PRODUCT #: 215783 NAME: ANTIMONY(III) CHLORIDE, 99%
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Friday, March 07, 1903 3:37PM
Sigma Chemical Co. Aldrich Chemical Co., Inc. Fluka Chemical Corp.
P.O. Box 14508 1001 West St. Paul 1001 West St. Paul
St. Louis, MO 63178 Milwaukee, WI 53233 Milwaukee, WI 53233
Phone: 314-771-5765 Phone: 414-273-3850 Phone: 414-273-3850
SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -
CATALOG #: 215783
NAME: ANTIMONY(III) CHLORIDE, 99%
SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -
CAS #: 10025-91-9
MF: CL3SB
EC NO: 233-047-2
SYNONYMS
ANTIMOINE (TRICHLORURE D') (FRENCH) * ANTIMONIO (TRICLORURO DI)
(ITALIAN) * ANTIMONOUS CHLORIDE * ANTIMONTRICHLORID (GERMAN) *
ANTIMONY BUTTER * ANTIMONY CHLORIDE (SB2CL6) * ANTIMONY TRICHLORIDE *
ANTIMONY TRICHLORIDE, LIQUID OR SOLID (DOT) * ANTIMOONTRICHLRIDE
(DUTCH) * BUTTER OF ANTIMONY * CHLORID ANTIMONITY (CZECH) * CHLORURE
ANTIMONIEUX (FRENCH) * C.I. 77056 * STIBINE, TRICHLORO- *
TRICHLOROSTIBINE * TRICHLORURE D'ANTIMOINE (FRENCH) * UN1733 (DOT) *
SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -
LABEL PRECAUTIONARY STATEMENTS
CORROSIVE
CAUSES BURNS.
HARMFUL BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED.
REACTS VIOLENTLY WITH WATER.
POSSIBLE RISK OF IRREVERSIBLE EFFECTS.
POSSIBLE MUTAGEN.
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
WATER AND SEEK MEDICAL ADVICE.
AFTER CONTACT WITH SKIN, WASH IMMEDIATELY WITH PLENTY OF WATER.
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE
PROTECTION.
STORE UNDER NITROGEN.
SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED
CLOTHING AND SHOES.
CONTAMINATION OF THE EYES SHOULD BE TREATED BY IMMEDIATE AND PROLONGED
IRRIGATION WITH COPIOUS AMOUNTS OF WATER.
ASSURE ADEQUATE FLUSHING OF THE EYES BY SEPARATING THE EYELIDS
WITH FINGERS.
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.
CALL A PHYSICIAN.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -
EXTINGUISHING MEDIA
NONCOMBUSTIBLE.
USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING FIRE CONDITIONS.
DO NOT USE WATER.
SPECIAL FIREFIGHTING PROCEDURES
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PRODUCT #: 215783 NAME: ANTIMONY(III) CHLORIDE, 99%
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Friday, March 07, 1903 3:37PM
WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN AND EYES.
REACTS VIOLENTLY WITH WATER.
UNUSUAL FIRE AND EXPLOSIONS HAZARDS
WATER HYDROLYZES MATERIAL LIBERATING ACIDIC GAS WHICH IN CONTACT
WITH METAL SURFACES CAN GENERATE FLAMMABLE AND/OR EXPLOSIVE
HYDROGEN GAS.
EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -
EVACUATE AREA.
WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY
RUBBER GLOVES.
ABSORB ON SAND OR VERMICULITE AND PLACE IN CLOSED CONTAINERS FOR
DISPOSAL.
VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -
REFER TO SECTION 8.
SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -
WEAR APPROPRIATE NIOSH/MSHA-APPROVED RESPIRATOR, CHEMICAL-RESISTANT
GLOVES, SAFETY GOGGLES, OTHER PROTECTIVE CLOTHING.
USE ONLY IN A CHEMICAL FUME HOOD.
SAFETY SHOWER AND EYE BATH.
FACESHIELD (8-INCH MINIMUM).
DO NOT BREATHE VAPOR.
DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
AVOID PROLONGED OR REPEATED EXPOSURE.
WASH THOROUGHLY AFTER HANDLING.
HARMFUL SOLID.
CORROSIVE.
POSSIBLE MUTAGEN.
KEEP TIGHTLY CLOSED.
DO NOT ALLOW CONTACT WITH WATER.
STORE IN A COOL DRY PLACE.
SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -
APPEARANCE AND ODOR
OFF-WHITE CRYSTALLINE POWDER
PHYSICAL PROPERTIES
BOILING POINT: 283 C
MELTING POINT: 73.4 C
VAPOR PRESSURE: 760MM 223 C 1MM 49 C
SPECIFIC GRAVITY: 3.140
SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -
INCOMPATIBILITIES
HEAT
STRONG BASES
REACTS VIOLENTLY WITH:
WATER
HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS
HYDROGEN CHLORIDE GAS
ANTIMONY/ANTIMONY OXIDES
SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -
ACUTE EFFECTS
HARMFUL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN.
CAUSES BURNS.
HIGH CONCENTRATIONS ARE EXTREMELY DESTRUCTIVE TO TISSUES OF THE MUCOUS
MEMBRANES AND UPPER RESPIRATORY TRACT, EYES AND SKIN.
CHRONIC EFFECTS
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PRODUCT #: 215783 NAME: ANTIMONY(III) CHLORIDE, 99%
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Friday, March 07, 1903 3:37PM
LABORATORY EXPERIMENTS HAVE SHOWN MUTAGENIC EFFECTS.
RTECS #: CC4900000
ANTIMONY(III) CHLORIDE
TOXICITY DATA
ORL-RAT LD50:525 MG/KG MARJV# 29MAR1977
IPR-MUS LD50:13 MG/KG 85GMAT -,23,1982
ORL-GPG LD50:574 MG/KG HYSAAV 29(12),16,1964
TARGET ORGAN DATA
PERIPHERAL NERVE AND SENSATION (SPASTIC PARALYSIS WITH/WITHOUT SENSORY CH
GASTROINTESTINAL (PERITONITIS)
GASTROINTESTINAL (NECROTIC CHANGES)
EFFECTS ON NEWBORN (GROWTH STATISTICS)
EFFECTS ON NEWBORN (DELAYED EFFECTS)
ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES
(RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR
COMPLETE INFORMATION.
SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -
DATA NOT YET AVAILABLE.
SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -
THE MATERIAL SHOULD BE DISSOLVED IN 1) WATER; 2) ACID SOLUTION OR 3)
OXIDIZED TO A WATER-SOLUBLE STATE. PRECIPITATE THE MATERIAL AS THE
SULFIDE, ADJUSTING THE PH OF THE SOLUTION TO 7 TO COMPLETE PRE-
CIPITATION. FILTER THE INSOLUBLES AND DISPOSE OF THEM IN A HAZARDOUS-
WASTE SITE. DESTROY ANY EXCESS SULFIDE WITH SODIUM HYPOCHLORITE.
NEUTRALIZE THE SOLUTION BEFORE FLUSHING DOWN THE DRAIN.
OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -
CONTACT ALDRICH CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.
SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -
EUROPEAN INFORMATION
EC INDEX NO: 051-001-00-8
CORROSIVE
R 34
CAUSES BURNS.
R 37
IRRITATING TO RESPIRATORY SYSTEM.
S 26
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
WATER AND SEEK MEDICAL ADVICE.
S 36/37/39
WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE
PROTECTION.
S 45
IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE
IMMEDIATELY (SHOW THE LABEL WHERE POSSIBLE).
REVIEWS, STANDARDS, AND REGULATIONS
OEL=MAK
ACGIH TLV-TWA 0.5 MG(SB)/M3 DTLVS* TLV/BEI,1996
MSHA STANDARD-AIR:TWA 0.5 MG(SB)/M3
DTLVS* 3,15,1971
OSHA PEL (GEN INDU):8H TWA 0.5 MG(SB)/M3
CFRGBR 29,1910.1000,1994
OSHA PEL (CONSTRUC):8H TWA 0.5 MG(SB)/M3
CFRGBR 29,1926.55,1994
OSHA PEL (SHIPYARD):8H TWA 0.5 MG(SB)/M3
CFRGBR 29,1915.1000,1993
OSHA PEL (FED CONT):8H TWA 0.5 MG(SB)/M3
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PRODUCT #: 215783 NAME: ANTIMONY(III) CHLORIDE, 99%
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Friday, March 07, 1903 3:37PM
CFRGBR 41,50-204.50,1994
OEL-ARAB REPUBLIC OF EGYPT:TWA 0.5 MG(SB)/M3 JAN 1993
OEL-AUSTRALIA:TWA 0.5 MG(SB)/M3 JAN 1993
OEL-AUSTRIA:TWA 0.5 MG(SB)/M3 JAN 1993
OEL-BELGIUM:TWA 0.5 MG(SB)/M3 JAN 1993
OEL-DENMARK:TWA 0.5 MG(SB)/M3 JAN 1993
OEL-FINLAND:.TWA (0.5 MG(SB)/M3) JAN 1993
OEL-FRANCE:TWA 0.5 MG(SB)/M3 JAN 1993
OEL-GERMANY:TWA 0.5 MG(SB)/M3 (TOTAL DUST) JAN 1993
OEL-HUNGARY:STEL 0.5 MG(SB)/M3 JAN 1993
OEL-THE NETHERLANDS:TWA 0.5 MG(SB)/M3 JAN 1993
OEL-THE PHILIPPINES:TWA 0.5 MG(SB)/M3 JAN 1993
OEL-POLAND:TWA 0.5 MG(SB)/M3 JAN 1993
OEL-RUSSIA:STEL 0.3 MG/M3 JAN 1993
OEL-RUSSIA:TWA 0.2 MG(SB)/M3;STEL 0.5 MG(SB)/M3 JAN 1993
OEL-SWEDEN:TWA 0.5 MG(SB)/M3 JAN 1993
OEL-SWITZERLAND:TWA 0.5 MG(SB)/M3 JAN 1993
OEL-TURKEY:TWA 0.5 MG(SB)/M3 JAN 1993
OEL-UNITED KINGDOM:TWA 0.5 MG(SB)/M3 JAN 1993
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA CHECK ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM CHECK ACGIH TLV
NIOSH REL TO ANTIMONY-AIR:10H TWA 0.5 MG(SB)/M3
NIOSH* DHHS #92-100,1992
NOHS 1974: HZD 07405; NIS 6; TNF 125; NOS 9; TNE 1947
NOES 1983: HZD 07405; NIS 9; TNF 344; NOS 11; TNE 22641; TFE 7292
EPA GENETOX PROGRAM 1988, POSITIVE: B SUBTILIS REC ASSAY
EPA TSCA SECTION 8(B) CHEMICAL INVENTORY
EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, APRIL 1997
U.S. INFORMATION
THIS PRODUCT IS SUBJECT TO SARA SECTION 313 REPORTING REQUIREMENTS.
SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -
THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO
BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,
FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING
OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR
PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.
COPYRIGHT 1997 SIGMA CHEMICAL CO., ALDRICH CHEMICAL CO., INC.,
FLUKA CHEMIE AG
LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY
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