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MATERIAL SAFETY DATA SHEET
MSDS Number: AMINE201-2 Revision Date: April 2, 2007
Supersedes: AMINE201-1 Issue Date: May 10, 2001
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
鈥? Product identification
Synonyms/Trade Names: N,N-Dialkyl (C8 鈥? 10) 鈥揘-methylamine / AD-810A
鈥? Product uses
There are many uses primarily as intermediates in the manufacture of cationic surfactants, quartenaries for biocides,
flotation agents, gasoline detergents, corrosion inhibitors, rubber processing additives, emulsifier for herbicides, textile
softeners, oilfield drilling materials.
鈥? Company/undertaking identification
North America: The Procter & Gamble Company
Procter & Gamble Chemicals
Sharon Woods Technical Center
11530 Reed Hartman Highway
Cincinnati, Ohio 45241
Department issuing MSDS:
Product Safety and Regulatory Affairs
1-800-477-8899
Europe: Procter & Gamble International
Operations S.A.
P&G Chemicals 鈥? Europe
The Heights
Brooklands
Weybridge
Surrey
Telephone Number: 01932-896000
鈥? P&G Ltd. - Brooklands, England: Tel 01932-896000 (day phone)
Emergency Telephone:
Emergency 0191-279-2000 (day phone)
CHEMTREC 1-800-424-9300 U.S. and Canada
+1-703-527-3887 For calls originating
elsewhere
Quality or Service Issues: Call Customer Service
1-800-477-8899 or 513-626-6882
NAME: AD-810A REVISION DATE: April 2, 2007 Page 2 of 8
2. HAZARDS IDENTIFICATION
鈥? This product is classified as C 鈥? Corrosive; R34 鈥? Causes
European Hazard Classification:
burns.
DANGER: CORROSIVE ! CAUSES CHEMICAL
鈥? Emergency Overview:
BURNS
鈥? Based on animal test data for similar material(s) the
Potential Health Effects:
following effect(s) can be anticipated:
Eye: Can cause severe eye irritation. Prolonged exposure to
eyes can cause severe chemical burns. Uncontrolled vapor
exposure may cause severe pain or serious damage to eye.
Skin: Can cause severe skin irritation. Prolonged exposure to
skin can cause severe chemical burns. Exposure can cause
latent severe burns. Heated product may cause thermal
burns if contacted.
Inhalation: Prolonged or repeated high level exposures may cause
severe irritation of respiratory passages and/or lung
congestion.
Ingestion: Anticipated to be harmful. Small amounts may cause
injury.
鈥? Not identified.
Physical/Chemical Hazards:
鈥? Not identified.
Environmental Hazards:
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/Preparation (mixture): Preparation
Name CAS No. Wt/Wt % EC No. EC Symbols EC R-phrases
1-Octanamine, N-methyl-N-octyl- 4455-26-9 22-28 2247039 C R34
1-Decanamine, N-methyl-N-octyl- 22020-14-0 47-53 2447247 C R34
1-Decanamine, N-decyl-N-methyl- 7396-58-9 22-28 2309901 C R34
Occupational exposure limits, if applicable, are listed in Section 8.
LC/LD50 information is listed in Section 11.
Full text of R phrase(s) are listed in Section 16.
4. FIRST AID MEASURES
鈥? Immediately flush eyes with plenty of water for at least 15 minutes. Get
Eye:
medical attention immediately.
鈥? Wash thoroughly with soap and water for at least 15 minutes while removing
Skin:
contaminated clothing and shoes. Immediately obtain medical attention.
Discard or decontaminate shoes and clothing.
鈥? If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
Inhalation:
breathing is difficult, give oxygen. Immediately get medical attention.
鈥? If swallowed, do not induce vomiting. If victim is fully conscious, dilute
Ingestion:
stomach contents with large amounts of water. Never give anything by mouth
to an unconscious person. Immediately call a physician.
NAME: AD-810A REVISION DATE: April 2, 2007 Page 3 of 8
5. FIRE FIGHTING MEASURES
鈥? Use foam, CO2, or dry chemical
Extinguishing Media:
鈥? Not identified
Unsuitable extinguishing media:
鈥? Flash Point and method: >200掳F (>93.3掳C) PMCC
鈥? Upper: Not available.
Explosive limits in air:
Lower: Not available.
鈥? Not available.
Auto-ignition temperature:
鈥? Not available.
Sensitivity to mechanical
impact/static discharge:
鈥? Wear self-contained breathing apparatus and full protective clothing.
Special Protective Equipment:
鈥? Cool containers with flooding quantities of water until well after fire
Other Fire Fighting Considerations:
is out.
鈥? When heated to decomposition, emits toxic fumes of ammonia and
Exposure hazards:
NOx.
6. ACCIDENTAL RELEASE MEASURES
鈥? Use self-contained breathing apparatus for exposure to contaminated
Personal Precautions:
atmosphere. Appropriate protective clothing should be worn during cleanup.
Do not touch damaged containers or spilled material unless wearing appropriate
protective clothing.
鈥? Dike flow of spilled material using inert material (soil, sandbags, etc.).
Environmental Precautions:
Keep material out of drains, surface and ground waters.
鈥? Remove all sources of ignition and ground all equipment before beginning
Procedures for Spill/Leak Clean-up:
cleanup. Contain spill. Absorb spillage onto inert materials (eg. sand) and
collect into suitably labeled containers for disposal.
Refer to Section 8 for additional personal protection information.
Refer to Section 13 for disposal considerations.
7. HANDLING AND STORAGE
鈥? Handle in accordance with good hygiene and safety procedures. Avoid contact
Handling:
with eyes, skin, and clothing. Wash thoroughly after handling. Since empty
containers contain product residue and can be dangerous, follow all hazard
warnings and precautions even after container is emptied. Keep away from
sources of ignition. Ground all containers prior to pouring.
鈥? Store in original closed containers in a cool, dry, well-ventilated area. Store
Storage:
containers in compliance with the most recent NFPA Code (NFPA 30). Store
separately from all combustible, organic and oxidizable materials.
鈥? Detergent intermediate: follow bulk handling and storage procedures as noted
Specific use(s):
above.
Refer to Section 6 for clean-up of spillages.
Refer to Section 13 for disposal considerations.
NAME: AD-810A REVISION DATE: April 2, 2007 Page 4 of 8
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
鈥? Good industrial hygiene practices should be followed.
General Precautions:
Avoid breathing (heated) vapors. Avoid eye and skin
contact.
鈥? Not established.
Exposure Limit Values:
鈥? Exposure Controls
Engineering Controls: Ventilation: Local exhaust: preferred
Mechanical: may be necessary if working at elevated
temperatures or in enclosed areas.
Personal Protective Equipment: Eye: Goggles or face shield with goggles, dependent upon
potential exposure.
Skin: Protective gloves: Rubber or neoprene
Dependent upon degree of potential exposure, additional
personal protective equipment may be required, such as
chemical boots and full protective clothing.
Inhalation: Use an appropriate NIOSH/MSHA approved respirator for
exposure to contaminated atmosphere. A NIOSH/MSHA
approved self-contained breathing apparatus or air-supplied
respirator is recommended if the concentration exceeds the
capacity of cartridge respirator. WARNING: Air purifying
respirators do not protect workers in oxygen-deficient
atmospheres.
Other Controls: Boots, eye wash fountain, safety shower, apron, protective
clothing.
鈥? Contact Procter and Gamble for specific Community
Environmental Exposure Controls:
information.
9. PHYSICAL AND CHEMICAL PROPERTIES
鈥? General Information:
Physical State: Liquid
Appearance: Colorless to pale yellow
Odor: Strong fishy
Odor Threshold: Not available.
鈥? Important health, safety and environmental information:
pH: Not applicable.
Boiling point/Boiling range: 379掳 F (193掳 C) @ 760 mm Hg (101.3kPa)
Flash Point & Method: >200掳F (93.3掳C) PMCC
Flammability (solid, gas): Not available
Explosive properties: Not available
Oxidising properties: Not available
Vapor pressure: Not available
Relative density: 0.8 @ 25掳C
Freezing point: -75掳C
Viscosity: 0.39 at 25掳C
Solubility: Water solubility: Insoluble
Fat solubility (solvent-oil to be specified): Not available
Partition coefficient: n-octanol/water: Not available
NAME: AD-810A REVISION DATE: April 2, 2007 Page 5 of 8
9. PHYSICAL AND CHEMICAL PROPERTIES - CONTINUED
Max. percent volatile: Nil
Vapor density (air=1): Not available
Evaporation Rate (nBuOAc=1): Not available
Explosive Limits: Not available
Auto ignition temperature: Not available
Coefficient of water/oil distribution: Not available
10. STABILITY AND REACTIVITY
鈥? Stability: Stable under normal operational procedures.
鈥? Alkaline corrosive properties.
Conditions to Avoid:
鈥? Copper and copper alloys. Strong oxidizing agents and strong acids.
Materials to Avoid:
鈥? Thermal decomposition may produce toxic vapors/fumes of amines, and
Hazardous Decomposition
other organic materials and oxides of carbon and nitrogen.
Products:
鈥? No hazardous polymerization reactions.
Hazardous Polymerization:
11. TOXICOLOGICAL INFORMATION
Not available. See Potential Health Effects in Section 3.
12. ECOLOGICAL INFORMATION
No available information.
13. DISPOSAL CONSIDERATIONS
DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL, STATE/PROVINCIAL AND LOCAL
REGULATIONS. Do not dispose of via sinks, drains or into the immediate environment.
14. TRANSPORT INFORMATION
U.S. DOT
UN No. 2735
Proper Shipping name Amines, liquid, corrosive, n.o.s.
(Dialkylmethylamines)
Hazard Class 8
Packaging group III
Land Transport (ADR/RID)
UN No. 2735
Proper Shipping name Amines, liquid, corrosive, n.o.s.
(Dialkylmethylamines)
Hazard Class 8
Packaging group III
Hazard ID No. 80
Sea Transport (IMDG)
UN No. 2735
Proper Shipping name Amines, liquid, corrosive, n.o.s.
(Dialkylmethylamines)
Hazard Class 8
Packaging group III
NAME: AD-810A REVISION DATE: April 2, 2007 Page 6 of 8
14. TRANSPORT INFORMATION - CONTINUED
Air transport (ICAO/IATA)
UN No. 2735
Proper Shipping name Amines, liquid, corrosive, n.o.s.
(Dialkylmethylamines)
Hazard Class 8
Packaging group III
15. ADDITIONAL REGULATORY INFORMATION
INVENTORY STATUS:
1-Octanamine, N-methyl-N-octyl- TSCA (US), AICS (Australia), DSL (Canada), IECSC (China), EINECS
(EU), ENCS (Japan), NZIoC (New Zealand), PICCS (Philippines)
1-Decanamine, N-methyl-N-octyl- TSCA (US), AICS (Australia), DSL (Canada), IECSC (China), EINECS
(EU), ENCS (Japan), KECI (Korea), NZIoC (New Zealand)
1-Decanamine, N-decyl-N-methyl- TSCA (US), AICS (Australia), DSL (Canada), IECSC (China), EINECS
(EU), ENCS (Japan), NZIoC (New Zealand)
USA REGULATORY INFORMATION
SARA Title III: Sections 311/312
Superfund Amendments and Reauthorization Act of 1986 requires reporting under the Community Right-To Know
provisions due to their inclusion in one of the five hazard categories listed in 40 CFR 370. Components present in this
product which could require reporting under the statute are:
IMMEDIATE (ACUTE) HEALTH HAZARD:
Chemical Name CAS No. Concentration (max/typ)
N-Octyl-N-decyl-N-methylamine 22020-14-0 47 - 53%
N, N-Didecyl-N-methylamine 7396-58-9 22 - 28%
N, N-Dioctyl-N-methylamine 4455-26-9 22 - 28%
California Proposition 65
Substances, which are known to the State of California to cause cancer and/or birth defects or other reproductive harm,
Must be identified when present in products. Components present in this product at a level which could require
reporting under the statute in either or both hazard categories are:
AS A CANCER HAZARD:
Chemical Name CAS No. Concentration (max/typ)
N-Nitrosodimethylamine 62-75-9 in traces
Massachusetts Right-To-Know Substance List (MSL)
Hazardous and Extraordinarily Hazardous Substances on the MSL must be identified when present in products.
Components present in this product at a level which could require reporting under the statute are:
EXTRAORDINARILY HAZARDOUS SUBSTANCES (>= 1 ppm or 0.0001%):
Chemical Name CAS No. Concentration (max/typ)
N-Nitrosodimethylamine 62-75-9 in traces
NAME: AD-810A REVISION DATE: April 2, 2007 Page 7 of 8
15. ADDITIONAL REGULATORY INFORMATION - CONTINUED
New Jersey Right-To-Know Substance List
Requires Hazardous Substances and Specially Hazardous Substances on the list to be identified when present in
products. Components present in this product at a level which could require reporting under the statute are:
HAZARDOUS substances ( 1.0 %):
Chemical Name CAS No. Concentration (max/typ)
N-Octyl-N-decyl-N-methylamine 22020-14-0 47 - 53%
N, N-Didecyl-N-methylamine 7396-58-9 22 - 28%
N, N-Dioctyl-N-methylamine 4455-26-9 22 - 28%
AD-810A WGK Water endangering 2, hazard to waters
class is based on the computation rule
of VwVwS Annex 4 for mixtures.
EC LABELING AND CLASSIFICATION:
According to Directives 67/548/EEC and 1999/45/EC
Symbol: C=Corrosive
Risk phrase(s): R34 Causes burns.
S36/37/39 Wear suitable protective clothing, gloves, and
eye/face protection.
Safety phrase(s): S26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S28 After contact with the skin, wash
immediately with plenty of soap and water
for at least 15 minutes while removing
contaminated clothing and shoes.
S45 In case of accident or if you feel unwell seek
medical advice immediately (show the label
where possible).
Canada
HAZARDOUS INGREDIENTS 鈥? WHMIS (Canadian Workplace Hazardous Materials Information System)
This product when tested as a whole is considered a controlled substance, Class E (corrosive) and Class D,
Division 2, Subdivision B (skin and eye irritant, Toxic) within the meaning of the Hazardous Products Act.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the
MSDS contains all the information required by the Controlled Products Regulations.
16. OTHER INFORMATION
EUROPE
This product safety data sheet was prepared in compliance with Directive 2001/58/EC.
R-phrase(s):
R34 Causes burns.
USA LABELING:
DANGER: CAUSES CHEMICAL BURNS.
Do not get in eyes, on skin, or on clothing.
Avoid breathing vapor, mist.
Keep container closed. Use only with adequate ventilation. Wash thoroughly
after handling.
NAME: AD-810A REVISION DATE: April 2, 2007 Page 8 of 8
16. OTHER INFORMATION - CONTINUED
USA LABELING (continued):
FIRST AID: In case of contact
EYES Immediately flush eyes with plenty of water for at least 15 minutes. Get medical
attention immediately.
SKIN Immediately wash thoroughly with mild soap and water. If available, use an
appropriate decontamination skin cleanser. Remove contaminated clothing and wash
before reuse. Destroy contaminated shoes. Immediately obtain medical attention.
References: OECD SIDS Dossier
The following sections contain revisions or new statements: 1-3, 15-16.
Department issuing MSDS: Product Safety and Regulatory Affairs 1-800-477-8899
DISCLAIMER: This MSDS is intended to provide a brief summary of our knowledge and guidance regarding the use of
this material. The information contained here has been compiled from sources considered by Procter & Gamble to be
dependable and is accurate to the best of the Company鈥檚 knowledge. It is not meant to be an all-inclusive document on
worldwide hazard communication regulations.
This information is offered in good faith. Each user of this material needs to evaluate the conditions of use and design the
appropriate protective mechanisms to prevent employee exposures, property damage or release to the environment. Procter
& Gamble assumed no responsibility for injury to the recipient or third persons, or for any damage to any property resulting
from misuse of the product.
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