2/17/99 MSDS No.: US-W8
Date:
6/13/97
Supersedes:
L-52
Trade Name:
All
Sizes:
MATERIAL SAFETY DATA SHEET
For Welding Consumables and Related Products
Conforms to Hazard Communication Standard 29CFR 1910.1200 Rev. October 1988
SECTION I - IDENTIFICATION
Manufacturer/ Product Type: Carbon Steel Electrode
Supplier: The Lincoln Electric Company
22801 St. Clair Avenue
Cleveland, OH 44117-1199 Classification: AWS ER70S-2
(216) 481-8100
SECTION II - HAZARDOUS MATERIALS (1)
IMPORTANT!
This section covers the materials from which this product is manufactured. The fumes and gases produced during welding with the
normal use of this product are covered by Section V; see it for industrial hygiene information.
CAS Number shown is representative for the ingredients listed.
(1) The term 'hazardous' in 'Hazardous Materials' should be interpreted as a term required and defined in the Hazards Communication
Standard and does not necessarily imply the existence of any hazard.
TLV PEL
mg/m3 mg/m3
Ingredients: CAS No. Wt.%
Carbon steel wire 100 10* 10*
Nominal wire composition:
Total manganese *** 7439-96-5 1 0.2 1.0(c)
Total copper including plated coating *** 7440-50-8 < 0.5 0.2(a) 0.1(a)
Titanium 12719-90-3 < 0.5 10* 10*
Aluminum *** 7429-90-5 < 0.5 10 15
Zirconium 12004-83-0 < 0.5 5 5
Iron 7439-89-6 bal. 10* 10*
(c) Values are for manganese fume. STEL (Short Term Exposure
Supplemental Information: (*) Not listed. Nuisance value
Limit) is 3.0 milligrams per cubic meter.
maximum is 10 milligrams per cubic meter. PEL value for iron
oxide is 10 mg/m3. TLV value for iron oxide is 5 milligrams per (a) values are for copper fumes.
cubic meter.
(***) Subject to the reporting requirements of Sections 311, 312, and
313 of the Emergency Planning and Community Right-to-Know
Act of 1986 and of 40CFR 370 and 372.
SECTION III - FIRE AND EXPLOSION HAZARD DATA
Non Flammable; Welding arc and sparks can ignite combustibles and flammable products. See Z49.1 referenced in Section VI.
(CONTINUED ON SIDE TWO)
Product: L-52
Date: 2/17/99
SECTION IV - HEALTH HAZARD DATA
Threshold Limit Value: The ACGIH recommended general limit for Welding Fume NOC - (Not Otherwise Classified) is 5 mg/m3.
ACGIH-1987-88 preface states that the TLV-TWA should be used as guides in the control of health hazards and should not be used as fine lines
between safe and dangerous concentrations. See Section V for specific fume constituents which may modify this TLV. Threshold Limit Values are
figures published by the American Conference of Government Industrial Hygienists. Units are milligrams per cubic meter of air.
Effects of Overexposure: Electric arc welding may create one or more of the following health hazards:
Fumes and Gases can be dangerous to your health. Common entry is by inhalation. Other possible routes are skin contact and ingestion.
Short-term (acute) overexposure to welding fumes may result in discomfort such as metal fume fever, dizziness, nausea, or
dryness or irritation of nose, throat, or eyes. May aggravate pre-existing respiratory problems (e.g. asthma, emphysema).
Long-term (chronic) overexposure to welding fumes can lead to siderosis (iron deposits in lung) and may affect pulmonary
function. Manganese overexposure can affect the central nervous system, resulting in impaired speech and movement.
Bronchitis and some lung fibrosis have been reported. WARNING: This product, when used for welding or cutting, produces
fumes or gases which contain chemicals known to the State of California to cause birth defects and, in some cases, cancer.
(California Health & Safety Code Section 25249.5 et seq).
Arc Rays can injure eyes and burn skin. Skin cancer has been reported.
Electric Shock can kill. If welding must be performed in damp locations or with wet clothing, on metal structures or when in cramped positions such
as sitting, kneeling or lying, if there is a high risk of unavoidable or accidental contact with workpiece, use the following equipment: Semiautomatic
DC Welder, DC Manual (Stick) Welder, or AC Welder with Reduced Voltage Control.
Emergency and First Aid Procedures: Call for medical aid. Employ first aid techniques recommended by the American Red Cross.
IF BREATHING IS DIFFICULT give oxygen. IF NOT BREATHING employ CPR (Cardiopulmonary Resuscitation) techniques.
IN CASE OF ELECTRICAL SHOCK, turn off power and follow recommended treatment. In all cases call a physician.
SECTION V - REACTIVITY DATA
Hazardous Decomposition Products: Welding fumes and gases cannot be classified simply. The composition and quantity of both are
dependent upon the metal being welded, the process, procedure and electrodes used.
Other conditions which also influence the composition and quantity of the fumes and gases to which workers may be exposed
include: coatings on the metal being welded (such as paint, plating, or galvanizing), the number of welders and the volume of the
worker area, the quality and amount of ventilation, the position of the welder's head with respect to the fume plume, as well as the
presence of contaminants in the atmosphere (such as chlorinated hydrocarbon vapors from cleaning and degreasing activities.)
When the electrode is consumed, the fume and gas decomposition products generated are different in percent and form from the
ingredients listed in Section II. Decomposition products of normal operation include those originating from the volatilization,
reaction, or oxidation of the materials shown in Section II, plus those from the base metal and coating, etc., as noted above.
Reasonably expected fume constituents of this product would include: Primarily iron oxide; secondarily complex oxides of
copper, manganese and silicon when used with gas shielding.
Maximum fume exposure guideline for this product (based on manganese content) is 2.5 milligrams per cubic meter.
Gaseous reaction products may include carbon monoxide and carbon dioxide. Ozone and nitrogen oxides may be formed by the radiation
from the arc.
Determine the composition and quantity of fumes and gases to which workers are exposed by taking an air sample from inside the welder's helmet if
worn or in the worker's breathing zone. Improve ventilation if exposures are not below limits. See ANSI/AWS F1.1, F1.2, F1.4, and F1.5, available from
the American Welding Society, 550 N.W. LeJeune Road, Miami, FL 33126.
SECTION VI AND VII
CONTROL MEASURES AND PRECAUTIONS FOR SAFE HANDLING AND USE
Read and understand the manufacturer's instruction and the precautionary label on the product. Request Lincoln Safety Publication E205. See
American National Standard Z49.1, 'Safety In Welding and Cutting' published by the American Welding Society, 550 N.W. LeJeune Road, Miami, FL, 33126
and OSHA Publication 2206 (29CFR1910), U.S. Government Printing Office, Washington, D.C. 20402 for more details on many of the following:
Ventilation: Use enough ventilation, local exhaust at the arc, or both to keep the fumes and gases from the worker's breathing zone and the general
area. Train the welder to keep his head out of the fumes. Keep exposure as low as possible.
Respiratory Protection: Use respirable fume respirator or air supplied respirator when welding in confined space or general work area when local
exhaust or ventilation does not keep exposure below TLV.
Eye Protection: Wear helmet or use face shield with filter lens shade number 12 or darker. Shield others by providing screens and flash goggles.
Protective Clothing: Wear hand, head, and body protection which help to prevent injury from radiation, sparks and electrical shock. See Z49.1.
At a minimum this includes welder's gloves and a protective face shield, and may include arm protectors, aprons, hats, shoulder protection, as well as
dark substantial clothing. Train the welder not to permit electrically live parts or electrodes to contact skin . . . or clothing or gloves if they are wet.
Insulate from work and ground.
Disposal Information: Discard any product, residue, disposable container, or liner as ordinary waste in an environmentally acceptable manner
according to Federal, State and Local Regulations unless otherwise noted.
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