CITGO Aquamarine庐 Oil 46
Material Safety Data Sheet
CITGO Petroleum Corporation
633561001
MSDS No.
P.O. Box 4689 Hazard Rankings
Houston, TX 77210 Revision Date 08/25/2004
HMIS NFPA
IMPORTANT: Read this MSDS before handling or disposing of this product and pass this 0 0
Health Hazard
information on to employees, customers and users of this product.
Fire Hazard 1 1
Emergency Overview 0
Reactivity 0
Physical State Liquid.
* = Chronic Health Hazard
Light green. Faint Odor
Color Odor
WARNING: Protective Equipment
Oil injected into the skin from high-pressure leaks can cause
Minimum Recommended
severe injury. See Section 8 for Details
Most damage occurs during the first few hours.
Seek medical attention immediately.
Surgical removal of oil may be necessary.
Spills may create a slipping hazard.
SECTION 1. PRODUCT IDENTIFICATION
CITGO Aquamarine庐 Oil 46 (800) 248-4684
Trade Name Technical Contact
Product Number Medical Emergency
633561001 (918) 495-4700
Mixture. (800) 424-9300
CAS Number CHEMTREC Emergency
(United States Only)
Hydraulic oil
Product Family
Industrial white oil;
Synonyms
Hydraulic oil;
CITGO庐 Material Code No.: 633561001
SECTION 2. COMPOSITION
Concentration (%)
Component Name(s) CAS Registry No.
White Mineral Oil 8042-47-5 95 - 100
Proprietary Ingredients Proprietary Mixture 0-5
SECTION 3. HAZARDS IDENTIFICATION
Also see Emergency Overview and Hazard Ratings on the top of Page 1 of this MSDS.
Major Route(s) of Entry Skin contact.
Signs and Symptoms of Acute Exposure
No significant adverse health effects are expected to occur upon short-term exposure.
Inhalation
Eye Contact No significant eye irritation is expected upon short-term exposure.
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CITGO Aquamarine庐 Oil 46
Injection under the skin can cause inflammation and swelling. Injection of pressurized
Skin Contact
hydrocarbons can cause severe, permanent tissue damage. Initial symptoms may be minor.
Injection of petroleum hydrocarbons requires immediate medical attention.
Ingestion If swallowed, large volumes of material can cause generalized depression, headache,
drowsiness, nausea, vomiting and diarrhea. Smaller doses can cause a laxative effect. If
aspirated into the lungs, liquid can cause lung damage.
Chronic Health Effects No significant signs or symptoms indicative of any adverse health effects are expected to
Summary occur.
None known.
Conditions Aggravated
by Exposure
Target Organs Contains material which causes damage to the following organs: skin.
Carcinogenic Potential This product is not known to contain any components at concentrations above 0.1% which
are considered carcinogenic by OSHA, IARC or NTP.
OSHA Hazard Classification is indicated by an "X" in the box adjacent to the hazard title. If no "X" is present,
the product does not exhibit the hazard as defined in the OSHA Hazard Communication Standard (29 CFR
1910.1200).
OSHA Physical Hazard Classification
OSHA Health Hazard Classification
Combustible Explosive Pyrophoric
Irritant Sensitizer
Highly Toxic Water-reactive
Toxic Oxidizer
Flammable
Corrosive Carcinogenic Compressed Gas Organic Peroxide Unstable
SECTION 4. FIRST AID MEASURES
Take proper precautions to ensure your own health and safety before attempting rescue or providing first aid.
For more specific information, refer to Exposure Controls and Personal Protection in Section 8 of this MSDS.
Move victim to fresh air. If victim is not breathing, immediately begin rescue breathing. If
Inhalation
breathing is difficult, 100 percent humidified oxygen should be administered by a qualified
individual. Seek medical attention immediately. Keep the affected individual warm and at
rest.
Check for and remove contact lenses. Flush eyes with cool, clean, low-pressure water while
Eye Contact
occasionally lifting and lowering eyelids. Seek medical attention if excessive tearing, redness,
or pain persists.
If burned by hot material, cool skin by quenching with large amounts of cool water. For
Skin Contact
contact with product at ambient temperatures, remove contaminated shoes and clothing.
Wipe off excess material. Wash exposed skin with mild soap and water. Seek medical
attention if tissue appears damaged or if pain or irritation persists. Thoroughly clean
contaminated clothing before reuse. Discard contaminated leather goods. If material is
injected under the skin, seek medical attention immediately.
Do not induce vomiting unless directed to by a physician. Do not give anything to drink unless
Ingestion
directed to by a physician. Never give anything by mouth to a person who is not fully
conscious. Seek medical attention immediately.
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CITGO Aquamarine庐 Oil 46
SKIN: In the event of injection in underlying tissue, immediate treatment should include
Notes to Physician
extensive incision, debridement and saline irrigation. Inadequate treatment can result in
ischemia and gangrene. Early symptoms may be minimal.
INGESTION: The viscosity range of the product(s) represented by this MSDS is greater than
100 SUS at 100掳F. There is a low risk of aspiration upon ingestion Careful gastric lavage or
emesis may be considered to evacuate large quantities of material.
SECTION 5. FIRE FIGHTING MEASURES
NFPA Class-IIIB combustible material.
NFPA Flammability
Classification
Open cup: 204掳C (399掳F) (Cleveland.).
Flash Point
Upper Flammable Limit
Lower Flammable Limit No data. No data.
Autoignition Not available.
Temperature
Hazardous Combustion Carbon dioxide, carbon monoxide, smoke, fumes, and/or unburned hydrocarbons.
Products
Special Properties This material can burn but will not readily ignite. This material will release vapors when
heated above the flash point temperature that can ignite when exposed to a source of
ignition. In enclosed spaces, heated vapor can ignite with explosive force. Mists or sprays
may burn at temperatures below the flash point.
Extinguishing Media Use dry chemical, foam, Carbon Dioxide or water fog.
Firefighters must use full bunker gear including NIOSH-approved positive pressure
Protection of Fire
self-contained breathing apparatus to protect against potential hazardous combustion or
Fighters
decomposition products and oxygen deficiencies.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Take proper precautions to ensure your own health and safety before attempting spill control or clean-up. For
more specific information, refer to the Emergency Overview on Page 1, Exposure Controls and Personal
Protection in Section 8 and Disposal Considerations in Section 13 of this MSDS.
Do not touch damaged containers or spilled material unless wearing appropriate protective
equipment. Slipping hazard; do not walk through spilled material. Stop leak if you can do so
without risk. For small spills, absorb or cover with dry earth, sand, or other inert
non-combustible absorbent material and place into waste containers for later disposal.
Contain large spills to maximize product recovery or disposal. Prevent entry into waterways or
sewers. In urban area, cleanup spill as soon as possible. In natural environments, seek
cleanup advice from specialists to minimize physical habitat damage. This material will float
on water. Absorbent pads and similar materials can be used. Comply with all laws and
regulations.
SECTION 7. HANDLING AND STORAGE
Avoid contamination and extreme temperatures to minimize product degradation. Empty
Handling
containers may contain product residues that can ignite with explosive force. Do not
pressurize, cut, weld, braze solder, drill, grind or expose containers to flames, sparks, heat or
other potential ignition sources. Consult appropriate federal, state and local authorities before
reusing, reconditioning, reclaiming, recycling or disposing of empty containers and/or waste
residues of this product.
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CITGO Aquamarine庐 Oil 46
Keep container closed. Do not store with strong oxidizing agents. Do not store at elevated
Storage
temperatures. Avoid storing product in direct sunlight for extended periods of time. Consult
appropriate federal, state and local authorities before reusing, reconditioning, reclaiming,
recycling or disposing of empty containers or waste residues of this product.
SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations
of mists and/or vapors below the recommended exposure limits (see below). An eye wash
station and safety shower should be located near the work-station.
Personal Protective Personal protective equipment should be selected based upon the conditions under which
Equipment this material is used. A hazard assessment of the work area for PPE requirements should
be conducted by a qualified professional pursuant to OSHA regulations. The following
pictograms represent the minimum requirements for personal protective equipment. For
certain operations, additional PPE may be required.
Eye Protection Safety glasses equipped with side shields are recommended as minimum protection in
industrial settings. Wear goggles and/or face shield if splashing or spraying is anticipated.
Wear goggles and face shield if material is heated above 125掳F (51掳C). Have suitable eye
wash water available.
Hand Protection Use gloves constructed of chemical resistant materials such as neoprene or heavy nitrile
rubber if frequent or prolonged contact is expected. Use heat-protective gloves when
handling product at elevated temperatures.
Use clean protective clothing (e.g., neoprene or Tyvek庐) if splashing or spraying conditions
Body Protection
are present. Protective clothing may include long-sleeve outer garment, apron, or lab coat.
If significant contact occurs, remove oil-contaminated clothing as soon as possible and
promptly shower. Launder contaminated clothing before reuse or discard. Wear heat
protective boots and protective clothing when handling material at elevated temperatures.
Vaporization is not expected at ambient temperatures. Therefore, the need for respiratory
Respiratory Protection
protection is not anticipated under normal use conditions and with adequate ventilation. If
elevated airborne concentrations above applicable workplace exposure levels are
anticipated, a NIOSH-approved organic vapor respirator equipped with a dust/mist prefilter
should be used. Protection factors vary depending upon the type of respirator used.
Respirators should be used in accordance with OSHA requirements (29 CFR 1910.134).
Use good personal hygiene practices. Wash hands and other exposed skin areas with
General Comments
plenty of mild soap and water before eating, drinking, smoking, use of toilet facilities, or
leaving work. DO NOT use gasoline, kerosene, solvents or harsh abrasives as skin
cleaners. Since specific exposure standards/control limits have not been established for this
product, the "Oil Mist, Mineral" exposure limits shown below are suggested as minimum
control guidelines.
Occupational Exposure Guidelines
Substance Applicable Workplace Exposure Levels
Oil Mist, Mineral ACGIH (United States).
TWA: 5 mg/m 3
STEL: 10 mg/m 3
OSHA (United States).
TWA: 5 mg/m 3
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CITGO Aquamarine庐 Oil 46
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES (TYPICAL)
Faint Odor
Odor
Color
Liquid. Light green.
Physical State
>1 (Air = 1)
Vapor
0.87 (Water = 1) Not Applicable.
Specific Gravity pH
Density
Boiling Range Not available. Not available.
Melting/Freezing
Point
Volatility Negligible volatility.
<0.01 kPa (<0.1 mm Hg) (at 20掳C)
Vapor Pressure
Viscosity
Negligible solubility in cold water. 46
Solubility in
(cSt @ 40掳C)
Water
Additional Gravity, 潞API (ASTM D287) = 32.0 @ 60潞 F
Properties Density = 7.22 Lbs/gal.
Viscosity (ASTM D2161) = 238 SUS @ 100潞 F
SECTION 10. STABILITY AND REACTIVITY
Hazardous Polymerization Not expected to occur.
Stable.
Chemical Stability
Keep away from heat and flame.
Conditions to Avoid
Strong oxidizers.
Materials
Incompatibility
No additional hazardous decomposition products were identified other than the combustion
Hazardous
products identified in Section 5 of this MSDS.
Decomposition
Products
SECTION 11. TOXICOLOGICAL INFORMATION
For other health-related information, refer to the Emergency Overview on Page 1 and the Hazards Identification
in Section 3 of this MSDS.
Toxicity Data White Mineral Oil:
ORAL (LD50): Acute: >5000 mg/kg [Rat].
DERMAL (LD50): Acute: >2000 mg/kg [Rabbit].
Low-viscosity and High-viscosity White Mineral Oils:
DRAIZE EYE, Acute: Non-irritating [Rabbit].
DRAIZE DERMAL, Acute: Non-irritating [Rabbit].
BUEHLER, Acute: Non-sensitizing [Guinea Pig].
28-Day DERMAL, Sub-Chronic: Non-irritating [Rabbit].
104-Week DERMAL, Chronic: No skin tumors at site of application [Mouse].
MUTAGENICITY:
Modified Ames Assay: Negative [Salmonella typhimurium].
in-vitro Lymphoma Assay: Negative or no toxicity [Mouse].
Lifetime mouse skin painting studies indicated that white mineral oils are not mutagenic or
carcinogenic. Mineral oil mists derived from highly refined oils are reported to have low acute
and sub-acute toxicities in animals. Effects from single and short-term repeated exposures to
high concentrations of mineral oil mists well above applicable workplace exposure levels
include lung inflammatory reaction, lipoid granuloma formation and lipoid pneumonia. In
acute and sub-acute studies involving exposures to lower concentrations of mineral oil mists
at or near current work place exposure levels produced no significant toxicological effects. In
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CITGO Aquamarine庐 Oil 46
long term studies (up to two years) no carcinogenic effects have been reported in any animal
species tested.
Hydraulic oil:
Repeated or prolonged skin contact with certain hydraulic oils can cause mild skin irritation
characterized by drying, cracking (dermatitis) or oil acne. Injection under the skin, in muscle
or into the blood stream can cause irritation, inflammation, swelling, fever, and systemic
effects, including mild central nervous system depression. Injection of pressurized
hydrocarbons can cause severe, permanent tissue damage.
SECTION 12. ECOLOGICAL INFORMATION
Based on 96-hr acute toxicity tests of similar products, releases to aquatic environments
Ecotoxicity
would present a minor risk to fish.
Environmental Fate Inherently biodegradable. An environmental fate analysis is not available for this specific
product. Plants and animals may experience harmful or fatal effects when coated with
petroleum products. Petroleum-based (mineral) lubricating oils normally will float on water. In
stagnant or slow-flowing waterways, an oil layer can cover a large surface area. As a result,
this oil layer might limit or eliminate natural atmospheric oxygen transport into the water. With
time, if not removed, oxygen depletion in the waterway may be sufficient to cause a fish kill or
create an anaerobic environment.
SECTION 13. DISPOSAL CONSIDERATIONS
Hazard characteristic and regulatory waste stream classification can change with product use. Accordingly, it is
the responsibility of the user to determine the proper storage, transportation, treatment and/or disposal
methodologies for spent materials and residues at the time of disposition.
Conditions of use may cause this material to become a "hazardous waste", as defined by
federal or state regulations. It is the responsibility of the user to determine if the material is a
"hazardous waste" at the time of disposal. Transportation, treatment, storage, and disposal
of waste material must be conducted in accordance with RCRA regulations (see 40 CFR 260
through 40 CFR 271). State and/or local regulations may be more restrictive. Contact the
RCRA/Superfund Hotline at (800) 424-9346 or your regional US EPA office for guidance
concerning case specific disposal issues. Empty drums and pails retain residue. DO NOT
pressurize, cut, weld, braze, solder, drill, grind, or expose this product's empty container to
heat, flame, or other ignition sources. DO NOT attempt to clean it. Empty drums and pails
should be drained completely, properly bunged or sealed, and promptly sent to a
reconditioner.
SECTION 14. TRANSPORT INFORMATION
The shipping description below may not represent requirements for all modes of transportation, shipping
methods or locations outside of the United States.
Not regulated by the U.S. Department of Transportation as a hazardous material.
US DOT Status
Not regulated.
Proper Shipping Name
Not regulated. Not applicable.
Hazard Class Packing Group(s)
Not regulated.
UN/NA Number
Reportable Quantity A Reportable Quantity (RQ) has not been established for this material.
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CITGO Aquamarine庐 Oil 46
Placard(s) Not applicable.
Emergency Response
Guide No.
2911415
HAZMAT STCC No.
Not a DOT "Marine
MARPOL III Status
Pollutant" per 49 CFR
171.8.
SECTION 15. REGULATORY INFORMATION
TSCA Inventory This product and/or its components are listed on the Toxic Substances Control Act (TSCA)
inventory.
The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires
SARA 302/304
facilities subject to Subparts 302 and 304 to submit emergency planning and notification
Emergency Planning
information based on Threshold Planning Quantities (TPQs) and Reportable Quantities
and Notification
(RQs) for "Extremely Hazardous Substances" listed in 40 CFR 302.4 and 40 CFR 355. No
components were identified.
The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires
SARA 311/312 Hazard
facilities subject to this subpart to submit aggregate information on chemicals by "Hazard
Identification
Category" as defined in 40 CFR 370.2. This material would be classified under the following
hazard categories:
No SARA 311/312 hazard categories identified.
This product contains the following components in concentrations above de minimis levels
SARA 313 Toxic
that are listed as toxic chemicals in 40 CFR Part 372 pursuant to the requirements of Section
Chemical Notification
313 of SARA: No components were identified.
and Release Reporting
The Comprehensive Environmental Response, Compensation, and Liability Act of 1980
CERCLA
(CERCLA) requires notification of the National Response Center concerning release of
quantities of "hazardous substances" equal to or greater than the reportable quantities (RQ's)
listed in 40 CFR 302.4. As defined by CERCLA, the term "hazardous substance" does not
include petroleum, including crude oil or any fraction thereof which is not otherwise
specifically designated in 40 CFR 302.4. This product or refinery stream is not known to
contain chemical substances subject to this statute. However, it is recommended that you
contact state and local authorities to determine if there are any other reporting requirements
in the event of a spill.
Clean Water Act This material is classified as an oil under Section 311 of the Clean Water Act (CWA) and the
(CWA) Oil Pollution Act of 1990 (OPA). Discharges or spills which produce a visible sheen on waters
of the United States, their adjoining shorelines, or into conduits leading to surface waters must
be reported to the EPA's National Response Center at (800) 424-8802.
California This material may contain the following components which are known to the State of California
Proposition 65 to cause cancer, birth defects or other reproductive harm, and may be subject to the
requirements of California Proposition 65 (CA Health & Safety Code Section 25249.5):
Ethylbenzene: 0.0001%
Ethyl acrylate: 0.0001%
New Jersey Petroleum Oil (Hydraulic Oil)
Right-to-Know Label
No additional regulatory remarks.
Additional Regulatory
Remarks
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CITGO Aquamarine庐 Oil 46
SECTION 16. OTHER INFORMATION
Refer to the top of Page 1 for the HMIS and NFPA Hazard Ratings for this product.
REVISION INFORMATION
1.1
Version Number
08/25/2004
Revision Date
Printed on 08/25/2004.
Print Date
ABBREVIATIONS
AP: Approximately EQ: Equal >: Greater Than <: Less Than NA: Not Applicable ND: No Data NE: Not Established
ACGIH: American Conference of Governmental Industrial Hygienists AIHA: American Industrial Hygiene Association
IARC: International Agency for Research on Cancer NTP: National Toxicology Program
OSHA: Occupational Safety and Health Administration
NIOSH: National Institute of Occupational Safety and Health
NPCA: National Paint and Coating Manufacturers Association HMIS: Hazardous Materials Information System
NFPA: National Fire Protection Association EPA: US Environmental Protection Agency
DISCLAIMER OF LIABILITY
THE INFORMATION IN THIS MSDS WAS OBTAINED FROM SOURCES WHICH WE BELIEVE ARE RELIABLE.
HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESSED OR IMPLIED
REGARDING ITS CORRECTNESS. SOME INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE
FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE SUBSTANCE ITSELF. THIS MSDS WAS PREPARED
AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS A COMPONENT IN ANOTHER
PRODUCT, THIS MSDS INFORMATION MAY NOT BE APPLICABLE. USERS SHOULD MAKE THEIR OWN
INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION OR PRODUCTS FOR THEIR
PARTICULAR PURPOSE.
THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND DISPOSAL OF THE PRODUCT ARE
BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS AND OTHER REASONS, WE DO
NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR EXPENSE
ARISING OUT OF OR IN ANY WAY CONNECTED WITH HANDLING, STORAGE, USE OR DISPOSAL OF THE
PRODUCT.
***** END OF MSDS *****
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