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MATERIAL SAFETY DATA SHEET
MSDS Number: MC105-2 Revision Date: April 5, 2007
Supersedes: MC105-1 Issue Date: December 1, 1999
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
鈥? Product identification
Material Name CAS NO. EINECS NO.
Mixture of:
Dodecanoic acid 143-07-7 2055821
Tetradecanoic acid 544-63-8 2088752
Hexadecanoic acid 57-10-3 2003129
Octadecanoic acid 57-11-4 2003134
9-Octadecenoic acid, (Z)- 112-80-1 2040071
Synonyms/Trade Names: C-1218D, C-1218LH
鈥? Product uses
The most common uses for this product are for the production of soaps, emulsifiers, lubricants, carriers, and soap
surfactants.
鈥? Company/undertaking identification
North America: The Procter & Gamble Company
Procter & Gamble Chemicals
Sharon Woods Technical Center
11530 Reed Hartman Highway
Cincinnati, Ohio 45241
Department issuing MSDS: Product Safety and Regulatory Affairs
1-800-477-8899
Europe: Procter & Gamble International
Operations S.A.
P&G Chemicals 鈥? Europe
The Heights
Brooklands
Weybridge
Surrey
ENGLAND KT13 0XP
Telephone Number: 01932 - 896000
鈥? Emergency Telephone: P&G Ltd. - Brooklands, England: Tel 01932-896000 (day phone)
Emergency 0191-279-2000 (day phone)
CHEMTREC 1-800-424-9300 U.S. and Canada
1-703-527-3887 For calls originating
elsewhere
Quality or Service Issues: Call Customer Service
1-800-477-8899 or 513-626-688
NAME: C-1218D, C-1218LH REVISION DATE: April 5, 2007 Page 2 of 9
2. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/Preparation(mixture): Preparation
EC EC
CAS No. Wt/Wt % EC-No. Symbols R-phrases
Decanoic Acid & lower 334-48-5 1 max. 2063764 Xi R36/38
Dodecanoic Acid 143-07-7 45-60 2055821 Xi R36
Tetradecanoic Acid 544-63-8 17-27 2088752 Not applicable Not applicable
Hexadecanoic Acid 57-10-3 5-15 2003129 Not applicable Not applicable
Octadecanoic Acid 57-11-4 8 max. 2003134 Not applicable Not applicable
9-Octadecenoic Acid, (Z)- 112-80-1 10 max. 2040071 Not applicable Not applicable
Occupational exposure limits, if applicable, are listed in Section 8.
LC/LD50 information is listed in Section 11.
Full text of R phrase(s) are listed in section 16.
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3. HAZARDS IDENTIFICATION
European Hazard Classification: This product is classified as Xi 鈥? Irritant, R36 鈥? Irritating to eyes.
CAUTION: MAY CAUSE EYE IRRITATION
鈥? Emergency Overview:
鈥? Potential Health Effects:
Eye - Accidental exposure to the eyes will cause irritation.
Skin - Mild, primary skin irritation with prolonged or repeated contact.
Heated product may cause thermal burns if contacted.
Inhalation - May elicit transient pulmonary irritation if inhaled.
Ingestion - Can cause irritation to mucous membranes.
鈥? Physical/Chemical Hazards: None identified.
鈥? Environmental Hazards: None identified.
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4. FIRST AID MEASURES
鈥? Eye - In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
Get medical attention.
鈥? Skin - Wash skin with soap and water upon contact. Remove contaminated clothing. If irritation develops,
get medical attention. Wash clothing before reuse.
鈥? Inhalation - Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical attention immediately.
鈥? Ingestion - If swallowed, do not induce vomiting. Get medical attention. Never give anything by mouth to an
unconscious person.
NAME: C-1218D, C-1218LH REVISION DATE: April 5, 2007 Page 3 of 9
5. FIRE FIGHTING MEASURES
鈥? Extinguishing media: SMALL FIRES: Use CO2 or dry chemical.
LARGE FIRES: Use foam.
鈥? Unsuitable extinguishing media: Do not use water as an extinguishing media.
鈥? Flash Point and method: >310掳 F (>154掳 C) PMCC
鈥? Explosive limits in air:
Upper: Not available
Lower: Not available
鈥? Auto-ignition temperature: Not available
鈥? Sensitivity to mechanical impact/static discharge: Not available
鈥? Special Protective Equipment: Wear self-contained breathing apparatus and full protective clothing.
鈥? Other Fire Fighting Considerations: Cool containers with flooding quantities of water until well after fire is out.
鈥? Exposure hazards: Does not decompose up to 400掳 F (204掳 C). Thermal decomposition may produce carbon
monoxide and/or carbon dioxide.
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6. ACCIDENTAL RELEASE MEASURES
鈥? Personal Precautions: An appropriate NIOSH/MSHA approved respirator should be used if a mist, vapor or dust is
generated. Wear suitable gloves and eye/face protection. Do not touch damaged containers
or spilled material unless wearing appropriate protective clothing.
鈥? Environmental Precautions: Minimize contamination of drains, surface and ground waters.
鈥? Procedures for Spill/Leak Clean-up: Sweep or shovel solids. For liquid spills, neutralization is not required.
Contain spill. Absorb or cover with dry earth, sand or other non-
combustible material and transfer to containers for disposal. Dispose as any
grease or oily material in compliance with Federal, State, and/or Local
requirements.
Refer to Section 8 for additional personal protection information.
Refer to Section 13 for disposal considerations.
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7. HANDLING AND STORAGE
鈥? Handling: Handle in accordance with good hygiene and safety procedures. Avoid contact with eyes, skin, and
clothing. Wash thoroughly after handling.
Since empty containers contain product residue and can be dangerous, follow all hazard warnings and
precautions even after container is emptied. Keep away from sources of ignition.
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7. HANDLING AND STORAGE-CONTINUED
鈥? Storage: Keep away from possible contact with incompatible substances.
Store in acid resistant vessels such as stainless steel, aluminum, or steel coated with resin lining
such as Lithcote LC-19 or Kanigen.
Do not store near sources of ignition.
鈥? Specific use(s): Follow bulk handling and storage procedures as noted above.
Refer to Section 6 for clean-up of spillages.
Refer to Section 13 for disposal considerations.
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
鈥? General Precautions: Good industrial hygiene should be followed.
Avoid breathing (heated) vapors. Avoid eye and skin contact.
鈥? Exposure Limit Values: Not established
鈥? Exposure Controls:
Engineering Controls: Ventilation: Local exhaust - preferred
Mechanical - may be necessary if working at elevated temperatures
or in enclosed areas.
Personal Protective Equipment:
Eye - Goggles or face shield with goggles, dependent upon potential exposure.
Skin - Protective gloves: Rubber or plastic
Dependent upon degree of potential exposure, additional personal protective
equipment may be required, such as chemical boots and full protective clothing.
Inhalation - None required for ambient temperature, although an appropriate NIOSH/MSHA approved air-purifying
respirator should be used if a mist, vapor or dust is generated. A NIOSH/MSHA approved self-contained
breathing apparatus or air-supplied respirator is recommended if the concentration exceeds the capacity
of cartridge respirator. WARNING: Air purifying respirators do not protect workers in oxygen-
deficient atmospheres.
Other Controls: Boots, eye wash fountain, safety shower, apron, protective clothing.
鈥? Environmental Exposure Controls: Contact Procter and Gamble for specific Community information.
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NAME: C-1218D, C-1218LH REVISION DATE: April 5, 2007 Page 5 of 9
9. PHYSICAL AND CHEMICAL PROPERTIES
鈥? General Information:
Physical State @ 72掳 F (22掳 C): Solid
Appearance: Off white to light brown
Odor: Bland odor note
Odor Threshold: Not available
鈥? Important health, safety and environmental information:
pH: Not available
Boiling point/Boiling range: >500掳 F (>260掳 C) @ 760 mm Hg (101.3kPa)
Flash Point & Method: >310掳 F (>154掳 C) PMCC
Flammability (solid, gas): Not available
Explosive properties: Not available
Oxidising properties: Not available
Vapor pressure @ 72掳 F (22掳 C) <1mm Hg
Relative density: 0.85 - 0.90 @ 49/25掳 C
Freezing point: Not available
Solubility:
Water solubility: Negligible @ 72掳 F (22掳 C)
Fat solubility (solvent-oil to be specified): Not available
Partition coefficient: n-octanol/water: Not available
Viscosity: Not available
Vapor density: Not available
Evaporation Rate (nBuOAc=1): Not available
Explosive Limits: Not available
Auto ignition temperature: Not available
Coefficient of water/oil distribution: Not available
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10. STABILITY AND REACTIVITY
鈥? Stability: Stable under normal operational conditions.
鈥? Conditions to Avoid: Not available.
鈥? Materials to Avoid: Strong oxidizing agents.
鈥? Hazardous Decomposition Products: Does not decompose up to 400掳 F (204掳 C). Thermal decompositon or burning
may produce carbon monxide and/or carbon dioxide.
鈥? Hazardous Polymerization: Will not occur
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NAME: C-1218D, C-1218LH REVISION DATE: April 5, 2007 Page 6 of 9
11. TOXICOLOGICAL INFORMATION
Dodecanoic Acid:
IRRITATION DATA:
Eye, rabbit Corneal opacity, mild conjunctivitis, iritis 鈥? 72 h observation
Skin, rabbit 500 mg. Mild irritation effects
ACUTE TOXICITY:
Oral, rat LD50 12 gm/kg
Tetradecanoic Acid:
IRRITATION DATA:
Eye, rabbit 100 mg. Mild irritation effects
Skin, human 75 mg/3D-I MOD
ACUTE TOXICITY:
Oral, rat LD50 >10 gm/kg
Hexadecanoic Acid:
IRRITATION DATA:
Eye, rabbit Not irritating
Skin, rabbit Not irritating
Skin, human 75 mg/3D-I MLD
ACUTE TOXICITY:
Oral, rat LD50 >10 gm/kg
Octadecanoic Acid
IRRITATION DATA:
Eye, rabbit Not irritating
Skin, rabbit Not irritating
500 mg/24H MOD
Skin, human 75 mg/3D-I MLD
ACUTE TOXICITY:
Oral, rat LD50 >10 gm/kg
Oleic Acid
IRRITATION DATA:
Eye, rabbit Not irritating
Skin, rabbit Not irritating
Skin sensitization No sensitization reaction
ACUTE TOXICITY:
Oral, rat LD50: >21.5 ml/kg
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NAME: C-1218D, C-1218LH REVISION DATE: April 5, 2007 Page 7 of 9
12. ECOLOGICAL INFORMATION
Dodecanoic acid:
Bluegill sunfish 96h LC50 63.3 mg/l
NOEC 32 mg/l
Oryzias latipes 96h LC50 8.6 mg/l
Gammarus sp. 48h EC50 8.6 mg/l
Nitzschia sp. 72h EC50 30000 mol/l
Microbial inhibition None at 10,000 mg/l
Tetradecanoic acid:
Gammarus (Hyale plumulosa) 96h LC50 no mortality at saturation conc.
goldfish lethal dose 9 mg/l (sodium salt)
red killifish (Oryzias latipes) 96h LC50 in seawater: no mortality at saturation conc.
118 mg/l (sodium myristate)
Hexadecanoic Acid:
Goldfish (lethal dose) 11 mg/l (sodium salt)
Red killifish 96h LD50 150 mg/l (sodium salt)
Octadecanoic Acid
goldfish: lethal dose: 14 mg/l (sodium salt)
red killifish (Oryzias latipes): 96h LC50: 125 mg/l (sodium salt)
Daphnia magna: Palmitic and stearic acids; not acutely toxic to Daphnia Magna at concentrations within its aqueous
solubility (water hardness of 215 & 54 mg/L CACO3).
Scenedesmus subspicatus EC50 > 1016 mg/l
Scenedesmus subspicatus NOEC > 1016 mg/l
Oleic Acid
goldfish: lethal dose: 8 mg/l (sodium salt)
fathead minnows 96h LC50: 205 mg/l
red killifish 96h LC50: 217 mg/l (sodium salt)
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13. DISPOSAL CONSIDERATIONS
DISPOSAL IS TO BE PERFORMED IN COMPLIANCE WITH ALL FEDERAL, STATE/PROVINCIAL AND LOCAL
REGULATIONS. Do not dispose of via sinks, drains or into the immediate environment.
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14. TRANSPORT INFORMATION
U.S. DOT: Not regulated for transport
Not classified in RID/ADR - ADNR - IMDG - ICAO/IATA - DGR
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15. ADDITIONAL REGULATORY INFORMATION
INVENTORY STATUS:
Dodecanoic acid TSCA (US), AICS (Australia), DSL (Canada), IECSC (China), EINECS (EU),
ENCS (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines)
NAME: C-1218D, C-1218LH REVISION DATE: April 5, 2007 Page 8 of 9
15. ADDITIONAL REGULATORY INFORMATION - CONTINUED
INVENTORY STATUS (continued):
Tetradecanoic acid TSCA (US), AICS (Australia), DSL (Canada), IECSC (China), EINECS (EU),
ENCS (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines),
Switzerland
Hexadecanoic acid TSCA (US), AICS (Australia), DSL (Canada), IECSC (China), EINECS (EU),
ENCS (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines),
Switzerland
Octadecanoic acid TSCA (US), AICS (Australia), DSL (Canada), IECSC (China), EINECS (EU),
ENCS (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines),
Switzerland
9-Octadecenoic acid, (Z)- TSCA (US), AICS (Australia), DSL (Canada), IECSC (China), EINECS (EU),
ENCS (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines),
Switzerland
C-1218D and C-1218LH WGK water 1- slightly water endangering
endangering class is based on the computation
rule of VwVwS Annex 4 for mixtures.
EC LABELING AND CLASSIFICATION:
According to Directives 67/548/EEC and 1999/45/EC.
- Symbol: Xi Irritant
- Risk phrase(s): R36 Irritating to eyes.
- Safety phrase(s): S25 Avoid contact with eyes.
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
Canada
HAZARDOUS INGREDIENTS 鈥? WHMIS (Canadian Workplace Hazardous Materials Information System)
This product when tested as a whole is considered a controlled substance Class D, Division 2, Subdivision b
(eye irritant, toxic) within the meaning of the Hazardous Products Act.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the
MSDS contains all the information required by the Controlled Products Regulations.
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16. OTHER INFORMATION
EUROPE
This product safety data sheet was prepared in compliance with 2001/58/EC.
R-phrase(s):
R36 Irritating to eyes.
USA LABELING:
CAUTION: MAY CAUSE EYE IRRITATION
Avoid contact with eyes. Wash thoroughly after handling.
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16. OTHER INFORMATION - CONTINUED
FIRST AID: In case of contact, immediately flush eyes with plenty of water for at
least 15 minutes. Get medical attention.
References: RTECS ACCESSION NUMBER OE9800000 鈥? Lauric acid
RTECS ACCESSION NUMBER QH4375000 鈥? Myristic acid
RTECS ACCESSION NUMBER RT4550000 鈥? Palmitic acid
RTECS ACCESSION NUMBER W12800000 鈥? Stearic acid
Acute toxicity and irritation studies on a series of fatty acids. J. Am. Oil Chem. Soc.,
56 (1979), p. 760A.
Patty鈥檚 Industrial Hygiene and Toxicology, 4th ed. Edited by George D. Clayton &
Florence E. Clayton
Handbook of Environmental Data on Organic Chemicals,
3rd Edition, Karel Verschueren
Onitsuka et al. 1989. Chemosphere. 18:1621-1631.
Mann & Florence. 1987. Fuel. 66:404-407.
The following sections contain revisions or new statements: 1, 15-16.
Department issuing MSDS: Product Safety and Regulatory Affairs 1-800-477-8899.
DISCLAIMER: This MSDS is intended to provide a brief summary of our knowledge and guidance regarding the use of
this material. The information contained here has been compiled from sources considered by Procter & Gamble to be
dependable and is accurate to the best of the Company鈥檚 knowledge. It is not meant to be an all-inclusive document on
worldwide hazard communication regulations.
This information is offered in good faith. Each user of this material needs to evaluate the conditions of use and design the
appropriate protective mechanisms to prevent employee exposures, property damage or release to the environment. Procter
& Gamble assumed no responsibility for injury to the recipient or third persons, or for any damage to any property resulting
from misuse of the product.
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