PRODUCT #: A9399 NAME: ANTIMONY TRIOXIDE
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Monday, March 10, 1903 1:44PM
Sigma Chemical Co. Aldrich Chemical Co., Inc. Fluka Chemical Corp.
P.O. Box 14508 1001 West St. Paul 1001 West St. Paul
St. Louis, MO 63178 Milwaukee, WI 53233 Milwaukee, WI 53233
Phone: 314-771-5765 Phone: 414-273-3850 Phone: 414-273-3850
SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -
CATALOG #: A9399
NAME: ANTIMONY TRIOXIDE
SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -
CAS #: 1309-64-4
EC NO: 215-175-0
SYNONYMS
A 1582 * A 1588LP * AMSPEC-KR * ANTIMONIOUS OXIDE * ANTIMONY(3+)
OXIDE * ANTIMONY SESQUIOXIDE * ANTIMONY TRIOXIDE * ANTIMONY TRIOXIDE
PRODUCTION (ACGIH) * ANTIMONY WHITE * ANTOX * AP 50 * AT 3 * AT 3
(FIREPROOFING AGENT) * ATOX F * ATOX S * CHEMETRON FIRE SHIELD * C.I.
77052 * C.I. PIGMENT WHITE 11 * DECHLORANE A-O * DIANTIMONY TRIOXIDE *
EXITELITE * FIRESHIELD FSPO 405 * FLOWERS OF ANTIMONY * NCI-C55152 *
NYACOL A 1530 * NYACOL A 1510LP * PATOX C * PATOX H * PATOX L * PATOX
M * PATOX S * STIBIOX MS * THERMOGUARD B * THERMOGUARD L *
THERMOGUARD S * TIMONOX * TIMONOX WHITE STAR * TWINKLING STAR *
WEISSPIESSGLANZ (GERMAN) * WHITE STAR *
SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -
LABEL PRECAUTIONARY STATEMENTS
TOXIC
MAY CAUSE CANCER.
MAY CAUSE HERITABLE GENETIC DAMAGE.
HARMFUL BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED.
MAY CAUSE SENSITIZATION BY SKIN CONTACT.
CAUSES IRRITATION.
TARGET ORGAN(S):
EYES
IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE
IMMEDIATELY (SHOW THE LABEL WHERE POSSIBLE).
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
WATER AND SEEK MEDICAL ADVICE.
WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE
PROTECTION.
SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED
CLOTHING AND SHOES.
ASSURE ADEQUATE FLUSHING OF THE EYES BY SEPARATING THE EYELIDS
WITH FINGERS.
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.
CALL A PHYSICIAN.
REMOVE AND WASH CONTAMINATED CLOTHING PROMPTLY.
SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -
EXTINGUISHING MEDIA
NONCOMBUSTIBLE.
USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING FIRE CONDITIONS.
SPECIAL FIREFIGHTING PROCEDURES
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PRODUCT #: A9399 NAME: ANTIMONY TRIOXIDE
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Monday, March 10, 1903 1:44PM
WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN AND EYES.
SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -
EVACUATE AREA.
WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY
RUBBER GLOVES.
SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL.
AVOID RAISING DUST.
VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -
REFER TO SECTION 8.
SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -
WEAR APPROPRIATE NIOSH/MSHA-APPROVED RESPIRATOR, CHEMICAL-RESISTANT
GLOVES, SAFETY GOGGLES, OTHER PROTECTIVE CLOTHING.
USE ONLY IN A CHEMICAL FUME HOOD.
SAFETY SHOWER AND EYE BATH.
DO NOT BREATHE DUST.
DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
AVOID PROLONGED OR REPEATED EXPOSURE.
WASH THOROUGHLY AFTER HANDLING.
IRRITANT.
CARCINOGEN.
MUTAGEN.
SEVERE IRRITANT.
KEEP TIGHTLY CLOSED.
STORE IN A COOL DRY PLACE.
SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -
APPEARANCE AND ODOR
WHITE POWDER
PHYSICAL PROPERTIES
MELTING POINT: 655 C
SPECIFIC GRAVITY: 5.200
SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -
INCOMPATIBILITIES
ACIDS
BASES
REDUCING AGENTS
HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS
NATURE OF DECOMPOSITION PRODUCTS NOT KNOWN.
SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -
ACUTE EFFECTS
HARMFUL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN.
CAUSES SEVERE IRRITATION.
HIGH CONCENTRATIONS ARE EXTREMELY DESTRUCTIVE TO TISSUES OF THE MUCOUS
MEMBRANES AND UPPER RESPIRATORY TRACT, EYES AND SKIN.
SYMPTOMS OF EXPOSURE MAY INCLUDE BURNING SENSATION, COUGHING,
WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND
VOMITING.
MAY CAUSE ALLERGIC SKIN REACTION.
CHRONIC EFFECTS
CARCINOGEN.
MAY ALTER GENETIC MATERIAL.
TARGET ORGAN(S):
EYES
RTECS #: CC5650000
ANTIMONY OXIDE
IRRITATION DATA
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PRODUCT #: A9399 NAME: ANTIMONY TRIOXIDE
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Monday, March 10, 1903 1:44PM
EYE-RBT 100 MG MLD NTIS** OTS0555447
TOXICITY DATA
ORL-RAT LD50:>34600 MG/KG NTIS** OTS0555447
IPR-RAT LD50:3250 MG/KG EQSSDX 1,1,1975
SCU-RAT LD50:7904 MG/KG GISAAA 38(1),99,1973
IPR-MUS LD50:172 MG/KG 85GMAT -,23,1982
TARGET ORGAN DATA
LUNGS, THORAX OR RESPIRATION (TUMORS)
LIVER (TUMORS)
SKIN AND APPENDAGES (TUMORS)
PATERNAL EFFECTS (SPERMATOGENESIS)
PATERNAL EFFECTS (TESTES, EPIDIDYMIS, SPERM DUCT)
EFFECTS ON FERTILITY (PRE-IMPLANTATION MORTALITY)
EFFECTS ON FERTILITY (POST-IMPLANTATION MORTALITY)
EFFECTS ON EMBRYO OR FETUS (FETOTOXICITY)
EFFECTS ON EMBRYO OR FETUS (FETAL DEATH)
TUMORIGENIC (CARCINOGENIC BY RTECS CRITERIA)
TUMORIGENIC (NEOPLASTIC BY RTECS CRITERIA)
ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES
(RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR
COMPLETE INFORMATION.
SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -
DATA NOT YET AVAILABLE.
SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -
BURY IN A LANDFILL SITE APPROVED FOR THE DISPOSAL OF CHEMICAL
AND HAZARDOUS WASTES.
OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -
CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.
SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -
EUROPEAN INFORMATION
TOXIC
R 40
POSSIBLE RISK OF IRREVERSIBLE EFFECTS.
S 22
DO NOT BREATHE DUST.
S 36/37
WEAR SUITABLE PROTECTIVE CLOTHING AND GLOVES.
REVIEWS, STANDARDS, AND REGULATIONS
OEL=MAK
ACGIH TLV-TWA 0.5 MG(SB)/M3 (SB2O3 HANDLING/USE) DTLVS* TLV/BEI,1996
ACGIH TLV-SUSPECTED HUMAN CARCINOGEN DTLVS* TLV/BEI,1996
IARC CANCER REVIEW:ANIMAL SUFFICIENT EVIDENCE IMEMDT 47,291,1989
IARC CANCER REVIEW:HUMAN INADEQUATE EVIDENCE IMEMDT 47,291,1989
IARC CANCER REVIEW:GROUP 2B IMEMDT 47,291,1989
OSHA PEL (GEN INDU):8H TWA 0.5 MG(SB)/M3
CFRGBR 29,1910.1000,1994
OSHA PEL (CONSTRUC):8H TWA 0.5 MG(SB)/M3
CFRGBR 29,1926.55,1994
OSHA PEL (SHIPYARD):8H TWA 0.5 MG(SB)/M3
CFRGBR 29,1915.1000,1993
OSHA PEL (FED CONT):8H TWA 0.5 MG(SB)/M3
CFRGBR 41,50-204.50,1994
OEL-ARAB REPUBLIC OF EGYPT:TWA 0.5 MG(SB)/M3 JAN 1993
OEL-AUSTRALIA:STEL 0.5 PPM JAN 1993
OEL-AUSTRALIA:TWA 0.5 MG(SB)/M3 JAN 1993
OEL-AUSTRIA:TWA 0.5 MG(SB)/M3 JAN 1993
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PRODUCT #: A9399 NAME: ANTIMONY TRIOXIDE
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Monday, March 10, 1903 1:44PM
OEL-BELGIUM:STEL 0.5 PPM JAN 1993
OEL-BELGIUM:TWA 0.5 MG(SB)/M3 JAN 1993
OEL-DENMARK:TWA 0.5 MG(SB)/M3 JAN 1993
OEL-FINLAND:.TWA (0.5 MG(SB)/M3) JAN 1993
OEL-FRANCE:TWA 0.5 MG(SB)/M3 JAN 1993
OEL-GERMANY:TWA 0.5 MG(SB)/M3 (TOTAL DUST) JAN 1993
OEL-GERMANY;CARCINOGEN JAN 1993
OEL-HUNGARY:STEL 0.5 MG(SB)/M3 JAN 1993
OEL-THE NETHERLANDS:TWA 0.5 MG(SB)/M3 JAN 1993
OEL-THE PHILIPPINES:TWA 0.5 MG(SB)/M3 JAN 1993
OEL-POLAND:TWA 0.5 MG(SB)/M3 JAN 1993
OEL-RUSSIA:STEL 1 MG/M3 JAN 1993
OEL-RUSSIA:TWA 0.2 MG(SB)/M3;STEL 0.5 MG(SB)/M3 JAN 1993
OEL-SWEDEN:TWA 0.5 MG(SB)/M3 JAN 1993
OEL-SWITZERLAND:TWA 0.1 MG/M3;CARCINOGEN JAN 1993
OEL-SWITZERLAND:TWA 0.5 MG(SB)/M3 JAN 1993
OEL-TURKEY:TWA 0.5 MG(SB)/M3 JAN 1993
OEL-UNITED KINGDOM:TWA 0.5 MG(SB)/M3 JAN 1993
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA CHECK ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM CHECK ACGIH TLV
NIOSH REL TO ANTIMONY-AIR:10H TWA 0.5 MG(SB)/M3
NIOSH* DHHS #92-100,1992
NOHS 1974: HZD M2263; NIS 31; TNF 1540; NOS 53; TNE 28957
NOES 1983: HZD M2263; NIS 72; TNF 7476; NOS 76; TNE 209773; TFE 56911
EPA GENETOX PROGRAM 1988, POSITIVE: B SUBTILIS REC ASSAY
EPA TSCA SECTION 8(B) CHEMICAL INVENTORY
EPA TSCA SECTION 8(D) UNPUBLISHED HEALTH/SAFETY STUDIES
ON EPA IRIS DATABASE
EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, APRIL 1997
U.S. INFORMATION
THIS PRODUCT IS SUBJECT TO SARA SECTION 313 REPORTING REQUIREMENTS -
ANTIMONY COMPOUNDS.
CALIFORNIA PROPOSITION 65:
THIS PRODUCT IS OR CONTAINS CHEMICAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER.
SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -
THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO
BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,
FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING
OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR
PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.
COPYRIGHT 1997 SIGMA CHEMICAL CO., ALDRICH CHEMICAL CO., INC.,
FLUKA CHEMIE AG
LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY
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