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MSDS Material Safety Data Sheet
CAS

71-23-8

File Name: palomar_edu---1-propanol.asp
 
                      PRODUCT #: 110035       NAME: 1-PROPANOL, 99+%

                      MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                         Printed Thursday, March 13, 1903 3:01PM



Sigma Chemical Co.          Aldrich Chemical Co., Inc.    Fluka Chemical Corp.

P.O. Box 14508              1001 West St. Paul            1001 West St. Paul

St. Louis, MO 63178         Milwaukee, WI 53233           Milwaukee, WI 53233

Phone: 314-771-5765         Phone: 414-273-3850           Phone: 414-273-3850









SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -

    CATALOG #:            110035

    NAME:                 1-PROPANOL, 99+%

SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -

    CAS #:     71-23-8

    MF: C3H8O

    EC NO: 200-746-9

  SYNONYMS

    ALCOOL PROPILICO (ITALIAN) * ALCOOL PROPYLIQUE (FRENCH) * ETHYL

    CARBINOL * 1-HYDROXYPROPANE * OPTAL * OSMOSOL EXTRA * PROPANOL * N-

    PROPANOL (DOT) * PROPANOL-1 * 1-PROPANOL * PROPANOLE (GERMAN) *

    PROPANOLEN (DUTCH) * PROPANOLI (ITALIAN) * N-PROPYL ALCOHOL * 1-

    PROPYL ALCOHOL * N-PROPYL ALCOHOL (ACGIH:OSHA) * PROPYL ALCOHOL,

    NORMAL (DOT) * N-PROPYL ALKOHOL (GERMAN) * PROPYLIC ALCOHOL *

    PROPYLOWY ALKOHOL (POLISH) * UN1274 (DOT) *

SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -

  LABEL PRECAUTIONARY STATEMENTS

    FLAMMABLE (USA)

    HIGHLY FLAMMABLE (EU)

    HARMFUL

    HARMFUL BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED.

    IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.

    RISK OF SERIOUS DAMAGE TO EYES.

    TARGET ORGAN(S):

    NERVES

    LIVER

    KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.

    KEEP CONTAINER TIGHTLY CLOSED IN A COOL WELL-VENTILATED PLACE.

    IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF

    WATER AND SEEK MEDICAL ADVICE.

    WEAR SUITABLE PROTECTIVE CLOTHING.

SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -

    IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH COPIOUS AMOUNTS OF

    WATER FOR AT LEAST 15 MINUTES.

    ASSURE ADEQUATE FLUSHING OF THE EYES BY SEPARATING THE EYELIDS

    WITH FINGERS.

    IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS

    AMOUNTS OF WATER.

    IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL

    RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.

    IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.

    CALL A PHYSICIAN.

    REMOVE AND WASH CONTAMINATED CLOTHING PROMPTLY.

SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -

  EXTINGUISHING MEDIA

    CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM.

  SPECIAL FIREFIGHTING PROCEDURES

    WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO

    PREVENT CONTACT WITH SKIN AND EYES.



                                           Page 1

                     PRODUCT #: 110035       NAME: 1-PROPANOL, 99+%

                     MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                        Printed Thursday, March 13, 1903 3:01PM



    USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS.

    FLAMMABLE LIQUID.

  UNUSUAL FIRE AND EXPLOSIONS HAZARDS

    VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION AND

    FLASH BACK.

    CONTAINER EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS.

SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -

    EVACUATE AREA.

    SHUT OFF ALL SOURCES OF IGNITION.

    WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY

    RUBBER GLOVES.

    COVER WITH AN ACTIVATED CARBON ADSORBENT, TAKE UP AND PLACE IN CLOSED

    CONTAINERS. TRANSPORT OUTDOORS.

    USE NONSPARKING TOOLS.

    VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.

SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -

    REFER TO SECTION 8.

SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -

    CHEMICAL SAFETY GOGGLES.

    SAFETY SHOWER AND EYE BATH.

    RUBBER GLOVES.

    MECHANICAL EXHAUST REQUIRED.

    NIOSH/MSHA-APPROVED RESPIRATOR.

    DO NOT GET IN EYES, ON SKIN, ON CLOTHING.

    DO NOT BREATHE VAPOR.

    WASH THOROUGHLY AFTER HANDLING.

    SEVERE EYE IRRITANT.

    HARMFUL LIQUID AND FUMES.

    KEEP TIGHTLY CLOSED.

    KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME.

    STORE IN A COOL DRY PLACE.

SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -

  PHYSICAL PROPERTIES

    BOILING POINT:          97 C

    MELTING POINT:       -127 C

    FLASHPOINT                    59 F

                                  14C

    EXPLOSION LIMITS IN AIR:

      UPPER                                    13.7%

      LOWER                                    2.1%

    AUTOIGNITION TEMPERATURE:          700 F         370C

    VAPOR PRESSURE:       14.9MM 20 C

    SPECIFIC GRAVITY:       0.804

    VAPOR DENSITY:      2.1

SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -

  INCOMPATIBILITIES

    OXIDIZING AGENTS

    ACID CHLORIDES

    ACID ANHYDRIDES

    ACIDS

    HALOGENS

    ALUMINUM

  HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS

    TOXIC FUMES OF:

    CARBON MONOXIDE, CARBON DIOXIDE

SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -

  ACUTE EFFECTS



                                          Page 2

                     PRODUCT #: 110035       NAME: 1-PROPANOL, 99+%

                     MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                        Printed Thursday, March 13, 1903 3:01PM



    HARMFUL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN.

    CAUSES SEVERE EYE IRRITATION.

    CAUSES SKIN IRRITATION.

    MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND UPPER

    RESPIRATORY TRACT.

    CAN CAUSE CNS DEPRESSION.

    PROLONGED EXPOSURE CAN CAUSE:

    NAUSEA, HEADACHE AND VOMITING

    NARCOTIC EFFECT

    TARGET ORGAN(S):

    NERVES

    LIVER

  RTECS #: UH8225000

    PROPYL ALCOHOL

  IRRITATION DATA

    SKN-RBT 500 MG OPEN MLD                       UCDS** 6/28/1972

    SKN-RBT 20 MG/24H MOD                         85JCAE -,191,1986

    EYE-RBT 4 MG OPEN SEV                         AMIHBC 10,61,1954

    EYE-RBT 20 MG/24H MOD                         85JCAE -,191,1986

  TOXICITY DATA

    ORL-WMN LDLO:5700 MG/KG                       ATXKA8 16,84,1956

    ORL-RAT LD50:1870 MG/KG                       AMIHBC 10,61,1954

    IPR-RAT LD50:2164 MG/KG                       EVHPAZ 61,321,1985

    IVN-RAT LD50:590 MG/KG                        EVHPAZ 61,321,1985

    ORL-MUS LD50:6800 MG/KG                       PSDTAP 9,276,1968

    IHL-MUS LC50:48 GM/M3                         GTPZAB 18(3),48,1974

    IPR-MUS LD50:3125 MG/KG                       EVHPAZ 61,321,1985

    SCU-MUS LD50:4700 MG/KG                       TXAPA9 18,185,1971

    IVN-MUS LD50:697 MG/KG                        EVHPAZ 61,321,1985

    ORL-RBT LD50:2825 MG/KG                       IMSUAI 41,31,1972

    SKN-RBT LD50:4060 MG/KG                       AMIHBC 10,61,1954

    IPR-RBT LD50:515 MG/KG                        EVHPAZ 61,321,1985

    IVN-RBT LD50:483 MG/KG                        EVHPAZ 61,321,1985

    IPR-GPG LD50:1208 MG/KG                       EVHPAZ 61,321,1985

    IPR-HAM LD50:2338 MG/KG                       EVHPAZ 61,321,1985

    ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES

    (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR

    COMPLETE INFORMATION.

SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -

    DATA NOT YET AVAILABLE.

SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -

    BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND

    SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS MATERIAL IS HIGHLY

    FLAMMABLE.

    OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.

SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -

    CONTACT ALDRICH CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.

SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -

  EUROPEAN INFORMATION

    EC INDEX NO:      603-003-00-0

    HIGHLY FLAMMABLE

    HARMFUL

    R 11

    HIGHLY FLAMMABLE.

    S7

    KEEP CONTAINER TIGHTLY CLOSED.

    S 16



                                          Page 3

                     PRODUCT #: 110035       NAME: 1-PROPANOL, 99+%

                     MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                        Printed Thursday, March 13, 1903 3:01PM



    KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.

  REVIEWS, STANDARDS, AND REGULATIONS

    OEL=MAK

    ACGIH TLV-STEL 614 MG/M3 (250 PPM) (SKIN)      DTLVS* TLV/BEI,1996

    ACGIH TLV-TWA 492 MG/M3 (200 PPM)              DTLVS* TLV/BEI,1996

    EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION

     FEREAC 54,7740,1989

    MSHA STANDARD-AIR:TWA 200 PPM (490 MG/M3)

     DTLVS* 3,217,1971

    OSHA PEL (GEN INDU):8H TWA 200 PPM (500 MG/M3)

     CFRGBR 29,1910.1000,1994

    OSHA PEL (CONSTRUC):8H TWA 200 PPM (500 MG/M3)

     CFRGBR 29,1926.55,1994

    OSHA PEL (SHIPYARD):8H TWA 200 PPM (500 MG/M3)

     CFRGBR 29,1915.1000,1993

    OSHA PEL (FED CONT):8H TWA 200 PPM (500 MG/M3)

     CFRGBR 41,50-204.50,1994

    OEL-AUSTRALIA:TWA 200 PPM (500 MG/M3);STEL 250 PPM;SKIN JAN 1993

    OEL-BELGIUM:TWA 200 PPM (492 MG/M3);STEL 250 PPM;SKIN JAN 1993

    OEL-DENMARK:TWA 200 PPM (500 MG/M3);SKIN JAN 1993

    OEL-FINLAND:TWA 200 PPM (500 MG/M3);STEL 250 PPM;SKIN JAN 1993

    OEL-FRANCE:TWA 200 PPM (500 MG/M3) JAN 1993

    OEL-HUNGARY:TWA 100 MG/M3;STEL 200 MG/M3 JAN 1993

    OEL-POLAND:TWA 200 MG/M3 JAN 1993

    OEL-RUSSIA:STEL 10 MG/M3 JAN 1993

    OEL-SWEDEN:TWA 150 PPM (350 MG/M3);STEL 250 PPM (ALL ISOMERS) JAN 1993

    OEL-SWITZERLAND:TWA 200 PPM (500 MG/M3);SKIN JAN 1993

    OEL-TURKEY:TWA 200 PPM (500 MG/M3) JAN 1993

    OEL-UNITED KINGDOM:TWA 200 PPM (500 MG/M3);STEL 250 PPM;SKIN JAN 1993

    OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA CHECK ACGIH TLV

    OEL IN NEW ZEALAND, SINGAPORE, VIETNAM CHECK ACGIH TLV

    NIOSH REL TO PROPYL ALCOHOL-AIR:TWA 200 PPM (SK);STEL 250 PPM (SK)

     NIOSH* DHHS #92-100,1992

    NOHS 1974: HZD M0256; NIS 151; TNF 18176; NOS 103; TNE 122603

    NOES 1983: HZD M0256; NIS 130; TNF 17036; NOS 99; TNE 226129; TFE 84196

    EPA GENETOX PROGRAM 1988, NEGATIVE: IN VITRO SCE-NONHUMAN

    EPA TSCA SECTION 8(B) CHEMICAL INVENTORY

    EPA TSCA SECTION 8(D) UNPUBLISHED HEALTH/SAFETY STUDIES

    EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, APRIL 1997

    NIOSH ANALYTICAL METHOD, 1994: ALCOHOLS II, 1401

SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -

    THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO

    BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,

    FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING

    OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR

    PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.

    COPYRIGHT 1997 SIGMA CHEMICAL CO., ALDRICH CHEMICAL CO., INC.,

    FLUKA CHEMIE AG

    LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY









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