MATERIAL SAFETY DATA SHEET
SECTION I 鈥? Product/Company Information
CALIBRA庐 Esthetic Resin Cement鈥揃ase Paste
1.1 Product Trade Name:
1.2 Part (Item) Number: 607058 鈥? 607080 All Package Configurations
1.3 Division Name: DENTSPLY Caulk
1.4 Address: 38 West Clarke Avenue
City State Zip: Milford DE 19963-0359
Internet Address: http://www.caulk.com
1.5 Emergency Telephone Number: (800) 424-9300 (Chemtrec)
1.6 Telephone Number for Information:(302) 422-4511 (8:00 AM 鈥? 4:30 PM Eastern Time)
1.7 Date Prepared: 3/8/99 Date Revised: 2/19/02
SECTION II 鈥? Hazardous Ingredients/Identity Information
Hazardous Components OSHA PEL ACGIH TLV CAS # Percent
Barium boron fluoroalumino silicate glass N. E. N. E. 65997-18-4 > than 60 %
Bis-GMA resin N. E. N. E. 1565-94-2 < than 15 %
Polymerizable dimethacrylate resin N. E. N. E. 109-16-0 < than 10 %
Polymerizable dimethacrylate resin N. E. N. E. 24448-20-2 < than 15 %
3 mg/m3 3 mg/m3
Hydrophobic Amorphous Fumed Silica 67762-90-7 < than 5 %
10 mg/m3 10 mg/m3
Titanium Dioxide 13463-67-7 < than 5 %
Other Information: Other colorants are inorganic iron oxides.
SECTION III 鈥? Physical/Chemical Characteristics
3.6 Specific Gravity: Approximately 1.8 g/cm2
3.1 Boiling point: N. A.
3.2 Vapor pressure: N. A. 3.7 Melting Point: N. E.
3.3 Vapor density: N. A. 3.8 Evaporation rate: N. A.
3.4 Solubility in water: Not Soluble
3.5 Appearance and odor: Creamy pastes with sweet acrylic ester odor. Multiple shades.
SECTION IV - Fire and Explosion Hazard Data
4.1 Flash point (method used): N. A.
4.2 Flammability (explosive limits): LEL: N. A. UEL: N. A.
4.3 Extinguishing media: Water spray, carbon dioxide, foam, or dry chemical.
4.4 Special fire fighting procedures: Firefighters should wear full protective clothing including a self contain
breathing apparatus.
4.5 Unusual fire and explosion hazards: During a fire, irritating gas may be present from the decomposition of the
dimethacrylate resins.
SECTION V 鈥? Reactivity Data
5.1 Stability: Unstable: Stable: X
5.2 Conditions to avoid (stability): Bright visible lights on paste, elevated temperatures above 50掳C (122掳F).
5.3 Incompatibility (materials to avoid): Strong oxidizing materials and peroxides.
5.4 Hazardous decomposition or byproducts: Irritating gases, CO and CO2
5.5 Hazardous polymerization: May occur: Will not occur: X
5.6 Conditions to avoid (polymerization): Elevated temperatures and oxidizing materials. Product is sensitive to
visible light and will harden if exposed to visible light. Heat greater
than 50掳C.
SECTION VI - Health Hazard Data
6.1 Route(s) of entry: Inhalation?: No Skin?: Yes Ingestion?: Possible
6.2 Health hazards (acute and chronic):Avoid contact with eyes. May cause irritation. Eyes: Material can cause
irritation. Skin: Material may be an irritant. Susceptible persons with known allergies to methacrylates and acrylates
may develop allergic response.Ingestion: Material is probably not harmful if swallowed.
6.3 Carcinogenicity: NTP?: Not listed IARC monographs?: Not listed OSHA regulated? : No
All components of this product are in compliance with the inventory listing Requirements of the U. S. Toxic
Substances Control Act (TSCA) Chemical Substance Inventory.
6.4 Signs and symptoms of exposure: Dermal redness or irritation. Eye contact: Irritation and possible corneal
damage. Skin contact: Irritation or possible allergic response. Severe allergic response may result in breathing
difficulties.
6.5 Medical conditions generally aggravated by exposure: Open sores and wounds of the skin. Individuals with known
sensitivity to methacrylates, acrylates.
6.6 Emergency first aid procedures: Eyes: In case of eye contact, flush with flowing water for 15 minutes. Get prompt
medical attention. Skin: Wash skin with soap and water. If irritation persists, call physician. Ingestion: If swallowed
give 2 glasses of water to drink. See a physician.
SECTION VII - Precautions for Safe Handling and Use
7.1 Steps to be taken in case material is released or spilled: Scoop up bulk material and place in a labeled plastic or
metal container. Avoid gross skin contact to minimize the possibility of contact dermatitis to susceptible persons.
7.2 Waste disposal methods: Dispose of material as solid waste in a closed container. Dispose of in accordance with
Federal, State and Local regulations.
7.3 Precautions to be taken in handling and storage: Store in a dry area, away from direct sunlight. Maximum storage
temperature is 50掳C(122掳F). Normal storage is at room temperature. Store away from food and beverages.
7.4 Other precautions: Avoid contact with skin. Observe normal warehouse handling procedures. Handling of this
product should be by trained dental healthcare professionals only.
SECTION VIII - Control Measures / Personal Protection
8.1 Respiratory protection: None required during normal use of this product.
8.2 Ventilation: None required during normal intended use of this product.
8.3 Protective gloves: Latex or vinyl gloves.
8.4 Eye protection: Protective goggles.
8.5 Other protective clothing or equipment: Chemically resistant apron or other impervious clothing.
8.6 Work/Hygienic practices: Observe normal care when working with chemicals. Avoid eye and skin
contact, inhalation and ingestion. Do not eat, drink or smoke when using.
NFPA HAZARD
CLASSIFICATIONS
Health 0 NFPA 鈥? National Fire Protection Association
Flammability 1 N.A. - Not Applicable
Reactivity 0 N.E. - Not Established
Specific Hazard N. A.
MATERIAL SAFETY DATA SHEET
SECTION I 鈥? Product/Company Information
CALIBRA庐 Esthetic Resin Cement鈥揅atalyst Paste
1.1 Product Trade Name:
1.2 Part (Item) Number: 607058 鈥? 607080 All Package Configurations
1.3 Division Name: DENTSPLY Caulk
1.4 Address: 38 West Clarke Avenue
City State Zip: Milford DE 19963-0359
Internet Address: http://www.caulk.com
1.5 Emergency Telephone Number: (800) 424-9300 (Chemtrec)
1.6 Telephone Number for Information:(302) 422-4511 (8:00 AM 鈥? 4:30 PM Eastern Time)
1.7 Date Prepared: 3/8/99 Date Revised: 2/19/02
SECTION II - Hazardous Ingredients/Identity Information
Hazardous Components OSHA PEL ACGIH TLV CAS # Percent
Barium boron fluoroalumino silicate glass N. E. N. E. 65997-18-4 > than 60 %
Bis-GMA resin N. E. N. E. 1565-94-2 < than 15 %
Polymerizable dimethacrylate resin N. E. N. E. 109-16-0 < than 10 %
Polymerizable dimethacrylate resin N. E. N. E. 24448-20-2 < than 15 %
3 mg/m3 3 mg/m3
Hydrophobic Amorphous Fumed Silica 67762-90-7 < than 5 %
10 mg/m3 10 mg/m3
Titanium Dioxide 13463-67-7 < than 5 %
5 mg/m3 5 mg/m3
Benzoyl Peroxide 94-36-0 < than 2 %
SECTION III - Physical/Chemical Characteristics
3.6 Specific Gravity: Approximately 1.8 g/cm2
3.1 Boiling point: N. A.
3.2 Vapor pressure: N. A. 3.7 Melting Point: N. E.
3.3 Vapor density: N. A. 3.8 Evaporation rate: N. A.
3.4 Solubility in water: Not Soluble
3.5 Appearance and odor: Creamy off white paste with sweet acrylic ester odor.
SECTION IV - Fire and Explosion Hazard Data
4.1 Flash point (method used): N. A.
4.2 Flammability (explosive limits): LEL: N. A. UEL: N. A.
4.3 Extinguishing media: Water spray, carbon dioxide, foam, or dry chemical.
4.4 Special fire fighting procedures: Firefighters should wear full protective clothing including a self contain
breathing apparatus.
4.5 Unusual fire and explosion hazards: During a fire, irritating gas may be present from the decomposition
of the dimethacrylate resins.
SECTION V 鈥? Reactivity Data
5.1 Stability: Unstable: Stable: X
5.2 Conditions to avoid (stability): Elevated temperatures above 50掳C (122掳F).
5.3 Incompatibility (materials to avoid): Amines
5.4 Hazardous decomposition or byproducts: Irritating gases, CO and CO2
5.5 Hazardous polymerization: May occur: Will not occur: X
5.6 Conditions to avoid (polymerization): Elevated temperatures and amines. Heat greater than 50掳C.
SECTION VI - Health Hazard Data
6.1 Route(s) of entry: Inhalation?: No Skin?: Yes Ingestion?: Possible
6.2 Health hazards (acute and chronic):Avoid contact with eyes. May cause irritation. Eyes: Material can cause
irritation. Skin: Material may be an irritant. Susceptible persons with known allergies to methacrylates and acrylates
may develop allergic response.Ingestion: Material is probably not harmful if swallowed.
6.3 Carcinogenicity: NTP?: Not listed IARC monographs?: Not listed OSHA regulated? : No
All components of this product are in compliance with the inventory listing Requirements of the U. S. Toxic
Substances Control Act (TSCA) Chemical Substance Inventory.
6.4 Signs and symptoms of exposure: Dermal redness or irritation. Eye contact: Irritation and possible corneal
damage. Skin contact: Irritation or possible allergic response. Severe allergic response may result in breathing
difficulties.
6.5 Medical conditions generally aggravated by exposure: Open sores and wounds of the skin. Individuals with known
sensitivity to methacrylates, acrylates.
6.6 Emergency first aid procedures: Eyes: In case of eye contact, flush with flowing water for 15 minutes. Get prompt
medical attention. Skin: Wash skin with soap and water. If irritation persists, call physician. Ingestion: If swallowed
give 2 glasses of water to drink. See a physician.
SECTION VII - Precautions for Safe Handling and Use
7.1 Steps to be taken in case material is released or spilled: Scoop up bulk material and place in a labeled plastic or
metal container. Avoid gross skin contact to minimize the possibility of contact dermatitis to susceptible persons.
7.2 Waste disposal methods: Dispose of material as solid waste in a closed container. Dispose of in accordance with
Federal, State and Local regulations.
7.3 Precautions to be taken in handling and storage: Store in a dry area, away from direct sunlight. Maximum storage
temperature is 50掳C(122掳F). Normal storage is at room temperature. Store away from food and beverages.
7.4 Other precautions: Avoid contact with skin. Observe normal warehouse handling procedures. Handling of this
product should be by trained dental healthcare professionals only.
SECTION VIII - Control Measures / Personal Protection
8.1 Respiratory protection: None required during normal use of this product.
8.2 Ventilation: None required during normal intended use of this product.
8.3 Protective gloves: Latex or vinyl gloves.
8.4 Eye protection: Protective goggles.
8.5 Other protective clothing or equipment: Chemically resistant apron or other impervious clothing.
8.6 Work/Hygienic practices: Observe normal care when working with chemicals. Avoid eye and skin
contact, inhalation and ingestion. Do not eat, drink or smoke when using.
NFPA HAZARD
CLASSIFICATIONS
Health 0 NFPA 鈥? National Fire Protection Association
Flammability 1 N.A. - Not Applicable
Reactivity 0 N.E. - Not Established
Specific Hazard N. A.
507895 (R-02/19/02)
MATERIAL SAFETY DATA SHEET
SECTION I 鈥? Product/Company Information
CALIBRA庐 Silane Coupling Agent
1.1 Product Trade Name:
1.2 Part (Item) Number: 607060 鈥? 607080 All Package Configurations
1.3 Division Name: DENTSPLY Caulk
1.4 Address: 38 West Clarke Avenue
City State Zip: Milford DE 19963-0359
Internet Address: http://www.caulk.com
1.5 Emergency Telephone Number: (800) 424-9300 (Chemtrec)
1.6 Telephone Number for Information: (302) 422-4511 (8:00 AM 鈥? 4:30 PM Eastern Time)
1.7 Date Prepared: 3/4/99 Date Revised: 02/19/02
SECTION II - Hazardous Ingredients/Identity Information
Hazardous Components OSHA PEL ACGIH TLV CAS # Percent
Ethyl Alcohol 1000 ppm 1000 ppm 64-17-5 92.6 %
Acetone 500 ppm 500 ppm 67-64-1 7.4 %
Benzene 0.5 ppm 0.5 ppm 71-43-2 < than 0.15 ppm
SECTION III 鈥? Physical/Chemical Characteristics
3.6 Specific Gravity: 0.8 g/cm2
3.1 Boiling point: 78掳C(173掳F)
3.2 Vapor pressure: 44.6 3.7 Melting Point: -114掳C(-173掳F)
3.3 Vapor density: 1.59 3.8 Evaporation rate: N. E.
3.4 Solubility in water: Completely Soluble.
3.5 Appearance and odor:Clear liquid with characteristic alcohol odor.
SECTION IV - Fire and Explosion Hazard Data
4.1 Flash point (method used): 6掳C(43掳F) Tag Closed Cup
4.2 Autoignition Temperature: 423掳C(793掳F)
4.3 Flammability (explosive limits): LEL: 3.3 UEL: 19
4.4 Extinguishing media: Use dry chemical, alcohol foam, or carbon dioxide. Water may be ineffective,
but should be used to keep fire-exposed containers cool.
4.5 Special fire fighting procedures: If a leak or spill has not ignited, use water spray to disperse vapors and protect
personnel attempting to stop a leak. Water spray may be used to flush spills
away from exposures and to dilute spills to nonflammable mixtures.
4.6 Unusual fire and explosion hazards: Firefighters should wear full protective clothing including a self-contained
breathing apparatus in the positive pressure mode with a full facepiece when
there is a possibility of exposure to smoke, fumes or hazardous decomposition
products.
4.7 Hazardous Combustion Products: Incomplete combustion may produce carbon monoxide and/or carbon dioxide.
SECTION V 鈥? Reactivity Data
5.1 Stability: Unstable: Stable: X
5.2 Conditions to avoid (stability): Heat, flame, sparks, elevated temperatures above 50掳C (122掳F).
5.3 Incompatibility (materials to avoid): Avoid acetyl chloride and strong oxidizing materials, which may react
violently.
5.4 Hazardous decomposition or byproducts: Incomplete combustion may produce carbon monoxide or carbon dioxide.
5.5 Hazardous polymerization: May occur: Will not occur: X
5.6 Conditions to avoid: Elevated temperatures and oxidizing materials.
SECTION VI - Health Hazard Data
6.1 Route(s) of entry: Inhalation?: Possible Skin?: Yes Ingestion?: Possible
6.2 Health hazards (acute and chronic):
Summary of Acute Hazards: Minimal health hazard in normal use and in the quantities present in this
product. For larger quantities and with prolonged exposure, ethyl alcohol is
considered a moderate health hazard.
Summary of Chronic Hazards: Not a chronic hazard under the normal conditions of use. However, if
ingested in large quantities for a prolonged period of time, may be a
carcinogenic or a cause of Fetal Alcohol syndrome.
6.3 Carcinogenicity: NTP?: Not listed IARC monographs?: Not listed OSHA regulated? : No
All components of this product are in compliance with the inventory listing
Requirements of the U. S. Toxic Substances Control Act (TSCA) Chemical
Substance Inventory. Not a carcinogen under normal conditions of use. The
IARC has reported a relationship between prolonged drinking of significant
quantities of alcoholic beverages and cancer of the oral cavity, pharynx,
esophagus and liver.
6.4 Teratogenicity, Mutagenicity, Reproductive Toxicity: Ingestion of alcohol by pregnant women is associated with
Fetal Reproductive Toxicity.
6.5 Signs and symptoms of exposure: Inhalation: None in normal conditions of use. Exposure to over 1000 ppm may
cause headache, drowsiness and lassitude, loss of appetite, inability to
concentrate, and irritation of throat. Eye Contact: Liquid or vapor may cause
irritation. Skin Absorption: None in normal conditions of use. However, for
large quantities and prolonged contact, similar symptoms to inhalation/
ingestion may occur. Skin Contact: May cause irritation and defatting of skin
on prolonged contact. Ingestion: None in small quantities of normal
conditions of use. For large quantities, may cause depression of the central
nervous system, nausea, vomiting, diarrhea.
6.6 Emergency first aid procedures: Eyes: In case of eye contact, flush immediately with flowing water for at least 15
minutes. Get prompt medical attention. Skin: Immediately flush affected area
with plenty of cool water. Wash skin with soap and water. If irritation persists,
call physician. Ingestion: For large quantities: if victim is conscious and able
to swallow, have victim drink water or milk to dilute. Never give anything by
mouth to an unconscious or convulsing person. Call a physician or Poison
Control Center immediately. Induce vomiting only on their advice.
SECTION VII 鈥? Precautions for Safe Handling and Use
7.1 Steps to be taken in case material is released or spilled: For small quantities (as in this product): Wear gloves and
safety glasses. Pick up with absorbent material, such as paper or cloth. Rinse
area of spill with water. Place all material in closed container away from heat,
sparks, sun and oxidizers.
7.2 Waste disposal methods: Dispose of in accordance with Federal, State and Local environmental control regulations.
7.3 Precautions to be taken in handling and storage: For small quantities (as in this product): Keep tightly closed, in a
well ventilated area, away from heat, sparks, direct sunlight, and oxidizing
agents. Protect container against physical damage. Take these same
precautions when container is empty, as residual product is hazardous. Store
away from food and beverages. Store away from extreme heat.
7.4 Other precautions: Avoid contact with skin. Observe normal warehouse handling procedures.
Handling of this product should be by trained dental healthcare professionals
only.
SECTION VIII 鈥? Control Measures / Personal Protection
8.1 Respiratory protection: None required during normal use of this product.
8.2 Ventilation: None required during normal intended use of this product. However for large quantities and prolonged
exposure, methods such as enclosure, local ventilation and dilution are recommended to reduce concentration below TLV.
8.3 Protective gloves: Chemically impervious gloves are recommended when skin contact is possible.
8.4 Eye protection: Safety glasses are recommended when no eye contact is anticipated. Chemical safety goggles should be
worn whenever there is a possibility of splashing or other contact with eyes.
8.5 Other protective clothing or equipment: Chemically resistant apron or other impervious clothing.
8.6 Work/Hygienic practices: Observe normal care when working with chemicals. Wash hands after use. Avoid eye and
skin contact, inhalation and ingestion. Do not eat, drink or smoke when using.
NFPA HAZARD
CLASSIFICATIONS
Health 0 NFPA 鈥? National Fire Protection Association
Flammability 3 N.A. - Not Applicable
Reactivity 0 N.E. - Not Established
Specific Hazard N. A.
507891 (R-02/19/02)
MATERIAL SAFETY DATA SHEET
SECTION I 鈥? Product/Company Identification
CALIBRA庐 TRY鈥揑N Pastes
1.1 Product Trade Name:
1.2 Part (Item) Number: 607058 - 607080 All Package Configurations
1.3 Division Name: DENTSPLY Caulk
1.4 Address: 38 West Clarke Avenue
City State Zip: Milford DE 19963-0359
Internet Address: http://www.caulk.com
1.5 Emergency Telephone Number: (800) 424-9300 (Chemtrec)
1.6 Telephone Number for Information: (302) 422-4511 (8:00 AM 鈥? 4:30 PM Eastern Time)
1.7 Date Prepared: 3/8/99 Date Revised: 2/19/02
SECTION II 鈥? Hazardous Ingredients/Identity Information
Hazardous Components OSHA PEL ACGIH TLV CAS # Percent
10 mg/m3 10 mg/m3
Glycerine 56-81-5 > than 70 %
10 mg/m3 10 mg/m3
Titanium Dioxide 13463-67-7 < than 2 %
2 mg/m3 2 mg/m3
Amorphous Fumed Silica 7631-86-9 < than 20 %
SECTION III 鈥? Physical/Chemical Characteristics
3.1 Boiling point: >290掳C(554掳F) 3.5 Appearance and odor: Multi-colored pastes with mild odor.
1.4 g/cm3
3.2 Vapor pressure: N. E. 3.6 Specific Gravity:
3.3 Vapor density: 3.1 3.7 Melting Point: N. E.
3.4 Solubility in water: Partially Soluble. 3.8 Evaporation rate: N. E.
SECTION IV 鈥? Fire and Explosion Hazard Data
4.1 Flash point (method used): 199掳C (390掳F) PMCC
4.2 Flammability (explosive limits): LEL: N. E. UEL: N. E.
4.3 Extinguishing media: Dry chemical, carbon dioxide water-spray.
4.4 Special fire fighting procedures: Fire fighter should wear full protective clothing including a self-contained
breathing apparatus.
4.5 Unusual fire and explosion hazards: During a fire, irritating gas may be present from the decomposition of the
glycerine.
SECTION V 鈥? Reactivity Data
5.1 Stability: Unstable: Stable: X
5.2 Conditions to avoid (stability): Heat greater than 50掳C/122掳F.
5.3 Incompatibility (materials to avoid): Avoid strong oxidizing agents, such as sodium hypochlorite,
hypochlorous acid.
5.4 Hazardous decomposition or byproducts: May liberate acrolein, carbon monoxide or carbon dioxide.
5.5 Hazardous polymerization: May occur: Will not occur: X
5.6 Conditions to avoid (polymerization): None.
SECTION VI - Health Hazard Data
6.1 Route(s) of entry: Inhalation?: No Skin?: Yes Ingestion?: No
6.2 Health hazards (acute and chronic):Eyes: Contact may cause irritation. Skin: Contact may cause irritation. Ingestion:
Material is probably not harmful if swallowed. Inhalation: None currently
known.
6.3 Carcinogenicity: NTP?: Not listed IARC monographs?: Not listed OSHA Regulated? : No
All components of this product are in compliance with the inventory listing
Requirements of the U. S. Toxic Substances Control Act (TSCA) Chemical
Substance Inventory.
6.4 Signs and symptoms of exposure: Eye contact: Irritation and possible corneal damage. Skin contact: Possible
irritation. Inhalation: None currently known.
6.5 Medical conditions generally
aggravated by exposure: Open sores or wounds of the skin. Skin contact may aggravate an existing
dermatitis and/or cause an allergic skin reaction is sensitized individuals.
6.6 Emergency first aid procedures: Eyes: In case of eye contact, flush with flowing water for 15 minutes, including
under the eyelids and get medical attention if irritation persists. Skin: Flush with
flowing water then wash area with mild soap and water. Ingestion: Rinse mouth
with water, do not induce vomiting. If conscious, give lots of water or milk. Get
immediate medical attention.
SECTION VII 鈥? Precautions for Safe Handling and Use
7.1 Steps to be taken in case material
is released or spilled: Scoop up bulk material and place in a labeled plastic or metal container.
7.2 Waste disposal methods: Dispose of material as solid waste in a closed container. Dispose of in accordance with
Federal, State and Local regulations.
7.3 Precautions to be taken in
handling and storage:Store in a dry area, away from direct sunlight. Maximum storage temperature is 50掳C
(122掳F). Normal storage is at room temperature. Store away from food and beverages.
7.4 Other precautions: Observe normal warehouse handling procedures. Store at ambient temperature out of
direct sunlight and heat. Keep away from food and beverages. Keep container closed to
prevent contamination. Handling of this product should be by trained dental healthcare
professionals only.
SECTION VIII 鈥? Control Measures / Personal Protection
8.1 Respiratory protection: None required during normal use of this product. Local ventilation if in
large quantities.
8.2 Ventilation: None required during normal use of this product.
8.3 Protective gloves: Rubber gloves.
8.4 Eye protection: Safety glasses.
8.5 Other protective clothing or equipment: Rubber apron.
8.6 Work/Hygienic practices: Observe normal care when working with chemicals. Avoid eye and skin
contact, inhalation and ingestion. Do not eat, drink or smoke when using
NFPA HAZARD
CLASSIFICATIONS
Health 0 NFPA - National Fire Protection Association
Flammability 0 N.A. 鈥? Not Applicable
Reactivity 0 N.E. 鈥? Not Established
Specific Hazard N. A.
507893 (R-02/19/02)
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