MATERIAL SAFETY DATA SHEET
SECTION I 鈥? Product/Company Identification
庐
PROBOND ADHESIVE All Purpose Bonding Agent
1.1 Product Trade Name:
1.2 Part (Item) Number: 634245 鈥? 634275 All Package Configurations
1.3 Division Name: DENTSPLY Caulk
1.4 Address: 38 West Clarke Avenue
City State Zip: Milford DE 19963-0359
Internet Address: http://www.caulk.com
1.5 Emergency Telephone Number: (800) 424-9300 (Chemtrec)
1.6 Telephone Number for Information: (302) 422-4511 (8:00 AM 鈥? 4:30 PM Eastern Time)
1.7 Date Prepared: 2/3/99 Date Revised: 02/02/02
SECTION II 鈥? Hazardous Ingredients/Identity Information
Hazardous Components OSHA PEL ACGIH TLV CAS # PERCENTAGE
Urethane dimethacrylate resin N. E. N. E. 127312-03-2 < 55 %
Polymerizable dimethacrylate resins N. E. N. E. 109-16-0 < 30 %
Dipentaerythritol pentaacrylate phosphate N. E. N. E. 87699-25-0 < 7 %
0.2 mg/m3 0.2 mg/m3
Glutaraldehyde 111-30-8 < 5 %
SECTION III 鈥? Physical/Chemical Characteristics
approximately 1.1 g/cm3
3.1 Boiling point: N. E. 3.6 Specific Gravity:
3.2 Vapor pressure: N. E. 3.7 Melting Point: N. E.
3.3 Vapor density: N. E. 3.8 Evaporation rate: N. E.
3.4 Solubility in water: Not Soluble
3.5 Appearance and odor: Light yellow liquid with sweet acrylic ester odor.
SECTION IV 鈥? Fire and Explosion Hazard Data
4.1 Flash point (method used): N. E.
4.2 Flammability (explosive limits): LEL: N. E. UEL: N. E.
4.3 Extinguishing media: Carbon dioxide, dry chemical, water fog, and foam.
4.4 Special fire fighting procedures: Firefighters should wear full protective clothing including a MSHA/NIOSH
approved, pressure demand, self-contained breathing apparatus.
4.5 Unusual fire and explosion hazards: Keep away from fire. During a fire irritating gases from the decomposition
of the resins may be present.
SECTION V 鈥? Reactivity Data
5.1 Stability: Unstable: Stable: X
5.2 Conditions to avoid (stability): Visible light, high temperatures, and humidity.
5.3 Incompatibility (materials to avoid): Strong oxidants, alkali metals, and halogens.
5.4 Hazardous decomposition or byproducts: Methacrylates, acrylates, and irritating gases.
5.5 Hazardous polymerization: May occur: Will not occur: X
5.6 Conditions to avoid (polymerization): Strong visible lights and elevated temperatures over 50掳C(122掳F).
SECTION VI - Health Hazard Data
6.1 Route(s) of entry: Inhalation?: Yes Skin?: Yes Ingestion?: Possible
6.2 Health hazards (acute and chronic): Eye Contact: Material may cause irritation and possible corneal
damage. Avoid contact with eyes. Skin: Material may be an irritant.
Susceptible persons with known allergies to methacrylates and
acrylates may develop allergic response.
6.3 Carcinogenicity: NTP?: Not listed IARC monographs?: Not listed OSHA regulated? : No
All components of this product are in compliance with the inventory listing
requirements of the U. S. Toxic Substances Control Act (TSCA) Chemical
Substance Inventory.
6.4 Signs and symptoms of exposure: Dermal redness or irritation. Severe allergic response may result in
breathing difficulties.
6.5 Medical conditions generally
aggravated by exposure: Open sores and wounds of the skin. Individuals with known sensitivity
to methacrylates, acrylates, or urethane dimethacrylates.
6.6 Emergency first aid procedures: Eyes: In case of eye contact, flush with flowing water for 15 minutes,
including under the eyelids. Get prompt medical attention. Skin: Wash
skin with soap and water. If irritation persists, call physician.
Ingestion: If swallowed give 2 glasses of water to drink. See a physician.
Inhalation: Move to fresh air. Call physician if discomfort persists or if
amount was large.
SECTION VII - Precautions for Safe Handling and Use
7.1 Steps to be taken in case material
is released or spilled: Absorb spilled material with inert material such as sand or vermiculite. Scoop up and
dispose of in accordance with Federal, State and Local environmental regulations.
7.2 Waste disposal methods: Dispose of in accordance with Federal, State and Local environmental regulations.
7.3 Precautions to be taken in
handling and storage:Store in a dry area, away from direct sunlight. Maximum storage temperature is
50掳C(122掳F). Normal storage is at room temperature.Store away from food and beverages.
7.4 Other precautions: Avoid contact with skin. Observe normal warehouse handling procedures. Handling of this
product should be by trained dental healthcare professionals only..
SECTION VIII 鈥? Control Measures / Personal Protection
8.1 Respiratory protection: None required during normal use of this product.
8.2 Ventilation: None required during normal intended use of this product. Local exhaust
can be used to keep vapors below threshold level.
8.3 Protective gloves: Latex or vinyl gloves.
8.4 Eye protection: Protective goggles.
8.5 Other protective clothing or equipment: Chemically resistant apron or other impervious clothing.
8.6 Work/Hygienic practices: Observe normal care when working with chemicals. Avoid eye and skin
contact, inhalation and ingestion. Do not eat, drink or smoke when using.
NFPA HAZARD
CLASSIFICATIONS
Health 0 NFPA - National Fire Protection Association
Flammability 1 N.A. - Not Applicable
Reactivity 0 N.E. - Not Established
Specific Hazard N. A.
534895 (R-02/02/02)
MATERIAL SAFETY DATA SHEET
SECTION I 鈥? Product/Company Identification
庐
PROBOND PRIMER All Purpose Bonding Agent
1.1 Product Trade Name:
1.2 Part (Item) Number: 634245 鈥? 634275 All Package Configurations
1.3 Division Name: DENTSPLY Caulk
1.4 Address: 38 West Clarke Avenue
City State Zip: Milford DE 19963-0359
Internet Address: http://www.caulk.com
1.5 Emergency Telephone Number: (800) 424-9300 (Chemtrec)
1.6 Telephone Number for Information: (302) 422-4511 (8:00 AM 鈥? 4:30 PM Eastern Time)
1.7 Date Prepared: 2/3/99 Date Revised: 02/02/02
SECTION II 鈥? Hazardous Ingredients/Identity Information
Hazardous Components OSHA PEL ACGIH TLV CAS # Percent
1188 mg/m3
Acetone 500 ppm 67-64-1 < than 80 %
1880 mg/m3
Ethyl Alcohol 1000 ppm 64-17-5 < than 25 %
Dipentaerythritol pentaacrylate phosphate N. E. N. E. 87699-25-0 < than 10 %
SECTION III 鈥? Physical/Chemical Characteristics
approximately 0.8 g/cm3
3.1 Boiling point: 56掳C (133掳F) 3.6 Specific Gravity:
3.2 Vapor pressure: N. E. 3.7 Melting Point: N. E.
3.3 Vapor density: N. E. 3.8 Evaporation rate: N. E.
3.4 Solubility in water: Soluble
3.5 Appearance and odor: Water white liquid with acetone and alcohol odor.
SECTION IV 鈥? Fire and Explosion Hazard Data
4.1 Flash point (method used): < 23掳C (-5掳F) Closed Cup
4.2 Flammability (explosive limits): LEL: 2.5 vol % UEL: 13 vol %
4.3 Extinguishing media: Carbon dioxide, dry chemical, water fog, and foam.
4.4 Special fire fighting procedures: Firefighters should wear full protective clothing including a MSHA/NIOSH
approved, pressure demand, self-contained breathing apparatus.
4.5 Unusual fire and explosion hazards: Keep away from fire. During a fire irritating gases from the decomposition
of the solvents may be present.
SECTION V 鈥? Reactivity Data
5.1 Stability: Unstable: Stable: X
5.2 Conditions to avoid (stability): High temperatures, greater than 37掳C(100掳F). Keep away from fire.
5.3 Incompatibility (materials to avoid): Strong oxidants.
5.4 Hazardous decomposition or byproducts: During a fire, smoke may contain the original material in addition to
unidentified toxic and/or irritating compounds. Hazardous combustion
products may include and are not limited to: carbon monoxide, and
carbon dioxide.
5.5 Hazardous polymerization: May occur: Will not occur: X
5.6 Conditions to avoid (polymerization): N. A.
SECTION VI - Health Hazard Data
6.1 Route(s) of entry: Inhalation?: Yes Skin?: Yes Ingestion?: Yes
6.2 Health hazards (acute and chronic): Eye Contact: Material may cause irritation and possible corneal
damage. Avoid contact with eyes. Skin: Material may be an irritant.
Possible nausea on prolonged exposure. Susceptible persons with known
allergies to methacrylates and acrylates may develop allergic response.
6.3 Carcinogenicity: NTP?: Not listed IARC monographs?: Not listed OSHA regulated? : No
All components of this product are in compliance with the inventory listing
requirements of the U. S. Toxic Substances Control Act (TSCA) Chemical
Substance Inventory.
6.4 Signs and symptoms of exposure: Eye Contact: Material may cause irritation and possible corneal damage.
Dermal redness, irritation or possible allergic reaction.
6.5 Medical conditions generally
aggravated by exposure: Open sores and wounds of the skin.
6.6 Emergency first aid procedures: Eyes: In case of eye contact, flush with flowing water for 15 minutes,
including under the eyelids. Get prompt medical attention. Skin: Wash
skin with soap and water. If irritation persists, call physician.
Ingestion: Consult a physician. Inhalation: Move to fresh air. Call
physician if discomfort persists.
SECTION VII - Precautions for Safe Handling and Use
7.1 Steps to be taken in case material
is released or spilled: Absorb spilled material with inert material such as sand or vermiculite. Scoop up and
dispose of in accordance with Federal, State and Local environmental regulations.
7.2 Waste disposal methods: Dispose of in accordance with Federal, State and Local environmental regulations.
7.3 Precautions to be taken in
handling and storage:Store in a dry area, away from direct sunlight. Maximum storage temperature is
50掳C(122掳F). Normal storage is at room temperature.Store away from food and beverages.
7.4 Other precautions: Avoid contact with skin. Observe normal warehouse handling procedures. Handling of this
product should be by trained dental healthcare professionals only.
SECTION VIII - Control Measures / Personal Protection
8.1 Respiratory protection: None required during normal use of this product. In large quantities use a
self-contained breathing apparatus.
8.2 Ventilation: Local exhaust is recommended. Mechanical ventilation using explosion-
proof motors is acceptable.
8.3 Protective gloves: Latex or rubber gloves.
8.4 Eye protection: Close fitting protective goggles.
8.5 Other protective clothing or equipment: Rubber apron. Eye wash, safety shower.
8.6 Work/Hygienic practices: Observe normal care when working with chemicals. Avoid eye and skin
contact, inhalation and ingestion. Do not eat, drink or smoke when using
NFPA HAZARD
CLASSIFICATIONS
Health 1 NFPA - National Fire Protection Association
Flammability 4 N.A. - Not Applicable
Reactivity 0 N.E. - Not Established
Specific Hazard N. A.
534896 (R-02/02/02)
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