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MSDS Material Safety Data Sheet
CAS

927-68-4
108-24-7

File Name: palomar_edu---2-bromoethyl_acetate.asp
 
                PRODUCT #: 137685       NAME: 2-BROMOETHYL ACETATE, 97%

                     MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                         Printed Monday, March 10, 1903 3:23PM



Sigma Chemical Co.         Aldrich Chemical Co., Inc.     Fluka Chemical Corp.

P.O. Box 14508             1001 West St. Paul             1001 West St. Paul

St. Louis, MO 63178        Milwaukee, WI 53233            Milwaukee, WI 53233

Phone: 314-771-5765        Phone: 414-273-3850            Phone: 414-273-3850









SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -

    CATALOG #:            137685

    NAME:                 2-BROMOETHYL ACETATE, 97%

SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -

    CAS #:    927-68-4

    MF: C4H7BRO2

    EC NO: 213-159-8

  ADDITIONAL INFORMATION

    CONTAINS ACETIC ANHYDRIDE, CHEMICAL ABSTRACTS REGISTRY NUMBER 108-24-7.

  SYNONYMS

    BROMOETHYL ACETATE * 2-BROMOETHYLACETATE *

SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -

  LABEL PRECAUTIONARY STATEMENTS

    CORROSIVE

    HARMFUL BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED.

    CAUSES BURNS.

    POSSIBLE RISK OF IRREVERSIBLE EFFECTS.

    POSSIBLE MUTAGEN.

    LACHRYMATOR.

    COMBUSTIBLE.

    KEEP AWAY FROM HEAT AND OPEN FLAME.

    DO NOT BREATHE VAPOR.

    IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF

    WATER AND SEEK MEDICAL ADVICE.

    IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE

    IMMEDIATELY (SHOW THE LABEL WHERE POSSIBLE).

    WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE

    PROTECTION.

SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -

    IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS

    AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED

    CLOTHING AND SHOES.

    ASSURE ADEQUATE FLUSHING OF THE EYES BY SEPARATING THE EYELIDS

    WITH FINGERS.

    IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL

    RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.

    IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.

    CALL A PHYSICIAN IMMEDIATELY.

    WASH CONTAMINATED CLOTHING BEFORE REUSE.

SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -

  EXTINGUISHING MEDIA

    WATER SPRAY.

    CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM.

  SPECIAL FIREFIGHTING PROCEDURES

    WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO

    PREVENT CONTACT WITH SKIN AND EYES.

    COMBUSTIBLE LIQUID.

  UNUSUAL FIRE AND EXPLOSIONS HAZARDS

    EMITS TOXIC FUMES UNDER FIRE CONDITIONS.



                                          Page 1

                PRODUCT #: 137685       NAME: 2-BROMOETHYL ACETATE, 97%

                     MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                         Printed Monday, March 10, 1903 3:23PM



SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -

    EVACUATE AREA.

    WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY

    RUBBER GLOVES.

    ABSORB ON SAND OR VERMICULITE AND PLACE IN CLOSED CONTAINERS FOR

    DISPOSAL.

    VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.

SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -

    REFER TO SECTION 8.

SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -

    CHEMICAL SAFETY GOGGLES.

    RUBBER GLOVES.

    NIOSH/MSHA-APPROVED RESPIRATOR.

    SAFETY SHOWER AND EYE BATH.

    MECHANICAL EXHAUST REQUIRED.

    DO NOT BREATHE VAPOR.

    AVOID CONTACT WITH EYES, SKIN AND CLOTHING.

    WASH THOROUGHLY AFTER HANDLING.

    CORROSIVE.

    LACHRYMATOR.

    POSSIBLE MUTAGEN.

    HARMFUL LIQUID.

    KEEP TIGHTLY CLOSED.

    KEEP AWAY FROM HEAT AND OPEN FLAME.

    STORE IN A COOL DRY PLACE.

SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -

  APPEARANCE AND ODOR

    COLORLESS LIQUID

  PHYSICAL PROPERTIES

    BOILING POINT:         159 C

    MELTING POINT:       -14 C TO -13.8 C

    FLASHPOINT                   160 F

                                  71C

    SPECIFIC GRAVITY:      1.514

SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -

  INCOMPATIBILITIES

    STRONG OXIDIZING AGENTS

    STRONG ACIDS

    STRONG BASES

    STRONG REDUCING AGENTS

  HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS

    TOXIC FUMES OF:

    CARBON MONOXIDE, CARBON DIOXIDE

    HYDROGEN BROMIDE GAS

SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -

  ACUTE EFFECTS

    HARMFUL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN.

    MATERIAL IS EXTREMELY DESTRUCTIVE TO TISSUE OF THE MUCOUS MEMBRANES

    AND UPPER RESPIRATORY TRACT, EYES AND SKIN.

    VAPOR OR MIST IS IRRITATING TO THE EYES, MUCOUS MEMBRANES AND UPPER

    RESPIRATORY TRACT.

    INHALATION MAY RESULT IN SPASM, INFLAMMATION AND EDEMA OF THE

    LARYNX AND BRONCHI, CHEMICAL PNEUMONITIS AND PULMONARY EDEMA.

    SYMPTOMS OF EXPOSURE MAY INCLUDE BURNING SENSATION, COUGHING,

    WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND

    VOMITING.

  CHRONIC EFFECTS



                                          Page 2

                PRODUCT #: 137685       NAME: 2-BROMOETHYL ACETATE, 97%

                     MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                         Printed Monday, March 10, 1903 3:23PM



    LABORATORY EXPERIMENTS HAVE SHOWN MUTAGENIC EFFECTS.

    TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND

    TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.

  RTECS #: KJ8227000

    ETHANOL, 2-BROMO-, ACETATE

    ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES

    (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR

    COMPLETE INFORMATION.

SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -

    DATA NOT YET AVAILABLE.

SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -

    THIS COMBUSTIBLE MATERIAL MAY BE BURNED IN A CHEMICAL INCINERATOR

    EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.

    OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.

SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -

    CONTACT ALDRICH CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.

SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -

  EUROPEAN INFORMATION

    CORROSIVE

    R 20/21/22

    HARMFUL BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED.

    R 34

    CAUSES BURNS.

    R 40

    POSSIBLE RISK OF IRREVERSIBLE EFFECTS.

    S 23

    DO NOT BREATHE VAPOR.

    S 26

    IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF

    WATER AND SEEK MEDICAL ADVICE.

    S 45

    IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE

    IMMEDIATELY (SHOW THE LABEL WHERE POSSIBLE).

    S 36/37/39

    WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE

    PROTECTION.

  TLV AND SOURCE

    FOR ACETIC ANHYDRIDE:

    ACGIH-TLV (1993-1994): TWA 5 PPM (21 MG/M3).

  REVIEWS, STANDARDS, AND REGULATIONS

    OEL=MAK

    EPA GENETOX PROGRAM 1988, POSITIVE: E COLI POLA WITHOUT S9

    EPA TSCA SECTION 8(B) CHEMICAL INVENTORY

SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -

    THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO

    BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,

    FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING

    OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR

    PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.

    COPYRIGHT 1997 SIGMA CHEMICAL CO., ALDRICH CHEMICAL CO., INC.,

    FLUKA CHEMIE AG

    LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY









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