chemical pneumonia or pulmonary edema (life-threatening lung conditions).
CHRONIC: Repeated skin contact with this product may cause dermatitis (dry, red, scaly skin). Chronic exposure may
cause liver and kidney damage. See Section 11 (Toxicology Information) for additional data.
TARGET ORGANS: ACUTE: Skin, eyes, central nervous system. CHRONIC: Skin, liver, kidneys.
PART II What should I do if a hazardous situation occurs?
4. FIRST-AID MEASURES
Contaminated individuals must be taken for medical attention. Rescuers should be taken for medical attention, if necessary.
Take a copy of label and MSDS to health professional with the contaminated individual.
SKIN EXPOSURE: If this product contaminates the skin, immediately begin decontamination with running water and soap.
Minimum flushing is for 15 minutes. Remove exposed or contaminated clothing, taking care not to contaminate eyes. The
contaminated individual must seek immediate medical attention if any adverse health effect occurs.
EYE EXPOSURE: If this product's liquid or vapors enter the eyes, open the contaminated individual's eyes while under
gently running water. Use sufficient force to open eyelids. Have the contaminated individual "roll" eyes. Minimum flushing is
for 15 minutes.
INHALATION: If vapors, mists, or sprays of this product are inhaled, remove the contaminated individual to fresh air. If
necessary, use artificial respiration to support vital functions. Remove or cover gross contamination to avoid exposure to
rescuers. The contaminated individual should seek immediate medical attention.
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4. FIRST-AID MEASURES (Continued)
INGESTION: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT
INFORMATION. If professional advice is not available, do not induce vomiting. Have victim rinse mouth with water or drink
several cupfuls of water, if conscious. Never induce vomiting or give a diluent (e.g., water) to someone who is unconscious,
having convulsions, or unable to swallow. If vomiting occurs, lean patient forward or place on left side (head-down
position, if possible) to maintain an open airway and prevent aspiration.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Preexisting respiratory problems, dermatitis, other skin
disorders, and central nervous disorders may be aggravated by exposure to this product.
RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate overexposure. Provide oxygen, if necessary.
Pulmonary function tests, chest X-rays, and nervous system evaluations may prove useful.
5. FIRE-FIGHTING MEASURES
The following values are for the main component, Stoddard Solvent.
NFPA RATING
FLASH POINT (closed cup): 37.7-39°C (100-102°F)
AUTOIGNITION TEMPERATURE: 229-232°C (444-450°F) FLAMMABILITY
FLAMMABLE LIMITS (in air by volume, %):
Lower (LEL): 0.9%
Upper (UEL): 6.0% 3
FIRE EXTINGUISHING MATERIALS:
1 0
Water Spray: YES Carbon Dioxide: YES HEALTH INSTABILITY
Foam: YES Dry Chemical: YES
Halon: YES Other: Any "ABC" Class.
UNUSUAL FIRE AND EXPLOSION HAZARDS: This product is
flammable; vapors and liquid may ignite if exposed to an ignition source or
OTHER
if heated to its flash point of 37.7-39°C (100-102°F). Vapors of this
product are heavier than air and can spread a long distance to an ignition
See Section 16 for
source and flashback. This product can float on water and may travel to
Definition of Ratings
distant locations and spread fire. If involved in a fire, this product will
produce irritating and toxic materials such as various carbon oxides,
aldehydes and hydrocarbons. Containers may rupture violently when exposed to fire or excessive heat for sufficient time.
Explosion Sensitivity to Mechanical Impact: Not sensitive.
Explosion Sensitivity to Static Discharge: In general, materials similar to this product have low electrical conductivities
and therefore the liquid can accumulate static charge by flow, agitation or pouring. The warmed vapour can be ignited
by an electrostatic discharge of sufficient energy.
SPECIAL FIRE-FIGHTING PROCEDURES: Structural firefighters must wear Self-Contained Breathing Apparatus and full
protective equipment. Chemical resistant clothing may be necessary. Move containers from fire area if it can be done
without risk to personnel. Water spray can be used to cool fire-exposed containers. Avoid getting water into containers
because of the danger of boiling over. Stop leak before attempting to stop the fire. If the leak cannot be stopped, and if
there is no risk to the surrounding area, let the fire burn itself out. Water fog or spray can also be used by trained
firefighters to disperse this product’s vapors and to protect personnel. If possible, prevent runoff water from entering storm
drains, bodies of water, or other environmentally sensitive areas. Rinse contaminated equipment thoroughly with soapy
water before returning such equipment to service.
6. ACCIDENTAL RELEASE MEASURES
RELEASE RESPONSE: In case of a release, clear the affected area and protect people. Spills will be slippery. Eliminate all
sources of ignition before cleanup begins. Use non-sparking tools. Appropriately trained personnel in proper personal
protective equipment, using pre-planned procedures should respond to uncontrolled releases. The proper personal
protective equipment for incidental releases (e.g., 32-ounce container) should be rubber gloves and goggles. In the event
that cleanup will generate excessive splashes, a face-shield, boots, and chemical resistant body protection should also be
worn. In the event of a non-incidental release (e.g., several 1-gallon containers released in a poorly ventilated area),
minimum Personal Protective Equipment should be Level B: triple-gloves (rubber gloves and nitrile gloves over latex gloves),
chemical resistant suit and boots, hard hat, and Self-Contained Breathing Apparatus. A fire-retardant suit must be worn over
the chemical resistant suit. Short-term colorimetric detector tubes for the determination of hydrocarbons and petroleum
hydrocarbons are commercially available. Monitor area for combustible vapor levels. Monitoring must indicate less than
10% LEL (refer to Section 5, Fire-fighting Measures) before emergency response personnel are permitted in the area.
Monitoring must indicate that oxygen levels are above 19.5% before anyone is permitted in the area without Self-Contained
Breathing Apparatus. Absorb spilled liquid with activated carbon, polypads, or other suitable absorbent materials.
Decontaminate the area thoroughly. Place all spill residue in an appropriate container and seal. Dispose of in accordance
with applicable U.S. Federal, State, or local procedures, or appropriate standards of Canada or EU Member States (see
Section 13, Disposal Considerations).
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PART III How can I prevent hazardous situations from occurring?
7. HANDLING and STORAGE
WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU.
Wash thoroughly after handling this product. Do not eat, drink, smoke, or apply cosmetics while handling this product. Avoid
breathing vapors, mists, or sprays of this product. Use in a well-ventilated location. Remove contaminated clothing
immediately.
STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to handle it safely.
Keep away from heat, sparks, and other sources of ignition. Keep container tightly closed when not in use. Open containers
slowly on a stable surface. Use non-sparking tools. Bond and ground containers during transfers of material. If this product
is transferred into another container, only use portable containers and dispensing equipment (faucet, pump, drip can)
approved for flammable liquids. Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or
where freezing is possible. Material should be stored in secondary containers or in a diked area, as appropriate. Store away
from incompatible materials (see Section 10, Stability and Reactivity). Containers should be separated from oxidizing
materials by a minimum distance of 20 ft. or by a barrier of non-combustible material at least 5 ft. high having a fire-resistance
rating of at least 0.5 hours. Storage areas should be made of fire resistant materials. Post warning and “NO SMOKING�
signs in storage and use areas, as appropriate. Have appropriate extinguishing equipment in the storage area (e.g., sprinkler
system, portable fire extinguishers). Inspect all incoming containers before storage to ensure containers are properly labeled
and not damaged. Refer to NFPA 30, Flammable and Combustible Liquids Code, for additional information on storage.
Empty containers may contain residual amounts of this product; therefore, empty containers should be handled with care.
Never perform any welding, cutting, soldering, drilling, or other hot work on an empty container or piping until all liquid,
vapors, and residue have been cleared.
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in
Section 6 (Accidental Release Measures). Make certain that application equipment is locked and tagged-out safely, if
necessary. Collect all rinsates and dispose of according to applicable U.S. Federal, State, or local procedures and
appropriate Canadian standards, or those of EU Member States.
8. EXPOSURE CONTROLS - PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are maintained
below the limits provided below, if applicable. Use a non-sparking, grounded, explosion-proof ventilation system separate
from other exhaust ventilation systems. Exhaust directly to the outside, taking necessary precautions for environmental
protection. Ensure eyewash/safety shower stations are available near areas where this product is used.
EXPOSURE LIMITS/GUIDELINES:
CHEMICAL CAS # EXPOSURE LIMITS IN AIR
NAME
ACGIH-TLVs OSHA-PELs NIOSH-RELs NIOSH AIHA WEELs OTHER
TWA STEL TWA STEL TWA STEL IDLH TWA STEL
mg/m3
ppm ppm ppm ppm ppm ppm ppm ppm ppm
8052-41-3 100 NE 500 NE 350 1800 20,000 NE NE NE
Stoddard
mg/m3 mg/m3
(ceiling)
Solvent 100
15 min.
(vacated
1989
PEL)
546-68-9 NE NE NE NE NE NE NE NE NE NE
Tetraisopropyl
Titanate
68988-89- NE NE NE NE NE NE NE NE NE NE
Trimethylated
6
Silica
1330-20-7 100 150 100 150 100 150 900 NE NE DFG MAKs:
Xylene (mixed
(vacated
isomers) TWA = 100 (skin)
1989 PEAK = 2•MAK 15 min.
PEL) average value, 1-hr
interval
DFG MAK Pregnancy
Risk Classification: D
Carcinogen: EPA-D, EA-I,
IARC-3, TLV-A4
NE = Not Established. P = Avoid prolonged and repeated skin contact to diesel fuels which can lead to dermal irritation and may be associated with
an increased risk of skin cancer. See Section 16 for Definitions of Terms Used.
EYE PROTECTION: Splash goggles or safety glasses. Face-shields should be worn if operations will generate splashes or
sprays. If necessary, refer to U.S. OSHA 29 CFR 1910.133, Canadian Standards, or the European Standard EN166.
STARBRITE WATERPROOFING WITH PTEF® MSDS
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8. EXPOSURE CONTROLS - PERSONAL PROTECTION (Continued)
RESPIRATORY PROTECTION: Maintain airborne contaminant concentrations below exposure limits listed above, if
applicable. If respiratory protection is needed, use only protection authorized in the U.S. Federal OSHA Standard (29 CFR
1910.134), applicable U.S. State regulations, the Canadian CSA Standard Z94.4-93, the European Standard EN149, or
Standards of EU member states. Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres, use of
a full-facepiece pressure/demand SCBA or a full facepiece, supplied air respirator with auxiliary self-contained air supply is
required under OSHAs Respiratory Protection Standard (1910.134-1998). The following are NIOSH respiratory protective
equipment for Stoddard Solvent, the main component.
STODDARD SOLVENT
CONCENTRATION RESPIRATORY PROTECTION
Up to 3500 mg/m3: Any Chemical Cartridge Respirator with organic vapor cartridge(s), or any Supplied-Air Respirator
(SAR).
Up to 8750 mg/m3: Any SAR operated in a continuous-flow mode, or any Powered, Air-Purifying Respirator (PAPR)
with organic vapor cartridge(s).
Up to 17,500 mg/m3: Any Chemical Cartridge Respirator with a full facepiece and organic vapor cartridge(s), or any Air-
Purifying, Full-Facepiece Respirator (gas mask) with a chin-style, front- or back-mounted organic
vapor canister, or any PAPR with a tight-fitting facepiece and organic vapor cartridge(s), or any
Self-Contained Breathing Apparatus (SCBA) with a full facepiece, or any SAR with a full facepiece.
Up to 20,000 mg/m3: Any SAR that has a full facepiece and is operated in a pressure-demand or other positive-pressure
mode.
Emergency or Planned Entry into Unknown Concentrations or IDLH Conditions: Any SCBA that has a full facepiece and is
operated in a pressure-demand or other positive-pressure mode, or any SAR that has a full
facepiece and is operated in a pressure-demand or other positive-pressure mode in combination
with an auxiliary SCBA operated in pressure-demand or other positive-pressure mode.
Escape: Any Air-Purifying, Full-Facepiece Respirator (gas mask) with a chin-style, front- or back-mounted
organic vapor canister, or any appropriate escape-type, SCBA.
HAND PROTECTION: Wear Nitrile rubber, Polyethylene, Viton â„? gloves (resistance to breakthrough longer than 8 hours
when tested against a similar petroleum substance) for routine industrial use. Natural rubber and butyl rubber gloves are
not recommended. Resistance of specific materials can vary from product to product. Evaluate resistance under
conditions of use and maintain clothing carefully. Use triple gloves for spill response, as stated in Section 6 (Accidental
Release Measures) of this MSDS. If necessary, refer to U.S. OSHA 29 CFR 1910.138, appropriate Standards of Canada,
or appropriate Standards of the European Union.
BODY PROTECTION: If operations will generate splashes or sprays, use body protection appropriate for task (e.g.,
coveralls or apron). If necessary, refer to appropriate Standards of Canada or the European Union. If a hazard of injury to
the feet exists due to falling objects, rolling objects, where objects may pierce the soles of the feet or where employee’s feet
may be exposed to electrical hazards, use foot protection, as described in U.S. OSHA 29 CFR 1910.136.
9. PHYSICAL and CHEMICAL PROPERTIES
The following values are for the main component, Stoddard Solvent.
SPECIFIC VAPOR DENSITY (air = 1): Not available. EVAPORATION RATE (n-BuAc = 1): 0.1
SPECIFIC GRAVITY @ 20°C (water = 1): 0.78 MELTING/FREEZING POINT: -70°C (-94°F)
SOLUBILITY IN WATER: Insoluble. BOILING POINT: 149-204.5°C (300-400°F)
VAPOR PRESSURE, mm Hg @ 25°C: 0.53 kPa (4-4.5 mmHg) pH: Not applicable.
ODOR THRESHOLD (Stoddard Solvent): < 1 ppm (5 mg/m3) VAPOR DENSITY (air = 1): 5
COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): Not established.
The following information is for the product.
VOLATILE ORGANIC COMPOUNDS (VOC): 94.25% by weight VISCOSITY @ 20°C: 75 (est.)
APPEARANCE, ODOR AND COLOR: This product is a light-yellow, colorless liquid with a kerosene/petroleum odor.
HOW TO DETECT THIS SUBSTANCE (warning properties): Although the odor threshold of Stoddard Solvent is below the
TLV, it may not be a good warning property as olfactory fatigue can occur.
10. STABILITY and REACTIVITY
STABILITY: Normally stable.
DECOMPOSITION PRODUCTS: Thermal decomposition of this product can produce various hydrocarbons, carbon oxides
and aldehydes.
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: This product is not compatible with strong oxidizers.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Avoid exposure to or contact with extreme temperatures and incompatible chemicals.
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PAGE 5 OF 12
PART IV Is there any other useful information about this material?
11. TOXICOLOGICAL INFORMATION
TOXICITY DATA: Currently, the following toxicological data are available for components
STODDARD SOLVENT: XYLENES (MIXED ISOMERS) [continued]: XYLENES (MIXED ISOMERS) [continued]:
TCLo (Inhalation-Rat) 12,740 μg/kg/30 days-
Standard Draize Test (Eye-Rabbit) 00 mg/24 LD50 (Oral-Mammal-Species Unspecified) 4300
hours: Moderate mg/kg intermittent: Blood: changes in serum
LD (Oral-Rat) > 5 gm/kg: Behavioral: LD50 (Intraperitoneal-Rat) 2459 mg/kg composition (e.g. TP, bilirubin, cholesterol);
somnolence (general depressed activity) LD50 (Subcutaneous-Rat) 1700 mg/kg Biochemical: Enzyme inhibition, induction, or
LD (Skin-Rabbit) > 3 gm/kg LD50 (Skin-Rat) > 1700 mg/kg change in blood or tissue levels:
3
LC (Inhalation-Rat) > 5500 mg/m /4 hours: LDLo (Intravenous-Rabbit) 129 mg/kg phosphatases, Enzyme inhibition, induction,
Behavioral: somnolence (general depressed LDLo (Intraperitoneal-Guinea Pig) 2 gm/kg: or change in blood or tissue levels:
activity) Liver: fatty liver degeneration; Biochemical: transaminases
3
LC (Inhalation-Dog) > 8 gm/m /8 hours- Enzyme inhibition, induction, or change in TCLo (Inhalation-Rat) 1000 ppm/6 hours/8
continuous: Behavioral: tremor, convulsions blood or tissue levels: other transferases days-intermittent: Nutritional and Gross
or effect on seizure threshold LDLo (Intraperitoneal-Mammal-Species Metabolic: weight loss or decreased weight
LCLo (Inhalation-Cat) 1700 ppm/7 hours: Unspecified) 2 gm/kg: Peripheral Nerve and gain
Behavioral: tremor, convulsions or effect on Sensation: flaccid paralysis without TCLo (Inhalation-Rat) 2000 ppm/6 hours/8
seizure threshold anesthesia (usually neuromuscular blockage); days-intermittent: Behavioral: food intake
3
Behavioral: convulsions or effect on seizure
LCLo (Inhalation-Rat) 8200 mg/m /8 hours: (animal)�
3
threshold, irritability
Behavioral: tremor TCLo (Inhalation-Rat) 250 mg/m /24 hours:
3
LCLo (Inhalation-Dog) 8000 mg/m /3 hours: TDLo (Oral-Rat) 28 gm/kg/14 days-continuous: female 7-15 day(s) after conception:
Behavioral: alteration of classical conditioning Related to Chronic Data: death Reproductive: Specific Developmental
TCLo (Inhalation-Rat) 330 ppm/65 days- TDLo (Oral-Rat) 63 gm/kg/90 days-intermittent: Abnormalities: musculoskeletal system
3
intermittent: Kidney, Ureter, Bladder: changes Liver: changes in liver weight; Endocrine: TCLo (Inhalation-Rat) 50 mg/m /6 hours: female
in tubules (including acute renal failure, acute changes in adrenal weight; Nutritional and 1-21 day(s) after conception: Reproductive:
tubular necrosis); Blood: other changes Gross Metabolic: weight loss or decreased Fertility: post-implantation mortality (e.g. dead
3
TCLo (Inhalation-Rat) 480 mg/m /65 days- weight gain and/or resorbed implants per total number of
intermittent: Blood: normocytic anemia TDLo (Oral-Mouse) 28 gm/kg/14 days- implants); Effects on Embryo or Fetus:
3
TCLo (Inhalation-Rat) 1100 mg/m /65 days- continuous: Nutritional and Gross Metabolic: fetotoxicity (except death, e.g., stunted fetus);
intermittent: Kidney, Ureter, Bladder: renal weight loss or decreased weight gain Specific Developmental Abnormalities:
TDLo (Oral-Mouse) 20,600 μg/kg: female 6-15
function tests depressed; Blood: normocytic craniofacial (including nose and tongue)
3
anemia day(s) after conception: Reproductive: Effects TCLo (Inhalation-Rat) 50 mg/m /6 hours: female
TDLo (Skin-Rabbit) 2 gm/kg/4 weeks- on Embryo or Fetus: fetotoxicity (except 1-21 day(s) after conception: Reproductive:
intermittent: Skin and Appendages: death, e.g., stunted fetus); Specific Specific Developmental Abnormalities:
dermatitis, other (after systemic exposure) Developmental Abnormalities: craniofacial musculoskeletal system, other developmental
TETRAISOPROPYL TITINATE: (including nose and tongue), musculoskeletal abnormalities; Effects on Newborn: growth
Standard Draize Test (Skin-Rabbit) 500 mg/24 system statistics (e.g.%, reduced weight gain)
hours: Mild TDLo (Oral-Mouse) 31 mg/kg: female 6-15 TCLo (Inhalation-Rat) 200 ppm/6 hours: female
Standard Draize Test (Eye-Rabbit) 20 mg/24 day(s) after conception: Reproductive: 4-20 day(s) after conception: Reproductive:
hours: Moderate Fertility: post-implantation mortality (e.g. dead Specific Developmental Abnormalities:
LD50 (Oral-Rat) 7460 μL/kg and/or resorbed implants per total number of musculoskeletal system; Effects on Newborn:
implants) behavioral
LD50 (Skin-Rabbit) > 16 mL/kg
3
TDLo (Intraperitoneal-Rat) 4128 mg/kg/3 days- TCLo (Inhalation-Mouse) 1250 mg/m /2
TRIMETHYLATED SILICA:
intermittent: Brain and Coverings: other hours/60 days-intermittent: Biochemical:
Currently, there are no toxicological data for this
degenerative changes; Biochemical: Enzyme Enzyme inhibition, induction, or change in
compound.
inhibition, induction, or change in blood or blood or tissue levels: phosphatases; Related
XYLENES (MIXED ISOMERS):
tissue levels: peptidases to Chronic Data: changes in testicular weight
Standard Draize Test (Eye-Human) 200 ppm
3
LC50 (Inhalation-Rat) 5000 ppm/4 hours TCLo (Inhalation-Monkey) 100 mg/m /90 days-
LDLo (Oral-Human) 50 mg/kg
LC50 (Inhalation-Mammal-Species Unspecified) intermittent: Blood: other changes
LCLo (Inhalation-Human) 10,000 ppm/6 hours:
3
30 gm/m TCLo (Inhalation-Mouse) 4000 ppm/6 hours:
Behavioral: general anesthetic; Lungs,
LCLo (Inhalation-Guinea Pig) 450 ppm: Lungs, female 6-12 day(s) after conception:
Thorax, or Respiration: cyanosis; Blood: other
Thorax, or Respiration: other changes; Liver: Reproductive: Effects on Newborn: growth
changes
fatty liver degeneration statistics (e.g.%, reduced weight gain),
TCLo (Inhalation-Human) 200 ppm: Sense
physical
TCLo (Inhalation-Rat) 1600 ppm/20 hours/7
Organs and Special Senses: Olfaction):
days-intermittent: Behavioral: general TCLo (Inhalation-Mouse) 2000 ppm/6 hours:
effect, not otherwise specified; Sense Organs
anesthetic; Blood: changes in erythrocyte female 6-12 day(s) after conception:
and Special Senses (Eye): conjunctive
(RBC) count; Related to Chronic Data: death Reproductive: Effects on Embryo or Fetus:
irritation; Lungs, Thorax, or Respiration: other
3
TCLo (Inhalation-Rat) 15 mg/m /24 hours/85 fetotoxicity (except death, e.g., stunted fetus)
changes
3
days-continuous: Brain and Coverings: TCLo (Inhalation-Mouse) 1 gm/m /12 hours:
Standard Draize Test (Skin-Rabbit) 100%:
recordings from specific areas of CNS; Blood: female 6-15 day(s) after conception:
Moderate
changes in leukocyte (WBC) count Reproductive: Effects on Embryo or Fetus:
Standard Draize Test (Skin-Rabbit) 500 mg/24
TCLo (Inhalation-Rat) 800 ppm/14 hours/6 fetotoxicity (except death, e.g., stunted fetus);
hours: Moderate
weeks-intermittent: Sense Organs and Specific Developmental Abnormalities:
Standard Draize Test (Eye-Rabbit) 87 mg: Mild
Special Senses (Ear): change in acuity musculoskeletal system
Standard Draize Test (Eye-Rabbit) 5 mg/24
3
TCLo (Inhalation-Rat) 300 ppm/6 hours/18 TCLo (Inhalation-Rabbit) 500 mg/m /24 hours:
hours: Severe
weeks-intermittent: Liver: other changes; female 7-20 day(s) after conception:
LD50 (Oral-Rat) 4300 mg/kg: Liver: other
Kidney, Ureter, Bladder: other changes; Reproductive: Effects on Embryo or Fetus:
changes; Kidney, Ureter, Bladder: other
Biochemical: Enzyme inhibition, induction, or fetotoxicity (except death, e.g., stunted fetus)
changes
3
change in blood or tissue levels: hepatic TCLo (Inhalation-Rabbit) 1 gm/m /24 hours:
LD50 (Oral-Mouse) 2119 mg/kg
microsomal mixed oxidase (dealkylation, female 7-20 day(s) after conception:
hydroxylation, etc.) Reproductive: Fertility: abortion
STARBRITE WATERPROOFING WITH PTEF® MSDS
PAGE 6 OF 12
11. TOXICOLOGICAL INFORMATION (Continued)
SUSPECTED CANCER AGENT: Components of this product are listed by agencies tracking the carcinogenic potential of
chemical compounds, as follows:
XYLENES: ACGIH TLV-A3 (Confirmed Animal Carcinogen); EPA-D (Not Classifiable as to Human Carcinogenicity (inadequate human and animal
evidence of carcinogenicity or no data available); EPA-I (Data are Inadequate for an Assessment of Human Carcinogenic Potential); IARC-3 (Not
Classifiable as to Carcinogenicity to Humans); ACGIH-TLV-A Compound (Not Classifiable as a Human Carcinogen)
The remaining component of this product is not found on the following lists: FEDERAL OSHA Z LIST, NTP, IARC, and
CAL/OSHA and therefore is neither considered to be nor suspected to be a cancer-causing agent by these agencies.
IRRITANCY OF PRODUCT: This product can be irritating to eyes, skin, and other contaminated tissue.
SENSITIZATION TO THE PRODUCT: No component of this product is known to be a human skin or respiratory sensitizer.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of this product and its
components on the human reproductive system.
Mutagenicity: The components of this product are not reported to cause mutagenic effects in humans.
Embryotoxicity: The components of this product are not reported to cause embryotoxic effects in humans. Mixed Xylenes
are considered fetotoxic in humans, based on observations of reduced fetal weight, delayed ossification and
persistent behavioral effects in animal studies in the absence of maternal toxicity. Other developmental effects have
been observed in animal studies in the presence of maternal toxicity.
Teratogenicity: The components of this product are not reported to cause teratogenic effects in humans.
Reproductive Toxicity: The components of this product are not reported to cause adverse reproductive effects in humans.
A mutagen is a chemical that causes permanent changes to genetic material (DNA) such that the changes will propagate
through generational lines. An embryotoxin is a chemical that causes damage to a developing embryo (i.e. within the first
eight weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a
chemical that causes damage to a developing fetus, but the damage does not propagate across generational lines. A
reproductive toxin is any substance that interferes in any way with the reproductive process.
ACGIH BIOLOGICAL EXPOSURE INDICES: Currently, there are ACGIH Biological Exposure Indices (BEIs) determined for
the components of this product, as follows:
CHEMICAL: SAMPLING TIME BEI
DETERMINANT
Xylenes
� End of Shift
� Methylhippuric Acids in urine � 1.5 g/g Creatinine
12. ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ENVIRONMENTAL STABILITY: The following is environmental information for components of this product.
XYLENES:
Aquatic Fate: Based on a recommended classification scheme and experimentally determined Koc values in the range of 39-359, Xylene is expected
to adsorb somewhat to suspended solids and sediment in water. Xylene is expected to volatilize from water surfaces based on an experimental
Henry's Law constant of 7.0X10-3 atm-cu m/mole reported for a mixture of Xylene isomers. Estimated half-lives for a model river and model lake
are 3 and 99 hours, respectively. Xylene is degraded in standard biodegradability and field tests using various inocula including sewage, activated
sludge and seawater.
Atmospheric Fate: According to a model of gas/particle partitioning of semi-volatile organic compounds in the atmosphere, Xylene, which has an
experimental vapor pressure of 7.99 mm Hg at 25°C, will exist solely as a vapor in the ambient atmosphere. Vapor-phase Xylene is degraded in
the atmosphere by reaction with photochemically-produced hydroxyl radicals; the atmospheric lifetime of Xylene is about 1-2 days. Ambient levels
of Xylene are detected in the atmosphere due to large emissions of this compound.
Bioconcentration: an experimental BCF value of 20 was measured for Xylene isomers in eels exposed to petroleum for 10 days. According to a
classification scheme, this BCF value suggests that bioconcentration in aquatic organisms is low.
EFFECT OF MATERIAL ON PLANTS or ANIMALS: This product may be harmful or fatal to contaminated plant and animal
life (especially if large quantities are released).
EFFECT OF CHEMICAL ON AQUATIC LIFE: This product may be harmful or fatal to contaminated aquatic plant and animal
life. This material floats on water, and can potentially form slicks that are capable of creating oxygen-deprived waterways
and severely contaminate coastal and shore life. The following are aquatic toxicity data for some components of this product.
XYLENE:
LD50 (goldfish) 24 hours = 13 mg/L (conditions of bioassay not specified, no specific isomer)
LC50 (rainbow trout) 96 hours = 13.5 mg/L (conditions of bioassay not specified, no specific isomer)
LC50 (fathead minnow) 1 hour = 42 mg/L at 18-22°C, in a static bioassay (No specific isomer)
LC50 (fathead minnow) 24-96 hours = 46 mg/L at 18-22°C, in a static bioassay (No specific isomer)
LC50 (Carassius auratus goldfish) 96 hours = 16.9 ppm (conditions of bioassay not specified, no specific isomer)
STARBRITE WATERPROOFING WITH PTEF® MSDS
PAGE 7 OF 12
13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate U.S. Federal, State, and
local regulations or with regulations of Canada or EU Member States. This product, if unaltered by use, may be disposed of
by treatment at a permitted facility or as advised by your local hazardous waste regulatory authority.
EPA WASTE NUMBER: Wastes of this product should be tested to see if they are wastes as defined under EPA criteria for
D001 listed wastes (Waste Characteristic- Ignitabity).
14. TRANSPORTATION INFORMATION
Call for information
15. REGULATORY INFORMATION
ADDITIONAL U.S. REGULATIONS:
U.S. SARA REPORTING REQUIREMENTS: The components of this product are subject to the reporting requirements of
Sections 302, 304, and 313 of Title III of the Superfund Amendments and Reauthorization Act and are listed as follows:
CHEMICAL NAME SARA 302 SARA 304 SARA 313
(40 CFR 355, Appendix A) (40 CFR Table 302.4) (40 CFR 372.65)
No No Yes
Xylenes
U.S. CERCLA REPORTABLE QUANTITY (RQ): Xylenes = 100 kg (45.4 kg)
U.S. TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
OTHER U.S. FEDERAL REGULATIONS: OSHA Standard for Flammable and Combustible Liquids (29 CFR 1910.106).
Depending on specific operations involving the use of this product, the regulations of the Process Safety Management of
Highly Hazardous Chemicals may be applicable (29 CFR 1910.119). Under this regulation, the components of this product
are/are not listed in Appendix A (provided Threshold Quantities for Listed Substances); however, any process that involves a
flammable liquid on-site, in one location, in quantities of 10,000 lb. (4,553 kg) or greater is covered under this regulation
unless it is used as a fuel. Vegetable Oils, such as the Linseed Oil components of this product, are considered OSHA
Table Z-1-A air contaminants. The components of this product have requirements under other U.S. Federal regulations as
follows:
XYLENE: Xylene is listed as a hazardous air pollutant (HAP) generally known or suspected to cause serious health problems. The Clean Air Act, as
amended in 1990, directs EPA to set standards requiring major sources to sharply reduce routine emissions of toxic pollutants. EPA is required to
establish and phase in specific performance based standards for all air emission sources that emit one or more of the listed pollutants. Xylenes are
included on this list. Xylene is designated as a hazardous substance under Section 311(b)(2)(A) of the Federal Water Pollution Control Act and further
regulated by the Clean Water Act Amendments of 1977 and 1978. These regulations apply to discharges of Xylene.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): No component of this
product is on the California Proposition 65 lists.
STARBRITE WATERPROOFING WITH PTEF® MSDS
PAGE 8 OF 12
15. REGULATORY INFORMATION (Continued)
ADDITIONAL U.S. REGULATIONS (continued):
LABELING (Precautionary Statements) ANSI LABELING (Z129.1): WARNING! COMBUSTIBLE LIQUID AND VAPOR.
MAY CAUSE RESPIRATORY, SKIN AND EYE IRRITATION. HARMFUL IF INHALED. ASPIRATION HAZARD-
INGESTION CAN CAUSE LIFE-THREATENING LUNG DAMAGE. Keep away from heat, sparks, and flame. Avoid
breathing mists or sprays. Avoid prolonged or repeated contact with skin. Use only with adequate ventilation. Keep
container closed. Wash thoroughly after handling. Wear gloves and goggles. FIRST-AID: In case of contact, immediately
flush skin or eyes for at least 15 minutes with large amounts of water. If inhaled, move to fresh air. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen. If ingested, do not induce vomiting. Get medical attention
immediately. IN CASE OF FIRE: Use foam, dry chemical, or carbon dioxide. Liquid will float and may re-ignite on the
surface of water. IN CASE OF SPILL: Absorb spill with inert material and place in suitable container. Refer to Material
Safety Data Sheet for additional information on this product.
ADDITIONAL CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS: The components of this product are listed on the DSL Inventory.
OTHER CANADIAN REGULATIONS: Not applicable.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: The components of this
product are not on the CEPA Priority Substances Lists.
CANADIAN WHMIS CLASSIFICATION and SYMBOLS: Class B2: Flammable Liquid
Class D2B: Materials Causing Other Toxic Effects/Toxic Material (irritation).
EUROPEAN UNION INFORMATION FOR PRODUCT:
EU LABELING AND CLASSIFICATION: This product meets the following definitions, per the European Union Council
Directives.
EU CLASSIFICATION: [T] Toxic; Carcinogenic Category 2; F [Flammable]
EU RISK PHRASES: [R: 10]: Flammable. [R: 45]: May cause cancer. [R: 65]: Harmful, may cause lung damage if swallowed.
EU SAFETY PHRASES: [S: 2-]: Keep out of the reach of children. (This safety phrase can be omitted from the label when the substance
or preparation is sold for industrial use only). [S: 23]: Do not breathe fumes, vapors or spray. [S: 24]: Avoid contact with skin. [S:
38]: In case of insufficient ventilation, wear suitable respiratory equipment. [S: 36/37]: Wear suitable protective clothing and gloves.
[S: 62]: If swallowed, do not induce vomiting. Seek medical advice immediately and show this container or label.
EUROPEAN UNION ANNEX II HAZARD SYMBOL:
EUROPEAN UNION INFORMATION FOR CONSTITUENTS: The following information is available for primary constituents
in the components of this product.
Stoddard Solvent:
EU EINECS/ELINCS NUMBER: 232-489-3
EU CLASSIFICATION: [T] Toxic; Carcinogenic Category 2
EU RISK PHRASES: [R: 45]: May cause cancer. [R: 65]: Harmful, may cause lung damage if swallowed.
EU SAFETY PHRASES: [S: 2-]: Keep out of the reach of children. (This safety phrase can be omitted from the label when the substance
or preparation is sold for industrial use only). [S: 23]: Do not breathe fumes, vapors or spray. [S: 24]: Avoid contact with skin. [S:
38]: In case of insufficient ventilation, wear suitable respiratory equipment. [S: 36/37]: Wear suitable protective clothing and gloves.
[S: 62]: If swallowed, do not induce vomiting. Seek medical advice immediately and show this container or label.
Tetraisopropyl Titanate:
EU EINECS/ELINCS NUMBER: 200-909-6
EU CLASSIFICATION: An official classification for this substance has not been published in Commission Directives 93/72/EEC,
94/69EC, or 96/54EC.
Trimethylated Silica:
EU EINECS/ELINCS NUMBER: Unlisted
EU CLASSIFICATION: An official classification for this substance has not been published in Commission Directives 93/72/EEC,
94/69EC, or 96/54EC.
STARBRITE WATERPROOFING WITH PTEF® MSDS
PAGE 9 OF 12
15. REGULATORY INFORMATION (Continued)
EUROPEAN UNION INFORMATION FOR PRODUCT (continued):
EUROPEAN UNION INFORMATION FOR CONSTITUENTS (continued):
XYLENES (MIXED ISOMERS):
EC EINECS/ELINCS NUMBER: 215-535-7
HAZARD CLASSIFICATION: [Xn]: Harmful. F [Flammable]
RISK PHRASES: [R: 10]: Flammable. [R: 20/21]: Harmful by inhalation and by skin contact. [R: 38]: Irritating to skin.
SAFETY PHRASES: [S: 2½-]: Keep locked-up and out of reach of children. (This safety phrase can be omitted from the label when the
substance or preparation is sold for industrial use only.) [S: 25]: Avoid contact with eyes.
16. OTHER INFORMATION
PREPARED BY: CHEMICAL SAFETY ASSOCIATES, Inc.
Po Box 36519, La Mesa, CA 91944-3519
(619) 670-0609
DATE OF PRINTING: January 16, 2007
The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of
these data or the results to be obtained from the use thereof. Star brite assumes no responsibility for injury to the vendee or third persons proximately
caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, Star brite assumes no
responsibility for injury to vendee or third persons proximately caused by abnormal use of the material even if reasonable safety procedures are
followed. Furthermore, vendee assumes the risk in his use of the material.
DEFINITIONS OF TERMS
A large number of abbreviations and acronyms appear on an MSDS. Some of these, which are commonly used, include the following:
CAS #: This is the Chemical Abstract Service Number that uniquely HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD
identifies each constituent. RATINGS (continued):
EXPOSURE LIMITS IN AIR: HEALTH HAZARD:
CEILING LEVEL: The concentration that shall not be exceeded during 0 (Minimal Hazard: No significant health risk, irritation of skin or eyes not
any part of the working exposure. anticipated. Skin Irritation: Essentially non-irritating. PII or Draize = �0�.
LOQ: Limit of Quantitation. Eye Irritation: Essentially non-irritating, or minimal effects which clear in <
24 hours [e.g. mechanical irritation]. Draize = �0�. Oral Toxicity LD50 Rat: <
MAK: Federal Republic of Germany Maximum Concentration Values in
5000 mg/kg. Dermal Toxicity LD50Rat or Rabbit: < 2000 mg/kg. Inhalation
the workplace.
Toxicity 4-hrs LC50 Rat: < 20 mg/L.); 1 (Slight Hazard: Minor reversible Injury
NE: Not Established. When no exposure guidelines are established, an
may occur; slightly or mildly irritating. Skin Irritation: Slightly or mildly
entry of NE is made for reference.
irritating. Eye Irritation: Slightly or mildly irritating. Oral Toxicity LD50 Rat: >
NIC: Notice of Intended Change.
500-5000 mg/kg. Dermal Toxicity LD50Rat or Rabbit: > 1000-2000 mg/kg.
NIOSH CEILING: The exposure that shall not be exceeded during any
Inhalation Toxicity LC50 4-hrs Rat: > 2-20 mg/L); 2 (Moderate Hazard:
part of the workday. If instantaneous monitoring is not feasible, the
Temporary or transitory injury may occur. Skin Irritation: Moderately
ceiling shall be assumed as a 15-minute TWA exposure (unless
irritating; primary irritant; sensitizer. PII or Draize > 0, < 5. Eye Irritation:
otherwise specified) that shall not be exceeded at any time during a
Moderately to severely irritating and/or corrosive; reversible corneal opacity;
workday.
corneal involvement or irritation clearing in 8-21 days. Draize > 0, < 25.
NIOSH RELs: NIOSH’s Recommended Exposure Limits.
Oral Toxicity LD50 Rat: > 50-500 mg/kg. Dermal Toxicity LD50Rat or Rabbit:
PEL-Permissible Exposure Limit: OSHA’s Permissible Exposure
> 200-1000 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: > 0.5-2 mg/L.); 3
Limits. This exposure value means exactly the same as a TLV, except
(Serious Hazard: Major injury likely unless prompt action is taken and
that it is enforceable by OSHA. The OSHA Permissible Exposure Limits
medical treatment is given; high level of toxicity; corrosive. Skin Irritation:
are based in the 1989 PELs and the June, 1993 Air Contaminants Rule
Severely irritating and/or corrosive; may destroy dermal tissue, cause skin
(Federal Register: 58: 35338-35351 and 58: 40191). Both the current
burns, dermal necrosis. PII or Draize > 5-8 with destruction of tissue. Eye
PELs and the vacated PELs are indicated. The phrase, “Vacated 1989
Irritation: Corrosive, irreversible destruction of ocular tissue; corneal
PEL,� is placed next to the PEL that was vacated by Court Order.
involvement or irritation persisting for more than 21 days. Draize > 80 with
SKIN: Used when a there is a danger of cutaneous absorption.
effects irreversible in 21 days. Oral Toxicity LD50 Rat: > 1-50 mg/kg.
STEL-Short Term Exposure Limit: Short Term Exposure Limit, usually
Dermal Toxicity LD50Rat or Rabbit: > 20-200 mg/kg. Inhalation Toxicity
a 15-minute time-weighted average (TWA) exposure that should not be
LC50 4-hrs Rat: > 0.05-0.5 mg/L.); 4 (Severe Hazard: Life-threatening;
exceeded at any time during a workday, even if the 8-hr TWA is within the
major or permanent damage may result from single or repeated exposure.
TLV-TWA, PEL-TWA or REL-TWA.
Skin Irritation: Not appropriate. Do not rate as a �4�, based on skin irritation
TLV-Threshold Limit Value: An airborne concentration of a substance
alone. Eye Irritation: Not appropriate. Do not rate as a �4�, based on eye
that represents conditions under which it is generally believed that nearly
irritation alone. Oral Toxicity LD50 Rat: < 1 mg/kg. Dermal Toxicity LD50Rat
all workers may be repeatedly exposed without adverse effect. The
or Rabbit: < 20 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: < 0.05 mg/L).
duration must be considered, including the 8-hour.
FLAMMABILITY HAZARD:
TWA-Time Weighted Average: Time Weighted Average exposure
0 (Minimal Hazard-Materials that will not burn in air when exposure to a
concentration for a conventional 8-hr (TLV, PEL) or up to a 10-hr (REL)
temperature of 815.5°C [1500°F] for a period of 5 minutes.); 1 (Slight
workday and a 40-hr workweek.
Hazard-Materials that must be pre-heated before ignition can occur.
IDLH-Immediately Dangerous to Life and Health: This level
Material require considerable pre-heating, under all ambient temperature
represents a concentration from which one can escape within 30-minutes
conditions before ignition and combustion can occur, Including: Materials
without suffering escape-preventing or permanent injury.
that will burn in air when exposed to a temperature of 815.5°C (1500°F) for
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
a period of 5 minutes or less; Liquids, solids and semisolids having a flash
HAZARD RATINGS: This rating system was developed by the
point at or above 93.3°C [200°F] (e.g. OSHA Class IIIB, or; Most ordinary
National Paint and Coating Association and has been adopted by
combustible materials [e.g. wood, paper, etc.];
industry to identify the degree of chemical hazards.
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PAGE 10 OF 12
DEFINITIONS OF TERMS (Continued)
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
RATINGS (continued): HAZARD RATINGS (continued):
FLAMMABILITY HAZARD (continued): PHYSICAL HAZARD (continued):
2 (Moderate Hazard-Materials that must be moderately heated or exposed 2 (continued): Unstable Reactives: Substances that may polymerize,
to relatively high ambient temperatures before ignition can occur. Materials decompose, condense, or self-react at ambient temperature and/or
in this degree would not, under normal conditions, form hazardous pressure, but have a low potential for significant heat generation or
atmospheres in air, but under high ambient temperatures or moderate explosion. Substances that readily form peroxides upon exposure to air
heating may release vapor in sufficient quantities to produce hazardous or oxygen at room temperature); 3 (Water Reactivity: Materials that may
atmospheres in air, Including: Liquids having a flash-point at or above form explosive reactions with water. Organic Peroxides: Materials that
are capable of detonation or explosive reaction, but require a strong
37.8°C [100°F]; Solid materials in the form of course dusts that may burn
initiating source, or must be heated under confinement before initiation; or
rapidly but that generally do not form explosive atmospheres; Solid
materials that react explosively with water. Explosives: Division 1.2 �
materials in a fibrous or shredded form that may burn rapidly and create
Explosive substances that have a fire hazard and either a minor blast
flash fire hazards (e.g. cotton, sisal, hemp; Solids and semisolids that
hazard or a minor projection hazard or both, but do not have a mass
readily give off flammable vapors.); 3 (Serious Hazard- Liquids and solids
explosion hazard. Compressed Gases: Pressure > 514.7 psi absolute at
that can be ignited under almost all ambient temperature conditions.
Materials in this degree produce hazardous atmospheres with air under 21.1°C (70°F) [500 psig]. Pyrophorics: No Rating. Oxidizers: Packing
almost all ambient temperatures, or, unaffected by ambient temperature, are Group I Solids: any material that, in either concentration tested, exhibits a
readily ignited under almost all conditions, including: Liquids having a flash mean burning time less than the mean burning time of a 3.:2 potassium
bromate/cellulose mixture. Liquids: Any material that spontaneously
point below 22.8°C [73°F] and having a boiling point at or above 38°C [100°
ignites when mixed with cellulose in a 1:1 ratio, or which exhibits a mean
F] and below 37.8°C [100°F] [e.g. OSHA Class IB and IC]; Materials that on
pressure rise time less than the pressure rise time of a 1:1 perchloric acid
account of their physical form or environmental conditions can form
(50%)/cellulose mixture. Unstable Reactives: Substances that may
explosive mixtures with air and are readily dispersed in air [e.g., dusts of
polymerize, decompose, condense or self-react at ambient temperature
combustible solids, mists or droplets of flammable liquids]; Materials that
and/or pressure and have a moderate potential to cause significant heat
burn extremely rapidly, usually by reason of self-contained oxygen [e.g. dry
generation or explosion.); 4 (Water Reactivity: Materials that react
nitrocellulose and many organic peroxides]); 4 (Severe Hazard-Materials
explosively with water without requiring heat or confinement. Organic
that will rapidly or completely vaporize at atmospheric pressure and normal
Peroxides: Materials that are readily capable of detonation or explosive
ambient temperature or that are readily dispersed in air, and which will burn
decomposition at normal temperature and pressures. Explosives:
readily, including: Flammable gases; Flammable cryogenic materials; Any
Division 1.1 & 1.2-explosive substances that have a mass explosion
liquid or gaseous material that is liquid while under pressure and has a flash
hazard or have a projection hazard. A mass explosion is one that affects
point below 22.8°C [73°F] and a boiling point below 37.8°C [100°F] [e.g.
almost the entire load instantaneously. Compressed Gases: No Rating.
OSHA Class IA; Material that ignite spontaneously when exposed to air at a
Pyrophorics: Add to the definition of Flammability �4�. Oxidizers: No �4�
temperature of 54.4°C [130°F] or below [e.g. pyrophoric]).
rating. Unstable Reactives: Substances that may polymerize,
PHYSICAL HAZARD:
decompose, condense or self-react at ambient temperature and/or
0 (Water Reactivity: Materials that do not react with water. Organic
pressure and have a high potential to cause significant heat generation or
Peroxides: Materials that are normally stable, even under fire conditions
explosion.).
and will not react with water. Explosives: Substances that are Non-
NATIONAL FIRE PROTECTION ASSOCIATION HAZARD
Explosive. Unstable Compressed Gases: No Rating. Pyrophorics: No
RATINGS:
Rating. Oxidizers: No �0� rating allowed. Unstable Reactives: Substances
HEALTH HAZARD: 0 (material that on exposure under fire conditions
that will not polymerize, decompose, condense or self-react.); 1 (Water
Reactivity: Materials that change or decompose upon exposure to moisture. would offer no hazard beyond that of ordinary combustible materials); 1
Organic Peroxides: Materials that are normally stable, but can become (materials that on exposure under fire conditions could cause irritation or
unstable at high temperatures and pressures. These materials may react minor residual injury); 2 (materials that on intense or continued exposure
with water, but will not release energy. Explosives: Division 1.5 & 1.6 under fire conditions could cause temporary incapacitation or possible
substances that are very insensitive explosives or that do not have a mass residual injury); 3 (materials that can on short exposure could cause
explosion hazard. Compressed Gases: Pressure below OSHA definition. serious temporary or residual injury); 4 (materials that under very short
Pyrophorics: No Rating. Oxidizers: Packaging Group III; Solids: any exposure could cause death or major residual injury).
material that in either concentration tested, exhibits a mean burning time FLAMMABILITY HAZARD: 0 Materials that will not burn under typical
less than or equal to the mean burning time of a 3:7 potassium fire conditions, including intrinsically noncombustible materials such as
bromate/cellulose mixture and the criteria for Packing Group I and II are not concrete, stone, and sand. 1 Materials that must be preheated before
met. Liquids: any material that exhibits a mean pressure rise time less than ignition can occur. Materials in this degree require considerable
or equal to the pressure rise time of a 1:1 nitric acid (65%)/cellulose mixture preheating, under all ambient temperature conditions, before ignition
and the criteria for Packing Group I and II are not met. Unstable Reactives: and combustion can occur 2 Materials that must be moderately
Substances that may decompose, condense or self-react, but only under heated or exposed to relatively high ambient temperatures before
conditions of high temperature and/or pressure and have little or no potential ignition can occur. Materials in this degree would not under normal
to cause significant heat generation or explosive hazard. Substances that conditions form hazardous atmospheres with air, but under high
readily undergo hazardous polymerization in the absence of inhibitors.); 2 ambient temperatures or under moderate heating could release vapor
(Water Reactivity: Materials that may react violently with water. Organic in sufficient quantities to produce hazardous atmospheres with air. 3
Peroxides: Materials that, in themselves, are normally unstable and will Liquids and solids that can be ignited under almost all ambient
readily undergo violent chemical change, but will not detonate. These temperature conditions. Materials in this degree produce hazardous
materials may also react violently with water. Explosives: Division 1.4 � atmospheres with air under almost all ambient temperatures or, though
Explosive substances where the explosive effect are largely confined to the unaffected by ambient temperatures, are readily ignited under almost
package and no projection of fragments of appreciable size or range are all conditions. 4 Materials that will rapidly or completely vaporize at
expected. An external fire must not cause virtually instantaneous explosion atmospheric pressure and normal ambient temperature or that are
of almost the entire contents of the package. Compressed Gases: readily dispersed in air and will burn readily.
Pressurized and meet OSHA definition but < 514.7 psi absolute at 21.1°C
(70°F) [500 psig]. Pyrophorics: No Rating. Oxidizers: Packing Group II
Solids: any material that, either in concentration tested, exhibits a mean
burning time of less than or equal to the mean burning time of a 2:3
potassium bromate/cellulose mixture and the criteria for Packing Group I are
not met. Liquids: any material that exhibits a mean pressure rise time less
than or equal to the pressure rise of a 1:1 aqueous sodium chlorate solution
(40%)/cellulose mixture and the criteria for Packing Group I are not met.
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DEFINITIONS OF TERMS (Continued)
NATIONAL FIRE PROTECTION ASSOCIATION HAZARD ECOLOGICAL INFORMATION:
EC is the effect concentration in water. BCF = Bioconcentration Factor,
RATINGS (continued):
which is used to determine if a substance will concentrate in lifeforms
INSTABILITY HAZARD: 0 Materials that in themselves are normally
which consume contaminated plant or animal matter. TLm = median
stable, even under fire conditions. 1 Materials that in themselves are
threshold limit; Coefficient of Oil/Water Distribution is represented by
normally stable, but that can become unstable at elevated
log Kow or log Koc and is used to assess a substance’s behavior in the
temperatures and pressures. 2 Materials that readily undergo violent
environment.
chemical change at elevated temperatures and pressures. 3 Materials
that in themselves are capable of detonation or explosive REGULATORY INFORMATION:
decomposition or explosive reaction, but that require a strong initiating U.S. and CANADA:
source or that must be heated under confinement before initiation. 4 ACGIH: American Conference of Governmental Industrial Hygienists, a
Materials that in themselves are readily capable of detonation or professional association which establishes exposure limits.
explosive decomposition or explosive reaction at normal temperatures
This section explains the impact of various laws and regulations on the
and pressures.
material. EPA is the U.S. Environmental Protection Agency. NIOSH is
FLAMMABILITY LIMITS IN AIR: Much of the information related to the National Institute of Occupational Safety and Health, which is the
fire and explosion is derived from the National Fire Protection Association research arm of the U.S. Occupational Safety and Health Administration
(NFPA). Flash Point - Minimum temperature at which a liquid gives off (OSHA). WHMIS is the Canadian Workplace Hazardous Materials
sufficient vapors to form an ignitable mixture with air. Autoignition Information System. DOT and TC are the U.S. Department of
Temperature: The minimum temperature required to initiate combustion Transportation and the Transport Canada, respectively. Superfund
in air with no other source of ignition. LEL - the lowest percent of vapor in Amendments and Reauthorization Act (SARA); the Canadian
air, by volume, that will explode or ignite in the presence of an ignition Domestic/Non-Domestic Substances List (DSL/NDSL); the U.S. Toxic
source. UEL - the highest percent of vapor in air, by volume, that will Substance Control Act (TSCA); Marine Pollutant status according to the
explode or ignite in the presence of an ignition source. DOT; the Comprehensive Environmental Response, Compensation, and
TOXICOLOGICAL INFORMATION: Liability Act (CERCLA or Superfund); and various state regulations.
Human and Animal Toxicology: Possible health hazards as derived This section also includes information on the precautionary warnings
from human data, animal studies, or from the results of studies with which appear on the material’s package label. OSHA - U.S.
similar compounds are presented. Definitions of some terms used in this Occupational Safety and Health Administration.
section are: LD50 - Lethal Dose (solids & liquids) which kills 50% of the EUROPEAN and INTERNATIONAL:
exposed animals; LC50 - Lethal Concentration (gases) which kills 50% of The DFG: This is the Federal Republic of Germany’s Occupation Health
the exposed animals; ppm concentration expressed in parts of material Agency, similar to the U.S. OSHA. EU is the European Union (formerly
3
per million parts of air or water; mg/m concentration expressed in weight known as the EEC, European Economic Community). EINECS: This is
of substance per volume of air; mg/kg quantity of material, by weight, the European Inventory of Now-Existing Chemical Substances. The ARD
administered to a test subject, based on their body weight in kg. Other is the European Agreement Concerning the International Carriage of
measures of toxicity include TDLo, the lowest dose to cause a symptom Dangerous Goods by Road and the RID are the International Regulations
and TCLo the lowest concentration to cause a symptom; TDo, LDLo, Concerning the Carriage of Dangerous Goods by Rail. AICS is the
and LDo, or TC, TCo, LCLo, and LCo, the lowest dose (or concentration) Australian Inventory of Chemical Substances. MITI is the Japanese
to cause lethal or toxic effects. Cancer Information: The sources are: Minister of International Trade and Industry
IARC - the International Agency for Research on Cancer; NTP - the
National Toxicology Program, RTECS - the Registry of Toxic Effects of
Chemical Substances, OSHA and CAL/OSHA. IARC and NTP rate
chemicals on a scale of decreasing potential to cause human cancer with
rankings from 1 to 4. Subrankings (2A, 2B, etc.) are also used. Other
Information: BEI - ACGIH Biological Exposure Indices, represent the
levels of determinants which are most likely to be observed in specimens
collected from a healthy worker who has been exposed to chemicals to
the same extent as a worker with inhalation exposure to the TLV.
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