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MSDS Material Safety Data Sheet
CAS

111-78-4
100-40-3

File Name: palomar_edu---15-cyclooctadiene.asp
 
                 PRODUCT #: C109207       NAME: 1,5-CYCLOOCTADIENE, 99%

                     MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                        Printed Thursday, March 20, 1903 11:28AM



Sigma Chemical Co.         Aldrich Chemical Co., Inc.     Fluka Chemical Corp.

P.O. Box 14508             1001 West St. Paul             1001 West St. Paul

St. Louis, MO 63178        Milwaukee, WI 53233            Milwaukee, WI 53233

Phone: 314-771-5765        Phone: 414-273-3850            Phone: 414-273-3850









SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -

    CATALOG #:            C109207

    NAME:                 1,5-CYCLOOCTADIENE, 99%

SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -

    CAS #:    111-78-4

    MF: C8H12

    EC NO: 203-907-1

  ADDITIONAL INFORMATION

    CONTAINS 4-VINYL-1-CYCLOHEXENE, CHEMICAL ABSTRACTS REGISTRY NUMBER

    100-40-3.

  SYNONYMS

    COD * CIS,CIS-CYCLOOCTA-1,5-DIENE *

SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -

  LABEL PRECAUTIONARY STATEMENTS

    FLAMMABLE

    TOXIC

    MAY CAUSE CANCER.

    MAY CAUSE SENSITIZATION BY INHALATION AND SKIN CONTACT.

    CAUSES SEVERE IRRITATION.

    TARGET ORGAN(S):

    BLOOD

    KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.

    TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.

    IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF

    WATER AND SEEK MEDICAL ADVICE.

    AFTER CONTACT WITH SKIN, WASH IMMEDIATELY WITH PLENTY OF WATER.

    WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE

    PROTECTION.

    HANDLE AND STORE UNDER NITROGEN.

SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -

    IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS

    AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED

    CLOTHING AND SHOES.

    ASSURE ADEQUATE FLUSHING OF THE EYES BY SEPARATING THE EYELIDS

    WITH FINGERS.

    IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL

    RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.

    IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.

    CALL A PHYSICIAN.

    WASH CONTAMINATED CLOTHING BEFORE REUSE.

SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -

  EXTINGUISHING MEDIA

    WATER SPRAY.

    CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM.

  SPECIAL FIREFIGHTING PROCEDURES

    WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO

    PREVENT CONTACT WITH SKIN AND EYES.

    FLAMMABLE LIQUID.

  UNUSUAL FIRE AND EXPLOSIONS HAZARDS



                                          Page 1

                 PRODUCT #: C109207       NAME: 1,5-CYCLOOCTADIENE, 99%

                     MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                        Printed Thursday, March 20, 1903 11:28AM



    VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION AND

    FLASH BACK.

SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -

    EVACUATE AREA.

    WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY

    RUBBER GLOVES.

    WEAR DISPOSABLE COVERALLS AND DISCARD THEM AFTER USE.

    ABSORB ON SAND OR VERMICULITE AND PLACE IN CLOSED CONTAINERS FOR

    DISPOSAL.

    VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.

    AVOID INHALATION.

SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -

    REFER TO SECTION 8.

SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -

    WEAR APPROPRIATE NIOSH/MSHA-APPROVED RESPIRATOR, CHEMICAL-RESISTANT

    GLOVES, SAFETY GOGGLES, OTHER PROTECTIVE CLOTHING.

    SAFETY SHOWER AND EYE BATH.

    USE ONLY IN A CHEMICAL FUME HOOD.

    DO NOT BREATHE VAPOR.

    DO NOT GET IN EYES, ON SKIN, ON CLOTHING.

    AVOID PROLONGED OR REPEATED EXPOSURE.

    WASH THOROUGHLY AFTER HANDLING.

    CARCINOGEN.

    SEVERE IRRITANT.

    SENSITIZER.

    KEEP TIGHTLY CLOSED.

    KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME.

    STORE IN A COOL DRY PLACE.

SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -

  APPEARANCE AND ODOR

    COLORLESS LIQUID

  PHYSICAL PROPERTIES

    BOILING POINT:         149 C TO 150 C

    MELTING POINT:       -69 C

    FLASHPOINT                   89 F

                                 31C

    AUTOIGNITION TEMPERATURE:         431 F           221C

    VAPOR PRESSURE:       6.8MM 25 C        25.8MM 37.7 C

    SPECIFIC GRAVITY:      0.882

SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -

  INCOMPATIBILITIES

    STRONG OXIDIZING AGENTS

  HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS

    TOXIC FUMES OF:

    CARBON MONOXIDE, CARBON DIOXIDE

SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -

  ACUTE EFFECTS

    HARMFUL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN.

    CAUSES SEVERE IRRITATION.

    HIGH CONCENTRATIONS ARE EXTREMELY DESTRUCTIVE TO TISSUES OF THE MUCOUS

    MEMBRANES AND UPPER RESPIRATORY TRACT, EYES AND SKIN.

    SYMPTOMS OF EXPOSURE MAY INCLUDE BURNING SENSATION, COUGHING,

    WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND

    VOMITING.

    MAY CAUSE ALLERGIC RESPIRATORY AND SKIN REACTIONS.

  CHRONIC EFFECTS

    CARCINOGEN.



                                          Page 2

                 PRODUCT #: C109207       NAME: 1,5-CYCLOOCTADIENE, 99%

                     MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                        Printed Thursday, March 20, 1903 11:28AM



    TARGET ORGAN(S):

    BLOOD

  RTECS #: GX9620000

    1,5-CYCLOOCTADIENE (Z,Z)

  IRRITATION DATA

    SKN-MUS 100%/12D OPEN SEV                     BJIMAG 25,75,1968

    SKN-RBT 2640 MG SEV                           BJIMAG 25,75,1968

    SKN-RBT 20 GM/31D-I OPEN SEV                  BJIMAG 25,75,1968

    EYE-RBT 88 MG MLD                             BJIMAG 25,75,1968

    SKN-GPG 10 GM/31D-I OPEN SEV                  BJIMAG 25,75,1968

    ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES

    (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR

    COMPLETE INFORMATION.

SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -

    DATA NOT YET AVAILABLE.

SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -

    BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND

    SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS MATERIAL IS HIGHLY

    FLAMMABLE.

    OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.

SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -

    CONTACT ALDRICH CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.

SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -

  EUROPEAN INFORMATION

    FLAMMABLE

    TOXIC

    R 45

    MAY CAUSE CANCER.

    R 42/43

    MAY CAUSE SENSITIZATION BY INHALATION AND SKIN CONTACT.

    FLAMMABLE

    S 16

    KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.

    S 27

    TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.

    S 26

    IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF

    WATER AND SEEK MEDICAL ADVICE.

    S 28

    AFTER CONTACT WITH SKIN, WASH IMMEDIATELY WITH PLENTY OF WATER.

    S 36/37/39

    WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE

    PROTECTION.

  TLV AND SOURCE

    FOR CYCLOOCTADIENE:

    MANUFACTURER'S EXPOSURE LIMIT: 5 PPM - 8 & 12 HR. TWA

SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -

    THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO

    BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,

    FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING

    OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR

    PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.

    COPYRIGHT 1997 SIGMA CHEMICAL CO., ALDRICH CHEMICAL CO., INC.,

    FLUKA CHEMIE AG

    LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY







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