Material Safety Data Sheet
Transportation and Medical Emergency Phone: 1-800-535-5053 (INFOTRAC)
General Phone: 317-580-8282
EPA Reg. No.: 67690-42
Creation Date: 11/16/2006
Renovate庐 OTF Aquatic Herbicide SePRO Corporation Carmel, IN 46032-4565
INGESTION: Call a poison control center or doctor immediately
1. PRODUCT AND COMPANY IDENTIFICATION
for treatment advice. Have person sip a glass of water if able to
swallow. Do not induce vomiting unless told to do so by a poison
PRODUCT: Renovate OTF Aquatic Herbicide
control center or doctor. Do not give anything by mouth to an
unconscious person.
COMPANY IDENTIFICATION:
SePRO Corporation
INHALATION: Move person to fresh air. If person is not
11550 North Meridian Street, Suite 600
breathing, call 911 or an ambulance, then give artificial respiration,
Carmel, IN 46032-4565
preferably mouth-to-mouth. Call a poison control center or doctor
www.sepro.com
for further treatment advice.
Information Phone: 317-580-8282 (Monday - Friday, 8:00 am to 5:00 pm EST)
2. HAZARDOUS IDENTIFICATIONS 5. FIRE FIGHTING MEASURES
FLASH POINT & METHOD USED: Not Applicable
EMERGENCY OVERVIEW
FLAMMABLE LIMITS: Not Applicable
Light gray, coarse flowable granule. Ammonia-like odor.
鈥? May cause moderate eye irritation. Avoid contact with eyes or
EXTINGUISHING MEDIA: Alcohol foam or carbon dioxide.
clothing.
鈥? Inhalation of excessive concentrations of dust may cause
FIRE-FIGHTING EQUIPMENT: Use positive-pressure,
irritation of mucous membranes and upper respiratory tract.
self-contained breathing apparatus and full protective clothing.
鈥? Triclopyr did not cause cancer in laboratory animals. This
product contains clay that has naturally occurring crystalline
FIRE AND EXPLOSION HAZARDS: This product does not
silica as quartz. Crystalline silica is listed by ACGIH, NIOSH,
normally present a fire or explosion hazard, however, at
NTP and IARC as a carcinogen for hazard communication
,
concentrations exceeding 01. oz/ft3 dusts can be ignited by
purposes under OSHA Standard 29 CFR part 1910.1200.7.
sparks or other ignition sources. Minimize hazard by avoiding the
Inhalation of excessive concentrations of any dust, including
generation of airborne dusts, electrically grounding equipment to
this material, may lead to lung injury.
prevent static sparks and by eliminating ignition sources in the
鈥? Acute Oral LD50 (rat) > 5,000 mg/kg.
work area. Combustion products may be hazardous.
鈥? Acute Dermal LD50 (rat) > 5,000 mg/kg.
鈥? Acute Inhalation LD50 (rat) > 2.04 mg/L.
鈥? Not considered to be a contact sensitizer. 6. ACCIDENTAL RELEASE MEASURES
EMERGENCY PHONE NUMBER: 1-800-535-5053
ACTION TO TAKE FOR SPILLS/LEAKS: Sweep up
small spills and dispose of as waste. Report large spills to
INFOTRAC at 1-800-535-5053 and consult SePRO
Corporation for assistance.
3. COMPOSITION / INFORMATION ON INGREDIENTS
COMPONENT CAS NUMBER W/W%
7. HANDLING AND STORAGE
Triclopyr TEA 057213-69-1 14%
Clay (Crystalline Silica) 14808-60-7 86% PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
Handling: Avoid contact with eyes or clothing. Avoid breathing
dust. Users should wash hands before eating, drinking, chewing
4. FIRST AID MEASURES
gum, using tobacco, or using the toilet.
EYES: Hold eye open and rinse slowly and gently with water for
15 - 20 minutes. Remove contact lenses, if present, after the first Storage: Store in dry area, in original container. Do not
5 minutes, then continue rinsing eye. Call a poison control center contaminate food, feed, or water by storage or disposal.
or doctor for treatment advice.
Keep out of reach of children.
SKIN: Take off contaminated clothing. Rinse skin immediately
with plenty of water for 15 - 20 minutes. Call a poison control
center or doctor for treatment advice.
Renovate is a registered trademark of Dow AgroSciences, LLC. 漏 Copyright 2008 SePRO Corporation.
Material Safety Data Sheet
Transportation and Medical Emergency Phone: 1-800-535-5053 (INFOTRAC)
General Phone: 317-580-8282
EPA Reg. No.: 67690-42
Creation Date: 11/16/2006
Renovate庐 OTF Aquatic Herbicide SePRO Corporation Carmel, IN 46032-4565
8. EXPOSURE CONTROL/PERSONAL PROTECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
These precautions are suggested for conditions where the APPEARANCE: Light gray, coarse flowable granule
potential for exposure exists. Emergency conditions may ODOR: Ammonia-like odor
require additional precautions. BULK DENSITY: 0.676 卤 0.007 g/mL
pH (1% @ 20掳C): 7.81 卤 0.07
EXPOSURE GUIDELINE(S):
鈥? Triclopyr TEA: The Industrial Hygiene Guideline is 2 mg/M3 as
10. STABILITY AND REACTIVITY
acid equivalent; Skin.
鈥? Crystalline silica: ACGIH TLV is 0.05 mg/m3 TWA; OSHA PEL is STABILITY Stable under normal storage conditions.
10 mg/m3 /% SiO2 +2 TWA.
INCOMPATIBILITY (Specific materials to avoid): Contact of dry
A "skin" notation following the exposure guideline refers to the clay with turpentine, vegetable oil or other unsaturated organic
potential for dermal absorption of the material including mucous compounds, or with hydrofluoric acid may generate heat and/or
membranes and the eyes either by contact with vapors or by fire. Do not use with these compounds.
direct skin contact. It is intended to alert the reader that inhalation
may not be the only route of exposure and that measures to HAZARDOUS DECOMPOSITION PRODUCTS: Nitrogen oxides
minimize dermal exposures should be considered. and hydrogen chloride may be formed under fire conditions.
ENGINEERING CONTROLS: Provide general and/or local HAZARDOUS POLYMERIZATION: Not known to occur.
exhaust ventilation to control airborne levels below the exposure
guidelines.
11. TOXICOLOGICAL INFORMATION
RECOMMENDATIONS FOR MANUFACTURING,
POTENTIAL HEALTH EFFECTS
COMMERCIAL BLENDING, AND PACKAGING WORKERS:
This section includes possible adverse effects, which could occur if
this material is not handled in the recommended manner.
EYE PROTECTION: Safety glasses or chemical goggles are
recommended.
EYE: May cause moderate eye irritation.
SKIN PROTECTION: None required for normal use. SKIN : Product is essentially non-irritating to the skin. Acute
Dermal LD50 (rat) > 5,000 mg/kg. Not considered to be a contact
RESPIRATORY PROTECTION: Atmospheric levels should be sensitizer.
maintained below the exposure guideline. For operations where
the exposure limit may be exceeded, a NIOSH approved high INGESTION: Low to non-existent toxicity if swallowed. Acute Oral
efficiency particulate respirator is recommended. LD50 (rat) > 5,000 mg/kg.
APPLICATORS AND ALL OTHER HANDLERS: Refer to the INHALATION: Inhalation of excessive concentrations of dust may
product label for personal protective clothing and equipment. cause irritation of mucous membranes and upper respiratory tract.
Acute Inhalation LC50 (rat) > 2.04 mg/L.
CHRONIC: Excessive exposure may cause liver or kidney
effects. Inhalation of excessive concentrations of dust, including
this material, may lead to lung injury. This product contains
trace amounts of crystalline silica. Excessive inhalation of
respirable crystalline silica may cause silicosis, a progressive,
disabling and fatal disease of the lung. Symptoms may include
cough, shortness of breath, wheezing and reduced pulmonary
function. Because the company is not aware of any scientific
or medical data available indicating that exposure to dust from
this product under conditions of normal use will cause silicosis,
adverse effects would not be expected form normal use of this
product.
Renovate is a registered trademark of Dow AgroSciences, LLC. 漏 Copyright 2008 SePRO Corporation.
2
Material Safety Data Sheet
Transportation and Medical Emergency Phone: 1-800-535-5053 (INFOTRAC)
General Phone: 317-580-8282
EPA Reg. No.: 67690-42
Creation Date: 11/16/2006
Renovate庐 OTF Aquatic Herbicide SePRO Corporation Carmel, IN 46032-4565
CANCER INFORMATION: Triclopyr did not cause cancer in
13. DISPOSAL CONSIDERATIONS
laboratory animal studies. This product contains trace amounts
of crystalline silica. The International Agency for Research on
PESTICIDE DISPOSAL: Do not contaminate food, feed, or water
Cancer (IARC), in Monograph 68, has concluded that
by storage or disposal. Wastes resulting from the use of this
crystalline silica inhaled in the form of quartz or cristobalite,
product must be disposed of on site or at an approved waste
from occupational sources, is carcinogenic to humans (Group
disposal facility.
1). However, in making the overall evaluation, the Working
group noted that carcinogenicity was not detected in all
CONTAINER DISPOSAL: Do not reuse container. Triple rinse
industrial circumstances studied. Carcinogenicity may be
(or equivalent). Then offer for recycling or reconditioning, or
dependent on inherent characteristics of the crystalline silica or
puncture and dispose of in a sanitary landfill, or by incineration, or,
on external factors affecting its biological activity or distribution
if allowed by state and local authorities, by burning. If burned, stay
of its polymorphs. The National Toxicology Program (NTP)
out of smoke.
classifies crystalline silica as reasonably anticipated to be a
carcinogen. Because applications and exposure data indicate
that exposure to respirable quartz in this product, with normal
14. TRANSPORT INFORMATION
use, is well below the OSHA Permissible Exposure Limit (PEL)
and ACGIH Threshold Limit Value (TLV), and because the
Department of Transportation (DOT) Not Regulated
company is not aware of any scientific or medical data available
indicating that exposure to dust from this product under
International Air Transport Not Regulated
conditions of normal use will cause cancer, adverse effects
Association (IATA)
would not be expected form normal use of this product.
International Maritime Not Regulated
TERATOGENICITY (BIRTH DEFECTS): For triclopyr, birth
Organization (IMO)
defects are unlikely. Even exposures having an adverse effect on
the mother should have no effect on the fetus.
For additional shipping information contact SePRO Corporation
at 317-580-8282 and speak with the Logistics Manager.
REPRODUCTIVE EFFECTS: For triclopyr, in laboratory animal
studies, effects on reproduction have been seen only at doses that
produced significant toxicity to the parent animals.
MUTAGENICITY: For triclopyr, in-vitro genetic toxicity studies and
animal genetic toxicity studies were negative.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL FATE: Based largely or completely on
information for triclopyr.
MOVEMENT & PARTITIONING: Bioconcentration potential is low
(BCF <100 or Log Pow <3).
DEGRADATION & PERSISTENCE:
鈥? Biodegradation under aerobic static laboratory conditions is high
(BOD20 or BOD28/ThOD >40%).
鈥? The 20-Day biochemical oxygen demand (BOD20) is 0.30 p/p.
鈥? Theoretical oxygen demand (ThOD) is calculated to be 0.75 p/p.
ECOTOXICOLOGY: Material is slightly toxic to aquatic organisms
on an acute basis (LC50 or EC50 is between 10 and 100 mg/L in
most sensitive species).
Renovate is a registered trademark of Dow AgroSciences, LLC. 漏 Copyright 2008 SePRO Corporation.
3
Material Safety Data Sheet
Transportation and Medical Emergency Phone: 1-800-535-5053 (INFOTRAC)
General Phone: 317-580-8282
EPA Reg. No.: 67690-42
Creation Date: 11/16/2006
Renovate庐 OTF Aquatic Herbicide SePRO Corporation Carmel, IN 46032-4565
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA 701) and
15. REGULATORY INFORMATION
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS):
(4 = Extreme; 3 = High; 2 = Moderate; 0 = Insignificant)
NOTICE: The information herein is presented in good faith and
believed to be accurate as of the effective date shown above.
Category Rating
However, no warranty, express or implied, is given. Regulatory
Health 1
requirements are subject to change and may differ from one
Flammability 0
location to another; it is the buyer鈥檚 responsibility to ensure that its
Reactivity 0
activities comply with federal, state or provincial, and local laws.
The following specific information is made for the purpose of
COMPREHENSIVE ENVIRONMENTAL RESPONSE
complying with numerous federal, state or provincial, and local
COMPENSATION AND LIABILITY ACT
laws and regulations.
(CERCLA, OR SUPERFUND): To the best of our knowledge, this
U.S. REGULATIONS product contains no chemical subject to reporting under CERCLA.
SARA 313 INFORMATION: To the best of our knowledge, this
16. OTHER INFORMATION, USES AND RESTRICTIONS
product contains no chemical subject to SARA Title III Section 313
supplier notification requirements. MSDS STATUS:
Creation Date: 11/16/2006
SARA HAZARD CATEGORY: This product has been reviewed
according to the EPA "Hazard Categories" promulgated under
Sections 311 and 312 of the Superfund Amendment and
Reauthorization Act of 1986 (SARA Title III) and is considered,
under applicable definitions, to meet the following categories:
The Information Herein Is Given In Good Faith, But No
鈥? An Immediate Health Hazard
Warranty, Express or Implied, Is Made. Consult SePRO
鈥? A Delayed Health Hazard
Corporation for Further Information.
TOXIC SUBSTANCES CONTROL ACT (TSCA): All components
are on the TSCA inventory or are not required to be listed on the
TSCA inventory.
STATE RIGHT-TO-KNOW: The product is not known to contain
any substances subject to the disclosure requirements of:
鈥? New Jersey
鈥? Pennsylvania
CALIFORNIA PROPOSITION 65: The following statement is
made in order to comply with the California Safe Water and
Toxic Enforcement Act of 1986: This product contains respirable
crystalline silica, which is known to the State of California to
cause cancer. (See section 11 of the MSDS for details on
carcinogenicity.)
OSHA HAZARD COMMUNICATION STANDARD: This product
is a "Hazardous Chemical" as defined by the OSHA Hazard
Communication Standard, 29 CFR 1910.1200.
Renovate is a registered trademark of Dow AgroSciences, LLC. 漏 Copyright 2008 SePRO Corporation.
4
Revised 3/13/08.
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