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MSDS Material Safety Data Sheet
CAS

513-81-5

File Name: palomar_edu---23-dimethyl-13-butadiene.asp
 
             PRODUCT #: 145491       NAME: 2,3-DIMETHYL-1,3-BUTADIENE, 98%

                     MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                        Printed Thursday, March 20, 1903 12:50PM



Sigma Chemical Co.         Aldrich Chemical Co., Inc.     Fluka Chemical Corp.

P.O. Box 14508             1001 West St. Paul             1001 West St. Paul

St. Louis, MO 63178        Milwaukee, WI 53233            Milwaukee, WI 53233

Phone: 314-771-5765        Phone: 414-273-3850            Phone: 414-273-3850









SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -

    CATALOG #:            145491

    NAME:                 2,3-DIMETHYL-1,3-BUTADIENE, 98%

SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -

    CAS #:    513-81-5

    MF: C6H10

    EC NO: 208-172-0

SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -

  LABEL PRECAUTIONARY STATEMENTS

    FLAMMABLE (USA)

    HIGHLY FLAMMABLE (EU)

    KEEP CONTAINER TIGHTLY CLOSED IN A COOL WELL-VENTILATED PLACE.

    KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.

    DO NOT EMPTY INTO DRAINS.

    TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES.

    REFRIGERATE.

SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -

    IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS

    AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED

    CLOTHING AND SHOES.

    IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL

    RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.

    IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.

    CALL A PHYSICIAN.

    REMOVE AND WASH CONTAMINATED CLOTHING PROMPTLY.

SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -

  EXTINGUISHING MEDIA

    CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM.

  SPECIAL FIREFIGHTING PROCEDURES

    WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO

    PREVENT CONTACT WITH SKIN AND EYES.

    USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS.

  UNUSUAL FIRE AND EXPLOSIONS HAZARDS

    VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION AND

    FLASH BACK.

    EXTREMELY FLAMMABLE.

    CONTAINER EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS.

    FORMS EXPLOSIVE MIXTURES IN AIR.

SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -

    EVACUATE AREA.

    SHUT OFF ALL SOURCES OF IGNITION.

    WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY

    RUBBER GLOVES.

    COVER WITH AN ACTIVATED CARBON ADSORBENT, TAKE UP AND PLACE IN CLOSED

    CONTAINERS. TRANSPORT OUTDOORS.

    VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.

SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -

    REFER TO SECTION 8.

SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -



                                          Page 1

             PRODUCT #: 145491       NAME: 2,3-DIMETHYL-1,3-BUTADIENE, 98%

                     MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                        Printed Thursday, March 20, 1903 12:50PM



    CHEMICAL SAFETY GOGGLES.

    RUBBER GLOVES.

    USE NONSPARKING TOOLS.

    MECHANICAL EXHAUST REQUIRED.

    NIOSH/MSHA-APPROVED RESPIRATOR.

    DO NOT BREATHE VAPOR.

    AVOID CONTACT WITH EYES, SKIN AND CLOTHING.

    WASH THOROUGHLY AFTER HANDLING.

    KEEP TIGHTLY CLOSED.

    KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME.

    REFRIGERATE.

SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -

  APPEARANCE AND ODOR

    COLORLESS LIQUID

  PHYSICAL PROPERTIES

    BOILING POINT:         68 C TO 69 C

    MELTING POINT:       -76 C

    FLASHPOINT                   -8 F

                               - 13C

    EXPLOSION LIMITS IN AIR:

      LOWER                                     1.2%

    VAPOR PRESSURE:       269MM 37.7 C

    SPECIFIC GRAVITY:      0.726

SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -

  INCOMPATIBILITIES

    OXIDIZING AGENTS

  HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS

    TOXIC FUMES OF:

    CARBON MONOXIDE, CARBON DIOXIDE

SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -

  ACUTE EFFECTS

    HARMFUL IF INHALED OR SWALLOWED.

    MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND UPPER

    RESPIRATORY TRACT.

SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -

    DATA NOT YET AVAILABLE.

SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -

    BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND

    SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS MATERIAL IS HIGHLY

    FLAMMABLE.

    OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.

SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -

    CONTACT ALDRICH CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.

SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -

  EUROPEAN INFORMATION

    HIGHLY FLAMMABLE

    HIGHLY FLAMMABLE

    S 3/7/9

    KEEP CONTAINER TIGHTLY CLOSED IN A COOL WELL-VENTILATED PLACE.

    S 16

    KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.

    S 29

    DO NOT EMPTY INTO DRAINS.

    S 33

    TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES.

SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -

    THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO



                                          Page 2

         PRODUCT #: 145491       NAME: 2,3-DIMETHYL-1,3-BUTADIENE, 98%

                 MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                    Printed Thursday, March 20, 1903 12:50PM



BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,

FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING

OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR

PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.

COPYRIGHT 1997 SIGMA CHEMICAL CO., ALDRICH CHEMICAL CO., INC.,

FLUKA CHEMIE AG

LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY









                                      Page 3
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