Material Safety Data Sheet
Transportation and Medical Emergency Phone: 1-800-535-5053 (INFOTRAC)
General Phone: 317-580-8282
EPA Reg. No.: 62719-37-67690
Revision Date: 01/10/2008
Renovate庐 3 Herbicide SePRO Corporation Carmel, IN 46032-4565
Exposure to amine vapors may cause minor transient edema of
1. PRODUCT AND COMPANY IDENTIFICATION
the corneal epithelium (glaucopsia) with blurred vision, blue haze,
and halos around bright objects. Effects disappear in a few hours
PRODUCT: Renovate 3 Herbicide
and temporarily reduce ability to drive vehicles. No specific
antidote. Treatment of exposure should be directed at the control
COMPANY IDENTIFICATION:
of symptoms and the clinical condition of the patient.
SePRO Corporation
11550 North Meridian Street, Suite 600
Carmel, IN 46032-4565 5. FIRE FIGHTING MEASURES
www.sepro.com
Information Phone: 317-580-8282 (Monday - Friday, 8:00 am to 5:00 pm EST) FLASH POINT & METHOD USED: 110掳F (43掳C); TCC
FLAMMABLE LIMITS: Not determined
2. HAZARDOUS IDENTIFICATIONS
EXTINGUISHING MEDIA: Alcohol foam and Carbon dioxide.
EMERGENCY OVERVIEW
Light purple-pink liquid, ammonia-like odor. FIRE AND EXPLOSION HAZARDS: Toxic, irritating vapors may
鈥? May cause eye irritation with corneal injury. be formed or given off if product is involved in fire. Although
鈥? May cause skin irritation. product is water-based, it has a flash point due to the presence
鈥? Toxic to aquatic organisms. of small amounts of ethanol and triethylamine.
EMERGENCY PHONE NUMBER: 1-800-535-5053
FIREFIGHTING EQUIPMENT/INSTRUCTIONS: Use
positive-pressure, self-contained breathing apparatus and
full protective clothing.
3. COMPOSITION / INFORMATION ON INGREDIENTS
6. ACCIDENTAL RELEASE MEASURES
COMPONENT CAS NUMBER W/W%
Triclopyr TEA Salt 057213-69-1 44.4
ACTION TO TAKE FOR SPILLS/LEAKS: Contain small spills
Triethylamine 000121-44-8 3.0
and absorb with an inert material such as clay or dry sand.
Ethanol 000064-17-5 2.1
Report large spills to INFOTRAC at 1-800-535-5053 and
Other Ingredients, Totaling 50.5
contact SePRO Corporation.
4. FIRST AID MEASURES
7. HANDLING AND STORAGE
EYES: Wash immediately and continuously with flowing water
PRECAUTIONS TO BE TAKEN IN HANDLING
for at least 30 minutes. Remove contact lenses after the first
AND STORAGE:
5 minutes and continue washing. Obtain prompt medical
Handling:
consultation, preferably from an ophthalmologist.
Keep out of reach of children. Causes irreversible eye damage.
Harmful if inhaled or absorbed through skin. Prolonged or
SKIN: Wash skin with plenty of water.
frequently repeated skin contact may cause allergic skin reaction
in some individuals. Avoid contact with eyes, skin, clothing,
INGESTION: Do not induce vomiting. Give one cup (8 ounces or
breathing vapor, or spray mist. Users should wash hands before
240 ml) of water or milk if available and transport to a medical
eating, drinking, chewing gum, using tobacco, or using the toilet.
facility. Do not give anything by mouth to an unconscious person.
Storage:
INHALATION: No emergency medical treatment necessary.
Store above 28掳F or agitate before use. Store in original
container. See product label for handling /storage precautions
NOTE TO PHYSICIAN: Due to irritant properties, swallowing may
relative to the end use of this product.
result in burns/ulceration of mouth, stomach and lower GI tract with
subsequent stricture. Aspiration of vomitus may cause lung injury.
Suggest endotracheal/esophageal control if lavage is done. If burn
is present treat as any thermal burn, after decontamination.
Renovate is a registered trademark of Dow AgroSciences, LLC. 漏 Copyright 2008 SePRO Corporation.
Material Safety Data Sheet
Transportation and Medical Emergency Phone: 1-800-535-5053 (INFOTRAC)
General Phone: 317-580-8282
EPA Reg. No.: 62719-37-67690
Revision Date: 01/10/2008
Renovate庐 3 Herbicide SePRO Corporation Carmel, IN 46032-4565
8. EXPOSURE CONTROL/PERSONAL PROTECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
These precautions are suggested for conditions where the APPEARANCE: Light purple-pink liquid
potential for exposure exists. Emergency conditions may ODOR: Ammonia-like odor
require additional precautions. BOILING POINT: Not determined
VAPOR PRESSURE: Not determined
EXPOSURE GUIDELINE(S): VAPOR DENSITY: Not applicable
鈥? Ethanol (ethyl alcohol): ACGIH TLV and OSHA PEL are SOLUBILITY IN WATER: Miscible
1000 ppm. ACGIH classification is A4. SPECIFIC GRAVITY: 1.135 (68/68掳F)
鈥? Triclopyr TEA Salt: The manufacturer鈥檚 Hygiene Guideline is
2 mg/M3 as acid equivalent; D-SEN. 10. STABILITY AND REACTIVITY
鈥? Triethylamine: ACGIH TLV is 1 ppm TWA, 3 ppm STEL,
Skin. OSHA PEL is 10 ppm TWA, 15 ppm STEL. STABILITY (Conditions to avoid): Avoid sources of ignition if
temperature is near or above flash point.
A D-SEN notation following the exposure guideline refers to the
potential to produce dermal sensitization, as confirmed by human INCOMPATIBILITY (Specific materials to avoid): Any oxidizing
or animal data. agent. Consult manufacturer for specific cases.
ENGINEERING CONTROLS: Provide general and/or local HAZARDOUS DECOMPOSITION PRODUCTS: Nitrogen oxides
exhaust ventilation to control airborne levels below the exposure and hydrogen chloride may be formed under fire conditions.
guidelines.
HAZARDOUS POLYMERIZATION: Not known to occur.
RECOMMENDATIONS FOR MANUFACTURING,
COMMERCIAL BLENDING AND PACKAGING WORKERS:
11. TOXICOLOGICAL INFORMATION
EYE PROTECTION: Use chemical goggles. Eye wash fountain
POTENTIAL HEALTH EFFECTS
should be located in immediate work area. If exposure causes
This section includes possible adverse effects, which could occur if
eye discomfort, use a full-face respirator.
this material is not handled in the recommended manner.
SKIN PROTECTION: When prolonged or frequently repeated
EYE: May cause severe irritation with corneal injury, which may
contact could occur, use chemically protective clothing resistant
result in permanent impairment of vision, even blindness. Chemical
to this material. Selection of specific items such as faceshield,
burns may occur. Vapor of amines may cause swelling of the
gloves, boots, and apron or full-body suit will depend on
cornea resulting in visual disturbances such as blurred or hazy
operation.
vision. Bright lights may appear to be surrounded by halos. Effects
may be delayed and typically disappear spontaneously.
RESPIRATORY PROTECTION: Atmospheric levels should be
maintained below the exposure guideline. When respiratory SKIN : Prolonged contact may cause skin irritation with local
protection is required for certain operations, use a NIOSH redness. Repeated contact may cause skin burns. Symptoms
approved air-purifying respirator. may include pain, severe local redness, swelling, and tissue
damage. Prolonged or frequently repeated skin contact may
APPLICATORS AND ALL OTHER HANDLERS: Refer to the cause allergic skin reactions in some individuals. With the dilute
product label for personal protective clothing and equipment. mix, no allergic skin reaction is expected. Prolonged skin contact
is unlikely to result in absorption of harmful amounts. The LD50
for skin absorption in rabbits is >5,000 mg/kg.
INGESTION: Low toxicity if swallowed. Small amounts swallowed
incidentally as a result of normal handling operations are not likely
to cause injury; however, swallowing larger amounts may cause
injury. Swallowing may result in gastrointestinal irritation or
ulceration. The oral LD50 for rats is 2,574 mg/kg (male) and
1,847 mg/kg (female).
Renovate is a registered trademark of Dow AgroSciences, LLC. 漏 Copyright 2008 SePRO Corporation.
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Material Safety Data Sheet
Transportation and Medical Emergency Phone: 1-800-535-5053 (INFOTRAC)
General Phone: 317-580-8282
EPA Reg. No.: 62719-37-67690
Revision Date: 01/10/2008
Renovate庐 3 Herbicide SePRO Corporation Carmel, IN 46032-4565
INHALATION: Brief exposure (minutes) is not likely to cause
13. DISPOSAL CONSIDERATIONS
adverse effects.
DISPOSAL METHOD: If wastes and/or containers cannot be
SYSTEMIC (OTHER TARGET ORGAN) EFFECTS: Effects have
disposed of according to the product label directions, disposal of
been reported on the following organs: liver and kidney.
this material must be in accordance with your local or area
regulatory authorities.
CANCER INFORMATION: Triclopyr did not cause cancer in
laboratory animal studies.
This information only applies to the material as supplied. The
identification based on characteristic(s) or listing may not apply if
TERATOGENICITY (BIRTH DEFECTS): Triclopyr did not cause
the material has been used or otherwise contaminated. It is the
birth defects or other effects in the fetus even at doses which
responsibility of the waste generator to determine the toxicity and
caused toxic effects in the mother. Ethanol has been shown to
physical properties of the material generated to determine the
cause birth defects and toxicity to the fetus in laboratory animal
proper waste identification and disposal methods in compliance
tests. It has also been shown to cause human fetotoxicity and/or
with applicable regulations. If the material as supplied becomes a
birth defects when ingested during pregnancy.
waste, follow all applicable regional, national and local laws and
regulations.
REPRODUCTIVE EFFECTS: For triclopyr, in laboratory animal
studies, effects on reproduction have been seen only at doses that
produced significant toxicity to the parent animals. 14. TRANSPORT INFORMATION
U.S. DEPARTMENT OF TRANSPORTATION (DOT)
MUTAGENICITY: For triclopyr and ethanol: in-vitro mutagenicity
INFORMATION:
studies were negative. For triclopyr: animal mutagenicity studies
were negative. For ethanol: animal mutagenicity studies were
For non-bulk shipments by land:
negative in some cases and positive in other cases.
This material is not regulated for transport.
12. ECOLOGICAL INFORMATION
For bulk shipments by land:
Proper Shipping Name: COMBUSTIBLE LIQUID, N.O.S
ENVIRONMENTAL FATE:
(TRIETHYLAMINE, ETHANOL) / COMBUSTIBLE
LIQUID/NA1993/PGIII
MOVEMENT & PARTITIONING: Based largely or completely on
information for triclopyr. Bioconcentration potential is low (BCF
For shipment by air or vessel:
<100 or Log Pow <3).
Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S
(TRIETHYLAMINE, ETHANOL)/3/UN1993/PGIII
DEGRADATION & PERSISTENCE:
Class 3
鈥? Biodegradation under aerobic static laboratory conditions is high
UN Number UN 1993
(BOD20 or BOD28/ThOD >40%).
Packing Group III
鈥? The 20-Day biochemical oxygen demand (BOD20) is 0.30 p/p.
鈥? Theoretical oxygen demand (ThOD) is calculated to be 0.75 p/p.
For additional shipping information contact SePRO Corporation
at 317-580-8282 and speak with the Logistics Manager.
ECOTOXICOLOGY: Material is slightly toxic to aquatic organisms
on an acute basis (LC50/EC50 is between 10 and 100 mg/L in
most sensitive species).
Renovate is a registered trademark of Dow AgroSciences, LLC. 漏 Copyright 2008 SePRO Corporation.
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Material Safety Data Sheet
Transportation and Medical Emergency Phone: 1-800-535-5053 (INFOTRAC)
General Phone: 317-580-8282
EPA Reg. No.: 62719-37-67690
Revision Date: 01/10/2008
Renovate庐 3 Herbicide SePRO Corporation Carmel, IN 46032-4565
OSHA HAZARD COMMUNICATION STANDARD: This product is
15. REGULATORY INFORMATION
a "Hazardous Chemical" as defined by the OSHA Hazard
Communication Standard, 29 CFR 1910.1200.
NOTICE: The information herein is presented in good faith and
believed to be accurate as of the effective date shown above.
NATIONAL FIRE PROTECTION ASSOCIATION
However, no warranty, express or implied, is given. Regulatory
(NFPA RATINGS:
requirements are subject to change and may differ from one
Category Rating
location to another; it is the buyer鈥檚 responsibility to ensure that its
Health 3
activities comply with federal, state or provincial, and local laws.
Flammability 2
The following specific information is made for the purpose of
Reactivity 0
complying with numerous federal, state or provincial, and local
laws and regulations.
COMPREHENSIVE ENVIRONMENTAL RESPONSE
U.S. REGULATIONS COMPENSATION AND LIABILITY ACT
(CERCLA, OR SUPERFUND): This product contains the following
SARA 313 INFORMATION: This product contains the following substance(s) listed as "Hazardous Substances" under CERCLA
substances subject to the reporting requirements of Section 313 of which may require reporting of releases:
Title III of the Superfund Amendments and Reauthorization Act of
1986 and 40 CFR Part 372: Chemical Name CAS Number RQ % in Product
Triethylamine 000121-44-8 5000 3%
Chemical Name CAS Number Concentration
Triethylamine 000121-44-8 3%
RCRA Categorization Hazardous Code: Triethylamine = U404
SARA HAZARD CATEGORY: This product has been reviewed
according to the EPA "Hazard Categories" promulgated under 16. OTHER INFORMATION, USES AND RESTRICTIONS
Sections 311 and 312 of the Superfund Amendment and
MSDS STATUS:
Reauthorization Act of 1986 (SARA Title III) and is considered,
Creation Date: 01/22/2003
under applicable definitions, to meet the following categories:
Revision Date: 01/10/2008 (Sections: 8, 14)
鈥? An Immediate Health Hazard Replaces MSDS Dated: 11/21/2006
鈥? A Delayed Health Hazard
鈥? A Fire Hazard
TOXIC SUBSTANCES CONTROL ACT (TSCA): All ingredients
are on the TSCA inventory or are not required to be listed on the
TSCA inventory. The Information Herein Is Given In Good Faith, But No
Warranty, Express or Implied, Is Made. Consult SePRO
STATE RIGHT-TO-KNOW: The following product components are
Corporation for Further Information.
cited on certain state lists as mentioned. Non-listed components
may be shown in the composition section of the MSDS.
Chemical Name CAS Number List
Ethanol 000064-17-5 NJ1 NJ3 PA1
Triethylamine 000121-44-8 NJ1 NJ3 PA1 PA3
NJ1=New Jersey Special Health Hazard Substance
(present at > or = to 0.1%).
NJ3=New Jersey Workplace Hazardous Substance
(present at greater than or equal to 1.0%).
PA1=Pennsylvania Hazardous Substance
(present at > or = to 1.0%).
PA3=Pennsylvania Environmental Hazardous Substance
(present at > or = to 1.0%).
Renovate is a registered trademark of Dow AgroSciences, LLC. 漏 Copyright 2008 SePRO Corporation.
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