Material Safety Data Sheet
Material Name: Optical Fiber with colored coating ID: C-089
* * * Section 1 - Chemical Product and Company Identification * * *
Product Name: Corning Vascade® EX1000, Corning® 62.5/125 fiber, Corning® InfiniCor® 300 fiber, InfiniCor® CL� 1000 fiber,
Corning® 50/125 fiber, Corning® InfiniCor® 600 fiber, Corning® InfiniCor® SX+ fiber, Corning® InfiniCor® SXi fiber,
InfiniCor® eSX+ optical fiber, Corning® SMF-28e® fiber, SMF-28e® photonic fiber, Corning® MetroCor® fiber, Corning®
Vascade® LS+ fiber, Corning® LEAF® fiber, Corning® Vascade® LEAF® fiber, Submarine LS, Corning® Vascade® L1000 fiber,
Submarine Hybrid optical fiber, Corning® Vascade® S1000 fiber, Vascade® R1000 fiber solution, Corning® NexCor� optical
fiber, ClearCurveâ„? fiber, SMF-28e+â„? fiber
Chemical Name: Glass core covered with a colored urethane acrylate polymer.
Product Use: Light transmission
Manufacturer Information
Corning Incorporated Phone: (910) 784-7200
Wilmington Plant
310 N. College Road Emergency # 24 Hr CHEMTREC U.S. (800) 424-9300
Wilmington, NC 28440 24 Hr CHEMTREC International (703) 527-3887
General Comments
NOTE: CHEMTREC telephone number is to be used only in the event of chemical emergencies involving a spill, leak, fire,
exposure, or accident involving chemicals.
* * * Section 2 - Hazards Identification * * *
Emergency Overview
This is a non-combustible, non-reactive solid material. It is supplied in the form of a glass filament in a polymer coating.
Exposure to glass powder or dusts may be irritating to eyes, nose, and throat. Use methods suitable to fight surrounding fire.
Combustion products can include irritating and toxic fumes and gases.
Hazard Statements
Dust or powder may be irritating to the eyes, skin, respiratory system and gastrointestinal tract.
Potential Health Effects: Eyes
Dust or powder may irritate eye tissue. Rubbing may cause abrasion of cornea. Symptoms can include redness and tearing.
Potential Health Effects: Skin
The cured polymer coating has been tested and found to be non-irritating to the skin. No components in this product have
been found to be absorbed through the skin.
Potential Health Effects: Ingestion
May cause temporary irritation of the throat, stomach, and gastrointestinal tract.
Potential Health Effects: Inhalation
Dusts from the grinding of this product may cause irritation of the nose, throat, and respiratory tract. When inhaled in very
large amounts, damage to the lung can occur.
HMIS Ratings: Health: 1 Fire: 0 Physical Hazard: 0 Pers. Prot.: gloves, goggles required only when cutting and splicing fiber
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard
* * * Section 3 - Composition / Information on Ingredients * * *
CAS # Component Percent
Not Available Urethane Acrylate Polymer <100
65997-17-3 Glass, oxide, chemicals <100
Not Available Ink <1
3524-68-3 Pentaerythritol Triacrylate <1
Component Related Regulatory Information
This product may be regulated, have exposure limits or other information identified as the following: Nuisance particulates.
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Page 1 of 6 Issue Date: 03/19/08 Revision: 8.0002 Print Date: 3/19/2008
Material Safety Data Sheet
Material Name: Optical Fiber with colored coating ID: C-089
Component Information/Information on Non-Hazardous Components
Optical Fiber consists of a thin glass filament in a polymer coating. The polymer coating has a thin outer coating of various
colored inks. Glass is a solid material produced by combining various raw materials (e.g. oxides, carbonates, etc.), melting
these components together, and cooling to a non-crystalline solid having its own unique properties.
Processing of this article may produce dusts or fumes which are considered hazardous under 29 CFR 1910.1200 (Hazard
Communication).
* * * Section 4 - First Aid Measures * * *
First Aid: Eyes
Eye injuries from glass fibers should be treated by a physician immediately.
First Aid: Skin
Abrasions from any cut or ground fibers should be treated promptly with thorough cleansing of the affected area. Seek
medical attention for prompt removal of any particles that may be embedded under the skin.
First Aid: Ingestion
Seek medical attention if material is ingested.
First Aid: Inhalation
If inhaled, remove person to fresh air. If symptoms develop or persist, get medical attention.
First Aid: Notes to Physician
Sharp edges of glass may cause mechanical injury.
* * * Section 5 - Fire Fighting Measures * * *
General Fire Hazards
See Section 9 for Flammability Properties.
Coating portion of this material may burn at elevated temperatures.
Hazardous Combustion Products
Carbon dioxide, carbon monoxide, various hydrocarbon fragments, phosphorus oxide, and possibly some carbon-containing
fragments of the polymer coating.
Extinguishing Media
Use methods for the surrounding fire.
Fire Fighting Equipment/Instructions
Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus,
protective clothing and face mask.
NFPA Ratings: Health: 1 Fire: 0 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
* * * Section 6 - Accidental Release Measures * * *
Containment Procedures
None necessary.
Clean-Up Procedures
Wear appropriate protective equipment and clothing during clean-up. Collect spilled material using a vacuum cleaner with a
HEPA filter. Place in a closed container.
Evacuation Procedures
None necessary.
Special Procedures
Spilled fibers tend to create a slipping hazard on hard surfaces.
* * * Section 7 - Handling and Storage * * *
Handling Procedures
Avoid inhalation/contact with dust.
Storage Procedures
Store in a dry area.
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Page 2 of 6 Issue Date: 03/19/08 Revision: 8.0002 Print Date: 3/19/2008
Material Safety Data Sheet
Material Name: Optical Fiber with colored coating ID: C-089
* * * Section 8 - Exposure Controls / Personal Protection * * *
Exposure Guidelines
A: General Product Information
The OSHA (Vacated) air contaminants exposure limits (PELs) are those provided in the 1989 update to 29 CFR 1910.1000.
These limits were vacated by OSHA and may not be enforceable.
B: Component Exposure Limits
Glass, oxide, chemicals (65997-17-3)
ACGIH: 10 mg/m3 TWA (inhalable particles, recommended); 3 mg/m3 TWA (respirable particles,
recommended) (related to Particulates (insoluble or poorly soluble) not otherwise specified
(PNOS))
OSHA (Final): 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) (related to Particulates not
otherwise regulated)
OSHA (Vacated): 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) (related to Particulates not
otherwise regulated)
Alberta: 10 mg/m3 TWA (total particulate); 3 mg/m3 TWA (respirable particulate) (related to
Particulates not otherwise regulated)
British Columbia: 10 mg/m3 TWA (total dust); 3 mg/m3 TWA (respirable fraction) (related to Particles (insoluble
or poorly soluble) not otherwise specified)
Manitoba: 10 mg/m3 TWA (inhalable particles, recommended); 3 mg/m3 TWA (respirable particles,
recommended) (related to Particulates (insoluble or poorly soluble) not otherwise specified
(PNOS))
New Brunswick: 10 mg/m3 TWA (particulate matter containing no asbestos and < 1% crystalline silica,
inhalable fraction); 3 mg/m3 TWA (particulate matter containing no asbestos and < 1%
crystalline silica, respirable fraction) (related to Particulates not otherwise classified (PNOC))
NW Territories: 5 mg/m3 TWA (respirable mass); 10 mg/m3 TWA (total mass) (related to Nuisance particulate)
Nova Scotia: 10 mg/m3 TWA (inhalable particles, recommended); 3 mg/m3 TWA (respirable particles,
recommended) (related to Particulates (insoluble or poorly soluble) not otherwise specified
(PNOS))
Nunavut: 5 mg/m3 TWA (respirable mass); 10 mg/m3 TWA (total mass) (related to Nuisance particulate)
Ontario: 10 mg/m3 TWAEV (inhalable); 3 mg/m3 TWAEV (respirable) (related to Particles (insoluble
or poorly soluble) Not Otherwise Specified (PNOS))
Quebec: 10 mg/m3 TWAEV (total dust, containing no asbestos and less than 1% crystalline silica)
(related to Particulates not otherwise classified (PNOC))
Saskatchewan: 10 mg/m3 TWA; 3 mg/m3 TWA (respirable size) (related to Particulates, n.o.c.)
20 mg/m3 STEL; 6 mg/m3 STEL (respirable size) (related to Particulates, n.o.c.)
Engineering Controls
If material is ground, cut, or used in any operation which may generate small particles, use appropriate local exhaust
ventilation.
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Wear safety glasses with side shields or goggles.
Personal Protective Equipment: Skin
Wear leather or other appropriate work gloves, if necessary for type of operation. The use of coveralls is recommended.
Personal Protective Equipment: Respiratory
Not normally needed. If permissible levels are exceeded, use NIOSH approved dust respirator.
Personal Protective Equipment: General
Use good hygiene practices when handling this material including changing and laundering work clothing after use.
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Page 3 of 6 Issue Date: 03/19/08 Revision: 8.0002 Print Date: 3/19/2008
Material Safety Data Sheet
Material Name: Optical Fiber with colored coating ID: C-089
* * * Section 9 - Physical & Chemical Properties * * *
Translucent white Acrylate odor
Appearance: Odor:
Solid Not applicable
Physical State: pH:
Not applicable Not applicable
Vapor Pressure: Vapor Density:
Not applicable Not applicable
Boiling Point: Melting Point:
Not applicable Not applicable
Solubility (H2O): Specific Gravity:
Not applicable Not applicable
Softening Point: Molecular Weight:
Not applicable Not applicable
Auto Ignition: Flash Point:
Not applicable Not applicable
Flash Point Method: Lower Flammability Limit (LFL):
Not applicable Not applicable
Upper Flammability Limit (UFL): OSHA Flammability Classification:
Physical Properties: Additional Information
None known.
* * * Section 10 - Chemical Stability & Reactivity Information * * *
Chemical Stability
Stable.
Chemical Stability: Conditions to Avoid
Keep away from heat and incompatible materials.
Incompatibility
Avoid contact with strong oxidizers, strong acids, and halogens.
Hazardous Decomposition
Carbon dioxide, carbon monoxide, various hydrocarbon fragments, phosphorus oxide, and possibly some carbon-containing
fragments of the polymer coating.
Possibility of Hazardous Reactions
Will not occur.
* * * Section 11 - Toxicological Information * * *
Acute Dose Effects
A: General Product Information
The product contains a thin outer coating of colored ink in a urethane acrylate polymer. Under normal conditions of use the
coating is inert. Dusts may cause mechanical irritation to eyes and skin. Ingestion may cause transient irritation of throat,
stomach and gastrointestinal tract. Inhalation may cause coughing, nose and throat irritation, and sneezing. Higher exposures
may cause difficulty breathing, congestion, and chest tightness.
B: Component Analysis - LD50/LC50
Pentaerythritol Triacrylate (3524-68-3)
Oral LD50 Rat: 2460 µL/kg; Dermal LD50 Rabbit: 4 mL/kg
Epidemiology
No information available.
Carcinogenicity
A: General Product Information
No additional information.
B: Component Carcinogenicity
None of this product's components are listed by ACGIH, IARC, OSHA, NIOSH, or NTP
Mutagenicity
No information available.
Teratogenicity
No information available.
Neurological Effects
No additional information.
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Page 4 of 6 Issue Date: 03/19/08 Revision: 8.0002 Print Date: 3/19/2008
Material Safety Data Sheet
Material Name: Optical Fiber with colored coating ID: C-089
Other Toxicological Information
Under normal conditions of use for this product, the likelihood of inhaling or ingesting amounts necessary for adverse effects
to occur is very small.
* * * Section 12 - Ecological Information * * *
Ecotoxicity
A: General Product Information
No information available for product.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
No ecotoxicity data are available for this product's components.
Environmental Fate
No information available for product.
* * * Section 13 - Disposal Considerations * * *
US EPA Waste Number & Descriptions
A: General Product Information
You must test your waste using methods described in 40 CFR Part 261 to determine if it meets applicable definitions of
hazardous wastes.
B: Component Waste Numbers
No EPA Waste Numbers are applicable for this product's components.
Disposal Instructions
Waste must be handled in accordance with all applicable regulations. Purchaser is advised to review regulations referenced
for applicability as determined by purchaser's use of the product. Glass products may be recycled.
See Section 7 for Handling Procedures. See Section 8 for Personal Protective Equipment recommendations.
* * * Section 14 - Transportation Information * * *
International Transportation Regulations
This product is not regulated as a hazardous material by the United States DOT or Canadian TDG.
* * * Section 15 - Regulatory Information * * *
US Federal Regulations
A: General Product Information
No additional information.
B: Component Analysis
None of this product's components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313 (40
CFR 372.65), or CERCLA (40 CFR 302.4).
State Regulations
A: General Product Information
Other state regulations may apply. Check individual state requirements.
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component CAS CA MA MN NJ PA RI
Glass, oxide, chemicals (Âąrelated to Nuisance particulates) 65997-17-3 No No Yes No No YesÂą
Pentaerythritol Triacrylate 3524-68-3 No No Yes No No No
Component Analysis - WHMIS IDL
No components are listed in the WHMIS IDL.
Additional Regulatory Information
A: General Product Information
All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory requirements.
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Page 5 of 6 Issue Date: 03/19/08 Revision: 8.0002 Print Date: 3/19/2008
Material Safety Data Sheet
Material Name: Optical Fiber with colored coating ID: C-089
B: Component Analysis - Inventory
Component CAS # TSCA DSL EINECS
Glass, oxide, chemicals 65997-17-3 Yes Yes Yes
Pentaerythritol Triacrylate 3524-68-3 Yes Yes Yes
* * * Section 16 - Other Information * * *
Other Information
Reasonable care has been taken in the preparation of this information, but Corning makes no warranty of merchantability or
any other warranty, expressed or implied, with respect to this information. Corning makes no representations and assumes no
liability for any direct, incidental or consequential damages resulting from its use.
MSDS History
Revision 8.0002: Name update: 03/19/08.
Revision 8.0001: Phone number, administrative changes: 12/7/07
Revision 8.0000: Regulatory update, product names updated: 5/26/2006
Revision 7.0000: Regulatory Update/Converted to ANSI Z400.1-2004: 9/26/2005
Revision 6.0000: Administrative update: 6/1/2004.
Revision 5.0000: consolidation with related optical fiber MSDS sheets. Sections 1,2,5,6,7,8,10,11,15 revised 1/2/2004.
Revision 4.0000: Regulatory/reformulation revision: 8/27/2002.
Revision 3.0000: Regulatory Update. 3/2/1999.
Revision 2.0000: 9/26/1998 Changes. Regulatory and literature review.
Previous issue 3/14/1995.
Key/Legend
ACGIH = American Conference of Governmental Industrial Hygienists. CERCLA = Comprehensive Environmental
Response, Compensation and Liability Act. CFR = Code of Federal Regulations. DSL = Canadian Domestic Substance List.
EINECS = European Inventory of New and Existing Chemical Substances. EPA = Environmental Protection Agency.
HEPA = High Efficiency Particulate Air. HMIS = Hazardous Material Identification System. IARC = International Agency
for Research on Cancer. NFPA = National Fire Protection Association. NIOSH = National Institute of Occupational Safety
and Health. NJTSR = New Jersey Trade Secret Registry. NTP = National Toxicology Program. OSHA = Occupational
Safety and Health Administration. NA = Not available or Not Applicable. SARA = Superfund Amendments and
Reauthorization Act. TLV = Threshold Limit Value. TSCA = Toxic Substance Control Act. WHMIS = Workplace
Hazardous Materials Information System.
NOTE: Corning is a registered trademark of Corning Incorporated, Corning, N.Y.
End of Sheet C-089
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