Material Safety Data Sheet
Transportation and Medical Emergency Phone: 1-800-535-5053 (INFOTRAC)
General Phone: 317-580-8282
EPA Reg. No.: 71711-25-67690
Creation Date: 06/08/2006
Octane庐 2% SC Herbicide SePRO Corporation Carmel, IN 46032-4565
SKIN: Take off contaminated clothing. Rinse skin immediately
1. PRODUCT AND COMPANY IDENTIFICATION
with plenty of soap and water for 15 - 20 minutes. Call a poison
control center or doctor for treatment advice
PRODUCT: Octane 2% SC Herbicide
INGESTION: Immediately call a poison control center or doctor
COMPANY IDENTIFICATION:
for treatment advice. Have person sip a glass of water if able to
SePRO Corporation
swallow. Do not induce vomiting unless told to do so by the
11550 North Meridian Street, Suite 600
poison control center or doctor. Do not give anything by mouth to
Carmel, IN 46032-4562
an unconscious person. Avoid alcohol.
www.sepro.com
Information Phone: 317-580-8282 (Monday - Friday, 8:00 am to 5:00 pm EST)
5. FIRE FIGHTING MEASURES
2. HAZARDOUS IDENTIFICATIONS FLASH POINT: No flash observed at temperatures up to 110掳C.
FIRE & EXPLOSION HAZARDS: No known explosion
EMERGENCY OVERVIEW
characteristics. Will burn to give off toxic oxides of carbon
鈥? Toxic to fish and aquatic invertebrates
and nitrogen.
EMERGENCY PHONE NUMBER: 800-535-5053
EXTINGUISHING MEDIA: Water, foam, carbon dioxide, or dry
powder.
PRIMARY ROUTE(S) OF ENTRY: Skin contact
FIRE-FIGHTING INSTRUCTIONS: Wear positive pressure,
EYE: Causes slight eye irritation.
self-contained breathing apparatus. Spray containers with water to
keep cool. Avoid runoff from extinguishing media such as water,
SKIN: Can cause mild skin irritation. Harmful if absorbed
foam, and dry chemicals into ponds, rivers, and lakes due to
through the skin. Does not cause skin sensitization in animal
danger of acute toxicity to aquatic organisms.
studies.
INGESTION: No specific health effects are associated with 6. ACCIDENTAL RELEASE MEASURES
ingestion of a small amount incidental to routine handling and
LAND SPILL OR LEAK: Liquid spills on the floor or other
use.
impervious surfaces should be contained or diked and then
absorbed with sawdust, sand, bentonite, or other absorbent clay.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Collect contaminated absorbent, and place it in a metal drum.
Thoroughly scrub the floor or other impervious surface with a
Pyraflufen ethyl: CAS #129630-19-9 2.0%
strong industrial-type detergent and rinse with water.
(ethyl 2-chloro-5-(4-chloro-5-
difluoromethoxy-1-methyl-1H-
Liquid spills that soak into the ground should be dug up and
pyrazol-3-yl) 4 fluorophenoxyacetate)
placed in metal drums. When a large spill or leakage is found,
Other Ingredients: 9.5%
wear protective clothing and respirator to avoid exposure.
Water 88.5%
Avoid contaminated absorbents or water flow into ponds, rivers,
4. FIRST AID MEASURES
and lakes, due to the danger of acute toxicity to aquatic
organisms.
INHALATION: Move person to fresh air. If person is not
breathing, call 911 or an ambulance, then give artificial respiration,
Notify the appropriate authorities immediately (see Section 15
preferably by mouth-to-mouth, if possible. Call a poison control
for any applicable Reportable Quantity (RQ)). Also, report to
center or doctor for further treatment advice.
authorities if contamination of waterways has occurred.
EYES: Hold eyes open and rinse slowly and gently with water for
15 - 20 minutes. Remove contact lenses, if present, after the first
5 minutes, then continue rinsing eyes. Call a poison control center
or doctor for treatment advice.
OCTANE is a registered trademark of Nichino America, Inc. 漏 Copyright 2006 SePRO Corporation.
Material Safety Data Sheet
Transportation and Medical Emergency Phone: 1-800-535-5053 (INFOTRAC)
General Phone: 317-580-8282
EPA Reg. No.: 71711-25-67690
Creation Date: 06/08/2006
Octane庐 2% SC Herbicide SePRO Corporation Carmel, IN 46032-4565
7. HANDLING AND STORAGE 9. PHYSICAL AND CHEMICAL PROPERTIES
HANDLING PRECAUTIONS: APPEARANCE: White, milky liquid
鈥? Open container with care. ODOR: Slight nonspecific odor
鈥? Use adequate ventilation. BOILING POINT: Not available
鈥? Avoid handling near an open flame or heat source or ignition MELTING POINT: Not applicable
source. VAPOR PRESSURE: Not available
鈥? Do not contaminate water by cleaning of equipment or disposal DENSITY: 1.023
of waste. VISCOSITY: Non-Newtonian
鈥? Avoid contact with skin, eyes, or clothing. pH: 6.84 at 24掳C (1% aqueous dilution)
鈥? Do not eat, drink, smoke, or chew gum or tobacco while
handling this product and until hands and face are thoroughly
10. STABILITY AND REACTIVITY
washed with soap and water.
鈥? Do not use the toilet before thoroughly washing hands.
STABILITY: Stable under normal conditions
鈥? Remove contaminated clothing immediately and wash
thoroughly before reuse.
FLASH POINT: No flash observed at temperatures up to 110掳C.
STORAGE PRECAUTIONS:
AUTO IGNITION: Not ignition below 400掳C
鈥? Keep container closed. Store in the original container.
鈥? Keep container at room temperature or store in a cool place.
HAZARDOUS POLYMERIZATION: None
鈥? Avoid storage in direct sunlight, excessive heat or cold.
11. TOXICOLOGICAL INFORMATION
8. EXPOSURE CONTROL/PERSONAL PROTECTION
ACUTE STUDIES:
ENGINEERING CONTROLS: Local exhaust ventilation may be
Rat LD50 Male: > 5,000 mg/kg
Oral
necessary under certain confined conditions. If practical, use
Female: > 5,000 mg/kg
ventilation at the sources of air contamination.
Rat LD50 > 2,000 mg/kg
Dermal
EYE/FACE PROTECTION: Safety glasses
Rat LD50 > 5.53 mg/L
Inhalation
Rabbit Slightly irritating
SKIN PROTECTION: Chemical resistant gloves Eye Irritation
Rabbit Slightly irritating
Skin Irritation
RESPIRATORY PROTECTION: Ensure good ventilation. If not
Guinea Pig Non-sensitizing
Skin Sensitization
adequate, use a suitable respirator.
APPLICATORS AND ALL OTHER HANDLERS: The following POTENTIAL HEALTH EFFECTS: This section includes possible
personal protective equipment (PPE) must be worn when using adverse effects, which could occur if this material is not handled in
product or upon early entry into treated areas during the the recommended manner.
Restricted Entry Interval (REI):
The following data were developed using technical grade
鈥? Coveralls
pyraflufen-ethyl.
鈥? Chemical-resistant gloves
鈥? Shoes plus socks
SUBCHRONIC AND CHRONIC EFFECTS: A 90-day rat feeding
study was conducted at dose levels up to 15,000 ppm pyraflufen
Note: Refer to the product label for applicable details concerning
ethyl showing liver and kidney effect at the high dose
the 鈥淯ser Safety Recommendations鈥? and the use of PPE under
(15,000 ppm, ~1500 mg/kg). The NOEL in this study was
the EPA Worker Protection Standards (40 CFR Part 170).
considered to be 1,000 ppm. In a 90-day oral toxicity study in
dogs, pyraflufen ethyl was administered at dose level up to 1,000
mg/kg/day. No effects in body weight or organ weight, clinical
chemistry, hematology, histopathology, or gross pathology were
observed.
OCTANE is a registered trademark of Nichino America, Inc. 漏 Copyright 2006 SePRO Corporation.
2
Material Safety Data Sheet
Transportation and Medical Emergency Phone: 1-800-535-5053 (INFOTRAC)
General Phone: 317-580-8282
EPA Reg. No.: 71711-25-67690
Creation Date: 06/08/2006
Octane庐 2% SC Herbicide SePRO Corporation Carmel, IN 46032-4565
In long-term studies, no effects were observed in dogs exposed
13. DISPOSAL CONSIDERATIONS
for one-year to a maximum dose of 1000 mg/kg. In a two-year
rat chronic study, liver and kidney effects were observed at
GENERAL DISPOSAL GUIDANCE: Any disposal practice must
2000 ppm. The NOEL was 400 ppm (~20 mg/kg).
be in compliance with all federal, state/provincial, and local
laws and regulations. State (provincial) and local requirements
CANCER INFORMATION: In accordance with the EPA Draft
for waste disposal may be more restrictive or otherwise
Guidelines for Carcinogen Risk Assessment (July, 1999), the EPA
different from federal laws and regulations. Chemical additions,
classified pyraflufen-ethyl as 鈥渓ikely to be carcinogenic to humans鈥?
processing, storage or otherwise altering this material may
by the oral route. Pyraflufen ethyl was tested in lifetime studies in
make the waste disposal information presented in this MSDS
rats and mice. There was no evidence of carcinogenicity in the
incomplete, inaccurate, or otherwise inappropriate. Waste
rat at doses as high as 10,000 ppm (~470 mg/kg). In the mouse
characterization and disposal compliance are the responsibility
study, the incidence of heptaocellular adenoma was increased in
solely of the party generating the waste or deciding to discard
animals receiving 5,000 ppm, a dose level considered to be in
or dispose of the material. Refer to appropriate federal
excess of a MTD (maximum tolerated dose). This benign tumor
(RCRA: 40 CFR.261), state/provincial, or local requirements for
was likely induced by the adaptive response to the heptaocellular
proper classification information. For regulatory information on
degeneration and not carcinogenic response to pyraflufen ethyl.
the ingredient components, see Section 15.
TERATOLOGY: Pyraflufen ethyl was not a developmental
Do not contaminate water, food, or feed by storage or disposal.
toxin in rats at dose levels of 1000 mg/kg or rabbits at doses of
Open dumping is prohibited. Pesticide wastes are toxic.
60 mg/kg.
Improper disposal of excess pesticide, pesticide spray, or rinsate
is a violation of Federal law. If these wastes cannot be disposed
REPRODUCTIVE EFFECTS: Pyraflufen ethyl is not a
of by use according to label instructions, contact your State
reproductive toxin. In a multi-generation rat reproduction study
Pesticide or Environmental Control Agency, or the Hazardous
conducted at dietary concentrations up to 10,000 ppm,
Waste representative at the nearest EPA Regional Office for
pyraflufen-ethyl had no effect on reproductive parameters,
guidance.
including mating indices, fertility index, gestation index, duration
of gestation, numbers of implantation sites, numbers and
CONTAINER DISPOSAL: Do not reuse empty container.
morphology of epididymal sperm, and estrous cycle at any dose
Triple rinse (or equivalent). Then offer for recycling or
level. The NOEL was 1,000 ppm, based on decreased body
reconditioning, or puncture and dispose of in a sanitary landfill,
weight.
or by incineration, or if allowed by state and local authorities, by
burning. If burned, stay out of smoke.
NEUROTOXICITY: There was no neurotoxicity seen in acute,
subchronic, chronic, reproduction, and teratology studies
RCRA: There are no hazardous waste ingredients in this product.
conducted with pyraflufen-ethyl after exposure in the diet.
14. TRANSPORT INFORMATION
MUTAGENICITY: Pyraflufen-ethyl was not mutagenic in any of
the genotoxicity studies conducted.
DOT: Not regulated
IATA: Not regulated
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL PRECAUTIONS: This product is toxic to fish
and aquatic invertebrates. This product may contaminate water
through drift of spray in wind or via runoff events. Use care when
applying in areas adjacent to any body of water. Do not apply
directly to water, to areas where surface water is present, or to
intertidal areas below the mean high water mark. Do not
contaminate water when disposing of equipment washwater or
rinsate. Do not apply when weather conditions favor drift from
treated areas. Do not apply if rainfall is expected within one hour.
OCTANE is a registered trademark of Nichino America, Inc. 漏 Copyright 2006 SePRO Corporation.
3
Material Safety Data Sheet
Transportation and Medical Emergency Phone: 1-800-535-5053 (INFOTRAC)
General Phone: 317-580-8282
EPA Reg. No.: 71711-25-67690
Creation Date: 06/08/2006
Octane庐 2% SC Herbicide SePRO Corporation Carmel, IN 46032-4565
15. REGULATORY INFORMATION 16. OTHER INFORMATION, USES AND RESTRICTIONS
NOTICE: The information herein is presented in good faith and MSDS STATUS: New 鈥? 06/08/2006
believed to be accurate as of the effective date shown above.
However, no warranty, express or implied, is given. Regulatory
requirements are subject to change and may differ from one
location to another; it is the buyer鈥檚 responsibility to ensure that its The Information Herein Is Given In Good Faith, But No
activities comply with federal, state or provincial, and local laws. Warranty, Express or Implied, Is Made. Consult SePRO
The following specific information is made for the purpose of Corporation for Further Information.
complying with numerous federal, state or provincial, and local
laws and regulations.
U.S. REGULATIONS
SARA Title III Notification and Information:
No components of the product are listed.
TOXIC SUBSTANCES CONTROL ACT (TSCA): All ingredients
are on the TSCA inventory or are not required to be listed on the
TSCA inventory.
STATE RIGHT-TO-KNOW:
U.S. State Right-to-Know (RTK) Ingredients: None
HMIS Hazard Rating:
Health: 2 Moderate
Fire: 1 Moderate
Reactivity: 0 Minimal
NFPA Hazard Rating:
Health: 2 Moderate
Fire: 1 Moderate
Reactivity: 0 Minimal
Spec. Haz.: None
OCTANE is a registered trademark of Nichino America, Inc. 漏 Copyright 2006 SePRO Corporation.
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