Product Name: Spray-A-Gasket(R) Copper High Temp. Adh. Slnt. Page 1 of 5
LOCTITE CORPORATION 10/20/98
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 01 of 05
Spray-A-Gasket(R) Copper High Temp. Adh. Slnt.
80697
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Item No.: 80697
Part No.: 101MA
Product Type: Aerosol Sealant
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
ACETONE 67-64-1 25-35
METHYLENE CHLORIDE* 75-09-2 10-20
V, M, & P NAPHTHA 8032-32-4 1-5
ETHYL ACETATE 141-78-6 1-10
COPPER* 7440-50-8 1-5%
PROPANE 74-98-6 5-50
BUTANE 106-97-8 5-50
* This component is listed as a SARA Section 313 Toxic Chemical.
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
ACETONE 500 ppm TWA 750 ppm TWA None
1188 mg/m3 1800 mg/m3
METHYLENE CHLORIDE 50 ppm TWA 25 ppm TWA None
174 mg/m3
V, M, & P NAPHTHA 300 ppm 300 ppm None
1370 mg/m3 1350 mg/m3
ETHYL ACETATE 400 ppm TWA 400 ppm TWA None
1440 mg/M3 1400 mg/M3
COPPER 1 mg/m3 dust 1 mg/m3 dust None
PROPANE 2500 ppm 1000 ppm None
1800 mg/m3
BUTANE 800 ppm TWA 800 ppm TWA None
1900mg/M3 1900mg/M3
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
ACETONE 750 ppm 1000 ppm
1782 mg/m3 2400 mg/m3
METHYLENE CHLORIDE None 125 ppm
V, M, & P NAPHTHA None 400 ppm
1800mg/m3
LOCTITE CORPORATION 10/20/98
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 02 of 05
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Product Name: Spray-A-Gasket(R) Copper High Temp. Adh. Slnt. Page 2 of 5
Item No.: 80697
2. COMPOSITION, INFORMATION ON INGREDIENTS (continued)
PROPANE Asphyxiant Asphyxiant
3. HAZARDS IDENTIFICATION
Toxicity: May cause transient irritation in eyes. High
concentrations may cause nasal and respiratory
irritation.
Primary Routes of Entry: Inhalation, Ingestion
Signs and Symptoms
of Exposure: May cause transient irritation in eyes. High
concentrations may cause nasal and respiratory
irritation
Existing Conditions
Aggravated by Exposure: Cardiovascular system
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
ACETONE AC4 BLO CNS IRR NO NO NO
METHYLENE CHLORIDE AC3 CNS IRR LIV YES 2B YES
V, M, & P NAPHTHA AC3 CNS IRR NO NO NO
ETHYL ACETATE AC4 CNS IRR NO NO NO
COPPER BLO CNS GAS IMM IRR KID LIV MUT NO NO NO
SEN SKI
PROPANE CAR CNS IRR NO NO NO
BUTANE CAR CNS IRR NO NO NO
-------------------------------------------------------------------------------
Abbreviations
2B Possibly carcinogenic to humans AC3 ACGIH animal carcinogen.
AC4 ACGIH-Unclassifiable as human carc. BLO Blood
CAR Cardiac CNS Central nervous system
GAS Gastrointestinal IMM Immune system
IRR Irritant KID Kidney
LIV Liver MUT Mutagen
SEN Sensory SKI Skin
4. FIRST AID MEASURES
Ingestion: Do not induce vomiting. Get medical attention
immediately
Inhalation: Remove victim to fresh air. Apply artificial
respiration if necessary. Get medical attention
Skin Contact: Remove contaminated clothing and wash before
reuse. Wash skin with soap and warm water. Get
LOCTITE CORPORATION 10/20/98
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 03 of 05
Item No.: 80697
4. FIRST AID MEASURES (continued)
medical attention if irritation persists.
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Product Name: Spray-A-Gasket(R) Copper High Temp. Adh. Slnt. Page 3 of 5
Eye Contact: Flush with water for at least 15 minutes. Get
medical attention.
5. FIRE FIGHTING MEASURES
Flash Point: Not applicable
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical(B-C)
Special Firefighting
Procedures: Keep containers cool using water spray. Use proper
equipment to protect personnel from bursting
containers.
Hazardous Products formed
by Fire or Thermal Decomp CO, CO2, hydrogen chloride, phosgene, chlorine.
Unusual Fire or
Explosion Hazards: Contents under pressure. Do not expose to
temperatures exceeding 120 degrees F as containers
may vent, rupture or burst.
Explosive Limits:
(% by volume in air)Lower Not established.
(% by volume in air)Upper Not established.
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Soak up with absorbent material. Scoop or scrape
up and place in closed container.
7. HANDLING AND STORAGE
Safe Storage: Do not store at temperatures above 120 degrees F
Do not puncture containers. Keep out of the reach
of chilldren.
(Contact Loctite Customer Service 1-800-243-4874 for shelf life information)
Handling: Avoid contact with eyes and skin. Avoid breathing
vapor.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Safety glasses or goggles.
Skin: Rubber gloves.
Ventilation: Maintain adequate ventilation
Respiratory None required for normal use.
See Section 2 for Exposure Limits.
LOCTITE CORPORATION 10/20/98
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 04 of 05
Item No.: 80697
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Copper spray
Odor: Solvent
Boiling Point: Not established
pH: Not established
Solubility in Water: Nil.
Specific Gravity 0.8
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Product Name: Spray-A-Gasket(R) Copper High Temp. Adh. Slnt. Page 4 of 5
Volatile Organic Compound
(EPA Method 24) <45% by Wt.
Vapor Pressure: 49psi.
Vapor Density: Not established
Evaporation Rate
(Ether = 1) Not established
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: Strong oxidizers, strong alkalis, reactive metals.
Conditions to Avoid: None known
Hazardous Decomposition
Products (non-thermal): CO, CO2, Hydrogen chloride, phosgene, chlorine.
11. TOXICOLOGICAL INFORMATION
See Section 3.
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Dispose of in accordance with local, state, and
federal regulations. Contains Methylene Cloride,
acetone and ethyl acetate
EPA Hazardous Waste
Number F002,F003 per 40 CFR 261.31
14. TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Consumer commodity
Hazard Class or
Division: ORM-D
Identification Number: None
Marine Pollutant: None
LOCTITE CORPORATION 10/20/98
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 05 of 05
Item No.: 80697
14. TRANSPORTATION INFORMATION (continued)
IATA
Proper Shipping Name: Aerosols, flammable, n.o.s., containing substance
in Division 6.1, Packing Group III
Class or Division: Division 2.1 Subsidiary Risk 6.1
UN or ID Number: UN 1950
15. REGULATORY INFORMATION
CA Proposition 65: WARNING: This product contains a chemical known to
the State of California to cause birth
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Product Name: Spray-A-Gasket(R) Copper High Temp. Adh. Slnt. Page 5 of 5
defects or other reproductive harm.
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 2
Fire Hazard: 4
Reactivity Hazard: 0
Specific Hazard: Does not apply
Estimated HMIS(R) Code:
Health Hazard: 2
Flammability Hazard: 4
Reactivity Hazards: 0
Personal Protection: See Section 8.
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By: C.J. Michaels
Title: Health & Safety Specialist.
Company: Loctite Corp.,
1001 Trout Brook Crossing, Rocky Hill CT 06067.
(24hr.) Phone: (860) 571-5100
Revision Date: August 20, 1998 Revision: 0004
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