MATERIAL SAFETY DATA SHEET
According to EU Directive 93/112/EEC
READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET
BEFORE HANDLING OR DISPOSING OF PRODUCT
33073 HAVOLINE XLC+B 50/50 (OF01)
1. PRODUCT AND COMPANY NAME
PRODUCT CODE AND NAME
33073 HAVOLINE XLC+B 50/50 (OF01)
DESCRIPTION
COMPANY
ARTECO N.V.
Technologiepark-Zwijnaarde 2
B-9052 Gent-Zwijnaarde
BELGIUM
Tel: 0032/(0)9 240 7320
Fax: 0032/(0)9 240 7324
Emergency phone number : 0044/(0)18 65 407 333
Poison Control Center (Belgium only) : +32/(0)70 245 245
2. COMPOSITION/INFORMATION ON INGREDIENTS
Name % Wt CAS No. EC No.
Ethylene glycol 45 - 54.99 107-21-1 203-473-3
Xn R 22 Harmful if swallowed.
Water and additives 45 - 54.99 CBI CBI
Aliphatic acid, sodium salt 1 - 2.99 CBI CBI
Xn R 63 Possible risk of harm to the unborn child.
The product contains a bittering repellent agent.
3. HAZARDS IDENTIFICATION
HARMFUL IF SWALLOWED
Warning statement
MAY ENTER LUNGS AND CAUSE DAMAGE IF SWALLOWED
MAY CAUSE DIZZINESS AND DROWSINESS
Acute effects of exposure to man
Inhalation Vapours or mist, in excess of permissible concentrations, or in unusually
high concentrations generated from spraying, heating the material or
from exposure in poorly ventilated areas or confined spaces, may cause
irritation of the nose and throat,
Inhalation headache, nausea, and drowsiness.
Skin contact Brief contact may cause slight irritation. Prolonged contact, as with
clothing wetted with material, may cause more severe irritation and
discomfort, seen as local redness and swelling.
Eye contact May cause irritation, experienced as mild discomfort and seen as slight
excess redness of the eye.
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33073 HAVOLINE XLC+B 50/50 (OF01)
Ingestion Ethylene glycol and diethylene glycol are toxic when swallowed. A
lethal dose for an adult is 1-2 ml per kilogram, or about 100 ml.
Symptoms include staggering, slurred speech, loss of coordination,
confusion, faintness, nausea, vomiting, increased
Ingestion heart rate, difficulty breathing, difficulty seeing, convulsions, and
collapse. Symptoms may be delayed. Decreased urine output, kidney
failure, and nervous system damage may also occur.
Aspiration may occur during swallowing or vomiting, resulting in lung
damage.
Repeated ingestion may cause kidney damage.
Chronic effects of exposure to man
Medical conditions aggravated by exposure Repeated overexposure may aggravate an existing kidney disease.
Because of its irritating properties, repeated skin contact may
aggravate an existing dermatitis (skin condition).
Believed not to be toxic to aquatic species.
Effects of exposure to the environment
4. FIRST AID MEASURES
Route of exposure
Inhalation If irritation, headache, nausea, or drowsiness occurs, remove to fresh
air. Get medical attention if breathing becomes difficult or symptoms
persist.
Skin contact Wash skin with plenty of soap and water for several minutes. Get
medical attention if skin irritation develops or persists.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes.
Hold eyelids apart while flushing to rinse entire surface of eye and lids
with water. Get medical attention.
Ingestion Get immediate medical attention. If person is conscious and can
swallow, immediately give two glasses of water (500 ml) but do not
induce vomiting. If vomiting occurs, give fluids again. Have physician
determine if condition of person will permit
Ingestion induction of vomiting or evacuation of stomach. Do not give anything by
mouth to an unconscious or convulsing person.
Ethylene glycol poisoning may initially produce behaviour changes,
Other recommendations
drowsiness, vomiting, diarrhoea, thirst and convulsions. Renal damage
or failure with metabolic acidosis are late signs of poisoning. Immediate
treatment may reduce toxic effects,
supplemented, if necessary with haemodialysis. Intravenous ethanol in
Other recommendations
sodium bicarbonate solution is a recognized antidote. Contact a poison
centre for further treatment information.
5. FIRE-FIGHTING MEASURES
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33073 HAVOLINE XLC+B 50/50 (OF01)
Suitable extinguishing media Use water fog, dry powder, foam, or carbon dioxide. Water or foam
may cause frothing. Use water to cool fire-exposed containers. If a leak
or spill has not ignited, use water fog to disperse the vapours and to
provide protection for persons attempting
Suitable extinguishing media to stop the leak.
Extinguishing media which must not be used Water jet
for safety reasons
Special exposure hazards arising from the
substance or preparation itself,
combustion products, resulting gases None
Special protective equipment for firefighters The nature of special protective equipment required will depend upon
the size of the fire, the degree of confinement of the fire and the
natural ventilation available. Fire-resistant clothing and self-contained
breathing apparatus is recommended for
Special protective equipment for firefighters fires in confined spaces and poorly-ventilated areas. Full fire-proof
clothing is recommended for any large fires involving this product.
6. ACCIDENTAL RELEASE MEASURES
Procedures in case of accidental release or Ventilate area. Avoid breathing vapour. Use self-contained breathing
leakage apparatus or supplied air mask for large spills or confined areas.
Contain spill if possible. Wipe up or absorb on suitable material and
shovel up. Prevent entry into sewers and
Procedures in case of accidental release or waterways. Avoid contact with skin, eyes or clothing.
leakage
7. HANDLING AND STORAGE
Handling Periods of exposure to high temperatures should be minimized. Water
contamination should be avoided.
Storage Transport, handle and store in accordance with applicable local
regulations and only in labelled containers designed for this product.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Respiratory protection Airborne concentrations should be kept to lowest levels possible. If
vapour, mist or dust is generated, use approved respirator as
appropriate. Supplied air respiratory protection should be used for
cleaning large spills or upon entry into tanks,
Respiratory protection vessels, or other confined spaces. See below for applicable permissible
concentrations.
Hand and skin protection Avoid skin contact. When contamination has occurred, workers should
wash exposed skin with soap and water. Soiled clothing should be
laundered or dry cleaned.
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33073 HAVOLINE XLC+B 50/50 (OF01)
Eye protection Chemical type goggles or face shield recommended to prevent eye
contact.
Exposure limit for the product Ethylene glycol: OSHA PEL-STEL 50 ppm; ACGIH TLV-STEL 50 ppm.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Fluorescent Orange Liquid
Odour Mild odour
Relative density 1.0707 @ 15 掳C
Viscosity Not determined
pH 8.4 @ 100 %
Solubility in water 100 %
10. STABILITY AND REACTIVITY
Conditions to avoid Sources of ignition such as naked flames, sparks, hot surfaces.
Materials to avoid Avoid contact with strong oxidising agents.
Hazardous decomposition products Oxides of carbon, aldehydes and ketones.
11. TOXICOLOGICAL INFORMATION
Acute
Inhalation High concentrations of vapours or mist are likely to be irritating to the
respiratory tract and may cause nausea, dizziness, headaches and
drowsiness.
Skin contact Slightly irritating to the skin.
Eye contact Unlikely to cause more than transient stinging or redness if accidental
eye contact occurs.
Ingestion Harmful. Causes headache, weakness, confusion, loss of coordination,
dizziness, difficulty walking, nausea, vomiting, decreased blood
pressure, increased heart rate, pulmonary oedema, kidney failure,
unconsciousness, convulsions, and coma. Symptoms may
Ingestion be delayed. Severe poisoning may cause death.
Repeated ingestion may cause kidney damage.
Chronic
Repeated overexposure may aggravate an existing kidney disease.
12. ECOLOGICAL INFORMATION
Mobility Not determined
Persistence and degradability According to EC criteria : Expected to be readily biodegradable
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33073 HAVOLINE XLC+B 50/50 (OF01)
Potential to bioaccumulate This product is estimated to have a low potential to bioconcentrate.
Aquatic toxicity Believed not to be toxic to aquatic species.
Remarks Releases of small quantities are unlikely to affect adversely the
functioning of water treatment plants.
13. DISPOSAL CONSIDERATIONS
Disposal Dispose in accordance with local laws and regulations governing
disposal of chemicals.
14. TRANSPORT INFORMATION
Not regulated
15. REGULATORY INFORMATION
Labelling information
Indication of danger Xn HARMFUL
Risk phrases
Xn R 22 Harmful if swallowed.
Safety phrases for public use
S2 Keep out of the reach of children.
S 46 If swallowed, seek medical advice immediately and show this
container or label.
Safety phrases for industrial use
S 36/37 Wear suitable protective clothing and gloves.
Hazardous ingredients
Ethylene glycol
Xn R 22 Harmful if swallowed.
Refer to any national measures that may be relevant.
Additional information
16. OTHER INFORMATION
Acute or chronic oral consumption of products containing ethylene
glycol can produce significant adverse health effects, including death, in
humans and animals. Keep out of reach of children. Such products
should not be used in potable (drinking) water
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33073 HAVOLINE XLC+B 50/50 (OF01)
systems or other systems where contamination of potable water
supplies is possible (e.g., recreational vehicles, winterizing potable
water systems).
Do not decant into unlabeled containers.
All information contained in this Material Safety Data Sheet and, in particular, the health and safety and environmental information is
accurate to the best of our knowledge and belief as at the date of issue specified. However, the Company makes no warranty or
representation, express or implied, as to the accuracy or completeness of such information.
The provision of this Material Safety Data Sheet is not intended, of itself, to obviate the need for all users to satisfy themselves that the
product described is suitable for their individual purposes and that the safety precautions and environmental advice are adequate for
their individual purposes and situation. Further, it is the user's obligation to use this product safely and to comply with all applicable
laws and regulations concerning the use of the product.
The company accepts no responsibility for any injury, loss or damage, consequent upon any failure to follow the safety and other
recommendations contained in this Material Safety Data Sheet, nor from any hazards inherent in the nature of the material, nor from
any abnormal use of the material.
Version nr : 0.06
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