http://www.zep.com/MSDS/english/0542.txt
ZEP MANUFACTURING COMPANY
07/19/01
PAGE 1
ISSUE DATE: 06/16/00 ZEP WHITEWALL SPRAY
SUPERSEDES: 07/24/87 PRODUCT NUMBER: 0542
Whitewall Tire Cleaner
SECTION I - E M E R G E N C Y CONTACTS
MEDICAL EMERGENCY: TOLL FREE 1-877-541-2016 ALL CALLS RECORDED
TRANSPORTATION EMERGENCY: CHEMTREC: TOLL FREE 1-800-424-9300 ALL CALLS RECORDED
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SECTION II - H A Z A R D O U S INGREDIENTS
TLV EFFECTS % IN
DESIGNATIONS (PPM) (SEE REVERSE) PROD.
** SODIUM HYDROXIDE ** caustic soda; soda lye; CAS# N/D TOX COR <5
1310-73-2; RTECS# WB4900000; OSHA/ACGIH CEILING
LIMIT-2 MG/M3
** SODIUM METASILICATE ** silicic acid (H2-Si-O3) di- N/D COR <5
sodium salt; water glass; CAS# 6834-92-0; RTECS#
VV9275000; OSHA Dust Limit-2mg/m3 (for powders only).
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SECTION III - H E A L T H HAZARD DATA
SPECIAL NOTE: MSDS data pertains to the product as dispensed from the container.
Adverse health effects would not be expected under recommended conditions
of use (diluted) so long as prescribed safety precautions are practiced.
ACUTE EFFECTS OF OVEREXPOSURE:
Corrosive on contact. Overexposure will produce tissue destruction particularly
on mucous membranes of eyes, mouth, and respiratory tract. Eye contact may pro-
duce severe irritation and blindness unless immediately flushed. Concentrated
solutions may produce immediate skin damage. Skin contact with dilute solutions
may produce severe irritation which intensifies as contact continues. Inhalation
of mists may produce severe nasal and respiratory irritation or permanent
damage. Ingestion will produce tissue damage of the gastrointestinal tract.
CHRONIC EFFECTS OF OVEREXPOSURE:
Repeated or prolonged exposure of skin can produce chronic dermatitis character-
ized by redness, scaling, and blistering. Repeated exposure to spray mists may
lead to chronic eye inflammation, chronic respiratory tract irritation or lung
damage.
None of the ingredients are listed as carcinogens by IARC, NTP, or OSHA.
EST'D PEL/TLV: Not established PRIMARY ROUTES OF ENTRY: Ing.
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HMIS CODES: HEALTH 3; FLAM. 0; REACT. 0; PERS. PROTECT. D ; CHRONIC HAZ. NO
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ISSUE DATE: 06/16/00 ZEP WHITEWALL SPRAY
SUPERSEDES: 07/24/87 PRODUCT NUMBER: 0542
Whitewall Tire Cleaner
SECTION III - H E A L T H HAZARD D A T A (CONTINUED)
FIRST AID PROCEDURES:
SKIN : Immediately flush contaminated skin with plenty of water for at least 15
minutes. Get medical attention immediately.
EYES : Immediately flush eyes with plenty of water for at least 15 minutes, oc-
casionally lifting upper and lower lids. Get medical attention at once.
INHALE: If symptoms occur, move affected person to fresh air. If symptoms
persist, get medical attention promptly.
INGEST: If this product is swallowed, do not induce vomiting. If individual
is alert, give plenty of water to drink. Get medical attention at once.
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SECTION IV - S P E C I A L PROTECTION INFORMATION
PROTECTIVE CLOTHING : Wear a face shield, rubber or neoprene gloves, a rubber
apron, and impervious footwear.
EYE PROTECTION : Use tight-fitting, splash-proof safety goggles. Contact
lenses should not be worn when handling this material.
RESPIRATORY PROTECTION: Avoid inhalation of spray mists, and do not direct spray
toward people.
VENTILATION : Ventilation should be equivalent to outdoors. Use ex-
haust fans and open windows in enclosed spaces.
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SECTION V - P H Y S I C A L DATA
BOILING POINT (F) : 215 Approx. SPECIFIC GRAVITY : 1.07
VAPOR PRESSURE(MMHG): N/D EVAPORATION RATE(WATER =1): 1.0
VAPOR DENSITY(AIR=1): N/D PH(CONCENTRATE) : 12.5-13.5
SOLUBILITY IN WATER : COMPLETE PH(USE DILUTION OF 1% SOLUTION ): 11.5-12.5
VOC CONTENT (CONCENTRATE) 0.0% 0.00 lb/gl
APPEARANCE AND ODOR :WATER THIN, BLUE, CLEAR, ESSENTIALLY ODORLESS LIQUID
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SECTION VI - F I R E AND EXPLOSION DATA
FLASH POINT(F) (METHOD USED): None (TCC )
FLAMMABLE LIMITS LEL N/A UEL N/A
EXTINGUISHING MEDIA : Noncombustible.
SPECIAL FIRE FIGHTING: None
UNUSUAL FIRE HAZARDS : None
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SECTION VII - R E A C T I V I T Y DATA
STABILITY : Stable
INCOMPATIBILITY(AVOID) : Strong oxidizers, acids, and active metals.
POLYMERIZATION : Will not occur.
HAZARDOUS DECOMPOSITION: Carbon dioxide, carbon monoxide and toxic/corrosive
fumes as oxides of phosphorous.
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SECTION VIII - S P I L L AND DISPOSAL PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
Observe safety precautions in sections 4 & 9 during clean-up. Absorb spill on
an inert absorbent material; pick up and place in a clean D.O.T. specification
container for disposal. Wash area thoroughly with a detergent solution and then
rinse well with water.
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ISSUE DATE: 06/16/00 ZEP WHITEWALL SPRAY
SUPERSEDES: 07/24/87 PRODUCT NUMBER: 0542
Whitewall Tire Cleaner
SECTION VIII - S P I L L AND DISPOSAL P R O C E D U R E S (CONTINUED)
WASTE DISPOSAL METHOD:
Liquids cannot be sent to landfills unless solidified. Unusable product and
some collected, spent use-dilutions may require disposal as a hazardous waste at
a permitted treatment/storage/disposal facility. In most states hazardous wastes
in total amounts of 220 lbs. or less per month may be disposed of in a chemical
or industrial waste landfill. If company effluent is ultimately treated by a
publicly owned treatment works, neutralization of spent tank-solutions with sub-
sequent discharge to the sewer may be possible. Consult local, state and fed-
eral agencies for proper disposal method in your area.
RCRA HAZ. WASTE NOS.: D002
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SECTION IX - S P E C I A L PRECAUTIONS
PRECAUTIONS TO BE TAKEN WHEN HANDLING AND STORING:
Store tightly closed container in a dry area at temps. between 40-120 degrees F.
Keep product away from skin and eyes.
Do not breathe spray mists or vapors.
Clothing or shoes which become contaminated with substance should be removed
promptly and not reworn until thoroughly cleaned.
Keep out of the reach of children.
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SECTION X - R E G U L A T O R Y INFORMATION
DOT PROPER SHIP NAME: CORROSIVE LIQUID, BASIC, INORGANIC,N.O.S. (SODIUM
HYDROXIDE)
NOTE: DOT information applies to larger package sizes of affected products.
For some products, DOT may require alternate names and labeling in
accordance with packaging group requirements.
DOT HAZARD CLASS: 8 DOT PACKING GROUP: II
DOT I.D. NUMBER : UN3266 DOT LABEL/PLACARD: CORROSIVE
EPA TSCA CHEMICAL INVENTORY - ALL INGREDIENTS ARE LISTED
EPA CWA 40CFR PART 117 SUBSTANCE(RQ IN A SINGLE CONTAINER): SODIUM HYDROXIDE,
1000#
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Date Last Reviewed by Compliance Services : 06/16/00
NOTICE
Thank you for your interest in, and use of, Zep products. Zep Manufacturing Co.
is pleased to be of service to you by supplying this Material Safety Data Sheet
for your files. Zep Manufacturing is concerned for your health and safety. Zep
products can be used safely with proper protective equipment and proper handling
practices consistent with label instructions and the MSDS. Before using any Zep
product, be sure to read the complete label and the Material Safety Data Sheet.
As a further word of caution, Zep wishes to advise that serious accidents have
resulted from the misuse of "emptied" containers. "Empty" containers retain
residue (liquid and/or vapor) and can be dangerous. DO NOT pressurize, cut,
weld, braze, solder, drill, grind or expose such containers to heat, flame, or
other sources of ignition; they may explode or develop harmful vapors and pos-
sibly cause injury or death. Clean empty containers by triple rinsing with water
or an appropriate solvent. Empty containers must be sent to a drum reconditioner
before reuse.
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TERMS AND ABBREVIATIONS - LISTED ALPHABETICALLY BY SECTION
SECTION II: HAZARDOUS INGREDIENTS
CAR: Carcinogen - A chemical listed by the National Toxicology Program (NTP),
the International Agency for Research on Cancer (IARC) or OSHA as a definite or
possible human cancer causing agent.
CAS #: Chemical Abstract Services Registry Number - A univers- ally accepted
numbering system for chemical substances.
CBL: Combustible - At temperatures between 100F and 200F chemical gives off
enough vapor to ignite if a source of ignition is present as tested with a
closed cup tester.
CNS: Central Nervous System depressant which reduces the activity of the brain
and spinal cord.
COR: Corrosive - Causes irreversible injury to living tissue (e.g. burns).
DESIGNATIONS: Chemical and common names of hazardous ingredients.
EIR: Eye Irritant Only - Causes reversible reddening and/or inflammation of eye
tissues.
EXPOSURE LIMITS: The time weighted average (TWA) airborne concentration at which
most workers can be exposed without any expected adverse effects.
Primary sources include ACGIH TLVs, and OSHA PELs (TWA, STEL and ceiling limits).
ACGIH: American Conference of Governmental Industrial Hygienists.
CEILING: The concentration that should not be exceeded in the workplace
during any part of the working exposure.
OSHA: Occupational Safety and Health Administration
PEL: Permissible Exposure Limit - A set of time weighted average exposure
values, established by OSHA, for a normal 8-hour day and a 40-hour work week.
PPM: Parts per million - unit of measure for exposure limits.
(S) SKIN: Skin contact with substance can contribute to overall exposure.
STEL: Short Term Exposure Limit - Maximum concentration for a continuous
15-minute exposure period.
TLV: Threshold Limit Value - A set of time weighted average exposure limits,
established by the ACGIH, for a normal 8-hour day and a 40-hour work week.
FBL: Flammable - At temperatures under 100F, chemical gives off enough vapor to
ignite if a source of ignition is present as tested with a closed cup tester.
HAZARDOUS INGREDIENTS: Chemical substances determined to be potential health or
physical hazards based on the criteria established in the OSHA Hazard Communi-
cation Standard - 29 CFR 1910.1200
HTX: Highly toxic - the probable lethal dose for a 70kg (150 lb.) man and may be
approximated as less than 6 teaspoons (2 tablespoons).
IRR: Irritant - Causes reversible effects in living tissues
(e.g. inflammation) - primarily skin and eyes.
N/A: Not Applicable - Category is not appropriate for this product.
N/D: Not Determined - Insufficient information to make a determination for this
item.
RTECS#: Registry of Toxic Effects of Chemical Substances - an unreviewed listing
of published toxicology data on chemical substances.
SARA: Superfund Amendment and Reauthorization Act - Section
313 designates chemicals for possible reporting for the Toxics Release Inventory.
SEN: Sensitizer - Causes allergic reaction after repeated exposure.
TOX: Toxic - The probable lethal dose for a 70 kg (150 lb.) man is one ounce
(2 tablespoons) or more.
SECTION III: HEALTH HAZARD DATA
ACUTE EFFECT: An adverse effect on the human body from a single exposure with
symptoms developing almost immediately after exposure or within a relatively
short time.
CHRONIC EFFECT: Adverse effects that are most likely to occur from repeated
exposure over a long period of time.
EST D PEL/TLV: This estimated, time-weighted average, exposure limit, developed
by using a formula provided by the ACGIH, pertains to airborne concentrations
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from the product as a whole. This value should serve as guide for providing safe
workplace conditions to nearly all workers.
HMIS CODES: Hazardous Material Identification System - a rating system developed
by the National Paint and Coating Association for estimating the hazard
potential of a chemical under normal workplace conditions. These risk estimates
are indicated by a numerical rating given in each of three hazard areas
(Health/Flammability/Reactivity) ranging from a low of zero to a high of 4. The
presence of a chronic hazard is indicated with a yes. Consult HMIS training
guides for Personal Protection letter codes which indicate necessary protective
equipment.
PRIMARY ROUTE OF ENTRY: The way one or more hazardous ingredients may enter the
body and cause a generalized-systemic or specific-organ toxic effect.
ING: Ingestion - A primary route of exposure through swallowing of material
INH: Inhalation - A primary route of exposure through breathing of vapors.
SKIN: A primary route of exposure through contact with the skin.
SECTION IV: SPECIAL PROTECTION INFORMATION
Where respiratory protection is recommended, use only MSHA and NIOSH approved
respirators and dust masks.
MSHA: Mine Safety and Health Administration
NIOSH: National Institute for Occupational Safety and Health
SECTION V: PHYSICAL DATA
EVAPORATION RATE: Refers to the rate of change from the liquid state to the
vapor state at ambient temperature and pressure in comparison to a given sub-
stance (e.g. water).
pH; A value representing the acidity or alkalinity of an aqueous solution
(Acidic pH = 1; Neutral pH = 7; Alkaline pH = 14)
VOC CONTENT: The percentage or amount in pounds per gallon of the product that
is regulated as a Volatile Organic Compound under the Clean Air Act of 1990 and
various state jurisdictions.
SOLUBILITY IN WATER: A description of the ability of the product to dissolve in
water.
SECTION VII: REACTIVITY DATA
HAZARDOUS DECOMPOSITION: Breakdown products expected to be produced upon product
decomposition by extreme heat or fire.
INCOMPATIBILITY: Material contact by extreme heat and the conditions to avoid to
prevent hazardous reactions.
POLYMERIZATION: Indicates the tendency of the product's molecules to combine
with themselves in a chemical reaction, releasing excess pressure and heat.
STABILITY: Indicates the susceptibility of the product to spontaneously and
dangerously decompose.
SECTION VIII: SPILL AND DISPOSAL PROCEDURES
RCRA WASTE NOS: RCRA (Resource Conservation and Recovery Act) waste codes
(40 CFR 261) applicable to the disposal of spilled or unusable product from the
original container.
SECTION X: TRANSPORTATION DATA
CWA: Clean Water Act- Federal Law which regulates chemical releases to bodies of
water.
RQ: Reportable Quantity - The amount of the specific ingredient that, when spil-
led to the ground and can enter a storm sewer or natural watershed, must be re-
ported to the National Response Center, and other regulatory agencies.
TSCA: Toxic Substances Control Act - a federal law requiring all commercial
chemical substances to appear on an inventory maintained by the EPA.
DISCLAIMER
All statements, technical information and recommendations contained herein are
based on available scientific tests or data which we believe to be reliable. The
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accuracy and completeness of such data are not warranted or guaranteed. We can-
not anticipate all conditions under which this information and our products, or
the products of other manufacturers in combination with out products, may be
used. Zep assumes no liability or responsibility for loss or damage resulting
from the improper use or handling of our products, from incompatible product
combinations, or from the failure to follow instructions, warnings, and
advisories in the products label and Material Safety Data Sheet.
(rev. 1/98)
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