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APG                                                                                                        Material Safety Data Sheet

Analytical Products Group, Inc.                                                                                Date prepared on: 3/8/00



2730 Washington Blvd., Belpre, OH 45714                                                                        Last revised on: 02/27/07

740-423-4200 800-272-4442 Fax 740-423-5588

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Section I: Product Identification

CATALOG NUMBER: 182001/183134                                           PRODUCT NAME: 0.0473N Iodine







Section II - Hazardous Ingredients/Identity Information



Chemical Name                                                           CAS Reg. No.                           OSHA PEL (TWA)                   % Composition*



Iodine                                                                  7553-56-2                              Cl 0.1 ppm                       0.6%



Potassium Iodide                                                        7681-11-0                              N/A                              5.7%







           Non-Hazardous Ingredients/Identity Information



Chemical Name                                                           CAS Reg. No.                           OSHA PEL (TWA)                   % Composition*



Water                                                                   7732-18-5                              N/A                              93.7%



* components are calculated on a weight/weight basis.





Section III - Physical/Chemical Characteristics of Hazardous Ingredients



Iodine

BOILING POINT: 185.24o C sublimes                                                         SPECIFIC GRAVITY: 4.93

                                        o

VAPOR PRESSURE: 0.03mm Hg @ 0 C                           SOLUBILITY IN WATER:         Very slightly soluble          APPEARANCE/ODOR: Violet-black crystals with

                                                                                                                      metallic luster.







Potassium Iodide

BOILING POINT: 1420o C                                                                    SPECIFIC GRAVITY: 3.13



VAPOR PRESSURE: 1mm Hg @ 745o C                           SOLUBILITY IN WATER: Soluble                                APPEARANCE/ODOR:           Color or white crystals or

                                                                                                                      granules.





Section IV - Fire and Explosion Hazard Data



FLASH POINT (Method used): Non-flammable                 AUTO IGNITION TEMPERATURE: N/A                              FLAMMABLE LIMITS         LEL N/A         UEL N/A



EXTINGUISHING MEDIA: Non-flammable: use agent most appropriate for surrounding fires.



SPECIAL FIRE FIGHTING PROCEDURES: As in any fire, wear a self-contained breathing apparatus in pressure demand, MSHA/NIOSH, and full protective gear. Use

water spray to keep exposed containers cool.

UNUSUAL FIRE AND EXPLOSION HAZARDS: Avoid irritating and toxic vapors.







Section V - Reactivity Data



                                     Unstable               Stable                  Conditions to Avoid: Incompatible materials.

          STABILITY:



INCOMPATIBILITY (Materials to avoid):

 IODINE: Violent or explosive reactions with gaseous or aqueous ammonia, acetylene, acetaldehyde, powdered aluminum, active metals; ethanolic solutions or

mercuric oxide, phosphorous; oxygen and trioxygen difluoride, ammonium hydroxide, sodium phosphinaye anhydrous, chlorine, metal carbides. Ignition/incandescent

reactions with phosphorus, bromine pentafluoride, chlorine trifluoride, halogens or interhalogens, zinc/water, fluorine, sodium hydride, other reducing materials, active

metals.     POTASSIUM IODIDE: Violent reactions with bromine pentafluoride, chlorine trifluoride, perchlorates, alkali metals, strong oxidants, diazonium salts,

trifluoroacetyl hypofluorite.



HAZARDOUS DECOMPOSITION PRODUCTS: Toxic potassium oxide, iodine and hydrogen iodine.



        HAZARDOUS                    May Occur              Will Not Occur          Conditions to Avoid:       N/A

      POLYMERIZATION:

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Section VI - Health Hazard Data



ROUTES OF                Inhalation? Yes                                    Skin? Yes                                         Ingestion? Yes

ENTRY

HEALTH HAZARDS (Acute and Chronic): ACUTE: Iodine may cause severe irritation to the respiratory tract causing sore throat, headache, vertigo, runny nose, fever,

aches, fluid in the lungs, chest tightness, frothy sputum, dyspnea. Dermal irritation, skin rash (sensitization) may occur with burns, blistering, and lesions. Iodine

solutions irritate and stain the eye, corrosion of epithelial layer can occur. Ingestion can result in severe vomiting, diarrhea, pain, thirst, metallic taste, shock, fever,

anuria, delirium, stupor, hemorrhagic nephritis, death. Fatal dose estimated at 2gm iodine. CHRONIC: “IODISM� may occur with symptoms of runny nose, bronchitis,

weight loss, insomnia, tremors, tachycardia, parotitis, diarrhea, laryngeal edema, skin rash (dermatitis), serum sickness (lymph node enlargement, joint swelling/pain

conjunctivitis, stomatitis, sneezing, headache, fever, erythema, acne, urtcaria). Use of iodides in pregnant asthmatics resulted in fetal death, cretinism, and severe

goiter.



COMPONENTS LISTED AS CARCINOGENS OR POTENTIAL CARCINOGENS: N/A



SIGNS AND SYMPTOMS OF EXPOSURE: Irritation or stain of eyes, skin. Irritation of respiratory and digestive tracts.



MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:                         Skin and respiratory disorders. Disease of thyroid, kidneys.



EMERGENCY AND FIRST AID PROCEDURES: Inhalation: Move victim to fresh air, give artificial respiration if necessary. Maintain airway, blood pressure. Medical

personnel may give oxygen. Keep victim warm, at rest. Get medical aid at once. Skin: Remove contaminated clothing and immediately wash affected area with soap

and water. Flush with large amounts of water (15-20 minutes), until chemical is gone. Skin eruptions may be treated with mild astringent and wet dressing. Get medical

aid. Eyes: Flush immediately with large amounts of water (15-20 minutes) lifting upper/lower lids occasionally until chemical is gone. Get medical attention.

Ingestion: Give conscious victim milk. Absorb iodine with starch solution (15 grams cornstarch or flour to 500ml water). Maintain airway and respiration. Emesis and

lavage should not be performed where there is esophageal injury. Milk every 15 minutes may relieve gastric irritation. Get medical aid at once.







Section VII - Precautions for Safe Handling and Use



STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:                     May be neutralized with soda ash, or absorbed with inert material.



WASTE DISPOSAL METHOD: Dispose of in a manner consistent with federal, state and local regulations.



PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:                     Store at room temperature, capped.



OTHER PRECAUTIONS* Wear impervious clothing.







Section VIII - Control Measures



RESPIRATORY PROTECTION (Please specify): Follow OSHA respirator regulations found in 29CFR 1010.134 when necessary.



VENTILATION: Provide local exhaust or genial dilution ventilation.



PROTECTIVE GLOVES: Wear appropriate glove.                                              EYE PROTECTION: Wear appropriate protective glasses or safety goggles.



OTHER PROTECTIVE EQUIPMENT:



EMERGENCY WASH FACILITIES: Provide eye-wash fountain and drench shower in work area.







The information stated in this Material Safety Data Sheet (MSDS) is believed to be correct on the date of publication and must not

be considered all conclusive. The information has been obtained only by a search of available literature and is only a guide for

handling the chemicals. Persons not specifically and properly trained should not handle this chemical or its container. This

MSDS is provided without any warranty expressed or implied, including merchantability or fitness for any particular purpose.



This product is furnished for laboratory use ONLY! Our standards may not be used as drugs, cosmetics, agricultural or pesticidal

products, food additives or as house hold chemicals.



* Various Government agencies (i.e., Department of Transportation, Occupational Safety and Health Administration,

Environmental Protection Agency, and others) may have specific regulations concerning the transportation, handling, storage or

use of this product which may not be contained herein. The customer or user of this product should be familiar with these

regulations.