MATERIAL SAFETY DATA SHEET
SECTION I 鈥? Product/Company Identification
FYNAL庐 LIQUID
1.1 Product Trade Name:
Zinc Oxide Eugenol Permanent Cement
1.2 Part (Item) Number: 609001, 609003
1.3 Division Name: DENTSPLY Caulk
1.4 Address: 38 West Clarke Avenue
City State Zip: Milford DE 19963-0359
Internet Address: http://www.caulk.com
1.5 Emergency Telephone Number: (800) 424-9300 (Chemtrec)
1.6 Telephone Number for Information: (302) 422-4511 (8:00 AM 鈥? 4:30 PM Eastern Time)
1.7 Date Prepared: 11/13/98 Date Revised: 11/12/01
SECTION II - Hazardous Ingredients/Identity Information
Hazardous Components OSHA PEL ACGIH TLV CAS # Percent
Eugenol NA NA 99-53-0 greater than99 %
Acetic Acid 10 ppm 10 ppm 64-19-7 less than 1 %
SECTION III - Physical/Chemical Characteristics
254oC/489掳F 1.0 g/cm3
3.1 Boiling point: 3.6 Specific Gravity:
3.2 Vapor pressure: 0.1 mm Hg@ 20掳C 3.7 Melting Point: -9掳C/-16掳F
3.3 Vapor density: N. E. 3.8 Evaporation rate: N. E.
3.4 Solubility in water: Slightly Soluble
3.5 Appearance and odor: Colorless or pale yellow liquid. Odor is oil of cloves.
SECTION IV - Fire and Explosion Hazard Data
4.1 Flash point (method used): Approximately 252掳F closed cup
4.2 Flammability (explosive limits): LEL: N.E. UEL: N.E.
4.3 Extinguishing media: Carbon dioxide, dry chemical or foam extinguishers.
4.4 Special fire fighting procedures: Fire fighters should wear full protective clothing including self-contained breathing
apparatus. Cool containers exposed to flame with water.
4.5 Unusual fire and explosion hazards: None, Material is not pyrophoric, does not react with water, not oxygen donor,
material is shock stable.
SECTION V 鈥? Reactivity Data
5.1 Stability: Unstable: Stable: X
5.2 Conditions to avoid (stability): Excessive heat greater than 37掳C/100掳F.
5.3 Incompatibility (materials to avoid): Keep separated from strong bases, and strong oxidizing agents. Ferric chloride
and potassium permanganate
5.4 Hazardous decomposition or byproducts: Forms carbon monoxide and/or carbon dioxide upon burning.
5.5 Hazardous polymerization: May occur: Will not occur: X
5.6 Conditions to avoid (polymerization): None.
SECTION VI - Health Hazard Data
6.1 Route(s) of entry: Inhalation?: Yes Skin?: Yes Ingestion?: Possible
6.2 Health hazards (acute and chronic):Liquid irritating to skin and eyes. Repeated contact may cause allergic dermatitis.
Repeated daily oral doses of large amounts to rats caused liver damage. The effects in
humans are unknown.
6.3 Carcinogenicity: NTP?: Not listed IARC monographs?: Not listed OSHA Regulated? : No
All components of this product are in compliance with the inventory listing requirements
of the U. S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
6.4 Signs and symptoms of exposure: Product may irritate the eyes and skin. Eye contact: Redness or irritation.
Skin contact: Redness or irritation.
6.5 Medical conditions generally
aggravated by exposure: Persons with known sensitization to eugenol. Open sores or wounds of the skin.
6.6 Emergency first aid procedures: Eyes: In case of eye contact, flush with flowing water for 15 minutes, including under
the eyelids and get medical attention. Skin: Flush with flowing water then wash area
with mild soap and water. Ingestion: Consult a physician.
SECTION VII 鈥? Precautions for Safe Handling and Use
7.1 Steps to be taken in case material is
released or spilled: Absorb liquid with inert materials (sand, soda ash, vermiculite) and transfer to an appropriate closed
container for disposal.
7.2 Waste disposal methods: Dispose of in accordance with Federal, State and Local regulations.
7.3 Precautions to be taken in handling
and storage: Always close container immediately after use to prevent water absorption and contamination. Store at
ambient temperature out of direct sunlight and heat. Do not store above 77掳F (25掳C). Do not expose to
temperatures above 35掳C Store in a dry area. Keep away from foodstuff and beverages.
7.4 Other precautions: Eugenol darkens and thickens upon exposure to air. Observe normal warehouse handling procedures.
Handling of this product should be by trained dental healthcare professionals only..
SECTION VIII 鈥? Control Measures / Personal Protection
8.1 Respiratory protection: None required during normal use of this product. Avoid casual breathing of vapors.
8.2 Ventilation: Local exhaust recommended.
8.3 Protective gloves: Rubber gloves.
8.4 Eye protection: Close fitting protective goggles.
8.5 Other protective clothing or equipment: Rubber apron.
8.6 Work/Hygienic practices: Avoid eye and skin contact, inhalation and ingestion. Observe normal care when
working with chemicals. Do not eat, drink or smoke when using.
NFPA HAZARD
CLASSIFICATIONS
Health 2 NFPA - National Fire Protection Association
Flammability 1 N.A. - Not Applicable
Reactivity 0 N.E. - Not Established
Specific Hazard NA
509899 (R-11/12/01)
MATERIAL SAFETY DATA SHEET
SECTION I 鈥? Product/Company Identification
FYNAL庐 POWDER
1.1 Product Trade Name:
Zinc Oxide Eugenol Permanent Cement
1.2 Part (Item) Number: 609001, 609002
1.3 Division Name: DENTSPLY Caulk
1.4 Address: 38 West Clarke Avenue
City State Zip: Milford DE 19963-0359
Internet Address: http://www.caulk.com
1.5 Emergency Telephone Number: (800) 424-9300 (Chemtrec)
1.6 Telephone Number for Information: (302) 422-4511 (8:00 AM 鈥? 4:30 PM Eastern Time)
1.7 Date Prepared: 11/13/98 Date Revised: 11/12/01
SECTION II - Hazardous Ingredients/Identity Information
Hazardous Components OSHA PEL ACGIH TLV CAS # Percent
10 mg/mm3 10 mg/mm3
Zinc oxide 1314-13-2 Greater than 75%
SECTION III - Physical/Chemical Characteristics
5.7 g/cm3
3.1 Boiling point: N. A. 3.6 Specific Gravity:
3.2 Vapor pressure: N. A. 3.7 Melting Point: N. A.
3.3 Vapor density: N. A. 3.8 Evaporation rate: N. A.
3.4 Solubility in water: Not Soluble
3.5 Appearance and odor: Whitish powder with faint odor.
SECTION IV - Fire and Explosion Hazard Data
4.1 Flash point (method used): N. A.
4.2 Flammability (explosive limits): LEL: N. A. UEL: N. A.
4.3 Extinguishing media: Water, carbon dioxide, or dry chemical extinguishers.
4.4 Special fire fighting procedures: Avoid extinguishing methods, which may generate dust clouds. Water stream can
disperse dust in air producing a fire hazard and possible explosion hazard if exposed to
ignition source. Fire fighters should wear full protective clothing including self-
contained breathing apparatus.
4.5 Unusual fire and explosion hazards: Polymer dust is combustible. The explosive limits of the polymer particles suspended
in air are approximately those of coal dust.
SECTION V 鈥? Reactivity Data
5.1 Stability: Unstable: Stable: X
5.2 Conditions to avoid (stability): Excessive heat, greater than 50掳C/122掳F.
5.3 Incompatibility (materials to avoid): N. A.
5.4 Hazardous decomposition or byproducts: From the polymer 鈥? methylmethacrylate and carbon monoxide.
5.5 Hazardous polymerization: May occur: Will not occur: X
5.6 Conditions to avoid (polymerization): None.
SECTION VI - Health Hazard Data
6.1 Route(s) of entry: Inhalation?: Yes Skin?: No Ingestion?: Possible
6.2 Health hazards (acute and chronic):It is not known to cause significant health problems. It is considered an inert or nuisance
dust. Avoid inhalation of dust. Keep dust out of eyes to prevent possible irritation.
6.3 Carcinogenicity: NTP?: Not listed IARC monographs?: Not listed OSHA Regulated? : No
All components of this product are in compliance with the inventory listing requirements
of the U. S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
6.4 Signs and symptoms of exposure: Product may irritate the eyes and skin. Eye contact: Redness or irritation.
Skin contact: Redness or irritation.
6.5 Medical conditions generally
aggravated by exposure: Open sores or wounds of the skin.
6.6 Emergency first aid procedures: Inhalation: Remove to fresh air. Eyes: In case of eye contact, flush with flowing water
for 15 minutes, including under the eyelids and get medical attention. Skin: Flush with
flowing water then wash area with mild soap and water. Ingestion: Rinse mouth with
water. Consult a physician if amount was large.
SECTION VII 鈥? Precautions for Safe Handling and Use
7.1 Steps to be taken in case material is
released or spilled: As with any nuisance dust, avoid excessive dusting. Sweep up spilled powder to avoid slipping hazard
and place in an appropriately marked container. Keep airborne particulates to a minimum when
cleaning up spills.
7.2 Waste disposal methods: Dispose of in accordance with Federal, State and Local regulations.
7.3 Precautions to be taken in handling
and storage: Always close container immediately after use to prevent water absorption and contamination. Store at
ambient temperature out of direct sunlight and heat. Store in a dry area. Keep away from foodstuff and
beverages.
7.4 Other precautions: Observe normal warehouse handling procedures. Handling of this product should be by trained dental
healthcare professionals only.
SECTION VIII 鈥? Control Measures / Personal Protection
8.1 Respiratory protection: None required during normal use of this product. Local ventilation or approved
nuisance dust mask, if in large quantities.
8.2 Ventilation: Local exhaust recommended.
8.3 Protective gloves: Rubber gloves.
8.4 Eye protection: Safety glasses.
8.5 Other protective clothing or equipment: Rubber apron.
8.6 Work/Hygienic practices: Observe normal care when working with chemicals. Handling of this product
should be by trained dental healthcare professionals only. Avoid eye and skin
contact, inhalation and ingestion. Do not eat, drink or smoke when using..
NFPA HAZARD
CLASSIFICATIONS
Health 1 NFPA - National Fire Protection Association
Flammability 0 N.A. - Not Applicable
Reactivity 0 N.E. - Not Established
Specific Hazard NA
509898 (R-11/12/01)
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