#820
MATERIAL SAFETY DATA SHEET
NFPA RATING: Health = 2 Flammability = 0 Reactivity = 0
HMIS RATING: Health = /2 Flammability = 0 Reactivity = 0
SECTION I 鈥? IDENTITY AND MANUFACTURER'S INFORMATION (502N-37A)
Manufacturer's Name: HILLYARD INDUSTRIES Product Name: ARSENAL SPRAY CLEAN HD
Address: 302 North Fourth Street Date Prepared: July 31, 2001
St. Joseph, MO 64501 Prepared by: Regulatory Affairs Department
Emergency Telephone No.: (800) 424-9300 (Only in the event of chemical emergency involving a spill, leak, fire, exposure or
accident involving chemicals.) Other information calls: (816) 233-1321 (Ext. 8285)
http://www.hillyard.com
SECTION II 鈥? INGREDIENTS/IDENTITY INFORMATION
(Specific Chemical Identity: OTHER LIMITS
Common Name(s) CAS# OSHA PEL ACGIH TLV RECOMMENDED %
Ethanolamine 141-43-5 3 ppm 3 ppm N/A 1-5%
Dipropylene glycol methyl ether 34590-94-8 100 ppm 100 ppm N/A 17-23%
Water 7732-18-5 none none N/A ---
Propylene glycol butyl ether 5131-66-8 not established not established N/A ---
Linear primary alcohol ethoxylate 68439-46-3 not established not established N/A ---
Tetrasodium salt of EDTA 64-02-8 not established not established N/A ---
V.O.S. (concentrate) = 33%; V.O.S. (Diluted 1:10) = 3%
SECTION III 鈥? PHYSICAL / CHEMICAL CHARACTERISTICS
Specific Gravity (H2O = 1): 25潞C 1.00 & 39潞C = 1.01
Boiling Point: 209掳F
19.5 91.39
Vapor Pressure (mm Hg.): Percent Volatile by Volume (%):
2.05 slower than 1
Vapor Density (AIR = 1): Evaporation Rate (ethyl ether = 1):
complete clear dark purple liquid; mountain berry odor
Solubility in Water: Appearance and Odor:
12
pH (concentrate):
SECTION IV 鈥? FIRE AND EXPLOSION HAZARD DATA
None (T.C.C.) Flammable Limits: LEL = N/A UEL = N/A
Flash point:
Extinguishing Media: Water, carbon dioxide, dry chemical or foam
Special Fire Fighting Procedures: Normal fire fighting procedures may be used. Cool and cautiously approach or handle fire-
exposed containers.
Unusual Fire and Explosion Hazards: N/A
SECTION V 鈥? PHYSICAL HAZARDS
Stable N/A
Stability: Conditions to Avoid:
Incompatibility (Materials to Avoid): Oxidizing materials and strong acids
Hazardous Decomposition Products or Byproducts: Produces normal products of combustion when exposed to fire.
Will not occur None known
Hazardous Polymerization: Conditions to Avoid:
SECTION VI 鈥? HEALTH HAZARD DATA
Routes of entry: Inhalation? Yes Skin? Yes Ingestion? Yes
HEALTH HAZARDS (1. Acute and 2. Chronic)
1. When tested per the Federal Hazardous Substance Act concentrate was not considered a primary skin irritant but was considered to
be an eye irritant. Concentrate was not acutely oral toxic at 5 g./kg. The submitted test sample (concentrated product) was acutely
toxic to 10% of the test subjects following a 1-hour inhalation exposure at a nominal concentration of 43.51 mg./kg. (actual
concentration 24.77 mg.); however when diluted it was not acutely toxic to test subjects following a 1 hour exposure at nominal
concentration of 39.66 mg./L (actual concentration =g./L). This was the maximum concentration that could be generated with this test
system. Direct contact with concentrate in eyes can cause severe irritation and damage. Prolonged and repeated exposure to skin may
produce irritation or damage. DO NOT SPRAY CONCENTRATED PRODUCT. Only spray diluted product. Inhalation of fine fog
mist can cause irritation of mucous membranes. Fine fog mist application is not recommended. Inhalation of spray mist may result in
varying degrees of irritation. 2. None known to Hillyard Inc.
Chemical listed as Carcinogen or Potential Carcinogen:
No No No
National Toxicology Program = I.A.R.C. Monographs = OSHA =
page 2 of #820 鈥? Arsenal Spray Clean HD
SECTION VI 鈥? HEALTH HAZARD DATA continued
This product has no carcinogens listed by IARC, NTP, NIOSH, or ACGIH as of this date, greater than or equal to 0.1%.
Signs and Symptoms of Exposure: Concentrated product may produce skin and eye burns. Ingestion may produce burns
of the mouth, throat, esophagus and stomach.
Medical Conditions Generally Aggravated by Exposure: Skin problems such as industrial dermatitis.
Emergency and First Aid Procedures: Inhalation: Remove person to fresh air. If breathing difficulty persists or occurs
later, call physician. Skin and eye contact: Immediately flush with plenty of water for 15 minutes. Get prompt medical
attention. Remove and wash all contaminated clothing before reuse. Ingestion: Immediately give large amounts of water
and CALL A PHYSICIAN, hospital emergency room or poison control center.
SECTION VII 鈥? PRECAUTIONS FOR SAFE HANDLING AND USE
Steps To Be Taken In Case Material Is Released Or Spilled: Absorb with floor dry or similar inert material. Sweep or
scrape up and put in appropriate container. Rinse spill area thoroughly with water. Use appropriate protective equipment.
Waste Disposal Method: Disposal is regulated by the Resource Conservation and Recovery Act; concentrate is
corrosive per EPA Hazardous Waste classification. Disposal of regulated quantities should be neutralized at a permitted
facility in accordance with all federal, state and local requirements.
Precautions To Be Taken In Handling And Storing: Keep container closed when not in use. Container disposal:
Triple rinse (or equivalent) then offer clean, dry container for recycling or reconditioning. Waste from normal use may be
sewered to public-owned treatment works in compliance with applicable federal, state and local requirements.
Other Precautions: Do not use with fog mist or fine droplet sprayer without respiratory protection. This product
contains no reportable quantities of toxic chemicals subject to reporting requirements of Section 313 of SARA Title III
Emergency Planning and Community Right to Know Act of 1986 and 40 CFR Part 372.
SECTION VIII 鈥? CONTROL MEASURES
Respiratory Protection (Specify Type): Ventilate to keep air concentration below TLV on ethanolamine.
Ventilation:
Recommended Mechanical (General) = Recommended
Local Exhaust =
N/A N/A
Special = Other =
Other Protective Clothing or Equipment: Impervious to water and alkaline liquid where concentrate is a concern
Work / Hygienic Practices: Wash thoroughly after handling.
SECTION IX 鈥? TRANSPORTATION INFORMATION
Applicable regulations: DOT = no; IMCO = no; IATA = no
Proper shipping name: Cleaning compound
UN No.: not applicable Limited Qty.: not applicable Hazard Class: not applicable
Labels required: not required DOT Exception: not applicable
EPA Hazardous waste/number code: not listed
Hazardous waste characteristics:
Ignitability = not applicable; Corrosivity = yes; Reactivity = not applicable
DISCLAIMER OF WARRANTIES
NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY,
FITNESS FOR A PARTICULAR PURPOSE, OR OF ANY NATURE ARE MADE WITH RESPECT TO THE
PRODUCT(S) OR INFORMATION CONTAINED IN THIS MATERIAL SAFETY DATA SHEET.
The information and recommendations contained in this Material Safety Data Sheet are supplied pursuant to 29
CFR 1910.1200 of the Occupational Safety and Health Standards Hazard Communication Rule. All information
contained herein is presented in good faith and is believed to be appropriate and accurate.
THE BUYER OR USER ASSUMES ALL RISKS ASSOCIATED WITH THE USE, MISUSE OR DISPOSAL OF
THIS PRODUCT. THE BUYER OR USER IS RESPONSIBLE TO COMPLY WITH ALL FEDERAL, STATE
OR LOCAL REGULATIONS CONCERNING THE USE, MISUSE OR DISPOSAL OF THESE PRODUCTS.
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