DENTSPLY/International
DENTSPLY/Caulk
593899
Material Safety Data Sheet
1. Product and Company Identification
Product Name MSDS Code Number
鈩?
XP BOND Universal Total-Etch Adhesive 593899
Trade Name & Synonyms Date of Last Revision
鈩?
XP BOND Universal Total-Etch Adhesive 02/23/07
Chemical Name Manufacturer
Dimethacrylate Resins DENTSPLY/Caulk
C.A.S. Number Address
N. A. 38 West Clarke Avenue
Milford DE 19963-1805
http://www.caulk.com
Grades or Minor Variant Identities Information Telephone Number
(302) 422-4511 (8:00 AM 鈥? 4:30 PM Eastern Time)
N. A.
Product Use (for Canada) Emergency Telephone Number
(302) 422-4511 (8:00 AM 鈥? 4:30 PM Eastern Time)
Dental Adhesive
2. Composition Of Ingredients
Hazardous Components C.A.S. Number Exposure Limits %
Hydroxyethylmethacrylate 868-77-9 N. A. < 40
Butyl Alcohol 75-65-0 100 ppm < 30
Dipentaerythritol pentaacrylate phosphate 87699-25-0 N. A. < 20
Carboxylic acid modified dimethacrylate 144144-04-7 N. A. < 10
Urethane Dimethacrylate Resin 105883-40-7 N. A. < 10
Triethyleneglycol dimethacrylate 109-18-0 N. A. < 10
3. Hazard Identification
Emergency Overview: Material is flammable. Material is irritating to eyes, respiratory system and skin.
Routes of Single, Repeated, or Severity (Mild, Acute and Chronic Health Effect(s) Target Organ(s)
Exposure Signs and Symptoms Lifetime Exposure Moderate, Severe)
Eye Material can cause irritation. Single Moderate Irritation and possible corneal damage Yes
Skin Material may be an irritant and may Single & Repeated Moderate Irritation or possible allergic response. Yes
be absorbed through the skin. Severe allergic response may result
in breathing difficulties.
Inhalation Inhalation of high concentrations Repeated Moderate Chronic inhalation may cause effects Yes
may cause central nervous system similar to those of acute inhalation. Causes
effects characterized by nausea, respiratory tract irritation. May cause
headache, dizziness, motor incoordination and speech
unconsciousness and coma. abnormalities.
Ingestion May cause irritation of the digestive Single & Repeated Mild Not Applicable No
tract.
Other Central Not Applicable Not Applicable Not Applicable Not Applicable Yes
nervous system
Medical Conditions Aggravated by Exposure Open sores and wounds of the skin. Individuals with known sensitivity to methacrylates, acrylates, or urethane
dimethacrylate resin used in Dental restorative products.
Carcinogenicity NTP?: Not listed IARC monographs?: Not listed OSHA regulated?: No. All components of this product are in
compliance with the inventory listing Requirements of the U. S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
Potential Environmental Effects Do not allow to enter sewers/ surface or ground water.
NFPA Hazard Classification Ratings (Scale 0-4) Health =2, Fire =3, Reactivity=1, Specific Hazard = None
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4. First Aid Measures
Routes of Exposure First Aid Instructions Immediate Medical Attention Delayed Effects
Eye Rinse opened eye for several minutes under running water. If Not Applicable Not Applicable
symptoms persist consult physician
Skin Immediately wash with soap and water and rinse thoroughly Not Applicable Not Applicable
Inhalation Supply fresh air, if symptoms persist consult physician Not Applicable Not Applicable
Ingestion If symptoms persist consult physician Not Applicable Not Applicable
Other Not Applicable Not Applicable Not Applicable
Note to Physicians (Treating, Testing and Monitoring): Treat symptomatically.
5. Fire and Explosion Data
Flashpoint Method: 19掳C (66掳F) Closed Cup Flammable (Explosive) Limits in Air Autoignition Temperature: Not Other: Not
LEL: 2.4 vol. % UEL: 8 vol. % Applicable Applicable
Flame Propagation or Burning Rate (for Properties Contributing to Fire Intensity: Not Applicable Flammability Classification: 3
Solids): Not Applicable
Extinguishing Media: CO2, sand or extinguishing powder. Extinguishing Media to Avoid: Do not use water or water with full jet.
Protection and Procedures for Firefighters: Firefighters should wear self-contained respiratory protective devices.
Unusual Fire and Explosion Hazards: Formation of toxic gases is possible during heating or in case of fire.
6. Accidental Release Measures
Containment Techniques: Wear protective clothing. Absorb with liquid binding material (sand, vermiculite, diatomite, acid binders, universal binders or
sawdust). Scoop up bulk material and place in a labeled plastic or metal container.
Spill/Leak Clean-up Procedures and Equipment: Wear protective clothing. Absorb with liquid binding material (sand, vermiculite, diatomite, acid binders,
universal binders or sawdust). Scoop up bulk material and place in a labeled plastic or metal container. Avoid gross skin contact to minimize the possibility
of contact dermatitis to susceptible persons. Ensure adequate ventilation.
Evacuation Procedures: Not Applicable Special Instructions: Not Applicable Reporting Requirements: Not Applicable
7. Handling and Storage
Handling Practices and Warnings: Handling of this product should be by trained dental healthcare professionals only. Observe normal care for working with
chemicals.
Storage Practices and Warnings: Store only in the original package. Keep package tightly sealed. Protect from exposure to direct light. Store away from food
and beverages.
8. Exposure Control / Personal Protection
Ventilation: None required during normal intended use of this product Other Engineering Controls: Not Applicable.
PPE for Emergencies
Routes of Entry Personal Protective Equipment (PPE) for Normal Use
Not Applicable
Eye/Face Safety Glasses
Not Applicable
Skin The glove material has to be impermeable and resistant to the product.
Not Applicable
Inhalation Not Required for normal volumes used in Dental office.
Not Applicable
Body Protection Protective work clothing.
General Hygiene Considerations and Work Practices: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated
clothing. Wash hands before breaks and at end of work. Avoid contact with the eyes and skin.
Protective Measures During Repair and Maintenance of Contaminated Equipment: Not Applicable
Other Protective Measures and Equipment: Not Applicable
9. Physical and Chemical Characteristics
Appearance: Light yellow liquid. Odor: Sweet acrylic ester odor.
Normal Physical State: Liquid Boiling Point: Not Established.
Specific Gravity: ~0.9 g/cm3 Solubility in Water: Partially pH: 2.5
Vapor Pressure (mm Hg): Not Applicable Vapor Density (AIR=1) Not Applicable Evaporation Rate (Butyl Acetate =1) Not Applicable
Other: Not Applicable
10. Stability and Reactivity Data
Incompatibility (Materials to Avoid): Visible light, high temperatures, strong acids, strong oxidizing agents. Keep away from sparks and sources of ignition.
Hazardous Products Produced During Decomposition: Methacrylates, acrylates, carbon dioxide, carbon monoxide, and irritating gases.
Hazardous Polymerization: May Occur May Not Occur Conditions to Avoid: High Temperatures, ignition sources.
Stability? Stable Unstable Conditions to Avoid: High Temperatures, ignition sources.
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Material Safety Data Sheet
11.Toxicological Information
Toxicity Data, Epidemiology Studies, Carcinogenicity, Neurological Effects, Genetic Effects, Reproductive Effects, or Structure Activity Data:
Product is an irritant to the skin and mucous membranes. The unpolymerized product may be an irritant to the skin in susceptible persons. On the eye the
product has an irritating effect. Sensitization: Repeated or prolonged contact with the unpolymerized material may cause sensitization for persons allergic to
acrylates and methacrylates. This product shows the following dangers according to internally approved calculation methods for composite materials:
Irritant. ACGIH: A4- Not classifiable as a Human Carcinogen.
12.Ecological Information
Toxicity Data, Environmental Fate, Physical/Chemical Data, or other Data Supporting Environmental Hazard Statements: Water Hazard class1 (Self-
assessment):
13.Disposal Considerations
Regulations: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Absorb any spilled material with
liquid binding material (sand, vermiculite, diatomite, acid binders, universal binders or sawdust). Scoop up bulk material and place in a labeled plastic or
metal container. Dispose of in accordance with Federal, State and Local regulations.
Properties (Physical/Chemical) Affecting Disposal: Dispose of material as solid waste in a closed container.
RCRA P-Series: None Listed, RCRA U-Series: Waste Number D001 (Ignitable Waste)
14.Transport Information
Regulated for Shipping: Yes Proper Shipping Name: Butyl Alcohol Solution Packing Group: II
Do Changes in Quantities, packaging, or shipment method change product classification? Yes Hazard Class: 3 UN Identification Number: 1120
Other: Not Applicable
15.Regulatory Information
U.S. Federal Regulations: CERCLA 103 Reportable Quantity: No chemicals have a reportable quantity. Report spills required under federal, state and local
regulations. Many states have more stringent release reporting requirements.
RCRA U-Series Hazardous Waste Code Not Applicable.
Section 313 Toxic Chemicals: This product contains CAS#75-65-0 tert-butyl alcohol, which is subject to Annual Release Reporting Requirements Under
SARA Title III, Section 313 (40 CFR 372).
Section 302 Extremely Hazardous Substances (TPQ): None
EPA Toxic Substances Control Act (TSCA) Status: All of the components of this product are listed on the TSCA inventory.
U.S. State Regulations California Proposition 65: This product does not contain any chemicals, which are on the California Proposition 65 list.
Federal Regulations: The product has been classified and marked in accordance with directives on hazardous materials. Hazard Symbol: Flammable Water
Hazard class1 (Self-assessment): slightly hazardous for water.
International Regulations: Hazard Symbol: Flammable XI F Risk Phrases: R11 Highly Flammable, R36/37/38 Irritating to eyes, respiratory system and skin.
R52/53 Harmful to aquatic organisms may cause long-term adverse effects in the aquatic environment. R66 Repeated exposure may cause dryness or
cracking, R67 Vapors may cause drowsiness and dizziness. Safety Phrases: S16 Keep away from sources of ignition 鈥? No Smoking, S26 In case of contact
with eyes, rinse immediately with plenty of water and seek medical advice, S9 Keep container in a well 鈥搗entilated place.
Other:
16.Other Information
To the best of our knowledge this product does not contain gluten, wheat grains, flaxseed, natural rubber, or natural latex. All components are synthetically
produced, none are derived from animal products.
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