Material Safety Data Sheet
Transportation and Medical Emergency Phone: 1-800-535-5053 (INFOTRAC)
General Phone: 317-580-8282
EPA Reg. No.: 67690-37
Creation Date: 07/28/2005
CuPRO* 2005 T/N/O Revision Date: 07/18/2006
Fungicide/Bactericide SePRO Corporation Carmel, IN 46032-4562
SKIN: Take off contaminated clothing. Rinse skin immediately
1. PRODUCT AND COMPANY IDENTIFICATION
with plenty of soap and water for 15 - 20 minutes. Call a poison
control center or doctor for treatment advice.
PRODUCT: CuPRO 2005 T/N/O Fungicide/Bactericide
NOTE TO PHYSICIAN: Probable mucosal damage may
COMPANY IDENTIFICATION:
contraindicate use of gastric lavage.
SePRO Corporation
11550 North Meridian Street, Suite 600
Carmel, IN 46032-4565
5. FIRE FIGHTING MEASURES
www.sepro.com
Information Phone: 317-580-8282 (Monday - Friday, 8:00 am to 5:00 pm EST) FLASH POINT & METHOD: Not determined
FLAMMABLE LIMITS: Not determined
2. HAZARDOUS IDENTIFICATIONS AUTO-IGNITION TEMPERATURE: Not determined
FIRE AND EXPLOSION HAZARDS: Negligible fire hazard when
EMERGENCY OVERVIEW exposed to heat or flame.
Medium-Blue Granulated Solid. Odor not determined.
鈥? WARNING! Causes substantial but temporary eye injury. EXTINGUISHING MEDIA: Use dry chemicals, carbon dioxide,
鈥? Harmful if swallowed, absorbed through skin or inhaled. water spray or foam. No incompatible fire fighting media known.
鈥? May cause skin sensitization reactions in certain individuals.
鈥? Avoid contact with skin, eyes and clothing. FIREFIGHTING EQUIPMENT: Wear self-contained breathing
鈥? Avoid breathing dust. apparatus and full protective clothing.
EMERGENCY PHONE NUMBER: 1-800-535-5053 HAZARDOUS COMBUSTION PRODUCTS: Decomposes to
CuO and H20 above 140藲C.
3. COMPOSITION / INFORMATION ON INGREDIENTS
6. ACCIDENTAL RELEASE MEASURES
Component Name CAS # % by Wt.
NOTE: Review FIRE FIGHTING MEASURES and HANDLING
Copper Hydroxide鈥? 20427-59-2 53.8%
(PERSONNEL) sections before proceeding with clean-up.
Inert Ingredients 46.2%
Use appropriate PERSONAL PROTECTIVE EQUIPMENT during
(鈥燤etallic Copper Equivalent 鈥? 35%)
clean-up.
Components not precisely identified are proprietary or not
hazardous. ACTION TO TAKE FOR SPILLS/LEAKS: Contain and sweep up
small spills. Dispose of as waste in a suitable (fiberboard)
containers. Prevent runoff.
4. FIRST AID MEASURES
EYES: Hold eyes open and rinse slowly and gently with water for Water Spills: If feasible, copper may be precipitated/ultra
15 - 20 minutes. Remove contact lenses, if present, after the first filtrated with caustics or other chemicals and resulting sludge
5 minutes, then continue rinsing eyes. Call a poison control center disposed of in a chemical landfill.
or doctor for treatment advice.
Report large spills to INFOTRAC and consult SePRO Corporation
INGESTION: Call a poison control center or doctor immediately
for assistance.
for treatment advice. Have person drink a large quantity of milk,
egg white, gelatin solution or if these are not available, large
7. HANDLING AND STORAGE
quantities of water. Do not induce vomiting unless told to do so by
the poison control center or doctor. Never give anything by mouth
HANDLING (Personnel)
to an unconscious person.
Users should: Wash hands before eating, drinking, chewing
gum, using tobacco, or using the toilet. Remove clothing
INHALATION: Move person to fresh air. If person is not
immediately if pesticide gets inside. Then wash thoroughly and
breathing, call 911 or ambulance, then give artificial respiration,
put on clean clothing.
preferably by mouth to mouth. Call a poison control center or
doctor for further treatment advice.
*Trademark of SePRO Corporation 漏 Copyright 2006 SePRO Corporation.
Material Safety Data Sheet
Transportation and Medical Emergency Phone: 1-800-535-5053 (INFOTRAC)
General Phone: 317-580-8282
EPA Reg. No.: 67690-37
Creation Date: 07/28/2005
CuPRO* 2005 T/N/O Revision Date: 07/18/2006
Fungicide/Bactericide SePRO Corporation Carmel, IN 46032-4562
STORAGE Follow manufacturer鈥檚 instruction for cleaning /maintaining PPE.
Do not contaminate water, food or feed by storage. Store in a If no such instructions for washables, use detergent and hot water.
cool, dry place at a temperature below 35藲C (95藲F). Average Keep and wash PPE separately from other laundry.
shelf life under proper storage conditions is 2 years.
Do not enter or allow worker entry into treated areas during the
Keep out of reach of children. restricted entry interval (REI) of 24 hours without required PPE.
8. EXPOSURE CONTROL/PERSONAL PROTECTION The following equipment and precautions must be followed for
7 days following the application of this product:
These precautions are suggested for conditions where the
鈥? An eye-flush container, designed specifically for flushing eyes,
potential for exposure exists. Emergency conditions may require
must be available at the WPS decontamination site for workers
additional precautions.
entering the area treated with copper hydroxide.
鈥? Notify workers of the application by warning them orally that
EXPOSURE GUIDELINES: Copper hydroxide鈥?: ACGIH TLV is
residue in the treated areas may be highly irritating to their eyes
1 mg/m3, dusts and mists, as Cu, 8 Hr. TWA; OSHA PEL is
and to take precautions such as refraining from rubbing their
1 mg/m3, dusts and mists, as Cu, 8 Hr. TWA; AEL鈥犫?? is 1.5 mg/m3,
eyes and if they get residues in their eyes they should
8 and 12 Hr. TWA (approximately 1 mg/m3, as Cu).
immediately flush their eyes using the eye-flush container.
Metallic Copper Equivalent = 35%
鈥?
PPE required for early entry to treated areas that is permitted under
AEL = Acceptable Exposure Limit. Where governmentally
鈥犫??
the Worker Protection Standard and that involves contact with
imposed occupational exposure limits, which are lower than the
anything that has been treated, such as plants, soil, or water, is:
AEL are in effect, such limits shall take precedence.
鈥? Coveralls
PESTICIDE APPLICATORS & WORKERS: Refer to the product
鈥? Chemical-resistant gloves made of any waterproof material, such
label and Directions for Use attached to the product for
as polyvinyl chloride, nitrile rubber, or butyl rubber.
Agricultural Use Requirements in accordance with the EPA
鈥? Shoes plus socks.
Worker Protection Standard 40 CFR part 170.
鈥? Protective eyewear.
MANUFACTURING, COMMERCIAL BLENDING,
AND PACKAGING WORKERS:
9. PHYSICAL AND CHEMICAL PROPERTIES
鈥? VENTILATION: Control enclosed spaces with adequate
COLOR: Medium blue
ventilation to prevent exceedance of ACGIH TLV or OSHA PEL.
PHYSICAL STATE: Granulated solid
鈥? RESPIRATORY PROTECTION: In enclosed spaces where the
ODOR: Not determined
TLV or PEL may be exceeded, wear NIOSH/OSHA approved
VAPOR PRESSURE: Not determined
dust or mist respirator.
DENSITY: 1.0417 g/mL
鈥? EYE/FACE PROTECTION: Wear safety glasses to prevent
SOLUBILITY IN WATER: 2.9 mg/L (copper hydroxide)
contact with this substance.
pH: 8.61
PERSONAL PROTECTIVE EQUIPMENT: Some of the materials BOILING POINT: Not determined
that are chemical-resistant to this product are listed below. If you MELTING POINT: Decomposes at >140藲C
want more options, follow the instruction for Category A on an EPA
chemical-resistant category selection chart.
10. STABILITY AND REACTIVITY
Applicators and other handlers must wear:
鈥? Long-sleeved shirt and long pants. STABILITY Stable under normal storage conditions.
鈥? Chemical-resistant gloves made of any waterproof material,
such as polyvinyl chloride, nitrile rubber, or butyl rubber. INCOMPATIBILITY (Specific materials to avoid): None known
鈥? Shoes plus socks.
鈥? Protective eyewear. HAZARDOUS DECOMPOSITION PRODUCTS: Decomposes to
CuO and H20 above 140藲C.
Discard clothing or other absorbent materials that have been
drenched or heavily contaminated with this product鈥檚 concentrate. HAZARDOUS POLYMERIZATION: Material not known to
Do not reuse them. polymerize.
*Trademark of SePRO Corporation 漏 Copyright 2006 SePRO Corporation.
2
Material Safety Data Sheet
Transportation and Medical Emergency Phone: 1-800-535-5053 (INFOTRAC)
General Phone: 317-580-8282
EPA Reg. No.: 67690-37
Creation Date: 07/28/2005
CuPRO* 2005 T/N/O Revision Date: 07/18/2006
Fungicide/Bactericide SePRO Corporation Carmel, IN 46032-4562
11. TOXICOLOGICAL INFORMATION 13. DISPOSAL CONSIDERATIONS
POTENTIAL HEALTH EFFECTS: This section includes possible WASTE DISPOSAL: Do not contaminate water, food, or feed by
adverse effects, which could occur if this material is not handled in disposal. Comply with appropriate disposal regulations. Landfill
the recommended manner. solids at permitted sites. Use registered transporters.
EYES: Eye contact may cause substantial, but temporary eye ENVIRONMENTAL HAZARDS: This pesticide is toxic to fish and
injury. aquatic organisms. DO NOT apply directly to water, to areas
where surface water is present or to intertidal areas below the
SKIN: No adverse effects are expected from incidental skin mean high water mark. Drift and runoff from treated areas may be
contact. While there are no reports of human sensitization with hazardous to fish and aquatic organisms in adjacent aquatic sites.
this product, there are inconclusive or unverified reports of human Do not contaminate water by disposal of equipment washwaters.
sensitization with the active ingredient, copper hydroxide. This
product was not a skin irritant or skin sensitizer in animals. Acute CONTAINER DISPOSAL: Completely empty bag into application
dermal LD50 > 5,000 mg/kg. equipment. Then dispose of empty bag in a sanitary landfill, or by
incineration, or, if allowed by state and local authorities, by burning.
INGESTION: Ingestion may cause nonspecific discomfort, such If burned, stay of out smoke.
as nausea, weakness, or central nervous system depression,
which; if severe enough may lead to death. This product did not PESTICIDE DISPOSAL: Pesticide wastes are acutely hazardous.
produce any adverse effects at 1000 mg/kg in a 28-day oral Improper disposal of excess pesticide, spray mixture, or rinsate is
feeding study in rats. Oral LD50 = 1,346 mg/kg. Repeated oral a violation of Federal Law. If these wastes cannot be disposed of
ingestion of copper hydroxide via gavage produced reduced body by use according to label instructions, contact your State Pesticide
weights and food consumption at 15 mg/kg/day and mortality at or Environment Control Agency, or the Hazardous Waste
30 mg/kg/day in rabbits. representative at the nearest EPA Regional Office for guidance.
INHALATION: Inhalation may cause irritation of the upper
14. TRANSPORT INFORMATION
respiratory passages, with coughing. Acute inhalation
LC50 = 1311 mg/m3 in rats (4 hour).
Department of Transportation (DOT) Not Regulated unless
CARCINOGENICITY: None of the components present in this
shipped in bulk or by water.
material at concentrations equal to or greater than 0.1% are listed
by IARC, NTP OSHA or ACGIH as a carcinogen. No animal data
, International Maritime Organization (IMO) Regulated鈥?
are available to define the carcinogenic hazards of this product or International Air Transport Association Not Regulated
Copper Hydroxide.
(IATA)
NOTE: No animal data are available to define the mutagenic,
developmental or reproductive hazards of this product or Copper
IMO鈥?/IMDG:
Hydroxide. Animal data show developmental effects only at
Proper Shipping Name: Organotin Pesticides, Solid, Toxic
exposure levels producing other toxic effects in the adult animal.
Class 9
Identification No. UN 3077
12. ECOLOGICAL INFORMATION Packing Group III
Special Notes MARINE POLLUTANT
ECOTOXICOLOGY
Species Value For additional shipping information contact SePRO Corporation at
Test Type
317-580-8282 and speak with the Logistics Manager.
Rainbow Trout 7.99 mg/L
Aquatic LC50 (96 hr)
Daphnia magna 1.61 mg/L
Aquatic EC50 (48 hr)
Freshwater algae 0.0157 mg/L
Aquatic EC50 (96 hr)
Bobwhite Quail 722 mg/kg
Avian Acute oral LD50
Honeybee 8.15 ug/be
Avian Acute oral LD50
*Trademark of SePRO Corporation 漏 Copyright 2006 SePRO Corporation.
3
Material Safety Data Sheet
Transportation and Medical Emergency Phone: 1-800-535-5053 (INFOTRAC)
General Phone: 317-580-8282
EPA Reg. No.: 67690-37
Creation Date: 07/28/2005
CuPRO* 2005 T/N/O Revision Date: 07/18/2006
Fungicide/Bactericide SePRO Corporation Carmel, IN 46032-4562
RESOURCE CONSERVATION AND RECOVERY ACT (RCRA):
15. REGULATORY INFORMATION
To the best of our knowledge, this product does not meet the
characteristic definition of ignitability, corrositivity or reactivity and is
NOTICE: The information herein is presented in good faith and
not listed in 40 CFR 261.33.
believed to be accurate as of the effective date shown above.
However, no warranty, express or implied, is given. Regulatory
STATE RIGHT-TO-KNOW: The following product component(s)
requirements are subject to change and may differ from one
are cited on the hazardous substance list(s) in the states indicated
location to another; it is the buyer鈥檚 responsibility to ensure that its
below. Non-listed components may be shown in the composition
activities comply with federal, state or provincial, and local laws.
section of the MSDS.
The following specific information is made for the purpose of
complying with numerous federal, state or provincial, and local Chemical Name CAS Number
laws and regulations. Metallic copper* 7440-50-8
(*from Copper hydroxide)
U.S. REGULATIONS
鈥? California 鈥? Listed under copper (CAS No. 7440-50-8) with
SARA TITLE III, SECTION 313: This product contains the
footnotes referencing above federal standards.
following substances subject to the reporting requirements of
鈥? New Jersey 鈥? Footnotes reference above federal standards plus
Section 313 of Title III of the Superfund Amendments and
listing of copper on the New Jersey Environmental Hazardous
Reauthorization Act of 1986 and 40 CFR Part 372:
Substances List (NJ Department of Environmental Protection,
Chemical Name CAS Number Concentration Title 7 New Jersey Administrative Code (NJAC) Chapter 1G).
Metallic copper* 7440-50-8 35.0% 鈥? Massachusetts 鈥? Listed as copper (CAS No. 7440-50-8) and
copper-based pesticide, solid, toxic (no CAS No. assigned).
SARA HAZARD CATEGORY: This product has been reviewed 鈥? Pennsylvania 鈥? Listed as copper fume or dust
according to the EPA 鈥淗azard Categories鈥? promulgated under (CAS No. 7440-50-8) as an environmental hazard.
Sections 311 and 312 of the Superfund Amendments and
Reauthorization Act of 1986 (SARA Title III) and is considered, NATIONAL FIRE PROTECTION ASSOCIATION (NFPA 701) and
under applicable definitions, to meet the following categories: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS):
(4=Extreme; 3=High; 2=Moderate; 0=Insignificant)
An Immediate Health Hazard
Category Rating
OSHA HAZARD COMMUNICATION STANDARD: This product Health 2
is a 鈥淗azardous Chemical鈥? as defined by the OSHA Hazard Flammability 1
Communication Standard (29 CFR 1910.1200). Reactivity 0
TOXIC SUBSTANCES CONTROL ACT (TSCA): All ingredients
are on the TSCA inventory or are not required to be listed on the
16. OTHER INFORMATION, USES AND RESTRICTIONS
TSCA inventory.
MSDS STATUS: New 鈥? 07/28/2005
COMPREHENSIVE ENVIRONMENTAL RESPONSE
Revised 鈥? 07/18/2006: All Sections
COMPENSATION AND LIABILITY ACT (CERCLA, OR
SUPERFUND): This product contains the
The information in this Material Safety Data Sheet relates to this
following substance(s) listed as 鈥淗azardous Substances鈥? under
specific material. It may not be valid for this material if used in
CERCLA which may require reporting of releases:
combination with any other materials or in any process. It is the
users' responsibility to satisfy themselves as to the suitability and
Chemical Name CAS NO. RQ
completeness of this information for their own particular use.
Metallic copper 7440-50-8 5000
The Information Herein Is Given In Good Faith, But No
Warranty, Express or Implied, Is Made. Consult SePRO
Corporation for Further Information.
*Trademark of SePRO Corporation 漏 Copyright 2006 SePRO Corporation.
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