Material Safety Data Sheet
Transportation and Medical Emergency Phone: 1-800-535-5053
General Phone: 317-580-8282
EPA Reg. Number: 62719-546-67690
Effective Date: 07/24/2007
Galleon* SC Aquatic Herbicide SePRO Corporation Carmel, IN 46032-4565
SKIN CONTACT: Take off contaminated clothing. Rinse skin
1. PRODUCT AND COMPANY IDENTIFICATION
immediately with plenty of water for 15 - 20 minutes. Call a
poison control center or doctor for treatment advice.
PRODUCT: Galleon* SC Aquatic Herbicide
INHALATION: Move person to fresh air. If person is not
COMPANY IDENTIFICATION: breathing, call 911 or ambulance, then give artificial respiration;
SePRO Corporation if by mouth to mouth use rescuer protection (pocket mask, etc).
11550 North Meridian Street, Suite 600 Call a poison control center or doctor for treatment advice.
Carmel, IN 46032-4565 INGESTION: Call a poison control center or doctor immediately
www.sepro.com for treatment advice. Have person sip a glass of water if able to
Information Phone: 317-580-8282 swallow. Do not induce vomiting unless told to do so by the
(Mon 鈥? Fri, 8 am to 5 pm EST) poison control center or doctor. Never give anything by mouth to
an unconscious person.
2. HAZARDOUS IDENTIFICATIONS NOTE TO PHYSICIAN: No specific antidote. Treatment of
exposure should be directed at the control of symptoms and the
EMERGENCY OVERVIEW clinical condition of the patient. Have the MSDS and, if available,
Tan liquid with a musty odor. the product container or label with you when calling a poison
鈥? CAUTION! Causes eye irritation control center or doctor or going for treatment.
Emergency Phone Number: 1-800-535-5053
5. FIRE FIGHTING MEASURES
OSHA HAZARD COMMUNICATION STANDARD: This product
is a "Hazardous Chemical" as defined by the OSHA Hazard
EXTINGUISHING MEDIA: To extinguish combustible residues of
Communication Standard, 29 CFR 1910.1200.
this product use water fog, carbon dioxide dry chemical or foam.
Potential Health Effects FIRE FIGHTING PROCEDURES: Keep people away. Isolate fire
and deny unnecessary entry. Contain fire water run-off if possible.
Eye Contact: May cause slight temporary eye irritation. Corneal
Fire water run-off, if not contained, may cause environmental
injury is unlikely.
damage. Review the 鈥淎ccidental Release Measures鈥? and the
Skin Contact: Prolonged contact is essentially non-irritating
鈥淓cological Information鈥? sections of this MSDS.
to skin.
Skin Absorption: Prolonged skin contact is unlikely to result in FIRE-FIGHTING EQUIPMENT: Wear positive-pressure,
absorption of harmful amounts. self-contained breathing apparatus (SCBA) and protective fire
Inhalation: No adverse effects are anticipated from single fighting clothing (includes fire fighting helmet, coat, trousers,
exposure to mist. boots, and gloves). If protective equipment is not available or
Ingestion: Harmful effects not anticipated from swallowing small not used, fight fire from a protected location or safe distance.
amounts. Very low toxicity if swallowed. FIRE & EXPLOSION HAZARDS: This material will not burn
Effects of Repeated Exposure: For the active until the water has evaporated. Residue can burn. If exposed to
ingredient, Penoxsulam, effects have been reported on the kidney fire from another source and water is evaporated, exposure to
and liver of animals. high temperatures may cause toxic fumes.
HAZARDOUS COMBUSTION PRODUCTS: Under fire
3. COMPOSITION / INFORMATION ON INGREDIENTS conditions some components of this product may decompose.
The smoke may contain unidentified toxic and/or irritating
INGREDIENTS CAS NO. W/W%
compounds. Combustion products may include and are not
Penoxsulam 219714-96-2 21.7
limited to: sulfur oxides, nitrogen oxides, hydrogen fluoride,
Propylene glycol 57-55-6 4.5
fluorinated hydrocarbons, carbon monoxide, carbon dioxide.
Other Ingredients, Totaling 73.8
6. ACCIDENTAL RELEASE MEASURES
4. FIRST AID MEASURES
ACTION TO TAKE FOR SPILLS/LEAKS: Contain spilled
EYE CONTACT: Hold eyes open and rinse slowly and gently
material if possible. For small spills, absorb with a material such
with water for 15 - 20 minutes. Remove contact lenses, if
as clay, dirt, sand, or Zorb-all庐. Collect in suitable and properly
present, after the first 5 minutes, then continue rinsing eyes.
labeled containers. For large spills, report to INFOTRAC at
Call a poison control center or doctor for treatment advice.
1-800-535-5053 and contact SePRO Corporation.
漏 Copyright 2007 SePRO Corporation.
Material Safety Data Sheet
Transportation and Medical Emergency Phone: 1-800-535-5053
General Phone: 317-580-8282
EPA Reg. Number: 62719-546-67690
Effective Date: 07/24/2007
Galleon* SC Aquatic Herbicide SePRO Corporation Carmel, IN 46032-4565
PERSONAL PRECAUTIONS: Use appropriate safety
9. PHYSICAL AND CHEMICAL PROPERTIES
equipment. For additional information, refer to Section 8,
鈥淓xposure Controls and Personal Protection鈥?.
COLOR AND PHYSICAL STATE: Tan Liquid
ENVIRONMENTAL PRECAUTIONS: Prevent from entering into ODOR: Musty
soil, ditches, sewers, waterways and/or groundwater. See Section FLASHPOINT (cc): >100掳C (>212掳F)
12, 鈥淓cological Information鈥?. FLAMMABLE LIMITS (upper/lower): Not determined
AUTOIGNITION TEMPERATURE: Not determined
VAPOR PRESSURE: Not determined
7. HANDLING AND STORAGE
BOILING POINT (760 mmHG): Not determined
HANDLING: Keep out of reach of children. Do not swallow. VAPOR DENSITY (Air = 1): Not determined
Avoid breathing vapor or mist. Avoid contact with eyes, skin, and SPECIFIC GRAVITY (H2O = 1): Not determined
clothing. Use with adequate ventilation. Wash thoroughly after LIQUID DENSITY: 1.11 g/cm3 Calculated; 1.104 g/cm3 Calculated
handling. FREEZING POINT: Not determined
MELTING POINT: Not determined
STORAGE: Store in a dry place. Store in original container.
SOLUBILITY IN WATER (by weight): Not determined
Keep container tightly closed when not in use. Do not store near
pH: 4.7 Electrode
food, foodstuffs, drugs or potable water supplies.
10. STABILITY AND REACTIVITY
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
STABILITY: Thermally stable at typical use temperatures.
EXPOSURE LIMITS:
Conditions to Avoid: Some components of this product
鈥? Propylene glycol: AIHA WEEL is 10 mg/m3 TWA Aerosol
can decompose at elevated temperatures.
Incompatible Materials: Avoid contact with any oxidizing
RECOMMENDATIONS IN THIS SECTION ARE FOR
agent.
MANUFACTURING, COMMERCIAL BLENDING, AND
HAZARDOUS POLYMERIZATION: Not known to occur.
PACKAGING WORKERS. APPLICATORS AND ALL OTHER
HANDLERS SHOULD REFER TO THE PRODUCT LABEL THERMAL DECOMPOSITION: Decomposition products
FOR PROPER PERSONAL PROTECTIVE EQUIPMENT AND depend upon temperature, air supply and the presence of other
CLOTHING. materials. Gases are released during decomposition.
PERSONAL PROTECTION 11. TOXICOLOGICAL INFORMATION
Eye/Face Protection: Use safety glasses.
ACUTE TOXICITY:
Skin Protection: No precautions other than clean body-cov-
Ingestion: LD50, Rat >5,000 mg/kg
ering clothing should be needed. Chemical protective gloves
Skin Absorption: LD50, Rat >5,000 mg/kg
should not be needed when handling this material. Consistent
Inhalation: Maximum attainable concentration. LC50, 4-hour,
with general hygienic practice for any material, skin contact
Aerosol, Rat >0.74 mg/L
should be minimized.
SENSITIZATION:
Respiratory Protection: Atmospheric levels should be main-
Skin: Did not cause allergic skin reactions when tested in guinea
tained below the exposure guideline. In dusty or misty atmos-
pigs.
pheres, use an approved particulate respirator. The following
REPEATED DOSE TOXICITY: For the active ingredient,
should be an effective type of air-purifying respirator: organic
Penoxsulam, effects have been reported on the kidney and liver of
vapor cartridge with a particulate pre-filter.
animals.
Ingestion: Use good personal hygiene. Do not consume or
CHRONIC TOXICITY AND CARCINOGENICITY: The active ingre-
store food in the work area. Wash hands before smoking or
dient did not cause cancer in laboratory animals.
eating.
DEVELOPMENTAL TOXICITY: The active ingredient did not cause
Engineering Controls: Provide general and/or local exhaust
birth defects in laboratory animals.
ventilation to control airborne levels below the exposure guide-
lines. REPRODUCTIVE TOXICITY: In animal studies, the active ingredi-
ent did not interfere with reproduction.
GENETIC TOXICITY: In vitro genetic toxicity studies were negative.
Animal genetic studies were negative.
漏 Copyright 2007 SePRO Corporation.
2
Material Safety Data Sheet
Transportation and Medical Emergency Phone: 1-800-535-5053
General Phone: 317-580-8282
EPA Reg. Number: 62719-546-67690
Effective Date: 07/24/2007
Galleon* SC Aquatic Herbicide SePRO Corporation Carmel, IN 46032-4565
Biological Oxygen Demand (BOD):
12. ENVIRONMENTAL INFORMATION
BOD 5 BOD10 BOD20 BOD28
CHEMICAL FATE: 69% 70% 86%
Data for Component: Penoxsulam
Chemical Oxygen Demand: 1.53 mg/mg
Movement and Partitioning
Theoretical Oxygen Demand: 1.68 mg/mg
Bioconcentration potential is low (BCF <100 or log Pow <3).
Potential for mobility in soil is high (Koc between 50 and 150).
ECOTOXICITY:
Henry鈥檚 Law Constant (H): 1.66E-16 atm*m3/mole; 25掳C
Estimated
Data for Component: Penoxsulam
Partition Coefficient, n-octanol/water (Iog Pow): -0.354
Material is very highly toxic to aquatic organisms on an acute basis
Measured
(LC50/EC50 <0.1 mg/L in most sensitive species). Material is practi-
Partition Coefficient, soil organic carbon/water (Koc):
cally non-toxic to birds on an acute basis (LD50 >2,000 mg/kg).
104 Measured
Fish Acute & Prolonged Toxicity: LC50, rainbow trout
Persistence and Degradability
(Oncorhynchus mykiss), static, 96-hour is >100 mg/L
Indirect Photodegradation with OH Radicals:
Aquatic Invertebrate Acute Toxicity: EC50, water flea (Daphnia
magna), static, 48-hour, immobilization is >100 mg/L
Rate Constant Atmospheric Half-life Method
Aquatic Plant Toxicity: EC50, green alga (Selenastrum capricor-
6.03E cm /s 2.1 hours Estimated
-11 3
nutum), biomass growth inhibition, 96-hour is 0.0864 mg/L
Toxicity to Microorganisms: EC50, activated sludge, activated
Data for Component: Propylene glycol
sludge test (OECD 209), respiration inhibition, 3-hour is >1,000
Movement and Partitioning
mg/L
Bioconcentration potential is low (BCF <100 or log Pow <3).
Potential for mobility in soil is very high (Koc between 0 and 50).
Fish Chronic Toxicity Value (ChV):
Given its very low Henry鈥檚 Constant, volatilization from natural bod-
ies of water or moist soil is not expected to be an important fate
process. ChV Value Exposure
Species Test Type Endpoint
Henry鈥檚 Law Constant (H): 1.2E-8 atm*m3/mole Measured (mg/l) Time
Partition Coefficient, n-octanol/water (Iog Pow):
Fathead min-
-0.92 Measured now
>10.2 Flow-through Growth 36 days
Partition Coefficient, soil organic carbon/water (Koc): (Pimephales
< 1 Estimated promelas)
Persistence and Degradability
Aquatic Invertebrates Chronic Toxicity Value:
Material is readily biodegradable. Passes OECD test(s) for ready
biodegradability. Biodegradation may occur under anaerobic con-
ditions (in the absence of oxygen). ChV Value Exposure
Species Test Type Endpoint
(mg/l) Time
Indirect Photodegradation with OH Radicals:
Water flea
Number of off-
Rate Constant Atmospheric Half-life Method
5.37 (Daphnia Static renewal 21 days
spring
magna)
1.28E cm /s 10 hours Estimated
-11 3
Saltwater
OECD Biodegradation Tests:
mysid
41.8 Flow-through Survival 28 days
(Mysidopsis
Biodegradation Exposure Time Method
bahia)
81% 28 days OECD 301F Test
95.8% 64 days OECD 306 Test
漏 Copyright 2007 SePRO Corporation.
3
Material Safety Data Sheet
Transportation and Medical Emergency Phone: 1-800-535-5053
General Phone: 317-580-8282
EPA Reg. Number: 62719-546-67690
Effective Date: 07/24/2007
Galleon* SC Aquatic Herbicide SePRO Corporation Carmel, IN 46032-4565
Toxicity to Non-mammalian Terrestrial Species:
15. REGULATORY INFORMATION
Dietary LC50, mallard duck (Anas platyrhynchos) >4,310 ppm
Oral LD50, bobwhite quail (Colinus virginianus) >2,025 mg/kg OSHA HAZARD COMMUNICATION STANDARD: This product
Contact LD50, Honey bee (Apis mellifera) >100 micrograms/bee
is a "Hazardous Chemical" as defined by the OSHA Hazard
Oral LD50, Honey bee (Apis mellifera) >110 micrograms/bee
Communication Standard, 29 CFR 1910.1200.
Toxicity to Soil Dwelling Organisms: SARA HAZARD CATEGORY: This product has been reviewed
LC50, Earthworm (Eisenia foetida), adult, 14-day >1,000 mg/kg according to the EPA "Hazard Categories" promulgated under
Sections 311 and 312 of the Superfund Amendment and
Data for Component: Propylene glycol Reauthorization Act of 1986 (SARA Title III) and is considered,
Material is practically non-toxic to aquatic organisms on an acute under applicable definitions, to meet the following categories:
basis (LC50/EC50 >100 mg/L in most sensitive species tested).
鈥? A delayed health hazard
Fish Acute & Prolonged Toxicity: LC50, rainbow trout SARA 313 INFORMATION: To the best of our knowledge, this
(Oncorhynchus mykiss), 96-hour is 44,000 鈥? 51,600 mg/L product contains no chemicals at levels which require reporting
under SARA Title III Section 313 supplier notification require-
Aquatic Invertebrate Acute Toxicity: EC50, water flea
ments.
(Daphnia magna), 48-hour, immobilization is 4,850 - 34,000 mg/L
STATE RIGHT-TO-KNOW: The following product components
LC50, Saltwater mysid (Mysidopsis bahia), static, 96-hour is
are cited on certain state lists as mentioned.
18,800 mg/L
CHEMICAL NAME CAS NUMBER LIST
Aquatic Plant Toxicity: EC50, green alga (Selenastrum capricor-
Propylene glycol 57-55-6 PA1, PA3
nutum), biomass growth inhibition is 19,000 mg/L
PA1 = Pennsylvania Hazardous Substances List
Toxicity to Microorganisms: EC50, activated sludge (OECD 209 (present at > or = to 1.0%).
Test), respiration inhibition, 3-hour is >1,000 mg/L PA3 = Pennsylvania Environmental Hazardous Substance List
(present at > or = to 1.0%).
13. DISPOSAL CONSIDERATIONS
TOXIC SUBSTANCES CONTROL ACT (TSCA): All components
of this product are either on the TSCA Inventory, are exempt from
If wastes and/or containers cannot be disposed of according to
TSCA Inventory Requirements under 40 CFR 720.30, or comply
the product label directions, disposal of this material must be in
with the PMN Polymer Exemption 40 CFR 723.250.
accordance with your local or area regulatory authorities.
This information presented below only applies to the material as 16. OTHER INFORMATION
supplied. The identification based on characteristic(s) or listing
may not apply if the material has been used or otherwise con- NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) RAT-
taminated. It is the responsibility of the waste generator to INGS:
determine the toxicity and physical properties of the material
CATEGORY RATING
generated and to determine the proper waste identification and
Health 1
disposal methods in compliance with applicable regulations. If
Flammability 0
the material as supplied becomes a waste, follow all applicable
Reactivity 0
regional, national and local laws and regulations.
MSDS STATUS:
14. TRANSPORT INFORMATION Creation Date: 07/24/07
LEGEND:
DOT Non-Bulk: Not Regulated
DOT Bulk: Not Regulated W/W Weight/Weight
IMDG: Not Regulated TWA Time Weighted Average
ICAO/IATA: Not Regulated WEEL Workplace Environmental Exposure Level
This information is not intended to convey all specific regulatory
or operational requirements/information relating to this product. The information herein is provided in good faith and believed to be accurate as of the
For additional shipping information contact SePRO Corporation effective date shown above. However, no warranty, express or implied, is given.
at 317-580-8282 and speak with the Logistics Manager. It is the Regulatory requirements are subject to change and may differ from one location to
responsibility of the transporting organization to follow all appli- another. It is the buyer鈥檚/user鈥檚 responsibility to ensure that his activities comply with
cable laws, regulations and rules relating to the transportation all federal, state, provincial, or local laws. The information presented here pertains
of this material. only to the product as shipped.
漏 Copyright 2007 SePRO Corporation.
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