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MATERIAL SAFETY DATA SHEET
MSDS Number: AMINE250-1 Revision Date: None
Supersedes: None Issue Date: May 2, 2006
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
鈥? Product identification
Synonyms/Trade Names: Behenyl Dimethyl Amine / AT-1822A
鈥? Product uses
Personal Care Products
鈥? Company/undertaking identification
The Procter & Gamble Company
North America:
Procter & Gamble Chemicals
Sharon Woods Technical Center
11530 Reed Hartman Highway
Cincinnati, Ohio 45241
Department issuing MSDS:
Product Safety and Regulatory Affairs
1-800-477-8899
P&G Chemicals Asia
Asia:
238-A Thompson Road #21-01/10
Novena Square Tower A
Singapore 307684
鈥? P&G Chemicals Asia: (65) 6824 5728 (day phone)
Emergency Telephone:
CHEMTREC 1-800-424-9300 U.S. and Canada
1-703-527-3887 For calls originating
elsewhere
Quality or Service Issues: Call Customer Service
1-800-477-8899 or 513-626-6882
NAME: AT-1822A ISSUE DATE: May 2, 2006 Page 2 of 8
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/Preparation (mixture): Substance
Name CAS No. Wt/Wt %
Amines, C16-22-alkyldimethyl 75444-69-8 100
Occupational exposure limits, if applicable, are listed in Section 8.
LC/LD50 information is listed in Section 11.
3. HAZARDS IDENTIFICATION
鈥? DANGER: CORROSIVE ! CAUSES CHEMICAL
Emergency Overview:
BURNS
鈥? Eye: Can cause severe eye irritation. Prolonged exposure to
Potential Health Effects:
eyes can cause severe chemical burns. Uncontrolled vapor
exposure may cause severe pain or serious damage to eye.
Skin: Can cause severe skin irritation. Prolonged exposure to
skin can cause severe chemical burns. Exposure can cause
latent severe burns. Heated product may cause thermal
burns if contacted.
Inhalation: Prolonged or repeated high level exposures may cause
severe irritation of respiratory passages and/or lung
congestion.
Ingestion: Small amounts may cause injury.
鈥? Not identified.
Physical/Chemical Hazards:
鈥? Expected to be toxic to freshwater and marine species.
Environmental Hazards:
4. FIRST AID MEASURES
鈥? Immediately flush eyes with plenty of water for at least 15 minutes. Get
Eye:
medical attention immediately.
鈥? Immediately wash thoroughly with mild soap and water. If available, use an
Skin:
appropriate decontamination skin cleanser. Remove contaminated clothing and
wash before reuse. Destroy contaminated shoes. Immediately obtain medical
attention.
鈥? If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
Inhalation:
breathing is difficult, give oxygen. Immediately get medical attention.
鈥? If swallowed, do not induce vomiting. If victim is fully conscious, dilute
Ingestion:
stomach contents with large amounts of milk or water. Never give anything by
mouth to an unconscious person. Immediately call a physician.
NAME: AT-1822A ISSUE DATE: May 2, 2006 Page 3 of 8
5. FIRE FIGHTING MEASURES
鈥? Use foam, CO2, or dry chemical
Extinguishing Media:
鈥? Not identified
Unsuitable extinguishing media:
鈥? >230掳F (>110掳 C) PMCC
Flash Point and Method:
鈥? Upper: Not available.
Explosive limits in air:
Lower: Not available.
鈥? Not available.
Auto-ignition temperature:
鈥? Not available.
Sensitivity to mechanical
impact/static discharge:
鈥? Wear self-contained breathing apparatus and full protective
Special Protective Equipment:
clothing.
鈥? Cool containers with flooding quantities of water until well
Other Fire Fighting Considerations:
after fire is out.
鈥? When heated to decomposition, emits toxic fumes of NOx.
Exposure hazards:
6. ACCIDENTAL RELEASE MEASURES
鈥? Use an appropriate NIOSH/MSHA approved respirator for exposure to
Personal Precautions:
contaminated atmosphere. Appropriate protective clothing should be worn
during cleanup. Do not touch damaged containers or spilled material unless
wearing appropriate protective clothing.
鈥? Prevent from reaching waterways.
Environmental Precautions:
鈥? SMALL SPILLS: Absorb on inert material and dispose.
Procedures for Spill/Leak Clean-up:
LARGE SPILLS: Contain spill and remove for disposal.
Refer to Section 8 for additional personal protection information.
Refer to Section 13 for disposal considerations.
7. HANDLING AND STORAGE
鈥? Handle in accordance with good hygiene and safety procedures. Avoid contact
Handling:
with eyes, skin, and clothing. Wash thoroughly after handling. Since empty
containers contain product residue and can be dangerous, follow all hazard
warnings and precautions even after container is emptied. Keep away from
sources of ignition.
鈥? Store in original closed containers in a cool, dry, well-ventilated area. Store
Storage:
separately from all combustible, organic and oxidizable materials. Avoid
contact with copper and alloys containing copper.
鈥? Detergent intermediate: follow bulk handling and storage procedures as noted
Specific use(s):
above.
Refer to Section 6 for clean-up of spillages.
Refer to Section 13 for disposal considerations.
NAME: AT-1822A ISSUE DATE: May 2, 2006 Page 4 of 8
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
鈥? Good industrial hygiene practices should be followed.
General Precautions:
Avoid breathing (heated) vapors. Avoid eye and skin
contact.
鈥? Not established.
Exposure Limit Values:
鈥? Exposure Controls
Engineering Controls: Ventilation: Local exhaust: preferred
Mechanical: may be necessary if working at elevated
temperatures or in enclosed areas.
Personal Protective Equipment: Eye: Goggles or face shield with goggles, dependent upon
potential exposure.
Skin: Protective gloves: Rubber or plastic
Dependent upon degree of potential exposure, additional
personal protective equipment may be required, such as
chemical boots and full protective clothing.
Inhalation: Use an appropriate NIOSH/MSHA approved respirator for
exposure to contaminated atmosphere. A NIOSH/MSHA
approved self-contained breathing apparatus or air-
supplied respirator is recommended if the concentration
exceeds the capacity of cartridge respirator. WARNING:
Air purifying respirators do not protect workers in oxygen-
deficient atmospheres.
Other Controls: Boots, eye wash fountain, safety shower, apron, protective
clothing.
鈥? Contact Procter and Gamble for specific Community
Environmental Exposure Controls:
information.
9. PHYSICAL AND CHEMICAL PROPERTIES
鈥? General Information:
Physical State: Solid
Appearance: Pasty (light yellow color)
Odor: Fishy
Odor Threshold: Not available.
鈥? Important health, safety and environmental information:
pH: Not applicable.
Boiling point/Boiling range: 380掳 C @ 760 mm Hg (101.3kPa)
Flash Point & Method: >230掳F (>110掳 C) PMCC
Flammability (solid, gas): Not available
Explosive properties: Not available
Oxidising properties: Not available
Vapor pressure @ 21掳 C: <1 mm Hg
Relative Density: 0.9
Freezing point: Not available
Solubility: Water solubility: Slight
Fat solubility (solvent-oil to be specified): Not available
Partition coefficient: n-octanol/water: Not available
Viscosity: >5 cps @ 55掳C
NAME: AT-1822A ISSUE DATE: May 2, 2006 Page 5 of 8
9. PHYSICAL AND CHEMICAL PROPERTIES - CONTINUED
Vapor density (AIR=1): Not available
Evaporation Rate (nBuOAc=1): Not available
Explosive Limits: Not available
Auto ignition temperature: Not available
Coefficient of water/oil distribution: Not available
10. STABILITY AND REACTIVITY
鈥? Stable under normal operational procedures.
Stability:
鈥? Not available.
Conditions to Avoid:
鈥? Copper and copper alloys. Strong oxidizing agents and strong acids.
Materials to Avoid:
鈥? Thermal decomposition to oxides of carbon and nitrogen.
Hazardous Decomposition Products:
鈥? No hazardous polymerization reactions.
Hazardous Polymerization:
11. TOXICOLOGICAL INFORMATION
No toxicological data are available for this specific material (C16-22-alkyldimethylamine). The following is P&G safety
information for C14 - C18 alkyl dimethylamines, a close chemical analogue whose toxicological profile is expected
to be similar.
Acute Oral Toxicity (Albino Rats)
LD50 = 1.0 g/kg. (C14 - C18 alkyl dimethylamines)
Eye Irritation (Rabbits)
Undiluted product, with no rinsing of the eyes after instillation, produced severe eye irritation. The severity of the response
decreased with rinsing.
Skin Irritation (Rabbits)
Undiluted product applied to the clipped, intact and abraded skin for 24 hours produced severe to corrosive skin response
in rabbits.
Primary Irritation Index = 7.0
Degree of Irritancy = Severe
Skin Sensitization (Guinea Pigs)
In a repeated insult patch test a 25% aqueous alkyl benzene sulfonate solution of product was applied to the clipped backs
of guinea pigs for 6 hours, once a week for 4 weeks. No sensitization was noted.
NAME: AT-1822A ISSUE DATE: May 2, 2006 Page 6 of 8
12. ECOLOGICAL INFORMATION
The following data is for 1-Octadecanamine, N, N-dimethyl (CAS RN 124-28-7), although expected to be
similar for related C16-22-alkyldimethylamine (75444-69-8).
Biodegradation: inherently degradable based on OECD 301B
Toxic to freshwater and marine species.
River Water:
LC50 96 hr. = 2.1 mg/l Bluegill
LC50 48 hr. = 0.35 mg/l Daphnia magna
Filtered Sea Water:
LC50 96 hr. = 8.8 mg/l Sheepshead minnow
LC50 96 hr. = 0.074 mg/l Mysid shrimp
13. DISPOSAL CONSIDERATIONS
DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL, STATE/PROVINCIAL AND LOCAL
REGULATIONS. Do not dispose of via sinks, drains or into the immediate environment.
14. TRANSPORT INFORMATION
U.S. DOT
UN No. 3259
Proper Shipping name Amines, solid, corrosive, n.o.s.
(Fatty Tertiary Amines)
Hazard Class 8
Packaging group III
Land Transport (ADR/RID)
UN No. 3259
Proper Shipping name Amines, solid, corrosive, n.o.s.
(Fatty Tertiary Amines)
Hazard Class 8
Packaging group III
Hazard ID No. 80
Sea Transport (IMDG)
UN No. 3259
Proper Shipping name Amines, solid, corrosive, n.o.s.
(Fatty Tertiary Amines)
Hazard Class 8
Packaging group III
Air transport (ICAO/IATA)
UN No. 3259
Proper Shipping name Amines, solid, corrosive, n.o.s.
(Fatty Tertiary Amines)
Hazard Class 8
Packaging group III
NAME: AT-1822A ISSUE DATE: May 2, 2006 Page 7 of 8
15. ADDITIONAL REGULATORY INFORMATION
INVENTORY STATUS:
TSCA (US), DSL (Canada), ENCS (Japan), KECI (Korea),
USA REGULATORY INFORMATION
SARA Title III: Sections 311/312
Superfund Amendments and Reauthorization Act of 1986 requires reporting under the Community Right-To Know
provisions due to their inclusion in one of the five hazard categories listed in 40 CFR 370. Components present in this
product which could require reporting under the statute are:
IMMEDIATE (ACUTE) HEALTH HAZARD:
Chemical Name CAS No. Concentration (max/typ)
Amines, C16-22-alkyldimethyl 75444-69-8 100
New Jersey Right-To-Know Substance List
Requires Hazardous Substances and Specially Hazardous Substances on the list to be identified when present in products.
Components present in this product at a level which could require reporting under the statute are:
HAZARDOUS substances (>= 1.0 %):
Chemical Name CAS No. Concentration (max/typ)
Amines, C16-22-alkyldimethyl 75444-69-8 100
Canada
HAZARDOUS INGREDIENTS 鈥? WHMIS (Canadian Workplace Hazardous Materials Information System)
This product when tested as a whole is considered a controlled substance, Class E (corrosive) and Class D, Division 2,
Subdivision B (skin and eye irritant, Toxic) within the meaning of the Hazardous Products Act.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the
MSDS contains all the information required by the Controlled Products Regulations.
___________________________________________________________________________________________________
16. OTHER INFORMATION
USA LABELING:
DANGER: CAUSES CHEMICAL BURNS.
Do not get in eyes, on skin, or on clothing.
Avoid breathing vapor, mist.
Keep container closed. Use only with adequate ventilation.
Wash thoroughly after handling.
In case of contact
FIRST AID:
Immediately flush eyes with plenty of water for at least 15 minutes. Get
EYES
medical attention immediately.
Immediately wash thoroughly with mild soap and water. If available, use an
SKIN
appropriate decontamination skin cleanser. Remove contaminated clothing and
wash before reuse. Destroy contaminated shoes. Immediately obtain medical
attention.
NAME: AT-1822A ISSUE DATE: May 2, 2006 Page 8 of 8
16. OTHER INFORMATION - CONTINUED
The following sections contain revisions or new statements: New MSDS.
Department issuing MSDS: Product Safety and Regulatory Affairs 1-800-477-8899
The submission of the MSDS may be required by law, but this is not an assertion that the substance is hazardous when used
in accordance with proper safety practices and normal handling procedures. Data supplied are for use only in connection
with occupational safety and health.
The information contained herein has been compiled from sources considered by Procter & Gamble to be dependable and is
accurate to the best of the Company's knowledge. The information relates to the specific product designated herein, and
does not relate to use in combination with any other material or any other process. Procter & Gamble assumes no
responsibility for injury to the recipient or third persons, or for any damage to any property resulting from misuse of the
controlled product.
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