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MSDS Material Safety Data Sheet
CAS

9082-00-2
7732-18-1
7631-86-9

File Name: dentsply_com---cristobal_msds_oxygenbarriergel.asp
MSDS #42                                                                                             Page 1 of 3

CERAMCO
MATERIAL SAFETY DATA SHEET
Issued on July22, 2003
========================================================================================
SECTION I - PRODUCT IDENTIFICATION
========================================================================================
PRODUCT NAME: Cristobal+ Oxygen Barrier Gel
PRODUCT CODE: 210814
MANUFACTURER/SUPPLIER: Dentsply Ceramco EU Rep., DeguDent GmbH
Six Terri Lane Rodenbacher Chaussee 4
Burlington, NJ 08016 D-63457 Hanau-Wolfgang,
USA Germany
Phone number: (800) 487-0100 Phone number: 49-6181-5950

========================================================================================
SECTION II - COMPOSITION/INFORMATION ON INGREDIENTS
========================================================================================
DESCRIPTION: Mixture of polyol, water and silica.
HAZARDOUS INGREDIENTS:
Component CAS No. Weight % OSHA ACGIH Hazards
Polyol 9082-00-2 <80% - - -
Water 7732-18-15 <15% - - -
80mg/m3 10mg/m3
Silica (amorphous) 7631-86-9 <25% Irritant

========================================================================================
SECTION III - HAZARDS IDENTIFICATION
========================================================================================
NFPA HAZARD DESIGNATIONS: Health: 1 (Slight)
Flammability: 0 (Minimal)
Reactivity: 0 (Minimal)
IMPORTANT HAZARD INFORMATION: Do not ingest. Irritating to eyes, respiratory system and skin.

========================================================================================
SECTION IV - FIRST AID MEASURES
========================================================================================
GENERAL INFORMATION: Seek medical attention for symptoms.
AFTER INHALATION: In case of prolonged exposure, take person into open air.
AFTER SKIN CONTACT: Wash skin with soap/water. Seek medical attention if condition persists.
AFTER EYE CONTACT: Immediately flush eyes with copious quantities of water for 15 minutes. Seek medical
attention immediately.
AFTER SWALLOWING: Seek medical attention immediately.

========================================================================================
SECTION V- FIRE FIGHTING MEASURES
========================================================================================
FIRE EXTINGUISHING AGENTS: Use sand, foam, carbon dioxide, or dry chemicals.
SPECIAL PROTECTIVE EQUIPMENT: Wear self contained breathing apparatus and protective clothing to prevent contact
with eyes and skin.

========================================================================================
SECTION VI - ACCIDENTAL RELEASE MEASURES
========================================================================================
PERSON-RELATED SAFETY PRECAUTIONS: Use in well-ventilated areas.
ENVIRONMENTAL PROTECTION: Avoid conditions which may result in dispersion to environment.
MEASURES FOR CLEANING/COLLECTING: Take up mechanically with inert fluid-binding material and store in
appropriate containers.
ADDITIONAL INFORMATION: No additional information.
Page 2 of 3
CERAMCO
MATERIAL SAFETY DATA SHEET
CRISTOBAL+ OXYGEN BARRIER GEL (continued)


========================================================================================
SECTION VII - HANDLING AND STORAGE
========================================================================================
INFORMATION FOR SAFE HANDLING: Ensure proper ventilation at workplace. Handle with gloves, avoid
contact with eyes.
PROTECTION AGAINST EXPLOSIONS/FIRES: Keep containers closed when not in use.
STORAGE: Store in tightly sealed metal or glass containers in a cool, dark location.
COMMON STORAGE FACILITIES: None.

========================================================================================
SECTION VIII - EXPOSURE CONTROLS AND PERSONAL PROTECTION
========================================================================================
VENTILATION: General exhaust.
EYE PROTECTION: Safety glasses are recommended. Eye wash station should be present.
SKIN PROTECTION: Rubber or plastic gloves.
RESPIRATORY PROTECTION: Do not breathe dust/vapors.

========================================================================================
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
========================================================================================
PHYSICAL STATE: Paste
APPEARANCE: Viscous gel
ODOR: Weak.
pH: Not Determined
DECOMPOSITION TEMPERATURE: > 200掳C
FLASH POINT: > 200掳C
MELTING POINT: Not Determined
BOILING POINT: Not Determined
EXPLOSION PROPERTIES: Not Determined
VAPOR PRESSURE: nil at 20掳C
RELATIVE VAPOR DENSITY: >1
SPECIFIC GRAVITY: 1.028 g/cc at 20掳C
SOLUBILITY/ MISCIBILITY Very slightly soluble in water

========================================================================================
SECTION X - STABILITY AND REACTIVITY
========================================================================================
STABILITY: Stable. Thermal decomposition at > 200掳C.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Flame and heat.
MATERIALS TO AVOID: Strong oxidizing or reducing agents, free radicals, heavy metal ions, acids.
DECOMPOSITION PRODUCTS: Acrylic fumes, Carbon dioxide, carbon monoxide.

========================================================================================
SECTION XI - TOXICOLOGICAL INFORMATION
========================================================================================
SKIN CONTACT: Repeated or prolonged contact may cause irritation of the skin. LD50(rabbit) >
5,000mg/kg
EYE CONTACT: May cause irritation upon prolonged contact.
INHALATION: No known hazards.
INGESTION: Do not ingest. LD50 (rat) > 10,000mg/kg
SPECIAL TOXIC EFFECTS: No known hazards.
Page 3 of 3
CERAMCO
MATERIAL SAFETY DATA SHEET
CRISTOBAL+ OXYGEN BARRIER GEL (continued)


========================================================================================
SECTION XII - ECOLOGICAL INFORMATION
========================================================================================
Stable organic carriers, does not degrade or evaporate. Do not discharge into streams or waterways.


========================================================================================
SECTION XIII - DISPOSAL CONSIDERATION
========================================================================================
PRODUCT DISPOSAL: Dispose of in accordance with Federal, State and Local regulations for
relatively non-toxic organics
CONTAMINATED PACKAGING: Dispose according to official regulations.
ADDITIONAL DISPOSAL INFORMATION: Local disposal regulations may exist.

========================================================================================
SECTION XIV - TRANSPORT INFORMATION
========================================================================================
Product is not regulated.

========================================================================================
SECTION XV - REGULATORY INFORMATION
========================================================================================
This material is not regulated under CERCLA, SARA.
Labeling according to international regulations: Xi, Irritant, Contains colloidal silica.

========================================================================================
SECTION XVI - OTHER INFORMATION
========================================================================================
INTERNATIONAL RISK PHRASES: 36/37/38
Irritating to eyes, respiratory system, skin
INTERNATIONAL SAFETY PHRASES: 26-28.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
After contact with skin, wash immediately with water and soap.

These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features
and shall not establish a legally valid contractual relationship.

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