PRODUCT #: 183164 NAME: (R)-(+)-LIMONENE, 97%
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Wednesday, March 12, 1903 2:58PM
Sigma Chemical Co. Aldrich Chemical Co., Inc. Fluka Chemical Corp.
P.O. Box 14508 1001 West St. Paul 1001 West St. Paul
St. Louis, MO 63178 Milwaukee, WI 53233 Milwaukee, WI 53233
Phone: 314-771-5765 Phone: 414-273-3850 Phone: 414-273-3850
SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -
CATALOG #: 183164
NAME: (R)-(+)-LIMONENE, 97%
SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -
CAS #: 5989-27-5
MF: C10H16
EC NO: 227-813-5
SYNONYMS
CARVENE * CYCLOHEXENE, 4-ISOPROPENYL-1-METHYL- * (+)-4-ISOPROPENYL-1-
METHYLCYCLOHEXENE * D-LIMONENE * D-(+)-LIMONENE * (+)-R-LIMONENE * D-
LIMONENO (SPANISH) * D-P-MENTHA-1,8-DIENE * P-MENTHA-1,8-DIENE, (R)-
(+)- * (R)-1-METHYL-4-(1-METHYLETHENYL)CYCLOHEXENE * NCI-C55572 *
REFCHOLE *
SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -
LABEL PRECAUTIONARY STATEMENTS
COMBUSTIBLE (USA)
FLAMMABLE (EU)
HARMFUL
HARMFUL BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED.
IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
MAY CAUSE SENSITIZATION BY SKIN CONTACT.
POSSIBLE RISK OF IRREVERSIBLE EFFECTS.
POSSIBLE CARCINOGEN.
TARGET ORGAN(S):
KIDNEYS
KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
WATER AND SEEK MEDICAL ADVICE.
WEAR SUITABLE PROTECTIVE CLOTHING.
SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED
CLOTHING AND SHOES.
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.
CALL A PHYSICIAN.
DISCARD CONTAMINATED CLOTHING AND SHOES.
SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -
EXTINGUISHING MEDIA
CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM.
SPECIAL FIREFIGHTING PROCEDURES
WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN AND EYES.
COMBUSTIBLE.
UNUSUAL FIRE AND EXPLOSIONS HAZARDS
VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION AND
FLASH BACK.
SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -
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PRODUCT #: 183164 NAME: (R)-(+)-LIMONENE, 97%
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Wednesday, March 12, 1903 2:58PM
EVACUATE AREA.
WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY
RUBBER GLOVES.
WEAR DISPOSABLE COVERALLS AND DISCARD THEM AFTER USE.
ABSORB ON SAND OR VERMICULITE AND PLACE IN CLOSED CONTAINERS FOR
DISPOSAL.
VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -
REFER TO SECTION 8.
SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -
CHEMICAL SAFETY GOGGLES.
NIOSH/MSHA-APPROVED RESPIRATOR.
RUBBER GLOVES.
USE ONLY IN A CHEMICAL FUME HOOD.
SAFETY SHOWER AND EYE BATH.
DO NOT BREATHE VAPOR.
DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
WASH THOROUGHLY AFTER HANDLING.
IRRITANT.
HARMFUL LIQUID AND FUMES.
SENSITIZER.
POSSIBLE CARCINOGEN.
KEEP TIGHTLY CLOSED.
KEEP AWAY FROM HEAT AND OPEN FLAME.
STORE IN A COOL DRY PLACE.
SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -
APPEARANCE AND ODOR
COLORLESS LIQUID
PHYSICAL PROPERTIES
BOILING POINT: 175.5 C TO 176 C
FLASHPOINT 119 F
48C
EXPLOSION LIMITS IN AIR:
UPPER 6.1%
LOWER 0.7%
VAPOR PRESSURE: <3MM 14.4 C
SPECIFIC GRAVITY: 0.840
VAPOR DENSITY: 4.7
SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -
INCOMPATIBILITIES
STRONG OXIDIZING AGENTS
HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS
TOXIC FUMES OF:
CARBON MONOXIDE, CARBON DIOXIDE
SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -
ACUTE EFFECTS
MAY BE HARMFUL BY INHALATION, INGESTION, OR SKIN ABSORPTION.
VAPOR OR MIST IS IRRITATING TO THE EYES, MUCOUS MEMBRANES AND UPPER
RESPIRATORY TRACT.
CAUSES SKIN IRRITATION.
MAY CAUSE ALLERGIC SKIN REACTION.
EXPOSURE CAN CAUSE:
NAUSEA, VOMITING, DIARRHEA
CHRONIC EFFECTS
POSSIBLE CARCINOGEN.
TARGET ORGAN(S):
KIDNEYS
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PRODUCT #: 183164 NAME: (R)-(+)-LIMONENE, 97%
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Wednesday, March 12, 1903 2:58PM
TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND
TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.
RTECS #: GW6360000
CYCLOHEXENE, 1-METHYL-4-(1-METHYLETHENYL)-, (R)-
TOXICITY DATA
ORL-RAT LD50:4400 MG/KG OYYAA2 9,387,1975
IPR-RAT LD50:3600 MG/KG OYYAA2 9,387,1975
IVN-RAT LD50:110 MG/KG OYYAA2 9,387,1975
ORL-MUS LD50:5600 MG/KG OYYAA2 9,387,1975
IPR-MUS LD50:600 MG/KG OYYAA2 8,1439,1974
SCU-MUS LD50:3170 MG/KG SIZSAR 3,73,1952
SKN-RBT LD50:>5 GM/KG FCTXAV 13,825,1975
TARGET ORGAN DATA
BEHAVIORAL (ALTERED SLEEP TIME)
BEHAVIORAL (SOMNOLENCE)
BEHAVIORAL (CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD)
LUNGS, THORAX OR RESPIRATION (RESPIRATORY DEPRESSION)
SKIN AND APPENDAGES (HAIR)
NUTRITIONAL AND GROSS METABOLIC (BODY TEMPERATURE DECREASE)
ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES
(RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR
COMPLETE INFORMATION.
SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -
DATA NOT YET AVAILABLE.
SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -
THIS COMBUSTIBLE MATERIAL MAY BE BURNED IN A CHEMICAL INCINERATOR
EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.
OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -
CONTACT ALDRICH CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.
SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -
EUROPEAN INFORMATION
FLAMMABLE
HARMFUL
R 20/21/22
HARMFUL BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED.
R 36/37/38
IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
R 43
MAY CAUSE SENSITIZATION BY SKIN CONTACT.
R 40
POSSIBLE RISK OF IRREVERSIBLE EFFECTS.
FLAMMABLE
S 16
KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.
S 26
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
WATER AND SEEK MEDICAL ADVICE.
S 36
WEAR SUITABLE PROTECTIVE CLOTHING.
REVIEWS, STANDARDS, AND REGULATIONS
OEL=MAK
IARC CANCER REVIEW:ANIMAL LIMITED EVIDENCE IMEMDT 56,135,1993
IARC CANCER REVIEW:HUMAN NO AVAILABLE DATA IMEMDT 56,135,1993
IARC CANCER REVIEW:GROUP 3 IMEMDT 56,135,1993
NOES 1983: HZD X9088; NIS 87; TNF 8310; NOS 65; TNE 138309; TFE 35634
EPA TSCA SECTION 8(B) CHEMICAL INVENTORY
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PRODUCT #: 183164 NAME: (R)-(+)-LIMONENE, 97%
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Wednesday, March 12, 1903 2:58PM
EPA TSCA SECTION 8(D) UNPUBLISHED HEALTH/SAFETY STUDIES
ON EPA IRIS DATABASE
EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, APRIL 1997
NTP CARCINOGENESIS STUDIES (GAVAGE);CLEAR EVIDENCE:RAT
NTPTR* NTP-TR-347,90
NTP CARCINOGENESIS STUDIES (GAVAGE);NO EVIDENCE:MOUSE
NTPTR* NTP-TR-347,90
SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -
THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO
BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,
FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING
OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR
PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.
COPYRIGHT 1997 SIGMA CHEMICAL CO., ALDRICH CHEMICAL CO., INC.,
FLUKA CHEMIE AG
LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY
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