Material Safety Data Sheet
Transportation and Medical Emergency Phone: 1-800-535-5053
(INFOTRAC)
General Phone: 317-580-8282
EPA Reg. Number: 66330-35-67690
Effective Date: 2/28/03
Decree 50 WDG Fungicide 庐
SePRO Corporation Carmel, IN 46032
INGESTION: This product is considered practically
1. PRODUCT AND COMPANY IDENTIFICATION
non-toxic if swallowed.
PRODUCT: Decree庐 50 WDG Fungicide
INHALATION: This product is considered practically
COMPANY IDENTIFICATION: non-toxic if inhaled.
SePRO Corporation
11550 North Meridian Street, Suite 600 CHRONIC TOXICITY (Including Cancer): After repeated
Carmel, IN 46032 oral administration of high doses to Technical material, no
www.sepro.com evidence of cumulative toxicity was seen in rats, mice and
dogs. It was not carcinogenic to animals.
2. COMPOSITION / INFORMATION ON INGREDIENTS
TERATOLOGY (Birth Defects) INFORMATION: No
Decree: N-(2,3-dichloro-4-hydroxyphenyl) development or maternal abnormalities were detected in
-1-methyl-cyclohexanecarboxamide rats exposed to technical material.
CAS # 126833-17-8.......................................................50.0%
Inert Ingredients, * Total..................................................50.0%
* REPRODUCTION INFORMATION: No reproductive
toxicity was observed in rats exposed to Technical material.
** Inert ingredients are any substance other than an active
ingredient contained in this product. Only those inert For complete discussion of the toxicology data from which
ingredients considered hazardous are listed. The identities this evaluation was made, refer to Section 11.
of any other substance are withheld because they are
considered trade secrets. Specific information on the inert 4. FIRST AID
ingredients for the management of exposures, spills, or
safety assessments can be obtained by the treating EYES: Flush eyes immediately with plenty of fresh water
physician or nurse by calling INFOTRAC 1-800-535-5053. for at least 15 minutes while holding the eyelids open.
Remove contact lenses if worn. Call a physician if irritation
persists.
3. HAZARDOUS IDENTIFICATIONS
SKIN: Remove contaminated clothing, wash skin with
plenty of soap and water. Discard contaminated non-
EMERGENCY OVERVIEW
waterproof shoes and boots. Wash contaminated clothing.
Caution: Avoid contact with eyes, skin, or clothing.
Call a physician if irritation persists.
Harmful if swallowed, inhaled or absorbed through
skin. Avoid breathing dust. Keep out of reach of
INGESTION: If swallowed, call a doctor or get medical
children.
attention. Do not induce vomiting. Promptly drink a large
EMERGENCY TELEPHONE NUMBER:
quantity of milk, egg whites, gelatin solution, or if these are
(800) 535-5053
not available drink large quantities of water. Avoid alcohol.
POTENTIAL HEALTH EFFECTS: This section includes INHALATION: If respirator discomfort or irritation occurs,
possible adverse effects which could occur if this material is move the person to fresh air. See a doctor if discomfort or
not handled in the recommended manner. irritation continues.
EYE: This product is slightly irritating to the eyes. NOTES TO PHYSICIAN: Provide basic first aid measures,
decontaminate individual and treat symptomatically.
SKIN: This product is slightly irritating to the skin. This
product is not a skin sensitizer. If absorbed through the
skin, this substance is considered practically non-toxic to
internal organs.
Decree is a registered trademark of Arvesta Corporation.
Material Safety Data Sheet
Transportation and Medical Emergency Phone: 1-800-535-5053
(INFOTRAC)
General Phone: 317-580-8282
EPA Reg. Number: 66330-35-67690
Effective Date: 2/28/03
Decree 50 WDG Fungicide 庐
SePRO Corporation Carmel, IN 46032
CLEANUP: Clean up spill immediately. Place product and
5. FIRE FIGHTING MEASURES
any contaminated cleanup materials in a chemical waste
FLASH POINT: N/A, Solid container. Wash area with soap and water. Pick up sash
Method Used: N/A liquid with additional absorbent and place in a disposable
container.
FLAMMABLE LIMITS:
LFL: NDA FOR SPILLS ON WATER:
UFL: NDA CONTAINMENT: Stop or reduce contamination of any
water. Isolate contaminated water.
AUTO-IGNITION TEMPERATURE: Spontaneous ignition CLEANUP: Remove contaminated water for removal or
temperature = 295藲C treatment.
EXTINGUISHING MEDIA: CO2, dry chemical, foam, water 7. HANDLING AND STORAGE
fog, sand.
DO NOT USE OR STORE near flame, sparks or hot
NFPA RATINGS: Health NDA; Flammability NDA, Reactivity surfaces. USE ONLY IN WELL VENTILATED AREA.
NDA; Special NDA (Least-0, slight-1, Moderate-2, High-3, Keep container closed. DO NOT weld, heat or drill contain-
Extreme-4). These values are obtained using the guidelines er. Replace cap or bung. Before entry into confined spaces
or published evaluations prepared by the National Fire that may have contained hazardous material, determine
Protection Association, NFPA. concentrations and take appropriate measures for personal
protection.
FIRE FIGHTING INSTRUCTIONS: Wear breathing
protection (respirator). Keep away from sources of ignition. Keep pesticide in original container. Store in a dry place to
No smoking. Keep container tightly closed. Prevent dust preserve product quality. Do not store or transport near food
formation and deposits. or feed. This product is dust exposable, and exhibits a lower
exposable limit of 90 g/m3.
Products of combustion from fires involving this material may
be toxic. Avoid breathing smoke and mists. Avoid personal 8. EXPOSURE CONTROL/PERSONAL PROTECTION
and equipment contact with fallout and runoff. Minimize the
amount of water used for fire fighting. Do not enter any EYE PROTECTION: Avoid contact with your eyes. Eye
enclosed area without full protective equipment, including contact can be avoided by wearing chemical eyewear.
self-contained breathing equipment. Contain and isolate
runoff and debris for proper disposal. Decontaminate RESPIRATORY/MENTILATION REQUIREMENTS: This
personal protective equipment and fire fighting equipment material is not expected to present an inhalation hazard.
before reuse. Read the entire document. However, the use of approved respiratory protection is
recommended (fine dust mask). Use this material only in
HAZARDOUS COMBUSTION PRODUCTS: Does not well-ventilated areas.
liberate gases in hazardous amounts in case of contact with
water or moist air. Does not undergo spontaneous SKIN PROTECTION: Avoid contact with skin or clothing.
combustion. Wearing protective clothing including gloves should minimize
skin contact.
6. ACCIDENTAL RELEASE MEASURES
FOR SPILLS ON LAND:
CONTAINMENT: Avoid runoff into storm sewers and ditches
that lead to waterways.
Decree is a registered trademark of Arvesta Corporation.
2
Material Safety Data Sheet
Transportation and Medical Emergency Phone: 1-800-535-5053
(INFOTRAC)
General Phone: 317-580-8282
EPA Reg. Number: 66330-35-67690
Effective Date: 2/28/03
Decree 50 WDG Fungicide
庐
SePRO Corporation Carmel, IN 46032
DERMAL TOXICITY: The dermal LD50 in rats was
9. PHYSICAL AND CHEMICAL PROPERTIES
>5,000 mg/kg.
BOILING POINT: N/A, Solid
ORAL TOXICITY: The oral LD50 in rats was
SOLUBILITY IN WATER: Varies between pH 3 and 9 >5,000 mg/kg.
from soluble to very soluble. Soluble in most polar organic
INHALATION TOXICITY: The 4-hour inhalation LC50
solvents (pure a.i.)
(dust) of Technical material in rats was >5057 mg/m3 air.
-7
VAPOR PRESSURE (pure a.i.): 4 x 10 Pa at 20藲C The
4-hour inhalation in LC50 (aerosol) of Technical in rats was
SPECIFIC GRAVITY: N/A
>332 mg/m3 air.
APPEARANCE: Beige, granule
SKIN SENSITIZATION: Negative
BULK DENSITY: Approximately 164 ml/100g (fluffed).
SUBCHRONIC: In subchronic studies with Technical
Approximately 154 ml/100g (jolted)
material, the NOEL for rat, mice and dog where 5,000 ppm,
ODOR: Weak, not characteristic 1000 ppm and 1000 ppm respectively. Reduced body
weight development, increased feed and water intake were
pH: 8.3 in 1% solution of water
seen in rats and mice. The liver is the main toxicological
MELTING POINT: 153<藲C target organ. In dogs, effects in the red blood system was
additionally seen.
SPECIFIC GRAVITY: N/A
CHRONIC/CARCINOGENICITY: Unspecific signs of
DESSOCIATION CONSTANT (pka) (pure a.i): 7.3
toxicity seen in rats treated with Technical material were
OCTANOL/WATER PARTITION COEFFICIENT reduced body weight development, increased feed and
3
(pure a.i.): Pow = 3.2 x 10 at pH 7 at 20藲C water intake and slight effects on liver and thyroid. In mice
the main effects were a decrease of kidney weights and an
MISCIBILITY: N/A
increase in chronic renal disease and basophilic tubuli.
CORROSION CHARACTERISTICS: Not corrosive to In dogs the red blood system was the main toxicological
composite foil or paper bag used in packaging. target. Technical material was not carcinogenic to rat or
mouse.
10. STABILITY AND REACTIVITY TERATOLOGY/DEVELOPMENTAL TOXICITY: In studies
with Technical material, the NOEL for both maternal and
CHEMICAL STABILITY: (CONDITIONS TO AVOID)
developmental effects in rats was 1,000 mg/kg bw/day.
Stable for 52 weeks at ambient temperature.
No maternal toxicity, no clinical signs, no necropsy findings,
INCOMPATIBILITY: NDA no compound related effects in body weight or food
consumption, mating, fertility, gestation indices, embryo
HAZARDOUS DECOMPOSITION PRODUCTS: NDA
toxicity, fetotoxicity or teratogenicity were observed.
HAZARDOUS POLYMERIZATION: NDA
REPRODUCTION: No reproduction toxicity was observed
IMPACT EXPLODABILITY: Not an explosive. in a 2-generation study with rats exposed to Technical
material.
OXIDATION/REDUCTION PROPERTIES: Not an oxidiz-
er. MUTAGENICITY: Technical material tested was negative
in the following genotoxicity assays: Samonella/microsome
11. TOXICOLOGICAL INFORMATION
test (Ames test), mouse micronucleus test, Reverse
mutation, chromosome aberration in vitro, V79-HGPRT in
ACUTE (Product Specific Information): vitro, rat primary hepatocyte UDS in vitro. Technical
material does not present a genetic hazard to intact animal
EYE IRRITATION: Slightly irritating in rabbits.
systems.
SKIN IRRITATION: Slightly irritating in rabbits.
3
Material Safety Data Sheet
Transportation and Medical Emergency Phone: 1-800-535-5053
(INFOTRAC)
General Phone: 317-580-8282
EPA Reg. Number: 66330-35-67690
Effective Date: 2/28/03
Decree 50 WDG Fungicide 庐
SePRO Corporation Carmel, IN 46032
facilities, spills or misuse of products, and storage of large
12. ECOLOGICAL INFORMATION
quantities of products containing hazardous or extremely
AVIAN TOXICITY: The acute toxicity of Technical material hazardous substances.
is very low.
U.S. FEDERAL REGULATIONS:
Bobwhite quail: LD50 = >2,000 mg a.i./kg bw
OSHA Status: N/A
Bobwhite quail: Dietary LC50 = >5,000 mg a.i./kg diet
TSCA Status: N/A
Mallard duck: Dietary LC50 = >5,000 mg a.i./kg diet
CERCLA Reportable Quantity: N/A
RCRA*:
AQUATIC ORGANISM TOXICITY: This product is
SARA Title III Status:
moderately toxic to fish, has a low toxicity to Daphnia
SARA 311 Categories
magna and the sensitivity to green algae ranges from low
1. Immediate (Acute) Health Effects: YES
to moderate.
2. Delayed (Chronic) Health Effects: NDA
Rainbow trout: 96-hour LC50 = 1.3 mg a.i./l
3. Fire Hazard: NO
Daphnia magna: 48-hour EC50 = 105 mg a.i./l
4. Sudden Release of Pressure Hazard: NO
Green algae (growth rate): 72-hour EC50 = 5.6 mg a.i./l
5. Reactivity Hazard: NO
OTHER NON-TARGET ORGANISMS: In acute toxicity STATE REGULATIONS: Each state may promulgate
studies, Technical material was found to be nontoxic to standards more stringent than the federal government.
honeybees. This section cannot encompass an inclusive list of all state
Oral LD50 = >97.7 ug a.i./bee regulations. Therefore, the user should consult state or
Contact LD50 = >188 ug a.i./bee local authorities.
*RCRA waste codes must be determined on a case by case basis
13. DISPOSAL CONSIDERATIONS (i.e., spill, processing waste, etc.). The waste code presented is based on
available product characteristics only.
END USER SHOULD CONTACT SePRO PRIOR TO
DISPOSAL OF ANY UNUSED PRODUCT.
16. OTHER INFORMATION
DISPOSAL METHODS: Check governmental regulations
The information on this MSDS is based on data available to
and local authorities for approved disposal of this
us as of the revision data given herein, and believed to be
material. Dispose in accordance with applicable laws and
correct. Contact SePRO at (317) 580-8282 to determine
regulations.
if additional data and information have become available
since the revision date.
14. TRANSPORT INFORMATION
Judgements as to the suitability of information herein for
D.O.T. SHIPPING NAME: Pesticide, Non-regulated
the individual's own use or purposes are necessarily in the
TECHNICAL SHIPPING NAME: N/A individual's own responsibility. Although reasonable care
has been taken in the preparation of such information,
D.O.T. HAZARD CLASS: N/A
SePRO extends no warranties, makes no representations,
U.N./N.A NUMBER: N/A and assumes no responsibility as to the accuracy or
suitability of such information for application to the
individual's purposes or the consequences of its use.
15. REGULATORY INFORMATION
REGULATIONS UNDER FIFRA: All pesticides are
governed under FIFRA (Federal Insecticide, Fungicide,
and Rodenticide Act). Therefore, the regulations presented The information herein is given in good faith, but no
below are pertinent only when handled outside of the warranty, express or implied, is made. Consult SePRO
normal use and applications of pesticides. This includes Corporation for further Information.
waste streams resulting from manufacturing/formulation
Form No. H-25-RG-03(03) Decree is a registered trademark of Arvesta Corporation.
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漏 Copyright 2003 SePRO Corporation.
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