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MSDS Material Safety Data Sheet
CAS

110-43-0

File Name: palomar_edu---2-heptanone.asp
 
                         PRODUCT #: H7883        NAME: 2-HEPTANONE

                      MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                         Printed Wednesday, March 12, 1903 1:01PM



Sigma Chemical Co.          Aldrich Chemical Co., Inc.    Fluka Chemical Corp.

P.O. Box 14508              1001 West St. Paul            1001 West St. Paul

St. Louis, MO 63178         Milwaukee, WI 53233           Milwaukee, WI 53233

Phone: 314-771-5765         Phone: 414-273-3850           Phone: 414-273-3850









SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -

    CATALOG #:            H7883

    NAME:                 2-HEPTANONE

SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -

    CAS #:   110-43-0

    MF: C7H14O

    EC NO: 203-767-1

  SYNONYMS

    AMYL-METHYL-CETONE (FRENCH) * AMYL METHYL KETONE (DOT) * N-AMYL

    METHYL KETONE * KETONE, METHYL PENTYL * METHYL-AMYL-CETONE (FRENCH) *

    METHYL N-AMYL KETONE (ACGIH:OSHA) * METHYL PENTYL KETONE * UN1110

    (DOT) *

SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -

  LABEL PRECAUTIONARY STATEMENTS

    COMBUSTIBLE (USA)

    FLAMMABLE (EU)

    HARMFUL

    HARMFUL IF SWALLOWED.

    IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.

    KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.

    IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF

    WATER AND SEEK MEDICAL ADVICE.

    WEAR SUITABLE PROTECTIVE CLOTHING.

SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -

    IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH COPIOUS AMOUNTS OF

    WATER FOR AT LEAST 15 MINUTES.

    IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS

    AMOUNTS OF WATER.

    IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL

    RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.

    IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.

    CALL A PHYSICIAN.

    WASH CONTAMINATED CLOTHING BEFORE REUSE.

SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -

  EXTINGUISHING MEDIA

    WATER SPRAY.

    CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM.

  SPECIAL FIREFIGHTING PROCEDURES

    WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO

    PREVENT CONTACT WITH SKIN AND EYES.

    COMBUSTIBLE.

  UNUSUAL FIRE AND EXPLOSIONS HAZARDS

    VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION AND

    FLASH BACK.

SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -

    EVACUATE AREA.

    WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY

    RUBBER GLOVES.

    ABSORB ON SAND OR VERMICULITE AND PLACE IN CLOSED CONTAINERS FOR



                                           Page 1

                        PRODUCT #: H7883        NAME: 2-HEPTANONE

                     MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                        Printed Wednesday, March 12, 1903 1:01PM



    DISPOSAL.

    VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.

SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -

    REFER TO SECTION 8.

SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -

    CHEMICAL SAFETY GOGGLES.

    RUBBER GLOVES.

    NIOSH/MSHA-APPROVED RESPIRATOR.

    SAFETY SHOWER AND EYE BATH.

    MECHANICAL EXHAUST REQUIRED.

    AVOID INHALATION.

    DO NOT GET IN EYES, ON SKIN, ON CLOTHING.

    WASH THOROUGHLY AFTER HANDLING.

    HARMFUL LIQUID.

    IRRITANT.

    KEEP TIGHTLY CLOSED.

    KEEP AWAY FROM HEAT AND OPEN FLAME.

    STORE IN A COOL DRY PLACE.

SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -

  APPEARANCE AND ODOR

    COLORLESS LIQUID

  PHYSICAL PROPERTIES

    BOILING POINT:         149 C TO 150 C

    MELTING POINT:       -35 C

    FLASHPOINT                 117F

                               47.22C

    EXPLOSION LIMITS IN AIR:

      UPPER                                    7.9% 121 C

      LOWER                                    1.11% 65 C

    AUTOIGNITION TEMPERATURE:         739 F          392C

    VAPOR PRESSURE:       2.14MM 20 C

    SPECIFIC GRAVITY:      0.820

    VAPOR DENSITY:      3.94

SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -

  INCOMPATIBILITIES

    STRONG OXIDIZING AGENTS

    STRONG REDUCING AGENTS

    STRONG BASES

  HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS

    TOXIC FUMES OF:

    CARBON MONOXIDE, CARBON DIOXIDE

SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -

  ACUTE EFFECTS

    HARMFUL IF SWALLOWED.

    MAY BE HARMFUL IF INHALED.

    MAY BE HARMFUL IF ABSORBED THROUGH THE SKIN.

    VAPOR OR MIST IS IRRITATING TO THE EYES, MUCOUS MEMBRANES AND UPPER

    RESPIRATORY TRACT.

    CAUSES SKIN IRRITATION.

  RTECS #: MJ5075000

    2-HEPTANONE

  IRRITATION DATA

    SKN-RBT 14 MG/24H OPEN MLD                    AIHAAP 23,95,1962

  TOXICITY DATA

    ORL-RAT LD50:1670 MG/KG                       UCDS** 8/11/1958

    IPR-RAT LD50:800 MG/KG                        38MKAJ 2C,4757,1982

    ORL-MUS LD50:730 MG/KG                        APJUA8 12,79,1962



                                          Page 2

                        PRODUCT #: H7883        NAME: 2-HEPTANONE

                     MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                        Printed Wednesday, March 12, 1903 1:01PM



    IPR-MUS LD50:400 MG/KG                         38MKAJ 2C,4757,1982

    SKN-RBT LD50:12600 UL/KG                       AIHAAP 23,95,1962

    ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES

    (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR

    COMPLETE INFORMATION.

SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -

    DATA NOT YET AVAILABLE.

SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -

    THIS COMBUSTIBLE MATERIAL MAY BE BURNED IN A CHEMICAL INCINERATOR

    EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.

    OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.

SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -

    CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.

SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -

  EUROPEAN INFORMATION

    EC INDEX NO:     606-024-00-3

    FLAMMABLE

    HARMFUL

    R 10

    FLAMMABLE.

    R 22

    HARMFUL IF SWALLOWED.

    S 23

    DO NOT BREATHE VAPOR.

  REVIEWS, STANDARDS, AND REGULATIONS

    OEL=MAK

    ACGIH TLV-TWA 233 MG/M3 (50 PPM)               DTLVS* TLV/BEI,1996

    MSHA STANDARD-AIR:TWA 100 PPM (465 MG/M3)

     DTLVS* 3,157,1971

    OSHA PEL (GEN INDU):8H TWA 100 PPM (465 MG/M3)

     CFRGBR 29,1910.1000,1994

    OSHA PEL (CONSTRUC):8H TWA 100 PPM (465 MG/M3)

     CFRGBR 29,1926.55,1994

    OSHA PEL (SHIPYARD):8H TWA 100 PPM (465 MG/M3)

     CFRGBR 29,1915.1000,1993

    OSHA PEL (FED CONT):8H TWA 100 PPM (465 MG/M3)

     CFRGBR 41,50-204.50,1994

    OEL-AUSTRALIA:TWA 50 PPM (235 MG/M3) JAN 1993

    OEL-BELGIUM:TWA 50 PPM (233 MG/M3) JAN 1993

    OEL-DENMARK:TWA 50 PPM (230 MG/M3) JAN 1993

    OEL-FINLAND:TWA 50 PPM (230 MG/M3);STEL 75 PPM (345 MG/M3) JAN 1993

    OEL-FRANCE:TWA 50 PPM (230 MG/M3) JAN 1993

    OEL-THE NETHERLANDS:TWA 100 PPM (465 MG/M3) JAN 1993

    OEL-SWITZERLAND:TWA 50 PPM (235 MG/M3) JAN 1993

    OEL-UNITED KINGDOM:TWA 50 PPM (240 MG/M3) JAN 1993

    OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA CHECK ACGIH TLV

    OEL IN NEW ZEALAND, SINGAPORE, VIETNAM CHECK ACGIH TLV

    NIOSH REL TO METHYL AMYL KETONE-AIR:10H TWA 100 PPM

     NIOSH* DHHS #92-100,1992

    NOHS 1974: HZD 36340; NIS 10; TNF 489; NOS 8; TNE 3345

    NOES 1983: HZD 36340; NIS 62; TNF 5080; NOS 47; TNE 78196; TFE 17866

    EPA TSCA SECTION 8(B) CHEMICAL INVENTORY

    EPA TSCA SECTION 8(D) UNPUBLISHED HEALTH/SAFETY STUDIES

    EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, APRIL 1997

    NIOSH ANALYTICAL METHOD, 1994: KETONES II, 1301

SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -

    THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO



                                          Page 3

                    PRODUCT #: H7883        NAME: 2-HEPTANONE

                 MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                    Printed Wednesday, March 12, 1903 1:01PM



BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,

FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING

OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR

PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.

COPYRIGHT 1997 SIGMA CHEMICAL CO., ALDRICH CHEMICAL CO., INC.,

FLUKA CHEMIE AG

LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY









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