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MATERIAL SAFETY DATA SHEET
MSDS Number: AMINE216-6 Revision Date: June 18, 2007
Supersedes: AMINE216-5 Issue Date: November 4, 2004
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
鈥? Product identification
Synonyms: Dimethylcetylamine, Fatty Tertiary Amine
Trade Names: AT-1695, AT-1695A, AT-1697A, AT-1697AS, AT-1698A, AT-1698AS
鈥? Product uses
There are many uses primarily as intermediates in the manufacture of cationic surfactants, quaternaries for biocides,
flotation agents, gasoline detergents, corrosion inhibitors, rubber processing additives, emulsifier for herbicides, textile
softeners, oilfield drilling materials.
鈥? Company/undertaking identification
North America: The Procter & Gamble Company
Procter & Gamble Chemicals
Sharon Woods Technical Center
11530 Reed Hartman Highway
Cincinnati, Ohio 45241
Department issuing MSDS:
Product Safety and Regulatory Affairs
1-800-477-8899
Europe: Asia:
Procter & Gamble International
P&G Chemicals Asia
Operations S.A.
238-A Thompson Road #21-01/10
P&G Chemicals 鈥? Europe
Novena Square Tower A
The Heights
Singapore 307684
Brooklands
Weybridge
Surrey
ENGLAND KT13 0XP
Telephone Number: 01932-896000
鈥? P&G Ltd. - Brooklands, England: Tel 01932-896000 (day phone)
Emergency Telephone:
Emergency 0191-279-2000 (day phone)
P&G Chemicals Asia: (65) 6824 5728 (day phone)
CHEMTREC 1-800-424-9300 U.S. and Canada
1-703-527-3887 For calls originating
elsewhere
Quality or Service Issues: Call Customer Service
1-800-477-8899 or 513-626-6882
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2. HAZARDS IDENTIFICATION
鈥? This product is classified as C 鈥? Corrosive; R34 鈥? Causes
European Hazard Classification:
burns, R22 鈥? Harmful if swallowed and N 鈥? Dangerous for
the environment; R50 鈥? Very toxic to aquatic organisms.
DANGER: CORROSIVE! CAUSES CHEMICAL
鈥? Emergency Overview:
BURNS
鈥? Eye: Can cause severe eye irritation. Prolonged exposure to
Potential Health Effects:
eyes can cause severe chemical burns. Uncontrolled vapor
exposure may cause severe pain or serious damage to eye.
Skin: Can cause severe skin irritation. Prolonged exposure to
skin can cause severe chemical burns. Exposure can cause
latent severe burns. Heated product may cause thermal
burns if contacted.
Inhalation: Prolonged or repeated high level exposures may cause
severe irritation of respiratory passages and/or lung
congestion.
Ingestion: Small amounts may cause injury.
鈥? Not identified.
Physical/Chemical Hazards:
鈥? Expected to be toxic to freshwater and marine species.
Environmental Hazards:
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/Preparation (mixture): Substance
Name CAS No. Wt/Wt % EC No. EC Symbols EC R-phrases
1-Hexadecanamine, N, N-dimethyl- 112-69-6 95 - 100 2039972 C, N R22, R34, R50
Contains approximately 0-% 1- Tetradecanamine, N, N- dimethyl- (CAS RN 112-75-4) and 0-2.5% 1-Octadecanamine,
N, N-dimethyl- (CAS RN 124-28-7).
Occupational exposure limits, if applicable, are listed in Section 8.
LC/LD50 information is listed in Section 11.
Full text of R phrase(s) are listed in Section 16.
4. FIRST AID MEASURES
鈥? Immediately flush eyes with plenty of water for at least 15 minutes. Get
Eye:
medical attention immediately.
鈥? Immediately wash thoroughly with mild soap and water. If available, use an
Skin:
appropriate decontamination skin cleanser. Remove contaminated clothing and
wash before reuse. Destroy contaminated shoes. Immediately obtain medical
attention.
鈥? If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
Inhalation:
breathing is difficult, give oxygen. Immediately get medical attention.
鈥? If swallowed, do not induce vomiting. If victim is fully conscious, dilute
Ingestion:
stomach contents with large amounts of milk or water. Never give anything by
mouth to an unconscious person. Immediately call a physician.
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5. FIRE FIGHTING MEASURES
鈥? Use foam, CO2, or dry chemical
Extinguishing Media:
鈥? Not identified
Unsuitable extinguishing media:
鈥? Flash Point and method: ~280掳F (137.8掳C) PMCC
鈥? Upper: Not available.
Explosive limits in air:
Lower: Not available.
鈥? Not available.
Auto-ignition temperature:
鈥? Not available.
Sensitivity to mechanical
impact/static discharge:
鈥? Wear self-contained breathing apparatus and full protective
Special Protective Equipment:
clothing.
鈥? Cool containers with flooding quantities of water until well
Other Fire Fighting Considerations:
after fire is out.
鈥? When heated to decomposition, emits toxic fumes of NOx.
Exposure hazards:
6. ACCIDENTAL RELEASE MEASURES
鈥? Use NIOSH/MSHA approved organic vapor respirator for exposure to
Personal Precautions:
contaminated atmosphere. Appropriate protective clothing should be worn
during cleanup. Do not touch damaged containers or spilled material unless
wearing appropriate protective clothing.
鈥? Prevent from reaching waterways.
Environmental Precautions:
鈥? SMALL SPILLS: Absorb on inert material and dispose.
Procedures for Spill/Leak Clean-up:
LARGE SPILLS: Contain spill and remove for disposal.
Refer to Section 8 for additional personal protection information.
Refer to Section 13 for disposal considerations.
7. HANDLING AND STORAGE
鈥? Handle in accordance with good hygiene and safety procedures. Avoid contact
Handling:
with eyes, skin, and clothing. Wash thoroughly after handling. Since empty
containers contain product residue and can be dangerous, follow all hazard
warnings and precautions even after container is emptied. Keep away from
sources of ignition.
鈥? Store in original closed containers in a cool, dry, well-ventilated area. Store
Storage:
separately from all combustible, organic and oxidizable materials.
鈥? Detergent intermediate 鈥? follow bulk handling and storage procedures as noted
Specific use(s):
above.
Refer to Section 6 for clean-up of spillages.
Refer to Section 13 for disposal considerations.
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
鈥? Good industrial hygiene should be followed. Avoid
General Precautions:
breathing (heated) vapors. Avoid eye and skin contact.
鈥? Not established.
Exposure Limit Values:
鈥? Exposure Controls
Engineering Controls: Ventilation: Local exhaust: preferred
Mechanical: may be necessary if working at elevated
temperatures or in enclosed areas.
Personal Protective Equipment: Eye: Goggles or face shield with goggles, dependent upon
potential exposure.
Skin: Protective gloves: Rubber or plastic
Dependent upon degree of potential exposure, additional
personal protective equipment may be required, such as
chemical boots and full protective clothing.
Inhalation: Use an appropriate NIOSH/MSHA approved respirator for
exposure to contaminated atmosphere. A NIOSH/MSHA
approved self-contained breathing apparatus or air-supplied
respirator is recommended if the concentration exceeds the
capacity of cartridge respirator. WARNING: Air purifying
respirators do not protect workers in oxygen-deficient
atmospheres.
Other Controls: Boots, eye wash fountain, safety shower, apron, protective
clothing.
鈥? Contact Procter and Gamble for specific Community
Environmental Exposure Controls:
information.
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9. PHYSICAL AND CHEMICAL PROPERTIES
鈥? General Information:
Physical State: Liquid
Appearance: Colorless to yellow, clear to slightly cloudy.
Odor: Fishy.
Odor Threshold: Not available.
鈥? Important health, safety and environmental information:
pH: Not applicable.
Boiling point/Boiling range: 626掳F (330掳 C) @ 760 mm Hg (101.3kPa)
Flash Point & Method: ~280掳F (137.8掳C) PMCC
Flammability (solid, gas): Not available
Explosive properties: Not available
Oxidising properties: Not available
Vapor pressure: @100掳F (37.8掳C) <1 mm Hg
Relative density: 0.8 @ 21/21掳 C
Freezing point: Not available
Solubility: Water solubility: Very slight
Fat solubility (solvent-oil to be specified): Not available
Partition coefficient: n-octanol/water: Not available
Viscosity: Not available
Vapor density: Not available
Evaporation Rate (nBuOAc=1): Not available
Explosive Limits: Not available
Auto ignition temperature: Not available
Coefficient of water/oil distribution: Not available
10. STABILITY AND REACTIVITY
鈥? Stable under normal operational procedures.
Stability:
鈥? Not available.
Conditions to Avoid:
鈥? Copper and copper alloys. Strong oxidizing agents and strong acids.
Materials to Avoid:
鈥? Thermal decomposition to oxides of carbon and nitrogen.
Hazardous Decomposition Products:
鈥? No hazardous polymerization reactions.
Hazardous Polymerization:
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11. TOXICOLOGICAL INFORMATION
The following is based on P&G safety information for C10 - C16 and C14 - C18 alkyl dimethylamines:
Acute Oral Toxicity (Albino Rats)
LD50 = 1.1 g/kg. (C10 - C16 alkyl dimethylamines)
LD50 = 1.0 g/kg. (C14 - C18 alkyl dimethylamines)
Eye Irritation (Rabbits)
Undiluted product, with no rinsing of the eyes after instillation, produced severe eye irritation. The severity of the response
decreased with rinsing.
Skin Irritation (Rabbits)
Undiluted product applied to the clipped, intact and abraded skin for 24 hours produced severe to corrosive skin response in
rabbits.
Primary Irritation Index = 7.0
Degree of Irritancy = Severe
Skin Sensitization (Guinea Pigs)
In a repeated insult patch test a 25% aqueous alkyl benzene sulfonate solution of product was applied to the clipped backs
of guinea pigs for 6 hours, once a week for 4 weeks. No sensitization was noted.
ACUTE TOXICITY:
>3 g/kg*
Oral, mouse LD50
>3 g/kg*
Subcutaneous, mouse LD50
12. ECOLOGICAL INFORMATION
The following data is for 1-Octadecanamine, N, N-dimethyl (CAS RN 124-28-7), although expected to be similar for
related 1-Hexadecanamine, N, N-dimethyl- (CAS RN 112-69-6).
Biodegradation: Inherently degradable based on OECD 301 B
Toxic to freshwater and marine species.
River Water:
2.1 mg/l Bluegill
LC50 96 hr.:
0.35 mg/l Daphnia magna
LC50 48 hr.:
Filtered Sea Water:
8.8 mg/l Sheepshead minnow
LC50 96 hr.:
0.074 mg/l Mysid shrimp
LC50 96 hr.:
13. DISPOSAL CONSIDERATIONS
DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL, STATE/PROVINCIAL AND LOCAL
REGULATIONS. Do not dispose of via sinks, drains or into the immediate environment.
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14. TRANSPORT INFORMATION
U.S. DOT
UN No. 2735
Proper Shipping name Amines, liquid, corrosive, n.o.s.
(Fatty Tertiary Amine)
Hazard Class 8
Packaging group III
Land Transport (ADR/RID)
UN No. 2735
Proper Shipping name Amines, liquid, corrosive, n.o.s.
(Fatty Tertiary Amine)
Hazard Class 8
Packaging group III
Hazard ID No. 80
Sea Transport (IMDG)
UN No. 2735
Proper Shipping name Amines, liquid, corrosive, n.o.s.
(Fatty Tertiary Amine)
Hazard Class 8
Packaging group III
Air transport (ICAO/IATA)
UN No. 2735
Proper Shipping name Amines, liquid, corrosive, n.o.s.
(Fatty Tertiary Amine)
Hazard Class 8
Packaging group III
15. ADDITIONAL REGULATORY INFORMATION
INVENTORY STATUS:
1-Hexadecanamine, N, N-dimethyl- TSCA (US), AICS (Australia), DSL (Canada), IECSC (China), EINECS
(EU), ENCS (Japan), KECI (Korea), NZIoC (New Zealand), PICCS
(Philippines), Switzerland
AT-1695 WGK Water endangering 3, severely water endangering
class is based on the computation rule
of VwVwS Annex 4 for mixtures.
USA REGULATORY INFORMATION
SARA Title III: Sections 311/312
Superfund Amendments and Reauthorization Act of 1986 requires reporting under the Community Right-To Know
provisions due to their inclusion in one of the five hazard categories listed in 40 CFR 370. Components present in this
product which could require reporting under the statute are:
IMMEDIATE (ACUTE) HEALTH HAZARD:
Chemical Name CAS No. Concentration (max/typ)
1-Hexadecanamine, N, N-dimethyl- 112-69-6 98%
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15. ADDITIONAL REGULATORY INFORMATION 鈥? CONTINUED
California Proposition 65
Substances, which are known to the State of California to cause cancer and/or birth defects or other reproductive harm,
must be identified when present in products. Components present in this product at a level which could require reporting
under the statute in either or both hazard categories are:
AS A CANCER HAZARD:
Chemical Name CAS No. Concentration (max/typ)
N-Nitrosodimethylamine 62-75-9 in traces
Massachusetts Right-To-Know Substance List (MSL)
Hazardous and Extraordinarily Hazardous Substances on the MSL must be identified when present in products.
Components present in this product at a level which could require reporting under the statute are:
EXTRAORDINARILY HAZARDOUS SUBSTANCES (>= 1 ppm or 0.0001%):
Chemical Name CAS No. Concentration (max/typ)
N-Nitrosodimethylamine 62-75-9 in traces
New Jersey Right-To-Know Substance List
Requires Hazardous Substances and Specially Hazardous Substances on the list to be identified when present in products.
Components present in this product at a level which could require reporting under the statute are:
HAZARDOUS substances (>= 1.0 %):
Chemical Name CAS No. Concentration (max/typ)
1-Hexadecanamine, N, N-dimethyl- 112-69-6 98%
EC LABELING AND CLASSIFICATION:
According to Directives 67/548/EEC and 1999/45/EC
Symbol: C=Corrosive, N= Dangerous to the environment
Risk phrase(s): R34 Causes burns.
R22 Harmful if swallowed.
R50 Very toxic to aquatic organisms.
Safety phrase(s): S36/37/39 Wear suitable protective clothing, gloves, and eye/face protection.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
S28 After contact with skin, wash immediately with plenty of mild soap and water. If
available, use an appropriate decontamination skin cleanser.
S45 In case of accident or if you feel unwell seek medical advice immediately (show the
label where possible).
S61 Avoid release to environment. Refer to Safety Data Sheet.
Canada
HAZARDOUS INGREDIENTS 鈥? WHMIS (Canadian Workplace Hazardous Materials Information System)
This product when tested as a whole is considered a controlled substance, Class E (corrosive) and Class D, Division 2,
Subdivision B (skin and eye irritant, Toxic) within the meaning of the Hazardous Products Act.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the
MSDS contains all the information required by the Controlled Products Regulations.
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16. OTHER INFORMATION
EUROPE
This product safety data sheet was prepared in compliance with Directive 2001/58/EC.
R-phrase(s):
R34 Causes burns.
R22 Harmful if swallowed.
R50 Very toxic to aquatic organisms.
USA LABELING:
DANGER: CAUSES CHEMICAL BURNS.
Do not get in eyes, on skin, or on clothing.
Avoid breathing vapor, mist.
Keep container closed. Use only with adequate ventilation.
Wash thoroughly after handling.
FIRST AID: In case of contact
EYES Immediately flush eyes with plenty of water for at least 15 minutes. Get medical
attention immediately.
SKIN Immediately wash thoroughly with mild soap and water. If available, use an
appropriate decontamination skin cleanser. Remove contaminated clothing and
wash before reuse. Destroy contaminated shoes. Immediately obtain medical
attention.
References: *RTECS ACCESSION NUMBER MM0750000 1-Hexadecanamine, N, N-
dimethyl-
The following sections contain revisions or new statements: 1-3, 15-16.
Department issuing MSDS: Product Safety and Regulatory Affairs 1-800-477-8899
DISCLAIMER: This MSDS is intended to provide a brief summary of our knowledge and guidance regarding the use of
this material. The information contained here has been compiled from sources considered by Procter & Gamble to be
dependable and is accurate to the best of the Company鈥檚 knowledge. It is not meant to be an all-inclusive document on
worldwide hazard communication regulations.
This information is offered in good faith. Each user of this material needs to evaluate the conditions of use and design the
appropriate protective mechanisms to prevent employee exposures, property damage or release to the environment. Procter
& Gamble assumed no responsibility for injury to the recipient or third persons, or for any damage to any property resulting
from misuse of the product.
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